多色宽带相干反斯托克斯拉曼散射过程的理论与实验研究

宽带相干反斯托克斯拉曼散射(coherent anti-Stokes Raman scattering,CARS)光谱技术能够同时获取完整的分子CARS光谱信息,以准确识别和定量分析混合物中的不同成分或未知成分.在宽带CARS光谱技术中,由于超连续谱激光有效光谱范围内各光谱成分的作用不同,分别会产生双色和三色CARS过程.这里我们在理论上分析了宽带激发条件下两种CARS过程的产生条件,以及不同CARS光谱信号强度与各激发光功率之间的关系.在此基础上,搭建了基于SC激光的宽带CARS光谱系统,分别实现了双色和三色CARS过程.通过对获得的苯甲腈样品的CARS光谱信号进行函数拟合分析,实验验证了上述两个过程中CARS信号的强度与各激发光强度之间的函数关系.理论和实验研究结果为进一步优化宽带时间分辨CARS光谱探测和显微系统,实现同时获取物质分子完整的CARS光谱信号提供了指导.     

甲烷-空气预混V形火焰的CARS实验研究

本文将相干反斯托克斯(CARS)理论光谱计算和实验光谱分析的方法应用于预混V形火焰燃烧的温度测量实验,利用N2的Q支CARS谱线,使用单脉冲宽带方法获得了预混V形火焰的CARS信号光谱强度特性,测量了V形火焰水平方向和竖直方向上的温度分布特征,从中得出了火焰锋面的厚度,分析了火焰锋面的皱褶与摆动对CARS信号的影响。同时测量了不同燃料系数下V形火焰燃烧产物的温度,得出了温度随燃料系数的变化趋势,为进一步研究预混 V形火焰的结构提供了依据。     

像散对轴棱锥衍射特性的影响与修正

光束斜入射到轴棱锥上引起的像散将导致其衍射光场发生畸变,由衍射理论出发推导了受像散影响的轴棱锥衍射光场表达式. 通过模拟不同像散的衍射光斑图和同一像散影响下随轴向距离变化的光强分布图,分析了轴外像散对轴棱锥衍射特性的影响. 提出修正像散的方法并通过实验验证利用可调精密旋转轴棱锥修正轴外像散导致的光束畸变,理论分析和实验结果相符合,研究结果使轴棱锥的应用更加广泛. 关键词： 像散 贝塞尔光 轴棱锥 光束畸变     

KCl晶体瞬态辐射谱时间分辨多道测量研究

报道了采用多通道光纤延迟和光学多道分析技术采集KCl晶体瞬态冲击辐射时间分辨光谱的新方法。多光纤延时耦合器由5条长度不等的光纤组成,光纤长度差决定延时时差,光纤出射光由透镜耦合进入多色仪,经色散后在面阵探测器上形成与信号光纤一一对应的光谱图形,经计算机处理获得该信号光的空间一时间分辨光谱。建立了实验装置,实现了KCl晶体冲击辐射谱时间分辨多道测量,时间分辨率达到20ns,谱强度分辨率1／18bit。     

燃烧流场线CARS测温技术研究

常规CARS采用凸透镜聚焦多束激光于空间一点,在满足相位匹配条件下产生携带该点温度信息的CARS信号。常规CARS一次只能测量一个空间点的温度,难以满足燃烧流场深入研究需要。为了提高CARS测量能力,使得CARS在一次测量中获得更多信息,提出了线CARS测量方法。线CARS测量方法在常规CARS基础上采用柱面凸透镜替换普通凸透镜,使得聚焦位置由焦点变为焦线。由于焦线上的点大部分满足相位匹配关系,因此可以同时获得多点CARS信号。后续光路同样采用柱面凸透镜替换普通凸透镜,通过光谱仪和ICCD相机将CARS信号传输至计算机,解析出聚焦线上CARS信号对应的温度信息,实现CARS测量能力由“点”到“线”的提升。基于平面火焰炉的燃烧实验结果表明：线CARS可以一次有效测量200个空间点的温度信息,空间测量长度约3.6 mm,空间分辨率约18 μm,测量结果相对不确定度优于7%,在保持测量精度的同时有效丰富了单次测量信息。     

抽运光波前畸变对拍瓦激光器前端OPA光束质量的影响

数值模拟了拍瓦激光器前端非共线光参变放大(OPA)过程中存在波前畸变的抽运光对信号光光束质量的影响.结果表明,当抽运光光束波前存在严重畸变时,衍射效应和走离效应通过不同的物理机制导致了信号光光束质量的急剧下降.在导致信号光光束质量下降的过程中,走离效应在OPA未饱和放大时起着主导作用,当OPA工作在过饱和状态时,过饱和导致的信号光近场空间分布中心凹陷成为光束质量下降的主要因素.     

用BOXCARS技术诊断含铝固体燃剂燃烧场

介绍了用单脉冲BOXCARS技术测量含铝固体燃剂燃烧场的温度及氮气的浓度。分析了激光光束质量对CARS信号强度的影响,给出了在燃烧场中取得的单脉冲CARS光谱,并进行了理论拟合,得到了燃烧场的温度及组份浓度数据。在燃烧场中心高5mm处温度值约为2550K,氮气浓度平均为25.5%。测量了燃烧场中不同高度处CARS光谱,给出了燃烧场温度、氮气浓度随高度变化的曲线,对结果进行了分析。     

Z箍缩等离子体X射线凸晶谱仪

 针对波长为0.3~0.5 nm的喷气箍缩等离子体X射线诊断,研制了一种适用的高空间分辨的晶体谱仪。色散元件采用云母（002）凸面晶体,布拉格角为37°,信号采用X射线胶片进行接收,有效接收面积为30 mm×80 mm。物理实验在“阳”加速器装置上进行,胶片获得了氩喷气K,L壳层光谱信号,其光谱范围较宽,为0.31~0.40 nm。经解谱发现,类氦谱线有明显的基底,用最小二乘法拟合包络曲线去噪处理后,得到类氦谱线光谱分辨力为200~300。实验结果表明,该谱仪获得的X射线测量值与理论值相符,适合喷气箍缩等离子体X射线光谱的诊断。     

全光纤傅里叶变换光谱仪消偏振衰落技术研究

针对全光纤傅里叶变换光谱仪中光束偏振态在双折射影响下带来的干涉信号"偏振诱导衰落"现象导致测量光谱畸变的问题,根据偏振光学原理,分析了光纤应力、弯曲和扭曲导致的双折射对传输光束偏振态的影响,找到了FFTS在测量宽谱光源发射谱时出现谱线畸变的原因,提出了建立偏振态反馈控制系统来稳定干涉信号可见度的方法.实验结果表明,该方法消除了偏振态变化对测量光谱的影响.     

时空分辨平焦场光栅谱仪

 利用2 400 lp/mm或1 200 lp/mm的平焦场光栅谱仪、门控宽微带X光单分幅相机及可见光CCD记录系统建立了一套时空分辨平焦场谱仪X光谱诊断系统。介绍了该谱仪系统的结构、工作原理和实验调试方法。利用该谱仪在星光激光装置上进行了时间分辨铝等离子体发射谱线的实验测量，获得了清晰的时间分辨铝等离子体谱线。在神光Ⅱ装置上初步观测到了时空分辨铝样品吸收谱，谱分辨为0.02～0.05nm。     

Single-pulse CARS spectra in solid propellant combustion at atmosphere pressure

The unstable-resonator spatially enhanced detection (USED) coherent anti-stokes Raman spectroscopy (CARS) measurements of temperature and N2 concentration in the combustion of solid propellant at atmosphere pressure are reported. The USED CARS measurement system has a high spatial solution of ~ 0.1 mm in diameter and 3 mm in length, and permits instantaneous measurement at 10-Hz rate. The single-pulse N2 Q-branch CARS spectra have been obtained from the propellant combustion. The temperatures and N2 concentrations of the propellant flame at different height have been achieved by fitting the experimental data to theoretical spectra. The results indicate that the temperature is up to ~ 2500 K with N2 concentration in a range from 10% to 26%.     

The application of single-pulse CARS for temperature measurements in a turbulent stagnation flame

N₂ Q-branch CARS spectra have been recorded and evaluated for temperature determination in a turbulent, premixed CH₄/air stagnation flame with a burner of 40 mm diameter and 22 kW thermal load. Temperature histograms on the flame axis at different distances from the stagnation plate have been measured. Problems of practical applicability are addressed, including those arising from the limited spatial resolution of the BOXCARS geometry, from an insufficient dynamic range of the diode array detector, and from a memory effect of the detector in the case of measurements in highly turbulent flame areas with strong intermittency. Some information is given on the computerized acquisition and on the evaluation of the large amounts of data that are necessary for extensive investigations in large combustion systems.     

Theoretical modeling of single-laser-shot, chirped-probe-pulse femtosecond coherent anti-Stokes Raman scattering thermometry

Chirped-probe-pulse (CPP) femtosecond (fs) coherent anti-Stokes Raman scattering (CARS) spectroscopy for single-laser-shot temperature measurements in flames is discussed. In CPP fs CARS, a giant Raman coherence is created in the medium by impulsive pump-Stokes excitation, and the temperature-dependent temporal decay of this initial coherence is mapped into the frequency of the CARS signal using a CPP. The theory of the CPP fs CARS technique is presented. A computer code has been developed to calculate theoretical CPP fs CARS spectra. The input parameters for the calculation of the theoretical spectra include the temperature, probe time delay, ratio of the resonant and nonresonant susceptibilities, and parameters for characterizing the pump, Stokes and probe pulses. The parameters for characterizing the pump, Stokes and probe pulses are determined from the best fit of theoretical spectra to experimental spectra acquired from calibration flames at a known temperature. For spectra acquired in subsequent measurements, these laser parameters are fixed and temperature is determined as one of the fit parameters from the best fit of theoretical spectra to experimental spectra. For single-laser-shot CPP fs CARS temperature measurements performed in steady, near-adiabatic flames, the best-fit temperature distribution width is typically less than 1.5% of the mean temperature. The mean temperature is accurate to within approximately 3% with respect to the adiabatic flame temperature. The most significant limitation on temperature measurement accuracy is associated with the evaluation of the theoretical laser parameters. Significant improvements in the temperature measurement accuracy are expected once monitoring equipment capable of characterizing the spectrum and phase of each laser pulse is incorporated in the experiments.     

BOXCARS测量燃烧场的温度

 介绍了用BOXCARS技术测量CH₄/air火焰的温度。给出了甲烷气体不同流量下和火焰不同高度处的温度测量结果，分析了温度随甲烷气体流量变化和火焰高度变化的变化趋势，根据实际的实验参数计算了相应的空间分辨率。实验结果表明：利用BOXCARS技术可进行高精度、高空间分辨的温度测量。     

CARS investigation of collisional shift of the hydrogen Q‐branch transitions by water at high temperatures

A high‐resolution (∼0.1 cm⁻¹) spectroscopic method based on the application of a Fabry–Pérot interferometer to the spectral analysis of the coherent anti‐Stokes Raman scattering (CARS) signal from an individual Raman transition was used to obtain single‐shot spectra of hydrogen Q‐branch transitions directly in the flame of a pulsed, high‐pressure H₂/O₂ combustion chamber. Simultaneously with the Fabry–Pérot pattern, a broadband CARS spectrum of the complete H₂Q ‐branch structure was recorded in order to measure the temperature of the probe volume. During every cycle of the combustion chamber, a pressure pulse together with single‐shot CARS spectra, providing information on individual line shapes and medium temperature, was recorded. On the basis of the experimental data, the temperature dependences of lineshift coefficients for several Q‐branch lines of hydrogen molecules under collisions with water molecules were determined in the temperature range 2100 < T < 3500 K, and an empirical ‘fitting law’ for H₂ H₂O lineshift coefficients is proposed. Copyright © 2010 John Wiley & Sons, Ltd.     

宽带相干反斯托克斯喇曼散射法诊断固体燃剂燃烧场

 报道了采用单次脉冲非稳腔空间增强探测 相干反斯托克斯喇曼散射（USED CARS）技术诊断常压下固体燃剂瞬态燃烧场温度和氮气浓度。采用宽带USED CARS技术，在固体燃剂瞬态燃烧场获得了较高信噪比的单次激光脉冲氮气Q支CARS实验谱，用CARS理论计算软件拟合CARS实验谱，给出了固体燃剂瞬态燃烧场温度和氮气浓度在不同高度的分布，固体燃剂燃烧场温度约2 250K、氮气相对浓度16%～20%。     

1维非稳腔空间增强探测CARS技术对稳态燃烧场温度的测量

 建立了1维非稳腔空间增强探测CARS实验系统，该系统由光源（YAG激光器、染料激光器）、实验光路和信号采集系统组成。分别测量了空气和化学平衡比为1，甲烷流量为0.7 L/min的甲烷-空气预混火焰中的氮气Q支的CARS实验谱。给出了火焰不同高度处小范围内的温度分布结果，并对实验结果进行了分析，结果表明：预混火焰温度随高度的增加呈下降趋势，测量结果的不确定度优于7%。该技术可用于稳态燃烧场温度的测量。