Studies on the microstructure of phase transitions in two kinds of liquid crystals by PAT and DSC

The positron lifetime and DSC measerments for EBBA and DOBAMBC have been made with heating and cooling clycles. The experimental results show that a shorter lifetime (₁) is essentially independent of temperature while the longer lifetime (₂) and the intensity (I ₂) change abruptly double or triple with temperature. Consequently, the EBBA has only nematic phases while the DOBAMBC has two liquid-crystalline phases (smectic C* and smectic A) with transition temperatures as follows: for EBBA, solid nematic (304.5 K), nematic isotropic (356.5 K), isotropic nematic (356.5 K), nematic solid (301 K); and for DOBAMBC, solid smectic C* (346 K), smectic C* smectic A (357.5 K), smectic A isotropic (389 K). These critical temperatures are in accordance with the transition temperatures measured by DSC. In addition, the difference in the solid-nematic transition temperature in the heating and cooling cycles was also observed. A discussion about the correlation of the observed changes in lifetime (₂) with the changes in molecular orientational order (S) and dielectric anisotropy () is presented.     

Rate equations in the hopping transport

The usual kinetic equations for the site occupation probabilities in an external field are solved exactly in a simple one-dimensional periodic model with two kinds of atoms using a) free boundary conditions and order of limitsN, 0 needed for a proper treatment of the dc conductivity here b) boundary conditions with metallic contacts and order of limitsN, 0 and c) the same boundary conditions but reversed order of limiting processes 0,N typical of e.g. numerical and percolation treatments. (N and are the number of sites and frequency.) It is demonstrated that though the bulk dc conductivity is the same in all three cases, local bulk properties of the material are strongly dependent on the régime used. The role of the order of all three limiting processes 0,N+ andn+ (N–n+) for local shifts of the chemical potential _n in the dc limit is examined (n is the number of the relevant site calculated from a boundary of the chain). It is shown especially that the rate equation treatment (régime a) on the one hand and numerical or percolation treatments (régime c) on the other hand never yield the same bulk values of _r.     

A derivation of the Broadwell equation

We consider a stochastic system of particles in a two dimensional lattice and prove that, under a suitable limit (i.e.N, 0,N²const, whereN is the number of particles and is the mesh of the lattice) the one-particle distribution function converges to a solution of the two-dimensional Broadwell equation for all times for which the solution (of this equation) exists. Propagation of chaos is also proven.Research partially supported by CNR-PS-MMAIT     

The low energy scattering for slowly decreasing potentials

For the radial Schrödinger equation with a potentialq(x) decreasing at infinity asq ₀ q ^–, (0, 2), the low energy asymptotics of spectral and scattering data is found. In particular, it is shown that forq ₀>0 the spectral function vanishes exponentially as the energyk ² tends to zero. On the contrary, there is always a zero-energy resonance forq ₀<0. These results determine the local asymptotics of solutions of the time-dependent Schrödinger equation for large timest. Specifically, for positive potentials its solutions decay as exp(–₀ t ^(2–)/(2+), ₀>0,t. In the case (1, 2) it is shown that for ±q ₀>0 the phase shift tends to ± ask0 and its asymptotics is evaluated.     

Scattering states and bound states in λ℘(φ)2

By analyzing the Bethe-Salpeter equation for even ()₂ models we show that for weak coupling the mass spectrum is discrete and of finite multiplicity below 2m. Moreover on even states of energy less than 4(m–) we show that theS matrix is unitary. Herem is the physical mass and =()0 as 0. Our results rely essentially only on a simple assumption about the analyticity of the Bethe-Salpeter kernel which has been verified for weak coupling. For the interaction ⁴, (/m _o ² 1) we show that there are no even bound states of energy less than 4(m–).Work supported in part by NSF, Grant MPS 74-13252     

From monotonic to oscillatory decay of correlations: Analytical approximation for the two-dimensional,one-component plasma

An approximate evaluation of the pair distribution and the structure factor is performed analytically for the two-dimensional, one-component plasma at any value of the coupling constant. The approximate distribution remains positive and satisfies three sum rules, including the compressibility one. When 0 or 2, exact results are found. At=2 the transition from monotonie (<2) to oscillatory (>2) decay of correlations takes place. Comparison with the Monte Carlo simulations shows good agreement for 0<<4.     

A Rigorous Derivation of a Linear Kinetic Equation of Fokker–Planck Type in the Limit of Grazing Collisions

We rigorously derive a linear kinetic equation of Fokker–Planck type for a 2-D Lorentz gas in which the obstacles are randomly distributed. Each obstacle of the Lorentz gas generates a potential V( ), where V is a smooth radially symmetric function with compact support, and >0. The density of obstacles diverges as ^– , where >0. We prove that when 0< <1/8 and =2+1, the probability density of a test particle converges as 0 to a solution of our kinetic equation.     

Phase Transformations α → β → γ → δ → ε in Titanium Hydride TiH x with Increase in Hydrogen Concentration

Structural phase transformations of the hcp bcc fct fcc fct ( ) type in titanium hydrides TiH _x experimentally found to occur with increase in the hydrogen concentration x are studied theoretically. Free energy phases are statistically calculated, and their concentration dependence is determined. Phase transformation temperatures are found from intersection points of free energy curves and from points of common tangents to the curves. The energy parameters of the system are estimated. The calculation results are compared with the experimental data.     

Braided structure of fractionalZ 3-supersymmetry

It is shown that fractionalZ ₃-superspace is isomorphic to theqexp(2/3i) limit of the braided line.Z ₃-supersymmetry is identified as translational invariance along this line. The fractional translation generator and its associated covariant derivative emerge as theqexp(2/3i) limits of the left and right derivatives from the calculus on the braided line.Presented at the 5th International Colloquium on Quantum Groups: Quantum Groups and Integrable Systems, Prague, 20–22 June 1996.This paper describes research supported in part by E.P.S.R.C and P.P.A.R.C. (UK) and by the C.I.C.Y.T (Spain). J.C.P.B. wishes to acknowledge an FPI grant from the CSIC and the Spanish Ministry of Education and Science.     

Scalar mesons in ππ and K¯K scattering

The s-wave pion scattering amplitude is analysed with the aim to clarify the mass spectrum of scalar mesons and to find evidence of lightest glueball. The S-matrix and K¯K coupled channel formalism is used. The existence of scalar mesons S^* and is implied by the data. The production K¯K and the elastic K¯KK¯K coupled amplitudes are predicted from the scattering data. The couplings c f S^* to and K¯K states are determined.     

Neutron diffraction studies of the premartensitic transformation B2 → B19′ in Ti49Ni51 single crystals

We have studied structural changes in the high-temperature B2-phase in a large single crystal at temperatures near the premartensitic transformation B2 B19. We are the first to observe an extra 1/2 (110) reflection in neutron diffraction patterns taken along the [110]_B2 direction as the sample is cooled below 420 K, but still far from the martensite start temperature (M_s=180 K). This extra reflection heralds the formation of long-range order in atomic displacements with wave vectorq=(1/2±)[110]2/a. Premartensitic diffraction effects (caused by the development and correlation of lattice waves of atomic displacements with wave vectorsq ₁2/a[1/3, 1/3, 0] andq ₁2/1[1/3, 1/3] that were clearly visible in this same single crystal before the martensitic transformation B2 R, appeared at even lower temperatures with substantially lower intensities.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 56–61, January, 1995.     

Some examples ofq-regularization

An introduction to Hopf algebras as a tool for the regularization of relevant quantities in quantum field theory is given. We deform algebraic spaces by introducingq as a regulator of a noncommutative and noncocommutative Hopf algebra. Relevant quantities are finite providedq 1 and diverge in the limitq 1. We discussq-regularization on differentq-deformed spaces for ⁴ theory as examples to illustrate the idea.     

Monte Carlo study of the generalized reaction-diffusion lattice-gas model system

The reaction-diffusion lattice-gas model is an interacting particle system out of equilibrium whose microscopic dynamics is a combination of Glauber (reaction) and Kawasaki (diffusion) processes; the Glauber ratec(s; x) at sitex when the configuration iss satisfies detailed balance at temperatureT, while the Kawasaki ratec(s; x, y) between nearest-neighbor sitesx andy satisfies detailed balance at a different temperatureT. We report on the phase diagram of that system as obtained from a series of Monte Carlo simulations of steady states in two-dimensional lattices with arbitrary values forT,T, and; this generalizes previous analytical and numerical studies for and/orT. When the rates are implemented by the Metropolis algorithm, the system is observed to undergo various types of first- and second-order (nonequilibrium) phase transitions, e.g., one may identify Onsager (equilibrium) as well as Landau (mean-field) types of continuous phase transitions.Dedicated to Joel L. Lebowitz on the occasion of his 60th birthday.     

Mean field theory for Coulomb systems

We study a classical charge symmetric system with an external charge distributionq in three dimensions in the limit that the plasma parameter zero. We prove that ifq is scaled appropriately then the correlation functions converge pointwise to those of an ideal gas in the external mean field(x) where is given by-+ 2z sinh() =q This is the mean field equation of Debye and Hückel. The proof uses the sine-Gordon transformation, the Mayer expansion, and a correlation inequality.Work partially supported by NSF Grant MCS 82-02115.     

Comparison of (π− d→nn withdσ(π+ d→pp) to test charge symmetry in the Δ-region

First results on ^– d are reported. The measurements were made using 8 specially designed neutron counters, which were carefully calibratedin situ. The differential cross sections atT =142, 180, 217, and 254 MeV were obtained at four angles between 0° and 90°, they are compared to ⁺ d pp data measured at the same energies and angles with the same setup. At every beam energy, the shape of the angular distributions of ^– d nn and ⁺ d pp is the same to ±2%. The absolute cross sections differ by 1 to 10%. The error in this comparison is ±4% implying a small violation of charge symmetry.Dedicated to Prof. I. laus on the occasion of his 60th birthdayDeceased     

Multiparticle fractal aggregation

Kinetic fractal aggregation in a particle bath where a fractionf of the sites are initially occupied is studied withd=2 computer simulations. Independent particles diffusing to a fixed cluster produce an aggregate with fractal dimensionD 1.7 up to a correlation length(f). At larger lengthsD2.(f) asf 0. When the particles remain fixed but the cluster undergoes a rigid random walkD appears constant at larger scales but varies withf. D 1.95 at largef andD 1.7 asf 0. In both cases, the aggregate sizeN(t) grows with timet ^(f) . Aggregation on a surface by independently diffusing particles produces shapes reminiscent of electrochemical dendritic growth. The dependence of growth rate and geometry is studied as a function of particle concentration and sticking probability.     

Phase segregation dynamics in particle systems with long range interactions. I. Macroscopic limits

We present and discuss the derivation of a nonlinear nonlocal integrodifferential equation for the macroscopic time evolution of the conserved order parameter (r, t) of a binary alloy undergoing phase segregation. Our model is ad-dimensional lattice gas evolving via Kawasaki exchange with respect to the Gibbs measure for a Hamiltonian which includes both short-range (local) and long-range (nonlocal) interactions. The nonlocal part is given by a pair potential ^dJ(|x–y|), >0 x and y in ^d, in the limit 0. The macroscopic evolution is observed on the spatial scale ^–1 and time scale ^–2, i.e., the density (r, t) is the empirical average of the occupation numbers over a small macroscopic volume element centered atr=x. A rigorous derivation is presented in the case in which there is no local interaction. In a subsequent paper (Part II) we discuss the phase segregation phenomena in the model. In particular we argue that the phase boundary evolutions, arising as sharp interface limits of the family of equations derived in this paper, are the same as the ones obtained from the corresponding limits for the Cahn-Hilliard equation.     

P-wave charmonium decays into baryon and antibaryon pairs in quark pair creation model

A simple quark pair creation model is introduced to study exclusive decays of _{{c_J}} into baryon-antibaryon pairs. With this simple model, some exclusive decay processes, for example, _{c0} B¯ (B = ,⁰,^-) are investigated and their decay widths are evaluated by inclusion of the properties of outgoing baryons, and the results show that the strengthened decay channels _{{c_J}} ¯(J = 0, 2) are easily understood by considering only the color singlet contribution of P-wave charmonium.     

Symmetries in quantum logics

A symmetry in the quantum logic (L, M) is defined as a pair of bijections :L L andv :M M such that the probabilities are preserved. Some properties of the symmetries are investigated.