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Alexei A. Gridnev 《合成通讯》2013,43(9):1679-1689
Detailed kinetic investigation of Rothemund synthesis of porphyrins was conducted in different solvents. A one-pot synthesis of tetrakis(4-methoxyphenyl)porphin–Co(II) from pyrrole, anisic aldehyde, and cobalt acetate was developed that gave 35% isolated yield. Chlorobenzene was found to be the best solvent for the reaction. The synthesis can be done with either propionic or chloroacetic acid as catalyst with about the same yield. Cobalt prevents the synthesis of the porphyrin, so it has to be added in the reaction mixture only after the synthesis of the free porphyrin is finished. Optimum time is 2–2.5 h at a temperature of 130°C. Lower temperatures reduce the yield. Potentially, these dependencies can be applied to synthesis of other analogous porphyrins. 相似文献
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《Mendeleev Communications》2022,32(1):109-110
The reaction of 2-methoxyphenyllithium with SbCl3 affords tris(2-methoxyphenyl)antimony. Its treatment with equimolar amount of I2 results in stiborane (2-MeOC6H4)3SbI2, while heating with 2 equivalents of I2 leads to iodotris(2-methoxyphenyl)stibonium triiodide [(2-MeOC6H4)3SbI]+ [I3]– featuring halogen bonding in solid state. 相似文献
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本文设计一条新的合成路线,以价廉的异香兰素、间苯二酚为起始原料,通过Dakin反应、乙酰化、酚羟基醚化等系列反应得到目标化合物1-(2,4二异丙基氧基苯基)乙酮(5b)和新化合物1-(2,4二异丙基氧基-5-甲氧基苯基)乙酮(5a)。通过对化合物(5a)进行条件因素探索,得出合成(5a)的最佳反应条件,并通过1H NMR、MS、熔点等技术手段对其进行结构的确认与表征。 相似文献
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I. S. Nizamov L. A. Al'metkina É. S. Batyeva V. A. Al'fonsov A. N. Pudovik 《Russian Chemical Bulletin》1992,41(8):1516-1516
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center, Russian Academy of Sciences, 420083 Kazan. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 8, pp. 1932–1933, August, 1992. 相似文献