共查询到18条相似文献,搜索用时 46 毫秒
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用Z扫描方法研究了富勒烯有机铬衍生物fac- and mer- [bis (1,2-diphenylphosphino) ethane] (tricarbonyl) (η2-fullerene-C60) chromium的非线性折射特性;用速率方程理论分析了激发态光学非线性材料非线性折射行为,以及大光强下高阶激发态折射度如何引起材料自散焦-自聚焦相互转化.计算出了转变光强.并数值模拟了不同光强下Z扫描实验曲线的变化过程.理论计算与实验符合得较好.关键词:自散焦自聚焦富勒烯衍生物Z扫描 相似文献
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We investigate theoretically and experimentally one-dimensional bright photovoltaic solitons in LiNbO3:Fe crystal by use of the background illumination. We find that, in LiNbO3:Fe crystal, bright photovoltaic solitons can be obtained with background illumination for κ>1, where κ is the ratio of the background illumination photovoltaic constant to the soliton optical beam's photovoltaic constant. For κ<1, dark photovoltaic solitons are generated. On the other hand, our experiments show good agreement with theoretical prediction for the soliton existence curve in a special intensity ratio. 相似文献
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O.M. Ntwaeaborwa Renjia Zhou Lei Qian Shreyas S. Pitale J. Xue H.C. Swart P.H. Holloway 《Physica B: Condensed Matter》2012,407(10):1631-1633
In this study, P3HT:PCBM organic photovoltaic (OPV) devices, with or without ZnO nanoparticles buffer layer between the photoactive layer (P3HT:PCBM) and the cathode (Al top electrode), were fabricated. The devices were annealed at 145 °C either before or after depositing the top electrode. The objective of this study was to investigate the effects of the ZnO buffer layer and pre-/post-fabrication annealing on the general performance of these devices. The short-circuit current density (JSC), open-circuit voltage (VOC) and the external quantum efficiency (EQE) of the OPV devices were improved by the insertion of the ZnO layer and post-fabrication annealing. The post-fabrication annealed devices, with or without the ZnO layer, exhibited higher values of JSC, VOC and EQE than those of similar devices annealed before depositing the Al metal. This can be attributed to, among other things, improved charge transport across the interface between the photoactive layer and the Al top electrode as a result of post-annealing induced modification of the interface morphology. 相似文献
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对大分子有机化合物钴卟啉的非线性光学特性在 4 5 7 9,4 88和 5 14 5nm三个连续激光波长下进行了研究。用单光束z scan技术测到三个曲线均是先出现峰值后出现谷值 ,按照Sheik bahae等人的理论该样品的非线性折射率为负值 ,即样品具有热自散焦效应。反饱和吸收特性的研究结果得到三个透射率T随入射激光功率的增大而减小的曲线 ,表明该样品在这三个波长下均呈现出反饱和吸收效应。众所周知 ,热自散焦效应和反饱和吸收效应都能导致光限幅。文章的实验结果也表明 :钴卟啉在三个波长下均具有光限幅特性 ,限幅阈值随着波长的减小而减小 ;其光学限幅效果好且限幅阈值低 ,是一种有较大潜在应用价值的新型光限幅材料。因此 ,可以利用这两种效应对钴卟啉的共同作用 ,制成新型光限幅器件 相似文献
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卟啉和金属卟啉不仅是良好的电子给予体,而且在紫外可见光区有着非常广泛的吸收,这有利于太阳能的利用.富勒烯(C60)由于自身独特的结构而成为较好的电子受体.近年来,大量共价键连卟啉-富勒烯D-A化合物被合成与研究[1-4].通过柔性连接体形成的卟啉-富勒烯化合物有利于增加给-受体间电子的流动性,使化合物具有优良的光电转换性能[2].中间体和产物的合成见图1.1和2的合成、纯化参照文献[2].3的合成:在N2下把37.2mg对羟基苯甲醛、75.2mg2、过量灼烧的无水碳酸钾加入30mL DMF中,80°C反应8h后,甲苯和蒸馏水分液,粗产品用硅胶柱层析,甲苯淋洗,… 相似文献
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Using a direct variational technique involving elliptic Gaussian laser beam trial function, the combined effect of nonlinearity and diffraction on wave propagation of optical beam in a homogeneous higher order nonlinear medium is presented. Particular emphasis is put to understand the variation of beam width and longitudinal phase delay with the distance of propagation in case of lossless and lossy medium. It is also observed that stationary self-trapping is possible in lossless medium at higher laser intensity where fifth order nonlinearity becomes comparable to third order nonlinearity. The phase is also seen to be always negative. 相似文献
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用自散焦介质观测Ce:BaTiO3晶体的自泵浦相位共轭频移 总被引:1,自引:1,他引:1
提出利用自散焦介质作为载体测量光折变晶体自泵浦相位共轭的微小频移的新方法,适宜用于区分二波耦合,四波辊频对频移的贡献,为研究光折变自泵浦相位共轭频移的产生机制提供了一种新的可能的途径。 相似文献