The crystal structure of copper dipyridine dibromide Cu(C5H5N)2Br2

The X-ray structural analysis of copper dipyridine dibromide was carried out. The substance is monoclinic, its space group isP2₁/n, having the lattice constantsa=8.30 kXU,b=17.72 kXU,c=4.04 kXU,=96°,Z=2. The localization of the heavy atoms was carried out by means of the projections of the Patterson functionsP(u, v) andP(v, w), which provided the bases for determining the signs of the majority of structure factors. The projections of the electron density(x, y) and(y, z) were calculated on the basis of these data. The positions of the atoms were refined three times by methods of differential syntheses and by geometrical analysis. The structure of CuPy₂Br₂ is very close to that of CuPy₂Cl₂ [1], [2], differing from it primarily in the orientation of the symmetry elements with respect to the crystallographic axes. In both structures the copper atom is octahedrally coordinated with four halogen and two nitrogen atoms. The nitrogen atoms and two bromine atoms are bound to the copper covalently in the structure of the bromine derivative, as follows from the length of the bonds (Cu-N 1.99 kXU, Cu-Br, 2.46 kXU), while the remaining two bromine atoms are bound to the copper by weaker bonds and mediate the chain formation of molecules in the direction of thec axis.

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Cu(C₅H₅N)₂Br₂

. , 2₁/ ==8,30 kX,b=17,72 kX,=4,04 kX,=96°,z=2. (, v) P(v, w), . (, ) (, z). . CuPy₂Br₂ u₂1₂, . . , (-N 1,99 kX, u-r 2,46 kX), .

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The authors thank M. Serátor for supplying the crystal samples and for initiating the work, the management of the Institute of Technical Physics, Czechoslovak Academy of Sciences, in Prague and especially Dr. A. Línek for making it possible to calculate some of the Fourier maps on the special computer Elika and finally A. lechtová for carefully calculating the Fourier maps and structure factors.

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The first stage of this work was reported on at the 3rd State Conference on Inorganic Chemistry, held in Bratislava from June 29th to July 4th, 1959.     

Dynamic scaling for spin glasses near the de Almeida-Thouless line

We calculate the dynamic local susceptibility () of an Ising spin glass near the de Almeida-Thouless (AT) line within the soft spin dynamics for the Sherrington-Kirkpatrick model. We find a crossover from analytic behaviour of () at =0 above the AT line to a power law behaviour ()(–i) ^v on the AT line and discuss the analytic properties of the crossover function. The frequencyscale is proportional to ^1/v , where measures the distance from the AT line. We determine the spectrum of relaxation times which diverge as ^1–1/v . The average relaxation time diverges as ^–1/v wherev1/2. In addition we determine the absolute frequency scale and prove the consistency of the ansatz of Sompolinsky and Zippelius ()–(0)(–i) ^v at and below the AT line.     

Equilibrium state of toroidal electron beam

The paper deals with the collective behaviour of electrons which rotate in a magnetic field used in a betatron. It is shown experimentally that there exists strong interaction between the electrons, which leads to the rapid formation of the equilibrium state with characteristic distribution of the charge density in the cross-section of the toroidal beam. The corresponding relaxation time is of the order of 1 sec. A statistical theory of the equilibrium beam is elaborated. Its main result is that the effective radius of the beam is a function of two parameters, one of which is proportional to the thermal energy of the electrons and the other to the perveance of the beam. The charge contained in a toroidal beam of given effective cross-section is equal to the product of the charge the beam would contain at zero temperature and a coefficient, which is a function of the temperature of the beam. Its value is unity at zero temperature and rapidly decreases with increasing temperature. The cause of cooling of the beam is shown.

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, . , , . 1S. . , , — I/(E₀/q)^3/2 (I — , ₀ — q ). , , , , , . . .

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Now Institute of Vacuum Electronics, Czechosl. Acad. Sci., Prague.

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In conclusion the author thanks J. Luká and L. Hyttych for invaluable help in the experiments, A. Rajský for constructing the electronic apparatus and J. Sokol for preparing the miniature probe.     

К ВОПРОСУ O КРИТИЧЕСКО Й ЧАСТОТЕ ПРИ ПРЕРЫВИСТОМ ОСВЕ ЩЕНИИ

c , c n , n AgBr. .     

On the problem of the phase shifts of reflected light

. , . , . .

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On the problem of the phase shifts of reflected light

The paper solves the topical question of phase shifts when light is reflected. By introducing the reflection tensor and its transformation it was found that all phase shifts hitherto given in the literature can be used. It was proved that when different phase shifts are used the corresponding unit vectors must be oriented. If an arbitrary coordinate system and the relations pertaining to it are used consistently it is not possible by calculation or experiment to arrive at contradictory results.

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. , , . .: , 1961. . 45–49 . . , .. . , .     

Der Einfluss der Plastischen Verformung durch Kaltwalzen auf die Koerzitivkraft

Zusammenfassung Es werden die Ergebnisse der Messungen der Koerzitivkraft von Eisen, Nickel und einiger Fe-Ni-Legierungen in Abhängigkeit von der plastischen Verformung durch Kaltwalzen angegeben. Gemessen wurde in Richtung parallel und senkrecht zur Walzrichtung. Die Ergebnisse werden insbesondere vom Gesichtspunkt des Einflusses der Versetzungen und der einachsigen induzierten Anisotropie diskutiert.

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, - , . . .

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Für die wertvollen Diskussionen und das Durchlesen der Arbeit danken wir den Kollegen J. Kaczér und V. Janovec, für die wirkungsvolle Hilfe bei den Messungen Koll. J. Grolmus.     

New derivation of Bardeen-Shockley formula for mobility of electrons in homopolar semi-conductors

The Bardeen-Shockley formula for the mobility of an electron or hole in a homopolar semi-conductor is derived in a different way to that in which its authors obtained it. The interaction energy of the electron with the acoustic lattice oscillations is derived in an original way. A new possibility for determining the energy gap is given.

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- , , , . . .

     

Infrared detection of crystalline forms of polyvinylidene fluoride

Two crystalline forms ( and) are demonstrated; the form goes over to the form above 200°C. The IR intensities of both forms are examined as functions of temperature; the crystalline and amorphous bands are identified, together with the melting points of both crystalline forms. The degree of crystallinity of the and forms can be deduced from the amorphous bands.I am indebted to V. N. Nikitin and N. A. Borisevich for their interest in this work.     

On the problem of the permittivity dispersion of barium titanate

The complex permittivity of multidomain single crystals of BaTiO₃ was measured in the decimetre and centimetre wave bands and it was proved that in this frequency region there is dispersion of the permittivity. Apparatus for measuring the permittivity of substances with a high is described and the influence of the inhomogeneity of the field in the sample on the characteristics of the cavity resonator is calculated. Present theories of the high-frequency properties of BaTiO₃ are discussed from the point of view of the experimental results.

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BaTiO₃ , . . BaTiO₃.

     

On the existence of invariant,absolutely continuous measures

Let (, , ) be a measure space with normalized measure,f: a nonsingular transformation. We prove: there exists anf-invariant normalized measure which is absolutely continuous with respect to if and only if there exist >0, and , 0<<1, such that (E)< implies (f ^–k(E))< for allk0.     

On the energy balance in the optics of metals

On the basis of the boundary conditions of the electromagnetic theory an explicit calculation of the absorption in a thin metallic film was carried out with the result that transport and interference components were found to exist. By applying the method to a simple metal-dielectric boundary the physical interpretation was given of the energy balance, which had hitherto been regarded as unclear. It was also explained why the reversibility principle fails when applied to a metal-dielectric boundary.

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, . - , . , - .

     

The basic equations of the dynamics of the continuous distribution of dislocations III. special problems

The basic equations of the dynamics of the continuous distribution of dislocations analogical to Maxwell equations are derived in a series of papers [I, II, III]. The analogy of the elastic and electromagnetic fields is analyzed. In part [III] some special problems are discussed, such as the density of the forces acting on the dislocations, the energy dissipation during the movement of dislocations, which is expressed by an equation analogical to Ohm's law. The equations derived in the previous parts in four-dimensional symbolics are considered in the three-dimensional differential and integral form. It is found that in special cases the relations become the known ones of elastodynamics, hydrodynamics and the static theory of the continuous distribution of dislocations. It is found that Kröner's method of integrating the equations of the dislocation field by means of so-called incompatibility tensors is analogical to the integration of the Maxwell equations by means of Hertz vectors. The analogy between the elastic dislocation field and the electromagnetic field is discussed in detail.

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III.

, . . : , , , , . , , . , , . , . .

     

Wavelength distribution of X-rays in the focus of a monochromator and an estimate of the influence of this distribution on precision measurements of lattice constants

Wavelength distribution in the focus of a Johansson type monochromator is computed assuming the tube focus emissivityG(), reflection curveR() and wavelength distribution of the incident radiationJ(-₀) are known. It is shown e.g. that the centre of gravity may be shifted in accordance with the position of the crystal on the focal circle which may considerably influence precision measurements of lattice parameters.

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, G(,) R() J(-₀) . , , , .

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The author is grateful to Z. Hemanová for carrying out all the computations very carefully.     

On the mechanism of rendering visible dislocations on the surface of iron crystals by anodic dissolving

The paper contains further results of studying dislocations rendered visible by anodic dissolving on the surface of single crystals of alpha-iron. The influence of the crystallographic orientation of the surface is investigated, the effect of carbon is confirmed and the anodic process is studied. The mechanism of dissolving of the crystal is given and a new more suitable method of rendering dislocations visible is derived.

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, . , . , .

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The author thanks F. Kroupa and J. Hejduk for critical remarks and discussion.     

Positive resonances and the limiting amplitude principle

We define the positive resonance points of self-adjoint operators without using the analytical continuation of corresponding resolvents and show that the limiting amplitude principle for the abstract wave equation does not take place in general, if ² = , where is the disturbing frequency and is the resonance point. The asymptotics of corresponding solutions as t are obtained, which imply the growth of the oscillation amplitude as t , 0<<1, or as ln t, t .     

Choice of parameters of an X-ray monochromating unit

In recent papers a way of computing the monochromated wavelength distribution in some current experimental arrangements was presented. In this paper an application is shown for the Johansson monochromating unit. The conditions are indicated for attaining the desired breadth of the monochromated interval and for its maximum intensity. The analysis implies that it is not advantageous to use very narrow foci and that the crystals should be neither very perfect nor very imperfect. The optimum conditions must be found in each case separately.

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. Johansson. , , . , , , . .

     

Anti-parallel ferroelectric domains in surface space-charge layers of BaTiO3

It is shown on simplified models of a surface space-charge layer of a single crystal of BaTiO ₃ that in the surface region, in which the direction of the electric field is opposite to the direction of spontaneous polarization inside the crystal, anti-parallel domains can exist. The dimensions of these domains are determined. The use of the results obtained is proposed for interpreting the microrelief of the etch figures and for explaining the different phases of the polarization reversal process of a single-domain single crystal of BaTiO ₃.

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BatiO₃

BaTiO₃ , , , . . BaTiO₃.

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The author would like to thank J. Kaczer, Z. Málek and V. Dvoák of the Institute of Physics, Czechoslovak Academy of Sciences, for valuable remarks on this paper and H. Havlíková for carefully carrying out the numerical calculations.     

Zur Temperaturabhängigkeit einiger Kenngrössen der Verfestigungskurven von Zinkeinkristallen

Zusammenfassung Es werden Ergebnisse beschrieben über die Temperaturabhängigkeit: der kritischen Schubspannung ₀, des Verfestigungskoeffizienten _A , im BereichA der Verfestigungskurve; des Verfestigungskoeffizienten _B im BereichB, der Längea _A des BereichsA und der Schubspannung _A am Ende des BereichsA. Die kritische Schubspannung wächst im Temperaturbereich 225–344°K linear mit abnehmender Temperatur. Der Temperaturverlauf des Verfestigungskoeffizienten _A , stimmt überein mit älteren Messungen an h.k.p. Metallen. Ähnlich verhält sich der Verfestigungskoeffizient _B . Die Schubspannung am Ende des BereichsA wird durch thermisch aktivierte Vorgänge beeinflußt. Der BereichA verkürzt sich im Temperaturbereich 0–85°C linear mit zunehmender Temperatur. Temperaturwechselversuche zeigen, daß im BereichB thermisch irreversible Änderungen in der Versetzungsstruktur auftreten.

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: ₀, _A , _B , _{A A} . 226 344°K . _A . _B . . 0–85°C . , .

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Herrn Dr. F. Kroupa und Ing. B. esták bin ich für das Durchlesen des Manuskripts sowie wertvolle Hinweise zu Dank verpflichtet. Mein besonderer Dank für zahlreiche fruchtbare Diskusionen und Anregungen gilt Herrn P. Kratochvíl. Herrn Prof. Dr. A. Seeger danke ich ganz besonders für Kritik des Manuskripts und wertvolle Ratschläge.     

УСТАНОВИВШЕЕСЯ ТЕМП ЕРАТУРНОЕ ПОЛЕ В БЕСКОНЕЧНОЙ ПЛОСКО Й ПЛАСТИНКЕ ИЗ ДВУХ СЛОЕВ С ОБЫЧНЫМ РАСПР ЕДЕЛЕНИЕМ ТЕМПЕРАТУ РЫ НА ГРАНИЧНЫХ СТЕНАХ

, , , , .     

The distribution of ions and their valencies in manganese ferrites I. MnFe2O4+γ ferrites

A model for the distribution of cations in the spinel lattice of manganese ferrites MnFe₂O₄₊ was elaborated on the basis of the experimental studies of the basic magnetic quantities, electrical conductivity and magnetic relaxation of the given ferrites, taking into consideration their crystallographic properties. The conclusions following from this model are in good agreement with the experimental results obtained by us and by other authors both for stoichiometric manganese ferrite and for a ferrite where 0.

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I. MnFe₂O₄₊

, MnFe₂O₄₊ . , , , , , 0.