On the dispersion of a solute in oscillating flow through a channel

The paper presents an exact analysis of the dispersion of a solute in an incompressible viscous fluid flowing slowly in a parallel plate channel under the influence of a periodic pressure gradient. Using a generalised dispersion model which is valid for all times after the solute injection, the diffusion coefficientsK _i (τ)(i=1,2,3,…) are determined as functions of timeτ when the initial distribution of the solute is in the form of a slug of finite extent. The second coefficientK ₂(τ) gives a measure of the longitudinal dispersion of the solute due to the combined influence of molecular diffusion and nonuniform velocity across the channel cross-section. The analysis leads to the novel result thatK ₂(τ) consists of a steady partS and a fluctuating partD ₂(τ) due to the pulsatility of the flow. It is shown thatS increases with increase inλ (the amplitude of pressure pulsation) for small values ofω (the frequency of the pulsation). But for largeω, S decreases with increase inλ. It is also found that for fixedλ, there is very little fluctuation inD ₂(τ) forω=1, butD ₂(τ) shows fluctuation with large amplitude whenω slightly exceeds unity. The amplitude ofD ₂(τ) then decreases with further increase inω. Thus the variation of bothS andD ₂(τ) withω is non-monotonic. Finally,? _m , the average concentration of the solute over the channel cross-section is determined for various values ofλ andω.     

A minimization problem related to the estimation of a lower bound for the temperature in a free boundary value problem related to the combustion of a solid

This paper investigates the least time τ_* of the first zero of the bounded solution to an initial boundary value problem for the heat equation. The heat equation is considered in the domain $$\left\{ {(x,t)| - \infty< x< s(t),0< t \leqslant T} \right\}$$ . The initial conditionu(x, 0)=φ(x) and the boundary conditionu _x (s(t),t)=?R are specified. Let τ=τ(φ,R, s) denote the first zero ofu onx=s(t), that is,u(s(τ), τ)=0. Let τ_*=min τ, where the minimum is taken over a class of functionss=s(t). The existence of τ_* is demonstrated, and a generalization of the problem is discussed.     

Creep in macromolecular solutions according to rigid dumbbell kinetic theory

The creep experiment is analyzed using the rigid-dumbbell suspension model. It is found that the equilibrium shear compliance J _e is given by $$J_e = \frac{{\theta _0 }}{{2\eta _0^2 }} + O(\kappa _\infty ^2 )$$ where η₀ and θ₀ are the viscosity and primary normal stress functions at zero-shear rate, and κ _∞ is the velocity gradient for large time. It is found that, to the lowest level of approximation, τ _yy ?τ _zz and τ _xx ?τ _yy have the same sign during the creep experiment.     

Delay in response of turbulent heat transfer against acceleration or deceleration of flow in a pipe

To predict the heat transfer enhancements that result from the application of a pulsating flow in a pipe, we experimentally investigated the turbulent heat transfer variations produced in response to sudden accelerations or decelerations to flows within a pipe. To accomplish this, the Reynolds numbers with the valve open (Re₁) and close (Re₀) were systematically varied in the range of 8,000 ≤ Re₁ ≤ 34,000 and 700 ≤ Re₀ ≤ 23,000, respectively, and in-pipe spatiotemporal heat transfer variations were measured using infrared thermography simultaneously with temporal variations to the in-pipe flow properties. Based on the experimental results, it was found that the heat transfer delays that occur in response to accelerations or decelerations can be characterized using the corresponding time lag Δt and first-order time constant τ. The values of Δt and τ can be expressed as non-dimensional forms of Δt/(ν/u_τ²) and τ/(R/u_τ), respectively, where u_τ is the pipe wall friction velocity, ν is the kinematic viscosity of the fluid, and R is the pipe radius.     

Trigonometric simplification of a class of conservative nonlinear oscillators

This paper deals with a class of conservative nonlinear oscillators of the form $\ddot x(t)+f(x(t))=0$ , where f(x) is analytic. A transformation of time from t to a new time coordinate τ is defined such that periodic solutions can be expressed in the form x(τ) = A ₀+A ₁ cos 2τ. We refer to this process of trigonometric simplification as trigonometrification. Application is given to the stability of nonlinear normal modes (NNMs) in two-degree-of-freedom systems.     

Steady and transient shear flows of polystyrene solutions I: Concentration and molecular weight dependence of non-dimensional viscometric functions

Start up from rest and relaxation from steady shear flow experiments have been performed on monodisperse polystyrene solutions with molecular weight ranging from 1.3 × 10⁵ to 1.6 × 10⁶ and concentration c ranging from 5% to 40%. A method of reduced variables based on the use of a characteristic time τ_w is proposed. τ_w is defined as the product of zero shear viscosity with the steady state elastic compliance.Reduced steady and transient viscometric functions so obtained depend on the ratio M/M_e (where M_e is the entanglement molecular weight). Limiting forms are obtained when M/M_e ? 18. In steady flow, a simple correlation is found between shear and normal stresses.In stress relaxation experiments, independent of shear rate, the long-time behaviour can be characterised by a single relaxation time τ₁, which is identical for shear and normal stresses. τ₁ can be simply related to the zero shear rate viscosity and the limiting elastic compliance.     

Effects of the Reynolds number on a scale-similarity model of Lagrangian velocity correlations in isotropic turbulent flows

A scale-similarity model of a two-point two-time Lagrangian velocity correlation(LVC) was originally developed for the relative dispersion of tracer particles in isotropic turbulent flows(HE, G. W., JIN, G. D., and ZHAO, X. Scale-similarity model for Lagrangian velocity correlations in isotropic and stationary turbulence. Physical Review E, 80, 066313(2009)). The model can be expressed as a two-point Eulerian space correlation and the dispersion velocity V. The dispersion velocity denotes the rate at which one moving particle departs from another fixed particle. This paper numerically validates the robustness of the scale-similarity model at high Taylor micro-scale Reynolds numbers up to 373, which are much higher than the original values(R_λ = 66, 102). The effect of the Reynolds number on the dispersion velocity in the scale-similarity model is carefully investigated. The results show that the scale-similarity model is more accurate at higher Reynolds numbers because the two-point Lagrangian velocity correlations with different initial spatial separations collapse into a universal form compared with a combination of the initial separation and the temporal separation via the dispersion velocity.Moreover, the dispersion velocity V normalized by the Kolmogorov velocity V_η≡η/τ_η in which η and τ_η are the Kolmogorov space and time scales, respectively, scales with the Reynolds number R_λ as V/V_η∝ R_λ~(1.39) obtained from the numerical data.     

State of stress at the vertex of a quarter-infinite crack in a half-space

Spherical coordinates are r, θ, φ. The half-space extends in θ < π/2. The crack occurs along φ = 0. The region to be investigated is the solid space-triangle (or cone) between the three planes θ = π/2, φ = +0 and φ = 2π ? 0, which planes are to be taken stress-free.In this space-angle a state of stress is considered in terms of the cartesian stress components σ_xx = r^λ?_xx(λ, θ, φ); σ_xy = r^λ(λ, θ, φ); etc. Possible values λ are determined from a characteristic (or eigenvalue) equation, expressing the condition that a determinant of infinite order is equal to zero. The root of λ which gives the most serious state of stress in the vertex region (the region r → 0) is the root closest to the limiting value Re λ > ?3/2. Knowledge of this state of stress, or at least of this value of λ is essential in the determination of the three-dimensional state of stress around a crack in a plate for distances of order of the plate thickenss.Along the front of the quarter-infinite crack (z-axis) the so called stress-intensity factor behaves like z^λ+½ (z → 0) and thus tends to zero, respectively to infinity, accordingly to Re λ being >?½ or <?½. But in the region z → 0 the notion stress-intensity factor loses its meaning. The required state of stress passes into the well-known state of plane strain around a crack tip if Poisson's ratio (v) tends to zero. The computed state of stress for the incompressible medium (v = ½) is confirmed by experiment.     

Correlation of turbulent flow rate-pressure drop data for non-newtonian solutions and slurries in pipes

Isothermal and non-isothermal flow rate-pressure drop data in turbulent flow through smooth pipes have been obtained for non-Newtonian fluids, including aqueous solutions of polymers and aqueous suspensions of titanium dioxide. It has been found that the friction factor, f, is a function of a new form of Reynolds number, Re_B, based on the parameters A, x and w of Bowen's correlation, viz.

$\text{τ}{}_{\mathrm{w}}\text{D}{}^{\mathrm{x}}\text{=A}\text{u}{}^{\mathrm{w}}$

where τ_w is the wall shear strees, ?u the mean velocity, D the pipe diameter; A, x and w are experimentally derived parameters which characterise the fluid.     

Kinetic modeling of particles in stratified flow – Evaluation of dispersion tensors in inhomogeneous turbulence

The continuum equations for a dilute particle distribution in inhomogeneous turbulence are tested against results from a Langevin particle tracking simulation. Reeks’ version of the kinetic theory is used to generate the mass, momentum and kinetic stress equations for the particle distribution. The particle tracking data are used to directly evaluate the dispersion tensors λ and μ which serve as closure relations for the continuum equations. These exact forms are compared to approximate, local forms. Even for low Stokes numbers (corresponding to low particle inertia defined by τ/τ_p ? 1), the tensor λ is strongly affected by the inhomogeneity and depends on turbulence parameters in the volume corresponding to the particle path dispersion over the particle Lagrangian integral timescale τ. In contrast, the locally homogeneous form of the velocity dispersion tensor μ is a sufficient approximation, since it depends on the dispersion volume over the much smaller particle relaxation time τ_p. It is demonstrated that the body force due to the dispersion vector γ cannot be neglected. In the limit of passive tracers (zero stopping distance), γ is equal to the gradient of λ, if the physical setting is such that we can invoke constant tracer density in this limit.     

Extensional rheology of concentrated emulsions as probed by capillary breakup elongational rheometry (CaBER)

Elongational flow behavior of w/o emulsions has been investigated using a capillary breakup elongational rheometer (CaBER) equipped with an advanced image processing system allowing for precise assessment of the full filament shape. The transient neck diameter D(t), time evolution of the neck curvature κ(t), the region of deformation l _def and the filament lifetime t _c are extracted in order to characterize non-uniform filament thinning. Effects of disperse volume fraction ?, droplet size d _sv , and continuous phase viscosity η _c on the flow properties have been investigated. At a critical volume fraction ? _c , strong shear thinning, and an apparent shear yield stress τ _y,s occur and shear flow curves are well described by a Herschel–Bulkley model. In CaBER filaments exhibit sharp necking and t _c as well as κ _max ?=?κ (t?=?t _c ) increase, whereas l _def decreases drastically with increasing ?. For ? <?? _c , D(t) data can be described by a power-law model based on a cylindrical filament approximation using the exponent n and consistency index k from shear experiments. For ??≥?? _c , D(t) data are fitted using a one-dimensional Herschel–Bulkley approach, but k and τ _y,s progressively deviate from shear results as ? increases. We attribute this to the failure of the cylindrical filament assumption. Filament lifetime is proportional to η _c at all ?. Above ? _c, κ _max as well as t _c /η _c scale linearly with τ _y,s . The Laplace pressure at the critical stretch ratio ε _c which is needed to induce capillary thinning can be identified as the elongational yield stress τ _y,e , if the experimental parameters are chosen such that the axial curvature of the filament profile can be neglected. This is a unique and robust method to determine this quantity for soft matter with τ _y ?< 1,000 Pa. For the emulsion series investigated here a ratio τ _y,e /τ _y,s = 2.8 ± 0.4 is found independent of ?. This result is captured by a generalized Herschel–Bulkley model including the third invariant of the strain-rate tensor proposed here for the first time, which implies that τ _y,e and τ _y,s are independent material parameters.     

Rheology of suspensions of spherical particles in a newtonian and a non-newtonian fluid

Properties of suspensions of spherical glass beads (25–38 μm dia.) in a Newtonian fluid and a non-Newtonian (NBS Fluid 40) fluid were measured at volume fractions, φ, of 0%, 10%, 20% and 30%. Measurements were made using a modified and computerized Weissenberg Rheogoniometer. Properties measured included steady shear viscosity, η($\text{γ}\text{.}$), first normal stress difference, N₁($\text{γ}\text{.}$), linear viscoelastic properties, η′(ω) and G′(ω), shear stress relaxation, σ^? ($\text{γ}\text{.}$, t), and growth, σ⁺($\text{γ}\text{.}$, t) and normal stress relaxation, N₁^?($\text{γ}\text{.}$, t).For a the Newtonian fluid, increasing φ causes both η and η′ to increase, with η′ showing a slight frequency dependence. Both N₁ and G′ are zero and stress relaxation and growth occur essentially instantaneously. For the NBS fluid, both η and η′ increse with φ at all $\text{γ}\text{.}$ and ω, respectively, the increase being greater as $\text{γ}\text{.}$ and ω approach zero. N₁ and G′ are less affected by the presence of the particles than η and η′ with the effect on G′ being more pronounced than on N₁. For fixed $\text{γ}\text{.}$, stress relaxation and growth exhibit greater non-linear effects as φ is increased. A model for predicting a priori the linear viscoelastic properties for suspensions was found to yeild reasonable estimates up to φ = 20%.     

Approximate representations and pointwise bounds for solutions of a class of non-linear boundary value problems

This article establishes an approximation in the implicit form (within the limits of error) of solutions of [L + M(ε)]x = ρ(t, x) satisfying the limiting conditions x^(2k)(0) = x^(2k+1)(τ) = 0, k = 0,1,…, n?1, L being a linear differential operator of degree equal to 2n with constant coefficients and M(ε) a differential operator of an inferior order enabling the absorption terms and the coefficients to vary slowly. f(t,x) is continuous in the sense of Lipschitz, not negative, monotonous, increasing in x and of the saturation type.     

Investigation of failure during elongational flow of polymer melts

A basic study of the mechanisms of necking and ductile failure of polymer melts in uniaxial elongational flow has been carried out. A linear stability analysis was carried out using a White—Metzner convected Maxwell model with a deformation-rate-dependent relaxation time, which varies according to τ = τ_o/(1 + aτ_o[2trd²]^{$\text{1}\text{2}$}). It was shown that filament stability and elongation to break depend upon τ_oE, where E is the elongation rate, and a. At fixed τ_oE, filament stability decreases with increasing a. At small a, stability increases with increasing τ_oE while for a > $\text{1}\text{√3}$, stability decreases with increasing τ_oE. For a material with small a, ductile failure can occur for small τ_oE, but cohesive fracture should be the cause of failure at larger τ_oE. For a material with large a, however, ductile failure always dominates the failure mode. These results are used to interpret failure in elongational flow of low density and high density polyethylene and polypropylene melts and describe how the latter two melts exhibit ductile failure.     

On the shearing zone around rotating vanes in plastic liquids: theory and experiment

The fracture zone (or shearing surface) around a four-bladed vane rotating in a Bingham liquid has a diameterD_c which is significantly larger than the vane diameter. In typical plastic liquidsD_c/D ≈ 1.00–1.05. We have measuredD_c and the rheology of some automotive greases. We have also photographed the fractural surface in a transparent Bingham liquid and have found it to be approximately cylindrical.Computer simulations of a four-bladed vane rotating in a Bingham liquid have produced a value ofD_c/D = 1.025 which agrees well with experimental data on two viscoelastic automotive greases. We have not been able to obtain agreement between experiment and theory on the dependence ofD_c/D on τ_y/η_p.The experimental and theoretical data presented here support the use of the vane for yield stress measurements if the diameter correction is applied. The present experimental data suggests the vane diameter has little or no effect onD_c/D.     

Recoil in macromolecular solutions according to rigid dumbbell kinetic theory

A macromolecular solution is represented by the simple model of rigid dumbbells suspended in a Newtonian fluid with Brownian motion included. Hydrodynamic interaction is not taken into account. It is found that for this model there will be recoil after the cessation of steady shearing flow. The ultimate shear recovery S _∞ is developed as a power series in κ^?, the shear rate prior to the cessation of the steady shear flow: $$S_\infty = (\theta _0 /2\eta _0 ) \kappa ^\user1{ - } + O(\kappa ^\user1{ - } )^3$$ where η₀ and θ₀ values of the viscosity and primary normal stress functions respectively at zero-shear rate. The coefficient of the term in (κ^?)³ is calculated. In addition, the behavior of the normal stresses during the recoil process is found; during recoil τ₂₂?τ₃₃ has the opposite sign from τ₁₁?τ₂₂.     

Tensile-shear transition in mixed mode I/III fracture

The propensity of the transition of fracture type in either brittle or ductile cracked solid under mixed-mode I and III loading conditions is investigated. A fracture criterion based on the competition of the maximum normal stress and maximum shear stress is utilized. The prediction of the fracture type is determined by comparing τ_max/σ_max at a critical distance from the crack tip to the material strength ratio τ_C/σ_C, i.e., (τ_max/σ_max)<(τ_C/σ_C) for tensile fracture and (τ_max/σ_max)>(τ_C/σ_C) for shear fracture, where σ_C (τ_C) is the fracture strength of materials in tension (shear). Mixed mode I/III fracture tests were performed using circumferentially notched cylindrical bars made of PMMA and 7050 aluminum alloy. Fracture surface morphology of the specimens reveals that: (1) for the brittle material, PMMA, only tensile type of fracture occurs, and (2) for the ductile material, 7050 aluminum alloy, either tensile or shear type of fracture occurs depending on the mode mixity. The transition (in ductile material) or non-transition (in brittle material) of the fracture type and the fracture path observed in experiments were properly predicted by the theory. Additional test data from open literature are also included to validate the proposed theory.     

Symbolic computation of flow in a rotating pipe

A perturbation solution of the fully developed flow through a pipe of circular cross-section, which rotates uniformly around an axis oriented perpendicularly to its own, is considered. The perturbation parameter is given by R = 2Ωa²/ν in terms of the angular velocity Ω, the pipe radius a and the kinematic viscosity ν of the fluid. The two coupled non-linear equations for the axial velocity ω and the streamfunction ? of the transverse (secondary) flow lead to an infinite system of linear equations. This system allows first the computation of a given order ?_n, n ? 1, of the perturbation expansion ? = ∑ Rⁿ?_n in terms of ω_n-1, the (n-1)-th order of the expansion ω = ∑ Rⁿω_n, and of the lower orders ?₁,…,?_{n ? 1}. Then it permits the computation of ω_n from ω₀,…,ω_{n ? 1} and ?₁,…,?;_n. The computation starts from the Hagen–Poiseuille flow ω₀, i.e. the perturbation is around this flow. The computations are performed analytically by computer, with the REDUCE and MAPLE systems. The essential elements for this are the appropriate co-ordinates: in the complex co-ordinates chosen the two-dimensional harmonic (Laplace, Δ) and biharmonic (Δ²) operators are ideally suited for (symbolic) quadratures. Symmetry considerations as well as analysis of the equations for ω_n, ?_n and of the boundary conditions lead to general (polynomial) formulae for these functions, with coeffcients to be determined. Their determination, order by order, implies, in complex co-ordinates, only (symbolic) differentiation and quadratures. The coefficients themselves are polynomials in the Reynolds number c of the (unperturbed) Hagen–Poiseuille flow. They are tabulated in the paper for the orders n ? 6 of the perturbation expansion.     

Dispersion and Dispersivity Tensors in Saturated Porous Media with Uniaxial Symmetry

The coefficient of dispersion, D _ij , and the dispersivity, a _ijkl , appear in the expression for the flux of a solute in saturated flow through porous media. We present a detailed analysis of these tensors in an axially symmetric porous medium, e.g., a stratified porous medium, with alternating layers, and show that in such a medium, the dispersivity is governed by six independent moduli. We present also the constraints that have to be satisfied by these moduli. We also show that at least two independent experiments are required in order to obtain the values of these coefficients for any three-dimensional porous medium domain.     

Some new classes of inverse coefficient problems in non-linear mechanics and computational material science

Three classes of inverse coefficient problems arising in engineering mechanics and computational material science are considered. Mathematical models of all considered problems are proposed within the J₂-deformation theory of plasticity. The first class is related to the determination of unknown elastoplastic properties of a beam from a limited number of torsional experiments. The inverse problem here consists of identifying the unknown coefficient g(ξ²) (plasticity function) in the non-linear differential equation of torsional creep −(g(|∇u|²)u_x1)_x1−(g(|∇u|²)u_x2)_x2=2?, x∈Ω⊂R², from the torque (or torsional rigidity) T(?), given experimentally. The second class of inverse problems is related to the identification of elastoplastic properties of a 3D body from spherical indentation tests. In this case one needs to determine unknown Lame coefficients in the system of PDEs of non-linear elasticity, from the measured spherical indentation loading curve P=P(α), obtained during the quasi-static indentation test. In the third model an inverse problem of identifying the unknown coefficient g(ξ²(u)) in the non-linear bending equation is analyzed. The boundary measured data here is assumed to be the deflections w_i[τ_k]?w(λ_i;τ_k), measured during the quasi-static bending process, given by the parameter τ_k, , at some points , of a plate. An existence of weak solutions of all direct problems are derived in appropriate Sobolev spaces, by using monotone potential operator theory. Then monotone iteration schemes for all the linearized direct problems are proposed. Strong convergence of solutions of the linearized problems, as well as rates of convergence is proved. Based on obtained continuity property of the direct problem solution with respect to coefficients, and compactness of the set of admissible coefficients, an existence of quasi-solutions of all considered inverse problems is proved. Some numerical results, useful from the points of view of engineering mechanics and computational material science, are demonstrated.