Critical dynamics of lateral and transversal phase separations in bilayer biomembranes and surfactants

We consider bilayer biomembranes or surfactants made of two chemically incompatible amphiphile molecules, which may laterally or transversely phase separate into macrodomains, upon variation of some suitable parameter (temperature, lateral pressure, etc.). The purpose is an extensive study of the dynamics of both lateral and transverse phase separations, when the bilayer is suddenly cooled down from a high initial temperature towards a final one very close to the spinodal point. The critical dynamics are investigated through the partial dynamic structure factors of different species. Using a two-order parameter field theory, where the two fields are the composition fluctuations of one component in the leaflets of the bilayer, combined with an extended van Hove approach that is based on two coupled Langevin equations (with noise), we exactly compute these dynamic structure factors. We first find that the dynamics is governed by two time scales. The longest one, , can be related to the thermal correlation length, | T - T _c|^-1/2 , by , with the dynamic critical exponent z = 4 , where is an atomic length scale, T the absolute temperature, and T_c its critical value. The characteristic time can be interpreted as the time required for the formation of the final macrophase domains. The second time scale is rather shorter, and can be viewed as the short time during which the unlike phospholipids execute local motion. Second, we demonstrate that the dynamic structure factors obey exact scaling laws, and depend on three lengths, namely the wavelength q^-1 (q is the wave vector modulus), the correlation length , and a length scale R(t) t ^1/z (z = 4representing the size of macrophase domains at time t . Of course, the two lengths and R(t) coincide at the final time at which the bilayer reaches its final equilibrium state. Finally, the present work must be considered as a natural extension of our previously published one dealing with the study of lateral and transverse phase separations from a static point of view.     

$ \Phi$ -variable calculated for the mixture of thermal sources

The -variable, a measure of statistical correlation of particle momenta, introduced by Mrówczyński and Gaździcki, has been calculated for the events simulated with a simple thermal toy model. It is shown that mixing two thermal sources of unequal temperature can result in negative values of .     

On the fluctuations of the force exerted by a lipid nanotubule

After deriving the projected stress tensor in cylindrical geometry for a fluid membrane described by the Helfrich Hamiltonian, we calculate the average force f exerted by a thermally fluctuating nanotubule of radius R , and its standard deviation f . We obtain f and f in terms of the internal membrane tension , the bending rigidity , the temperature k _B T and a molecular cutoff . We find for f a shift ∼ 1/ with respect to the mean field behavior ∼ . We obtain ( f )² ∼ R ln(R/b) where b is a molecular length, f being typically small compared to f . Taking into account the difference between the internal tension and the actual mechanical tension applied to the membrane from which the tubule is drawn, we discuss the amplitude of the fluctuation-induced corrections to the average force. Our results, obtained in the harmonic approximation, hold for tubules with aspect ratio not larger than 200 , of radius significantly smaller than 100nm, that are connected to a large membrane reservoir, e.g., a giant vesicle.     

Microwave propagation parameters in magnetic fluids

Complex dielectric permittivity and complex magnetic permeability measurements of two magnetic fluids (as microwave propagation media), in the approximate range 0.2-5GHz were performed. The two samples consisted of magnetite nanoparticles, dispersed in kerosene and in water, respectively. Based on the dielectric and magnetic measurements, the frequency (f ) dependence of the attenuation parameter, , the phase constant, , the propagation constant, , the intrinsic impedance, Z_m, the refractive index, n , the reflection coefficient, R , the wavelength, and the skin depth, , of the investigated samples were determined.     

Thermoelectric effect on charged colloids in the Hückel limit

We study the thermophoretic coefficient D_T of a charged colloid. The non-uniform electrolyte is characterized in terms of densities and diffusion currents of mobile ions. The hydrodynamic treatment in the vicinity of a solute particle relies on the Hückel approximation, which is valid for particles smaller than the Debye length, a ≪ . To leading order in the parameter a/ , we find that the coefficient D_T consists of two contributions, a dielectrophoretic term proportional to the permittivity derivative d/dT , and a Seebeck term, i.e., the macroscopic electric field induced by the thermal gradient in the electrolyte solution. Depending on the particle valency, these terms may take opposite signs, and their temperature dependence may result in a change of sign of thermophoresis, as observed in several recent experiments.     

Thermal unparticles: a new form of energy density in the universe

An unparticle with scaling dimension has peculiar thermal properties due to its unique phase space structure. We find that the equation of state parameter , the ratio of pressure to energy density, is given by providing a new form of energy in our universe. In an expanding universe, the unparticle energy density evolves dramatically differently from that for photons. For , even if at a high decoupling temperature T _D is very small, it is possible to have a large relic density at present photon temperature T _γ ⁰, large enough to play the role of dark matter. We calculate T _D and using photon–unparticle interactions for illustration.     

Finite- N effects for ideal polymer chains near a flat impenetrable wall

This paper addresses the statistical mechanics of ideal polymer chains next to a hard wall. The principal quantity of interest, from which all monomer densities can be calculated, is the partition function, G _N(z) , for a chain of N discrete monomers with one end fixed a distance z from the wall. It is well accepted that in the limit of infinite N , G _N(z) satisfies the diffusion equation with the Dirichlet boundary condition, G _N(0) = 0 , unless the wall possesses a sufficient attraction, in which case the Robin boundary condition, G _N(0) = - G _N ^′(0) , applies with a positive coefficient, . Here we investigate the leading N ^-1/2 correction, G _N(z) . Prior to the adsorption threshold, G _N(z) is found to involve two distinct parts: a Gaussian correction (for z aN ^1/2 with a model-dependent amplitude, A , and a proximal-layer correction (for z a described by a model-dependent function, B(z) .     

Segmental relaxation in semicrystalline polymers: A mean-field model for the distribution of relaxation times in confined regimes

The effect of confinement in the segmental relaxation of polymers is considered. On the basis of a thermodynamic model we discuss the emerging relevance of the fast degrees of freedom in stimulating the much slower segmental relaxation, as an effect of the constraints at the walls of the amorphous regions. In the case that confinement is due to the presence of crystalline domains, a quasi-Poissonian distribution of local constraining conditions is derived as a result of thermodynamic equilibrium. This implies that the average free-energy barrier F for conformational rearrangement is of the same order of the dispersion of the barrier heights, ( F) , around F . As an example, we apply the results to the analysis of the -relaxation as observed by dielectric broad-band spectroscopy in semicrystalline poly(ethylene terephthalate) cold-crystallized from either an isotropic or an oriented glass. It is found that in the latter case the regions of cooperative rearrangement are significantly larger than in the former.     

Transmission of information through mesoscopic scattering systems

The storage and transmission of information is well defined using the notions of entropy, mutual information and channel capacity as formalized by Shannon. These quantities are calculated for a quantum mesoscopic system in terms of scattering parameters. For a one-dimensional system, the mutual information is related to the thermal conductance. This relation allows to show that for an incident signal of power P, the channel capacity C has a universal upper bound given by C independent of quantum statistics. A general framework is proposed which makes use of a natural underlying symplectic structure, to relate the entropy of a quantum mesoscopic system to the scattering matrix.     

Harmonic Bilocal Fields Generated by Globally Conformal Invariant Scalar Fields

The twist two contribution in the operator product expansion of for a pair of globally conformal invariant, scalar fields of equal scaling dimension d in four space–time dimensions is a field V ₁ (x₁, x₂) which is harmonic in both variables. It is demonstrated that the Huygens bilocality of V ₁ can be equivalently characterized by a “single–pole property” concerning the pole structure of the (rational) correlation functions involving the product . This property is established for the dimension d = 2 of . As an application we prove that any system of GCI scalar fields of conformal dimension 2 (in four space–time dimensions) can be presented as a (possibly infinite) superposition of products of free massless fields.     

Polymer translocation in a double-force arrangement

Using Langevin dynamics simulations, we investigate the translocation dynamics of an externally driven polymer chain through a nanopore, where a pulling force F is exerted on the first monomer whilst there is an opposing force F _E < F within the pore. Such a double-force arrangement has been proposed recently to allow better dynamical control of the translocation process in order to sequence biopolymers. We find that in the double-force arrangement translocation becomes slower as compared to the case under a single monomer pulling force of magnitude F - F _E , but scaling of the translocation time as a function of the chain length ∼ N ² does not change. The waiting time (m) for monomer m to exit the pore is found to be a monotonically increasing function of the bead number almost until m N , which indicates relatively well-defined slowing down and control of the chain velocity during translocation. We also study the waiting time distributions for the beads in the chain, and characterize in detail fluctuations in the bead positions and their transverse position coordinates during translocation. These data should be useful in estimating position-dependent sequencing errors in double-force experiments.     

Investigating the inner structure of irregular $ \beta$ -lactoglobulin spherulites

When -lactoglobulin in low p H aqueous solutions is exposed to high temperature for extended time, spherulites composed of amyloid fibrils of the -lactoglobulin protein form. Many of these spherulites have fibrils that radiate out from a centre and, under crossed polarisers, exhibit a symmetric Maltese Cross structure. However, a significant fraction (50 of the 101 observed spherulites) of -lactoglobulin spherulites formed under these conditions demonstrate various forms of irregularity in apparent structure. The irregularities of spherulites structures were qualitatively investigated by comparing optical microscopy images observed under crossed polarisers to computationally produced images of various internal structures. In this way, inner spherulite structures are inferred from microscopy images. Modelled structures that were found to produce computed images similar to some of the experimentally viewed images include fibrils curving as they radiate from a single nucleation point; multiple spherulites nucleating in close proximity to one another; and fibrils curving in opposite directions above and below a single nucleation point.     

Gravitational compression of colloidal gels

We study the compression of depletion gels under the influence of a gravitational stress by monitoring the time evolution of the gel interface and the local volume fraction, , inside the gel. We find is not constant throughout the gel. Instead, there is a volume fraction gradient that develops and grows along the gel height as the compression process proceeds. Our results are correctly described by a non-linear poroelastic model that explicitly incorporates the -dependence of the gravitational, elastic and viscous stresses acting on the gel.     

Analysis of Ωb? (bss) and Ωc0 (css) with QCD sum rules

We calculate the masses and the pole residues of the heavy baryons Ω _c ⁰(css) and Ω _b ⁻(bss) with the QCD sum rules. The numerical values  GeV (or  GeV) and  GeV (or  GeV) are in good agreement with the experimental data.     

Single-pion production in pp collisions at 0.95 GeV/c (II)

The single-pion production reactions pp d , pp np and pp pp were measured at a beam momentum of 0.95GeV/c ( T _p 400 MeV) using the short version of the COSY-TOF spectrometer. The central calorimeter provided particle identification, energy determination and neutron detection in addition to time-of-flight and angle measurements from other detector parts. Thus all pion production channels were recorded with 1-4 overconstraints. The main emphasis is put on the presentation and discussion of the np channel, since the results on the other channels have already been published previously. The total and differential cross-sections obtained are compared to theoretical calculations. In contrast to the pp channel we observe in the np channel a strong influence of the excitation. In particular, the pion angular distribution exhibits a (3 cos² + 1) -dependence, typical for a pure s -channel excitation and identical to that observed in the d channel. Since the latter is understood by a s -channel resonance in the ¹ D ₂ pn partial wave, we discuss an analogous scenario for the pn channel.     

Improved bounds on the radius and curvature of the K$ \pi$ scalar form factor and implications to low-energy theorems

We obtain stringent bounds in the 〈r ² -c plane where these are the scalar radius and the curvature parameters of the scalar K form factor, respectively, using analyticity and dispersion relation constraints, the knowledge of the form factor from the well-known Callan-Treiman point , as well as at , which we call the second Callan-Treiman point. The central values of these parameters from a recent determination are accomodated in the allowed region provided the higher loop corrections to the value of the form factor at the second Callan-Treiman point reduce the one-loop result by about 3% with . Such a variation in magnitude at the second Callan-Treiman point yields 0.12 fm² 〈r ² 0.21 fm²and 0.56 GeV^-4 c 1.47 GeV^-4and a strong correlation between them. A smaller value of shifts both bounds to lower values.     

Exact effective force between star-polymers in a $\Theta$-solvent

We re-examine here the computation of the effective force between two star-polymers of respective numbers of branches f₁ and f₂, immersed in a common -solvent. Such a force originates essentially from the repulsive three-body interactions. To achieve this, we take advantage of some established results using renormalization theory for three-dimensional star-polymers, or conformal invariance for two-dimensional ones. We first show that, in dimension d = 3, the force, , decreases with the center-to-center distance r as , with the exact universal amplitude . Second, in dimension d = 2, we find that the force decays more slowly as , with the exact universal amplitude . For high distances compared to the gyration radius, , of a single polymer chain at the -point, an exponential decay of the force is expected.Received: 3 February 2004, Published online: 24 May 2004PACS: 61.25.Hq Macromolecular and polymer solutions; polymer melts; swelling - 05.20.-y Classical statistical mechanics     

Dual parametrization of GPDs versus the double distribution Ansatz

We establish a link between the dual parametrization of GPDs and a popular parametrization based on the double distribution Ansatz, which is in prevalent use in phenomenological applications. We compute several first forward-like functions that express the double distribution Ansatz for GPDs in the framework of the dual parametrization and show that these forward-like functions make the dominant contribution into the GPD quintessence function. We also argue that the forward-like functions with 1 contribute to the leading singular small-x_Bj behavior of the imaginary part of DVCS amplitude. This makes the small-x_Bj behavior of independent of the asymptotic behavior of PDFs. Assuming analyticity of Mellin moments of GPDs in the Mellin space we are able to fix the value of the D -form factor in terms of the GPD quintessence function N(x, t) and the forward-like function Q ₀(x, t) .     

Single heavy flavour baryons using Coulomb plus a power law interquark potential

Properties of single heavy flavor baryons in a non-relativistic potential model with colour Coulomb plus a power law confinement potential have been studied using a simple variational method. The ground-state masses of single heavy baryons and the mass difference between the J ^P = ⁺ and J ^P = ⁺ states are computed using a spin-dependent two-body potential. Using the spin-flavour structure of the constituting quarks and by defining an effective confined mass of the constituent quarks within the baryons, the magnetic moments are computed. The masses and magnetic moments of the single heavy baryons are found to be in accordance with the existing experimental values and with other theoretical predictions. It is found that an additional attractive interaction of the order of -200 MeV is required for the antisymmetric states of (Q c, b) . It is also found that the spin-hyperfine interaction parameters play a decisive role in hadron spectroscopy.     

Negative elliptic flow of J/ψ’s: A qualitative signature for charm collectivity at RHIC

We discuss one of the most prominent features of the very recent preliminary elliptic flow data of J/ψ-mesons from the PHENIX Collaboration (PHENIX Collaboration (C. Silvestre), arXiv:0806.0475 [nucl-ex]). Even within the rather large error bars of the measured data a negative elliptic flow parameter (v₂) for J/ψ in the range of p _T = 0.5-2.5 GeV/c is visible. We argue that this negative elliptic flow at intermediate p_T is a clear and qualitative signature for the collectivity of charm quarks produced in nucleus-nucleus reactions at RHIC. Within a parton recombination approach we show that a negative elliptic flow puts a lower limit on the collective transverse velocity of heavy quarks. The numerical value of the transverse flow velocity for charm quarks that is necessary to reproduce the data is (charm) ∼ 0.55-0.6c and therefore compatible with the flow of light quarks.