Summary of ISO/TC 201 Standard XII. ISO 17973:2002—Surface chemical analysis—Medium‐resolution Auger electron spectrometers—Calibration of energy scales for elemental analysis

This International Standard specifies a method for calibrating the kinetic energy scale of Auger electron spectrometers with an uncertainty of 3 eV for general analytical use for identifying elements at surfaces. It is suitable for instruments used in either the direct mode or the differential mode where the resolution is equal to or less than 0.5% and the modulation amplitude for the differential mode, if used, is 2 eV peak to peak. The spectrometer shall be equipped with an inert gas ion gun or other method for sample cleaning and with an electron gun capable of operating at 4 keV or higher beam energy. This International Standard further specifies a calibration schedule. Crown Copyright © 2003. Published by John Wiley & Sons, Ltd.     

Summary of ISO/TC 201 Technical Report: ISO/TR 19319: 2003—Surface chemical analysis—Auger electron spectroscopy and x‐ray photoelectron spectroscopy—Determination of lateral resolution,analysis area and sample area viewed by the analyser

ISO Technical Report 19319:2003 contains information on the determination of lateral resolution, analysis area and sample area viewed by the analyser in surface analyses by Auger electron spectroscopy and x‐ray photoelectron spectroscopy. This article provides a brief summary of this information. Copyright © 2004 John Wiley & Sons, Ltd.     

Summary of ISO/TC201 standard: ISO/TR 18394:2006—surface chemical analysis—Auger electron spectroscopy—derivation of chemical information

ISO/TR 18394 provides guidance for the identification of chemical effects on x‐ray or electron‐excited Auger electron spectra as well as for applications of these effects in chemical characterization of surface/interface layers of solids. In addition to elemental composition, information can be obtained on the chemical state and the surrounding local electronic structure of the atom with the initial core hole from the changes of Auger electron spectra upon the alteration of its local environment. The methods of identification and use of chemical effects on Auger electron spectra, as described in this Technical Report, are very important for accurate quantitative applications of Auger electron spectroscopy. Copyright © 2007 John Wiley & Sons, Ltd.     

Summary of ISO/TC 201 standard: XXXIII,ISO 18115:2001/Amd. 2:2007—Surface Chemical Analysis—Vocabulary—Amendment 2

This International Standard adds a further 87 terms to this Vocabulary series, many for secondary ion mass spectrometry, elastic peak electron spectroscopy and reflected electron energy loss spectroscopy, together with 76 acronyms for scanned probes, 33 definitions of scanned probe techniques, 6 terms for contact mechanics and 147 terms for concepts in scanned probe analysis. This brings the total number of terms and acronyms to over 750 in these documents. The terms cover words or phrases used in describing the samples, instruments and theoretical concepts involved in surface chemical analysis. Copyright © 2008 John Wiley & Sons, Ltd.     

Summary of ISO/TC 201 standard: XVIII,ISO 19318:2004—surface chemical analysis—X‐ray photoelectron spectroscopy—Reporting of methods used for charge control and charge correction

International Standard ISO 19318 specifies the minimum amount of information describing the methods of charge control and charge correction in measurements of core‐level binding energies for insulating specimens by x‐ray photoelectron spectroscopy, which is to be reported with the analytical results. Information is also provided on methods that have been found useful for charge control and charge correction in the measurement of binding energies. Copyright © 2005 John Wiley & Sons, Ltd.     

Summary of ISO/TC 201 standard: XXI. ISO 21270:2004—Surface chemical analysis—X‐ray photoelectron and Auger electron spectrometers—Linearity of intensity scale

This International Standard specifies two methods for determining the maximum count rate for an acceptable limit of divergence from linearity of the intensity scale of Auger and x‐ray photoelectron spectrometers. It also includes methods to correct for intensity non‐linearities so that a higher maximum count rate can be employed for those spectrometers for which the relevant correction equations have been shown to be valid. Copyright © 2004 John Wiley & Sons, Ltd.     

Summary of ISO/TC 201 Standard XI. ISO 17974:2002—Surface chemical analysis—High‐resolution Auger electron spectrometers—Calibration of energy scales for elemental and chemical‐state analysis

This International Standard specifies a method for calibrating the kinetic energy scales of Auger electron spectrometers for elemental and chemical‐state analysis at surfaces. It is only applicable to instruments that incorporate an ion gun for sputter cleaning. This International Standard further specifies a method to establish a calibration schedule, to test for the kinetic energy scale linearity at one intermediate energy, to confirm the uncertainty of the scale calibration at one low and one high kinetic energy value, to correct for small drifts of that scale and to define the expanded uncertainty of the calibration of the kinetic energy scale for a confidence level of 95%. This uncertainty includes contributions for behaviours observed in interlaboratory studies but does not cover all of the defects that could occur. This International Standard is not applicable to instruments with kinetic energy scale errors that are significantly non‐linear with energy, to instruments operated at relative resolutions poorer than 0.2% in the constant ΔE/E mode or poorer than 1.5 eV in the constant ΔE mode, to instruments requiring tolerance limits of ±0.05 eV or less or to instruments equipped with an electron gun that cannot be operated in the energy range 5–10 keV. This standard does not provide a full calibration check, which would confirm the energy measured at each addressable point on the energy scale and should be performed according to the manufacturer's recommended procedures. Crown Copyright © 2003. Published by John Wiley & Sons, Ltd.     

Summary of ISO/TC 201 standard: ISO 19668—Surface chemical analysis—X‐ray photoelectron spectroscopy—Estimating and reporting detection limits for elements in homogeneous materials

This International Standard specifies a procedure by which elemental detection limits in X‐ray photoelectron spectroscopy (XPS) can be estimated from data for a particular sample in common analytical situations and reported. This document is applicable to homogeneous materials and is not applicable if the depth distribution of elements is inhomogeneous within the information depth of the technique.     

Summary of ISO/TC 201 standard: XIII,ISO 18114:2003—surface chemical analysis—secondary ion mass spectrometry—determination of relative sensitivity factors from ion‐implanted reference materials

This International Standard specifies a method of determining relative sensitivity factors (RSFs) for secondary ion mass spectrometry (SIMS) from ion‐implanted reference materials. The method is applicable to specimens in which the matrix is of uniform chemical composition, and in which the peak concentration of the implanted species does not exceed one atomic percent. Published in 2006 by John Wiley & Sons, Ltd.     

Summary of ISO/TC 201 Standard: ISO 29081: 2010, surface chemical analysis—Auger electron spectroscopy—reporting of methods used for charge control and charge correction

This international standard specifies the minimum amount of information required for describing the methods of charge control and charge correction in measurements of Auger electron transitions from insulating specimens by electron‐stimulated AES to be reported with the analytical results. Information is provided in an Annex on methods that have been found useful for charge control prior to or during AES analysis. The Annex also includes a summary table of methods or approaches, ordered by simplicity of approach. A similar international standard has been published for XPS (ISO 19318: 2003(E), Surface chemical analysis—XPS—reporting of methods used for charge control and charge correction. Copyright © 2010 John Wiley & Sons, Ltd.     

Summary of ISO/TC 201 Standard: ISO 14701:2011 – Surface chemical analysis – X‐ray photoelectron spectroscopy—measurement of silicon oxide thickness

This International Standard specifies several methods for measuring the oxide thickness at the surfaces of (100) and (111) silicon wafers as an equivalent thickness of silicon dioxide when measured using X‐ray photoelectron spectroscopy. It is only applicable to flat, polished samples and for instruments that incorporate an Al or Mg X‐ray source, a sample stage that permits defined photoelectron emission angles and a spectrometer with an input lens that may be restricted to less than a 6° cone semiangle. For thermal oxides in the range 1‐ to 8‐nm thickness, using the best method described in this International Standard, uncertainties at a 95% confidence level around 2% may be typical and around 1% at optimum. A simpler method is also given with slightly poorer, but often adequate, uncertainties. Copyright © 2012 Crown copyright.     

Summary of ISO/TC201 technical report: ISO/TR 18392: 2005—Surface chemical analysis—X‐ray photoelectron spectroscopy—Procedures for determining backgrounds

ISO Technical Report 18392 provides the guidance for determining backgrounds in X‐ray photoelectron spectra. The methods of background determination described in this report are applicable for the quantitative evaluation of the spectra of photoelectrons and Auger electrons excited by X‐rays from solid surfaces and surface nanostructures. Copyright © 2006 John Wiley & Sons, Ltd.     

Summary of ISO/TC 201 Standard: XIX ISO 17331:2004—Surface chemical analysis—Chemical methods for the collection of elements from the surface of silicon‐wafer working reference materials and their determination by total‐reflection x‐ray fluorescence (TXRF) spectroscopy

This international standard specifies chemical methods for the collection of iron and/or nickel from the surface of silicon‐wafer working reference materials by the vapour‐phase decomposition method or the direct acid droplet decomposition method. The determination of the elements collected may be carried out by total‐reflection x‐ray fluorescence spectroscopy, as well as by graphite‐furnace atomic absorption spectroscopy or inductively coupled plasma mass spectroscopy. This international standard applies to iron and/or nickel atomic surface densities from 6 × 10⁹ to 5 × 10¹¹ atoms cm^?2. Copyright © 2005 John Wiley & Sons, Ltd.     

Summary of ISO/TC 201 Standard: XXIII,ISO 24236:2005—surface chemical analysis—Auger electron spectroscopy—repeatability and constancy of intensity scale

This International Standard specifies a method for evaluating the constancy and repeatability of the intensity scale of Auger electron spectrometers, for general analytical purposes, using an electron gun with a beam energy of 2 keV or greater. It is only applicable to instruments that incorporate an ion gun for sputter cleaning. It is not intended to be a calibration of the intensity/energy response function. 1 , 2 That calibration may be made by the instrument manufacturer or other organization. The present procedure provides data to evaluate and confirm the accuracy with which the intensity/energy response function remains constant with instrument usage. Guidance is given to some of the instrumental settings that may affect this constancy. © Crown Copyright 2006. Reproduced with the permission of the Controller of HMSO.     

Summary of ISO/TC 201 Standard: XXVIII,ISO 18115:2001/Amd. 1:2006—surface chemical analysis—vocabulary—amendment 1

This International Standard adds 5 abbreviations and 71 terms, many for glow discharge spectrometry, to the 340 defined terms for surface chemical analysis in ISO 18115:2001. The terms cover words or phrases used in describing the samples, instruments and theoretical concepts involved in surface chemical analysis. Copyright © 2006 John Wiley & Sons, Ltd.     

NMR Microscopy—Fundamentals,Limits and Possible Applications

Alongside the numerous applications of NMR spectroscopy to structural elucidation in analytical chemistry, and to biochemical and morphological studies by NMR tomography, NMR microscopy makes possible a whole new range of applications. These include imaging, the investigation of biological objects such as plants and small animals, and also the observation of microscopic structures and structural changes in polymers and ceramics. NMR spectroscopy can also be conducted combinationally as volume-selective spectroscopy, whereby it is possible to spatially resolve the NMR-specific parameters: spin density ?, chemical shifts δ, and the relaxation times T₁ and T₂. The numerous well developed methods available make it possible to study dynamic processes by fast imaging with a temporal resolution in milliseconds. This not only allows the imaging of moving objects without incurring movement artefacts but also the measurement of diffusion constants in isotropic and anisotropic diffusion—in the latter case allowing, in principle, the determination of the complete diffusion tensor. The spatially resolved measurement of the relaxation times yields information on molecular mobility and bonding, e. g. the bonding of water, or other solvents, to polymers, the mobility of fluids in polymers or ceramics, or the three-dimensional evaluation of pore size in porous materials. In biomedicine, NMR microscopy allows the observation of growth on the cellular level, the study of embryos, and the development of therapeutic methods in animal experiments. It can lead to a drastic reduction in the number of animal experiments, and in combination with volume-selective spectroscopy gives valuable information on in-vivo metabolism.     

Summary of ISO/TC 201 Standard: XXIV,ISO 24237:2005—surface chemical analysis—X‐ray photoelectron spectroscopy—repeatability and constancy of intensity scale

This International Standard specifies a method for evaluating the repeatability and constancy of the intensity scale of X‐ray photoelectron spectrometers, for general analytical purposes, using non‐monochromated Al or Mg X‐rays or monochromated Al X‐rays. It is only applicable to instruments that incorporate an ion gun for sputter cleaning. It is not intended to be a calibration of the intensity/energy response function (Seah MP. J. Electron Spectrosc. 1995; 71: 191; http://www.npl.co.uk/nanoanalysis/a1calib.html [2006]). That calibration may be made by the instrument manufacturer or other organization. The present method provides data to evaluate and confirm the accuracy with which the intensity/energy response function remains constant with instrument usage. Guidance is given to some of the instrument settings that may affect this constancy. Copyright © 2006 John Wiley & Sons, Ltd.     

Summary of ISO/TC 201 Standard: X ISO 17560:2002—Surface chemical analysis—Secondary ion mass spectrometry—Method for depth profiling of boron in silicon

This International Standard specifies a secondary ion mass spectrometric method using magnetic‐sector or quadrupole mass spectrometers for depth profiling of boron in silicon, and using stylus profilometry or optical interferometry for depth calibration. This method is applicable to single‐crystal, polycrystal or amorphous silicon specimens with boron atomic concentrations between 1 × 10¹⁶ and 1 × 10²⁰ atoms cm^?3, and to the crater depth of 50 nm or deeper. Optical interferometry is generally applicable to crater depths in the range 0.5–5 µm. Copyright © 2004 John Wiley & Sons, Ltd.     

Summary of ISO/TC 201 standard: XXII. ISO 22048:2004—Surface chemical analysis—Information format for static secondary ion mass spectrometry

This International Standard provides a digital format to store and transfer between computers, in a compact way, important calibration and instrumental parameter data necessary to make effective use of spectral data files from static SIMS instruments. This format is designed to supplement the data transfer format specified in ISO 14976. Copyright © 2004 John Wiley & Sons, Ltd.     

Summary of ISO/TC 201 Standard: XXX. ISO 18516: 2006—Surface chemical analysis—Auger electron spectroscopy and X‐ray photoelectron spectroscopy—Determination of lateral resolution

This International Standard describes three methods for measuring the lateral resolution achievable in Auger electron spectrometers and X‐ray photoelectron spectrometers under defined settings. The straight‐edge method is suitable for instruments where the lateral resolution is expected to be larger than 1 µm. The grid method is suitable if the lateral resolution is expected to be less than 1 µm but more than 20 nm. The gold‐island method is suitable for instruments where the lateral resolution is expected to be less than 50 nm. The standard contains three informative annexes that provide illustrative examples of measurements of lateral resolution. Copyright © 2008 John Wiley & Sons, Ltd.