Emission spectroscopy of the A<Superscript>1</Superscript>Π–X<Superscript>1</Superscript>Σ<Superscript>+</Superscript> system of AlH

The high-resolution emission spectrum of the A¹ Π–X¹Σ⁺ transition of AlH was observed in the 18 000–25 000 cm^-1 spectral region using a conventional spectroscopic technique. The AlH molecules were excited in an Al hollow-cathode lamp filled with a mixture of Ne carried gas and a trace amount of NH₃. The emission from the discharge was observed with a plane grating spectrograph and recorded by a photomultiplier tube. In total 163 transition wave numbers belonging to six bands (0-0,1 and 1-0,1,2,3) were precisely measured and rotationally analysed. In the final fit the present data have been combined with available high-resolution measurements of the vibration-rotation bands by White et al. [J. Chem. Phys. 99, 8371 (1993)]. This procedure enabled extracting molecular constants for the A¹ Π and X¹ Σ⁺ states of AlH. A very slight local perturbation has been discovered in the v=1 vibration level of the A¹ Π state at J=5. This was probably caused by the interaction with the a³Π state.     

Accurate characterisation of the C(3)<Superscript>1</Superscript>Σ<Superscript>+</Superscript> state of the NaRb molecule

We present a first detailed experimental study of the C(3)¹Σ⁺ state of the NaRb molecule converging to the Na(3p) + Rb(5s) states of separated atoms. Two different high resolution spectroscopic methods have been applied: the Fourier transform spectroscopy of laser induced fluorescence and the V-type optical-optical double resonance polarization labeling spectroscopy. The entire data field for the C¹Σ⁺ state of Na⁸⁵Rb and Na⁸⁷Rb consists of rovibrational levels with v'=0–64 and J'=4–123. The data were incorporated into a direct fit of a single potential energy curve to the level energies using the Inverted Perturbation Approach method. As the experimental data extend to the “shelf" region of the potential at large internuclear separations of 8.5 ?, the C state's suitability for photoassociation yielding cold heteronuclear NaRb is discussed. Electronic supplementary material Online Material     

Study of the parameters of the He(3 <Superscript>3</Superscript>S)-He(2 <Superscript>3</Superscript>P) line *

We have observed emission spectrum in dense plasmas of helium excited by a corona discharge at 706.69 nm. In continuation of an analysis of spectra obtained in gaseous helium at 300 K, we report on a study of the line parameters of the observed spectra. We discuss the major importance of temperature and perturber density in the broadening, shift and asymmetry measured from calculated profiles within a unified line shape semi-classical theory. The comparison is done with existing data derived from experimental spectra at 300 K. The theoretical work is extended at lower temperatures down to 40 K.     

Cold and ultracold collisions of MgH (<Superscript>2</Superscript>Σ<Superscript>+</Superscript>) with helium

The cross sections for rotational, fine-structure and projection-change transitions in collision of MgH (²Σ⁺) molecule with ³He and ⁴He atoms were computed at cold and ultracold temperatures using the ab initio potential energy surface. The significant suppression feature and resonance pattern caused by spin-rotation interaction were found and discussed. The collisions exhibit a strong isotope effect in the ultracold regime. The rotational relaxations of the fine-structure excited energy levels tendentiously preserve the F index. The ratio of the cross sections for elastic and spin-flipping collision with ³He partner is always greater than seven orders of magnitude for the energy range 10^-6−1cm^-1 and suggests the MgH molecule is a good candidate for ³He buffer gas cooling.     

(EC + β<Superscript>+</Superscript>) decays of the 11/2<Superscript>-</Superscript> isomer and 1/2<Superscript>+</Superscript> ground state of <Superscript>143</Superscript>Dy

The 1/2⁺ ground state and a 11/2^- isomer of very neutron-deficient isotope ¹⁴³Dy were produced by irradiation of an enriched target of ¹⁰⁶Cd with ⁴⁰Ca and studied by using a helium-jet fast tape-transport system in combination with proton-γ, X-γ and γ-γ coincidence measurements. A simple ( EC + β⁺) decay scheme of ^143mDy with a half-life of 3.0(3) s and a tentative ( EC + β⁺) decay scheme of ^143gDy with a half-life of 5.6(10) s are proposed. As a by-product, the 347- and 545-keV γ transitions in ¹³⁸Sm following the β-delayed proton emission of ¹³⁹Gd decay and the 323-keV γ transition in ¹³⁹Eu following the β-delayed proton emission of ¹⁴⁰Tb decay could be observed for the first time. Received: 20 August 2002 / Accepted: 28 October 2002 / Published online: 11 February 2003 RID="a" ID="a"e-mail: xsw@ns.lzb.ac.cn Communicated by D. Schwalm     

The evaluation of the branching ratios of the decays φ(1020)→2π<Superscript>+</Superscript>2π<Superscript>−</Superscript>π<Superscript>0</Superscript>, π<Superscript>+</Superscript>π<Superscript>−</Superscript>3π<Superscript>0</Superscript>

Combining the Okubo-Zweig-Iizuka rule in the decay φ→ρπ→π⁺π^?π⁰ with the ρ→4π decay amplitudes, we calculate the φ→2π⁺2π^?π⁰ and φ→π⁺π^?3π⁰ ones. The partial widths of the above φ decays are evaluated, and the excitation curves in e⁺e^? annihilation are obtained, assuming reasonable particular relations among the parameters characterizing the anomalous terms of the HLS Lagrangian. The evaluated branching ratios B_φ→π⁺_π^?_3π⁰ ≈ 2 × 10^?7 and B_φ→2π⁺_2π^?_π⁰ ≈ 7 × 10^?7 are such that, with the luminosity L=500 pb^?1 attained at DAΦNE φ factory, one may already possess about 1685 events of the decays φ→5π.     

Perturbative analysis of the 2νββ decays of <Superscript>100</Superscript>Mo and <Superscript>116</Superscript>Cd

We have performed a theoretical analysis of the ground-state-to-ground-state transitions in ¹⁰⁰Mo and ¹¹⁶Cd, based on the quasiparticle random-phase approximation and on a straightforward perturbative scheme. The results show that the single-state dominance found in the realistic calculations of the nuclear matrix elements, which is consistent with data, can be viewed as a result of the interference between few two-quasiparticle configurations. Received: 12 August 2002 / Accepted: 23 October 2002 / Published online: 18 February 2003 RID="a" ID="a"e-mail: civitarese@fisica.unlp.edu.ar Communicated by V.V. Anisovich     

Nonadiabatic effects in (1~2)<Superscript>1</Superscript>Π–X<Superscript>1</Superscript>Σ<Superscript>+</Superscript> rovibronic transitions of KRb molecules

Numerical simulation of the effect of intramolecular electrostatic interactions on redistribution of relative intensities in the vibrational structure of (1 ~ 2)¹Π–X¹Σ⁺ rotationally resolved transitions of the KRb molecule is performed within the precision nonadiabatic model of coupled vibrational channels. It is established that mutual perturbation of electronically excited states modifies in a nontrivial way a nodal structure of nonadiabatic wavefunction of the (1 ~ 2)¹Π complex, which is possible to use for rising efficiency of twostep laser synthesis and stabilization of ultracold ensembles of KRb molecules in the ground electronic state.     

Radiation widths of resonances in the <Superscript>40</Superscript>Ar(pγ)<Superscript>41</Superscript>K reaction

The excitation function for the ⁴⁰Ar(pγ)⁴¹K reaction at the accelerated proton energy E _p= 450–2700 keV is studied. Positions of 168 resonances identified as levels of the ⁴¹K nucleus are observed in this energy range. The data for the proton energy E _p < 1 MeV and E _p > 2 MeV are obtained for the first time. Relative yields of γ rays observed in the decay of the resonances are calculated from a comparison with the yield of the calibrating resonance at E _p= 1102 keV. Total radiation widths of the resonances are calculated on the basis of the data obtained.     

Decays of baryon resonances into ΛK<Superscript>+</Superscript>, ΣK<Superscript>+</Superscript> and Σ<Superscript>+</Superscript>K<Superscript>0</Superscript>

Cross-sections, beam asymmetries, and recoil polarisations for the reactions γp → K ⁺Λ;γp → K ⁺Σ⁰, and γp → K ⁰Σ⁺ have been measured by the SAPHIR, CLAS, and LEPS Collaborations with high statistics and good angular coverage for centre-of-mass energies between 1.6 and 2.3 GeV. The combined analysis of these data with data from π and η photoproduction reveals evidence for new baryon resonances in this energy region. A new P₁₁ state with mass 1840 MeV and width 140 MeV was observed contributing to most of the fitted reactions. The data demand the presence of two D₁₃ states at 1875 and, optimistically, at 2170 MeV.     

Inhibitors of adenosine consuming parasites through polymer-assisted N-acylation of N<Superscript>6</Superscript>-substituted 5<Superscript>′</Superscript>-amino-5<Superscript>′</Superscript>-deoxyadenosines

Abstract  

A series of 30 adenosine derivatives with three different substituents at the N⁶-position were prepared in order to evaluate their potential to inhibit the pathogenic protozoa Plasmodium falciparum and Trypanosoma brucei in vitro. The rationale for synthesis of these structures was the high probability of interactions with multiple adenosine associated targets and the assumption that N⁶-substitutents should increase stability against adenosine deaminases and allow the molecules to diffuse across parasite membranes. Starting from inosine, the new compounds were prepared as single isomers using a polymer-assisted acylation protocol enabling the straightforward isolation of the target compounds in pure form. Three of the compounds displayed anti-plasmodial and one anti-trypanosomal activity in the single digit micromolar concentration range.     

Scheme of the β-decay of <Superscript>234</Superscript>Th

The scheme of the β-decay of ²³⁴Th is still not completely clear. Only the upper bound (10 keV) of the energy of the isomeric transition from level T_1/2 = 1.17 min of the ²³⁴Pa nucleus is known, and the correspondence between gamma quanta of several energies emitted in the β-decay of ²³⁴Th and specific nuclear levels of ²³⁴Pa has not been established. In this work, the isomeric transition energy of 2.6 ± 0.5 keV is determined via the γ-spectrometry of a ²³⁴Th source in γγ-coincidences, and a new ²³⁴Pa level populated in the β-decay of ²³⁴Th is introduced.     

A new determination of the γπ → ππ anomalous amplitude via πe<Superscript>-</Superscript> → π<Superscript>-</Superscript>e<Superscript>-</Superscript>π<Superscript>0</Superscript> data

We discuss the reaction π^-e^- → π^-e^-π⁰ with the purpose of obtaining information on the γπ → ππ anomalous amplitude _3π. We compare a full calculation at (p⁶) in chiral perturbation theory and various phenomenological predictions with the existing data of Amendolia et al. By integrating our theory results using Monte Carlo techniques, we obtain σ = 2.05 nb at (p⁶) and σ = 2.17 nb after including the dominant electromagnetic correction. Both results are in good agreement with the experimental cross-section of σ = (2.11±0.47) nb. On the basis of the ChPT results one would extract from the experimental cross-section as amplitudes _3π^(0)extr = (9.9±1.1) GeV^-3 and _3π^(0)extr = (9.6±1.1) GeV^-3, respectively, which have to be compared with the low-energy theorem _3π = e/(4π²F_π³) = 9.72GeV^-3. We emphasize the need for new data to allow for a comparison of experimental and theoretical distributions and to obtain _3π with smaller uncertainty.     

Investigation of the reaction D(<Superscript>4</Superscript>He, γ)<Superscript>6</Superscript>Li at ultralow energies

The cross section of the reaction D(⁴He, γ)⁶Li with titanium and zirconium deuterides as targets is measured for incident ⁴He⁺ ion energies of 30 and 36 keV, respectively. The ion beam is generated by a Hall pulsed plasma accelerator. For the first time, upper limits on the cross section of the reaction D(⁴He, γ)⁶Li at ultralow energies are imposed (at 90% confidence level): σ ≤ 1.2 × 10^?35 cm² for the TiD₂ target and E(⁴He⁺) = 30 keV, and σ ≤ 7 × 10^?36 cm² for the ZrD₂ target and E(⁴He⁺) = 36 keV     

Conversion electron measurement in the β<Superscript>-</Superscript>-decay of <Superscript>151</Superscript>Pr

The β^--decay of ¹⁵¹Pr produced by the thermal neutron-induced fission of ²³⁵U has been studied using an on-line isotope separator. From an internal-conversion electron measurement with a Si(Li) detector, K-conversion coefficients were obtained for 20 γ-transitions. Spins and parities of 6 excited levels in ¹⁵¹Nd were newly determined from the deduced multipolarities: even parities for the 543 and 627 keV levels, odd parities for 250 and 599 keV, (3/2, 5/2)⁺ for 685 keV, and (1/2, 3/2)⁺ for 880 keV. The level structure was compared with the rotation-vibration coupling Nilsson model. Received: 28 June 2002 / Accepted: 31 October 2002 / Published online: 25 February 2003 RID="a" ID="a"e-mail: ykojima@hiroshima-u.ac.jp Communicated by J. ?yst?     

Study of ground states of <Superscript>3</Superscript>H, <Superscript>3,4,6</Superscript>He, <Superscript>6</Superscript>Li,and <Superscript>9</Superscript>Be nuclei by Feynman’s continual integrals method

The ground-state energies and the squared moduli of the ground-state wave functions are calculated for the ³H, ^3,4,6He, ⁶Li, and ⁹Be nuclei by Feynman’s continual (path) integrals method. The results are in satisfactory agreement with experimental data.     

Detailed Investigations of Neutron–Neutron Angular Correlations in Slow-Neutron-Induced Fission of <Superscript>233</Superscript>U, <Superscript>235</Superscript>U,and <Superscript>239</Superscript>Pu

An experiment devoted to studying neutron–neutron angular correlations in the slow-neutroninduced fission of ²³³U, ²³⁵U and ²³⁹Pu nuclei was performed. The experimentally determined angular dependence of the number of neutron–neutron coincidences was compared with the results of a Monte Carlo simulation for various values of the neutron-detection threshold in the range between 490 and 2080 keV. It was found that the experimental angular distributions in question can be described well under the assumption that 2% to 5% of all prompt fission neutrons are emitted isotropically in the laboratory frame. Probably, such neutrons can be interpreted as so-called scission neutrons directly associated with the nuclear-rupture instant. Energy distributions of this component were also obtained from the present analysis.     

Absolute cross section of p(<Superscript>7</Superscript>Be,γ)<Superscript>8</Superscript>B using a novel approach

The absolute cross section σ (E) of the radiative capture reaction p(⁷Be,γ)⁸B at the center-of-mass energy E = 992 keV has been measured using a radioactive ⁷Be ion beam and a windowless gas target system filled with H₂ gas. The ⁸B residual nuclides were detected with a recoil separator consisting of momentum and velocity filters and a ΔE-E detector telescope. The ⁸B yield was observed concurrently with the ⁷Be + p elastic scattering yield, relating σ(E) to the Rutherford scattering cross section. The resulting value, σ(E) = 0.41 ± 0.11 μb, leads to an S(E) factor at zero energy of S(0) = 16 ± 4 eV b, in fair agreement with recommended values. Received: 8 February 2000     

Concept of an Electron–Positron Collider for Production and Study of the (μ<Superscript>+</Superscript>μ<Superscript>–</Superscript>) Bound State

The possibility of producing and studying thus far unobserved dimuonium atoms (μ⁺μ^?) using low-energy colliding е⁺е^? beams is considered. Possible collider implementations are discussed, processes affecting its efficiency are investigated, and its parameters are estimated. The collider can probably also be used for high-luminosity experiments on the study of π^± and η mesons.