A Back Propagation Artificial Neural Network Prediction Model of the Gate Freeze Time for Injection Molded Polypropylenes

This paper presents a back propagation artificial neural network (BP ANN) prediction model of the gate freeze time (t_gf) for injection molded polypropylenes. An orthogonal design method was applied to enhance the BP ANN performance. The test results on the performance of the BP ANN prediction model showed that it can predict t_gf with reasonable accuracy. Utilizing the BP ANN prediction model, the effects of the process factors, melt temperature (T_me), fill time (t_f), gate area (A_in), packing pressure (P_p), and mold temperature (T_mo) on t_gf were investigated. The simulation results showed that the most important process factor affecting t_gf was T_me, followed by t_f, A_in, and P_p, with T_mo having the least effect. The gate freeze time increased with elevated T_me, t_f, A_in, and P_p.     

Modeling the Effect of Injection Molding Process Parameters on Warpage Using Neural Network Theory

A back propagation artificial neural network (BPANN) prediction model for warpage of injection-molded polypropylene was developed based on an orthogonal design method. The BPANN model was trained by the input and output data obtained from the moldflow software platform simulations. It is proved that the BPANN model can predict the warpage with reasonable accuracy. Utilizing the BPANN model, the effects of the process parameters, packing pressure (Pp), melt temperature (T_me), mold temperature (T_mo), packing time (t_p), cooling time (t_c), and fill pressure (p_f), on the warpage were investigated. The most important process parameter affecting the warpage was Pp, and the second most important was T_me. The rest of the process parameters, T_mo, t_p, t_c, and p_f, were found to be relatively less influential. Warpage increased with elevating T_mo. In contrast, an increase in Pp and T_me caused the warpage to decrease.     

Effect of γ irradiation on the low-temperature electrical conductivity and dielectric properties of TlGaSe2 crystals

Electrical conductivity and dielectric properties of single-crystal TlGaSe₂ have been studied as a function of γ irradiation dose in the 100–280 K range including the existence of an incommensurate phase. Anomalies in the form of maxima have been observed in the σ=f(T), tan δ=f(T), and ɛ=f(T) curves at the points of transition from the paraphase to incommensurate (IC) phase, T _i, and from the IC to commensurate phase, T _c. The increase in the quantities σ, tan δ, and ɛ observed initially with increasing irradiation dose is followed by their strong decrease and disappearance of the anomalies. It has been established that γ irradiation does not affect the phase transition temperatures T _i and T _c. Fiz. Tverd. Tela (St. Petersburg) 40, 1328–1331 (July 1998)     

Temporal correlations and persistence in the kinetic Ising model: the role of temperature

We study the statistical properties of the sum S _t = dt'σ _t', that is the difference of time spent positive or negative by the spin σ _t, located at a given site of a D-dimensional Ising model evolving under Glauber dynamics from a random initial configuration. We investigate the distribution of S_t and the first-passage statistics (persistence) of this quantity. We discuss successively the three regimes of high temperature ( T > T _c), criticality ( T = T _c), and low temperature ( T < T _c). We discuss in particular the question of the temperature dependence of the persistence exponent , as well as that of the spectrum of exponents (x), in the low temperature phase. The probability that the temporal mean S _t/t was always larger than the equilibrium magnetization is found to decay as t ^{- - ?}. This yields a numerical determination of the persistence exponent in the whole low temperature phase, in two dimensions, and above the roughening transition, in the low-temperature phase of the three-dimensional Ising model. Received 4 December 2000     

Scaling models of thermodynamic properties on the coexistence curve: Problems and some solutions

Models consistent with the scaling theory of critical phenomena and capable of describing the thermodynamic properties F of substances on the coexistence curve, such as the density of the liquid ρ _l , density of the gas ρ _g , order parameter f _s , mean coexistence curve diameter f _d , and saturation pressure P _s are discussed. The models are presented in the form of equations F = (τ, D, C), where τ = (T _c ? T)/T _c , and D = (α, β, T _c , ρ _c , P _c , ...) are the critical characteristics, such as T _c , ρ _c , and P _c (temperature, density, and pressure, respectively), α and β are the scaling exponents, and C are adjustable coefficients. The authors developed combined models f(τ, D, C) for describing the indicated properties of a number of compounds (CH₄, NH₃, SF₆, water, methanol, ethanol, diethyl ether, and freons R134a, R143a, and R236ea). The coefficients C were determined based on experimental data over a wide temperature range, including the critical point. The equations derived are used to perform practical calculations, including estimates of the first and second derivatives of the saturation pressure with respect to the temperature in the critical region.     

Low-temperature x-ray diffraction studies of the crystallographic parameters and thermal expansion of (CH3)2NH2Al(SO4)2 · 6H2O crystals

The a, b, c, and β crystallographic parameters of the (CH₃)₂NH₂Al(SO₄)₂ · 6H₂O crystal (DMAAS) have been measured by x-ray diffraction in the 90–300-K temperature range. The thermal expansion coefficients along the principal crystallographic axes α_a, α_b, and α_c have been determined. It was shown that, as the temperature is increased, the parameter α decreases and b increases, whereas c decreases for T<T _c (where T _c is the transition temperature) and increases for T>T _c, so that one observes a minimum in the c=f(T) curve in the region of the phase transition (PT) temperature T _c ～ 152 K. The thermal expansion coefficients α_a, α_b, and α_c vary in a complicated manner with increasing temperature, more specifically, α_a and α_c assume negative values at low temperatures, and the α_a=f(T), α_b=f(T), and α_c=f(T) curves exhibit anomalies at the PT point. The crystal has been found to be substantially anisotropic in thermal expansion.     

聚丁二烯中的等待时间效应

测量了高聚物材料聚丁二烯的比热,发现在温度T_g=178K出现玻璃转变且转变点附近的比热与降温过程有关。在降温过程中,若控制样品在某一温度T_wg等待时间t_w,则升温比热测量表明,T_g处的比热跃变△c_p存在明显的等待时间效应,即△c_p随t_w的增大而增大。在T_w=169K条件下,△c_p(t< 关键词：     

Bootstrap Percolation on Homogeneous Trees Has 2 Phase Transitions

We study the threshold θ bootstrap percolation model on the homogeneous tree with degree b+1, 2≤θ≤b, and initial density p. It is known that there exists a nontrivial critical value for p, which we call p _f , such that a) for p>p _f , the final bootstrapped configuration is fully occupied for almost every initial configuration, and b) if p<p _f , then for almost every initial configuration, the final bootstrapped configuration has density of occupied vertices less than 1. In this paper, we establish the existence of a distinct critical value for p, p _c , such that 0<p _c <p _f , with the following properties: 1) if p≤p _c , then for almost every initial configuration there is no infinite cluster of occupied vertices in the final bootstrapped configuration; 2) if p>p _c , then for almost every initial configuration there are infinite clusters of occupied vertices in the final bootstrapped configuration. Moreover, we show that 3) for p<p _c , the distribution of the occupied cluster size in the final bootstrapped configuration has an exponential tail; 4) at p=p _c , the expected occupied cluster size in the final bootstrapped configuration is infinite; 5) the probability of percolation of occupied vertices in the final bootstrapped configuration is continuous on [0,p _f ] and analytic on (p _c ,p _f ), admitting an analytic continuation from the right at p _c and, only in the case θ=b, also from the left at p _f . L.R.G. Fontes partially supported by the Brazilians CNPq through grants 475833/2003-1, 307978/2004-4 and 484351/2006-0, and FAPESP through grant 04/07276-2. R.H. Schonmann partially supported by the American N.S.F. through grant DMS-0300672.     

Maximum of a Fractional Brownian Motion: Probabilities of Small Values

Let b _γ (t), b _γ(0)= 0 be a fractional Brownian motion, i.e., a Gaussian process with the structure function , 0 < γ < 2. We study the logarithmic asymptotics of P _T = P{b _γ (t) < 1,□t∈TΔ} as T→∞, where Δ is either the interval (0,1) or a bounded region that contains a vicinity of 0 for the case of multidimensional time. It is shown that ln P _T = - D ln T(1 + o(1)), where D is the dimension of zeroes of b _γ (t) in the former case and the dimension of time in the latter. Received: 28 September 1998 / Accepted: 19 February 1999     

Dynamics of forest fire under rotational constraint

A rotationally constrained forest fire model is studied on square and triangular lattices of size 400×400. The critical probabilityp _c for onset of fire propagation is determined. The scaling relationsMt ^d _r, R_gt^v andMR _g ^d _f are analysed at fire propagation probabilityp=p _c whereM is the number of burnt trees,R _g the radius of gyration andd _f the fractal dimension of the cluster of burnt trees at timet. Numerical estimates ofd _t, v andd _f have been obtained.     

Asymptotic behavior of orbits of C 0-semigroups and solutions of linear and semilinear abstract differential equations

In this paper, we study the asymptotic behavior of solutions of semilinear abstract differential equations (*) u′(t) = Au(t) + t ⁿ f(t, u(t)), where A is the generator of a C ₀-semigroup (or group) T(·), f(·, x) ∈ A for each x ∈ X, A is the class of almost periodic, almost automorphic or Levitan almost periodic Banach space valued functions ϕ: ℝ → X and n ∈ {0, 1, 2, ...}. We investigate the linear case when T(·)x is almost periodic for each x ∈ X; and the semilinear case when T(·) is an asymptotically stable C ₀-semigroup, n = 0 and f(·, x) satisfies a Lipschitz condition. Also, in the linear case, we investigate (*) when ϕ belongs to a Stepanov class S ^p-A defined similarly to the case of S ^p-almost periodic functions. Under certain conditions, we show that the solutions of (*) belong to A _u:= A ∩ BUC(ℝ, X) if n = 0 and to t ⁿ A _u ⊕ w _n C ₀ (ℝ, X) if n ∈ ℕ, where w _n(t) = (1 + |t|)ⁿ. The results are new for the case n ∈ ℕ and extend many recent ones in the case n = 0. Dedicated to the memory of B. M. Levitan     

Isothermal and non-isothermal crystallization kinetics of PVA + ionic liquid [BDMIM][BF4]-based polymeric films

The effect of ionic liquid (IL), 1-butyl-2,3-dimethylimidazolium tetrafluoroborate [BDMIM][BF₄], on crystallization behavior of poly(vinyl alcohol) (PVA) has been studied by isothermal and non-isothermal differential scanning calorimetry techniques. The PVA + IL based polymer electrolyte films have been prepared using solution casting technique. To describe the isothermal and non-isothermal crystallization kinetics, several kinetic equations have been employed on PVA + IL based films. There is strong dependence of the peak crystallization temperature (T_c), relative degree of crystallity (X_t), half-time of crystallization (t_1/2), crystallization rate constants (Avrami K_t and Tobin A_T), and Avrami (n) and Tobin (n_T) exponents on the cooling rate and IL loading.     

Dynamics of the formation of two-dimensional ordered structures

The growth of ordered domains in lattice gas models, which occurs after the system is quenched from infinite temperature to a state below the critical temperatureT _c, is studied by Monte Carlo simulation. For a square lattice with repulsion between nearest and next-nearest neighbors, which in equilibrium exhibits fourfold degenerate (2×1) superstructures, the time-dependent energy E(t), domain size L(t), and structure functionS(q, t) are obtained, both for Glauber dynamics (no conservation law) and the case with conserved density (Kawasaki dynamics). At late times the energy excess and halfwidth of the structure factor decrease proportional tot ^–x, whileL(t) t ^x, where the exponent x=1/2 for Glauber dynamics and x1/3 for Kawasaki dynamics. In addition, the structure factor satisfies a scaling lawS(k,t)=t ^2xS(kt^x). The smaller exponent for the conserved density case is traced back to the excess density contained in the walls between ordered domains which must be redistributed during growth. Quenches toT>T _c, T=T_c (where we estimate dynamic critical exponents) andT=0 are also considered. In the latter case, the system becomes frozen in a glasslike domain pattern far from equilibrium when using Kawasaki dynamics. The generalization of our results to other lattices and structures also is briefly discussed.     

Relaxation of post-illumination electric fields in strongly biased high-resistance structures with a single deep impurity level

This paper examines how an electric field relaxes when a discontinuous large carrier-depleting voltage applied to high-resistance symmetric metal-semiconductor-metal (MSM) and metal-insulator-semiconductor-insulator-metal (MISIM) structures having a single impurity level, and how its energy level ɛ _t=E _c−E _t and the tunneling transparency T _n,p of the metal-semiconductor or metal-insulator boundary affect the relaxation. It is shown that the relaxation of the field and the form of its steady-state distribution depend on the ratio of the time constant t _p in the majority-carrier (hole) region to the ionization time τ _t ⁻¹ =α _n (n _*+n ₁)+α _p (p _*+p ₁) of a deep trap in the bulk. This ratio determines the relative contributions of free ρ _p,n and bound charge dnsities ρ _t (where α _n,p is the coefficient for capture by an impurity, and p _*, n _*, p ₁, n ₁ are equilibrium concentrations and Shockley-Read constants in the bulk). For τ _t ≈(τ _t )_max≫t _p ,ρ _t ≫ it is found that ρ _p,n and ρ _t ≫ρ _p,n , which corresponds to a trap energy close to , independent of the value of T _n,p , decaying oscillations arise in the concentration distribution, bulk charge, and field appear in the bulk. The amplitude of these oscillations reaches a maximum at time t≈0.4τ _t. Decreasing the ratio α _p/α_n causes τ _t to deviate from (τ _t)_max. When this happens, the field no longer oscillates; instead, it increases with positive curvature in the cathode portion of the bulk. The quantity T _n,p determines the behavior of the field in the neighborhood of the anode. The value of (dE/dx)₀ is positive for MSM structures (T _n,p ≈1), and negative for MISIM structures (T _n,p ≈0). For transparencies close to a critical value T _n,p ⁰ , the field in the structure remains almost uniform over an impurity ionization time. Fiz. Tverd. Tela (St. Petersburg) 39, 1775–1782 (October 1997)     

Size and interface effects on Curie temperature of perovskite ferroelectric nanosolids

A simple and unified model, without any adjustable parameter, is established for size effect on Curie temperature of low-dimensional ferroelectrics (thin films, nanowires and nanoparticles), T _c(D), where D denotes size of low-dimensional ferroelectrics. T _c(D) function is based on consideration on the size dependence of spontaneous polarization of low-dimensional ferroelectrics P _s(D), which is determined by the misfit strain at the ferroelectrics/substrate interface. It is shown that P _s(D) and T _c(D) functions decrease or increase when the misfit strain is tensile or compressive. The numerically predicted results are in agreement with the available experimental results of BaTiO₃ and PbTiO₃ nanoparticles and thin films.     

On the Poisson Limit Theorems of Sinai and Major

Let f(ϕ) be a positive continuous function on 0 ≤ϕ≤Θ, where Θ≤ 2 π, and let ξ be the number of two-dimensional lattice points in the domain Π _R (f) between the curves r=(R+c ₁/R)f(ϕ) and r=(R+c ₂/R)f(ϕ), where c ₁<c ₂ are fixed. Randomizing the function f according to a probability law P, and the parameter R according to the uniform distribution μ _L on the interval [a ₁ L,a ₂ L], Sinai showed that the distribution of ξ under P×μ _L converges to a mixture of the Poisson distributions as L→∞. Later Major showed that for P-almost all f, the distribution of ξ under μ _L converges to a Poisson distribution as L→∞. In this note, we shall give shorter and more transparent proofs to these interesting theorems, at the same time extending the class of P and strengthening the statement of Sinai. Received: 15 June 1999 / Accepted: 11 February 2000     

Stereodynamics of the reactions Ne+H2+/Ne+D2+/Ne+T2

The vector correlations between products and reagents for the reactions Ne+H + 2 , Ne+D + 2 , and Ne+T + 2 are calculated by means of the quasi-classical trajectory method on a new potential energy surface constructed by Lü et al. [J. Chem. Phys. 2010 132, 014303]. The polarization-dependent differential cross-sections (2π/σ)(dσ 00 /dω t ), (2π/σ)(dσ 20 /dω t ), (2π/σ)(dσ 22+ /dω t ), and (2π/σ)(dσ 21 /dω t ), and the distributions of P (θ r ), P (φ r ), and P (θ r ,φ r ) are calculated. The isotopic effect, which is associated with the difference in mass factor among the three reactions, is revealed.     

Free energy of the chiral Potts model in the scaling region

We explicitly calculate the free energy of the general solvableN-state chiral Potts model in the scaling region, forT<T _c . We do this from both of the two available results for the free energy, and verify that they are mutually consistent. Ift=T _c –T, then we find that - _c /t has a Taylor expansion in powers oft ^2/N (together with higher-order non-scaling terms of ordert, ort logt).     

Segregation of impurities and vacancies on phase and antiphase boundaries in alloys

The equilibrium distribution of low-concentration impurities or vacancies is investigated in the region of a coherent phase boundary or antiphase boundary in a binary alloy. A general expression for the free energy of an inhomogeneous multicomponent alloy, which generalizes the expression previously derived for a binary alloy, is presented. Explicit formulas for the impurity concentration profile c _im(x) in terms of the distribution of the principal components of the alloy near a boundary are obtained from this expression in the mean-field and pair-cluster approximations. The shape of this profile is determined by a “preference potential” P, which characterizes the attraction of an impurity to one of the alloy components, as well as by the temperature T and the phase transition temperature T c. At small values of P/T impurities segregate on a phase boundary, and the degree of this segregation, i.e, the height of the maximum of c _im(x), in the region of the boundary increases exponentially as the ratio T _c/T increases. For P ≠ 0 the c _im(x) profile near a phase boundary is asymmetric, and as P/T increases, it takes on the form of a “worn step.” The maximum on the c _im(x) curve then decreases, and at a certain |P|≳T _c it vanishes. Segregation on an antiphase boundary is investigated in the case of CuZn ordering in a bcc alloy. The form of c _im(x) near an antiphase boundary depends significantly both on the form of the potential P and on the stoichiometry of the alloy. At small P impurities segregate on an antiphase boundary, and at fairly large P “antisegregation,” i.e., a decrease in the impurity concentration on the antiphase boundary in comparison with the value within the antiphase domains, is also possible. Zh. éksp. Teor. Fiz. 112, 714–728 (August 1997)     

Dynamics of the infinite-range ising spin glass

The Glauber dynamics of an Ising spin glass with infinite-range interactions and additional static field, h, is investigated near the freezing temperature, T_f. We obtain critical slowing down at and below the de Almeida-Thouless instability line, h_c(T), to order (1?T/T_f)³ with algebraic decay of the spin correlations ～t^?ν, where $\text{ν=}\text{1}\text{2}$ at T_f and $\text{ν≤}\text{1}\text{2}$ for T<T_f.