Die charakteristische Thermokraft der Grenzflächenatome

For a single-band conductor where two or more scattering mechanisms are present, each giving rise to a characteristic thermoelectric powerS _n and a electrical resistivity? _n the resultant thermoelectric powerS is given, as a first approximation, by\(S = \sum\limits_n {\varrho _n S_n /\varrho } \). Denoting withS ₀ the characteristic thermoelectric power due to the scattering of the conduction electrons by the boundary atoms, and withS _i and? _i the resultant thermoelectric power and electrical resistivity arising from all other scattering mechanisms, one may writeS=S ₀+? _i(S _i?S ₀)/?. The thermoelectric powerS and the electrical resistivity? of thin layers of potassium, evaporated in a vacuum ～5·10^?9 Torr on a glass substrate at 90° K temperature, were measured at different thicknesses. The variation ofS as a function of 1/? verifies the above mentioned relation. Thus, the thermoelectric power, characteristic for the scattering by potassium boundary atoms can be determined.     

Precision measurements of optical excitation functions for the mercury atom

We describe a computer-based facility for studying the excitation of atoms by ultramonochromatic electrons and give optical excitation functions for the 12 mercury spectral lines that originate from the n ¹ S ₀, n ¹ P ₁, n ¹ D ₂, n ³ S ₁, n ³ P _j , and n ³ D _j levels. We detected about 100 features in the energy dependences measured from the excitation threshold to 15.5 eV. The previously found positions of the features on the energy scale are in good agreement with our results. Most of the resonant features are shown to be mainly attributable to the decay of short-lived states of the negative mercury ion. We detected a postcollision interaction effect in the optical excitation functions of the lines that originate from the n ¹ S ₀ levels at energies of about 11 eV.     

Probabilities of radiative dipole transitions of parahelium in an electric field

Quadratic Stark corrections to the wave functions, matrix elements, and probabilities of transitions between the singlet states ¹ S ₀ and ¹ P ₁ of helium atoms are calculated. The coefficients of the polynomials that depend on the effective principal quantum number of the upper level v _f and that approximate the numerical values of the polarizabilities, the quadratic corrections to the wave functions, and the probabilities of transitions to highly excited Rydberg states with large v _f are determined. The results of calculations testify that the probabilities of all σ transitions n _i ¹ S ₀ → n _f ¹ P ₁ and π transitions to the states with n _f > n _i /2 are decreased with increasing electric field strength, except for the transition 2¹ S ₀ → 2¹ P ₁, whose probability increases both for σ and for π transitions.     

Spin-selective low temperature spectroscopy on single molecules with a triplet-triplet optical transition: Application to the NV defect center in diamond

The spin-selective photokinetics of a single matrix-isolated impurity molecule with a triplet-triplet optical transition, T ₀–T ₁, is considered and the manifestations of the photokinetics in the fluorescence excitation spectra and intensity autocorrelation functions g ⁽²⁾(τ) of the molecule undergoing narrow-band optical excitation is studied to resolve the fine structure of the transition. The rates of intersystem crossings (ISCs) T ₁→S→T ₀ to and from a nonradiating singlet state S of the molecule and the rate of population relaxation among the ground (T ₀) state sublevels can be obtained from the spectra and g ⁽²⁾(τ) using the analytical expressions obtained. New experiments on an individual NV defect center in nanocrystals of diamond, where, for the first time, the fine structure of its triplet-triplet ³ A-³ E zero-phonon optical transition (~637 nm) at 1.4 K was resolved, are interpreted. It is concluded that the rate of the ISC transition from the m _S =0 sublevel of the excited ³ E state to the singlet ¹ A state (~1 kHz) is much slower than the rates from the m _S =±1 substates, while the rates of ISC transitions to different m _S substates of the ground ³ A state are close to each other (~1 Hz). As a result, only the optical transition between m _S =0 sublevels in the ³ A-³ E manifold contributes strongly to the fluorescence. The experimentally observed double-exponential decay of the g ⁽²⁾(τ) function is explained by the two pathways available to the center for it to leave the S state: (i) the S→ T ₀(m _S )=0) transition and (ii) the S→T ⁰(m _S =±1) transitions followed by the slow spin-lattice relaxation T ₀(m _S =±1)→T ₀(m _S =0) (rate ~0.1 Hz). The work is important for studies where the NV center is used as a single photon source or for quantum information processing.     

Single and double spin asymmetries in the elastic <Emphasis Type="Italic">e</Emphasis>-<Emphasis Type="Italic">d</Emphasis> scattering and their dependence on the deuteron wave function

Single and double spin asymmetries in the elastic electron-deuteron (e-d ) scattering were investigated. The tensor-deuteron asymmetries T_2i(i = 0, 1, 2) and the beam-vector-deuteron asymmetries T ^e _1i(i = 0, 1) were calculated and compared with the available experimental data. The sensitivity of the results for these spin asymmetries to the deuteron wave function has been investigated. The predicted asymmetries were found to be agree with one another and with experiment. It was found that, the double spin asymmetry T ^e ₁₀ is much smaller than the T ^e ₁₁-asymmetry. Therefore, in addition to the single tensor-deuteron asymmetry T₂₀, the doubly beam-vector-deuteron asymmetry T ^e ₁₁ can be used as an another tool for extracting the deuteron electromagnetic form factors.     

Zur Chronologie des alten Ägypten

The velocityv of the propagation of discharge along the anode of a self-quenchingG—M-counter is a function of total pressureP, pressure of the quenching gasP _D, radius of the cathoder _a and of the anoder _i andV _ü the difference between working- and starting-potential. For the mixtures argon-methylal, argon-alcohol and helium-alcohol isv=v ₀·exp[k·(V _ü/V _e)^1/2] withv ₀ the velocity at the starting potentialV _e v ₀=(a+b·P _D/P)·V _n ^1/2 ·exp [(c?d·P_D/P·V _n ^?1/2 ] andV _n=V _e·(lnr _a/r _i)^?1.k, a, b, c andd are characteristical constants of the filling gas.     

Spin-orbit interactions in heterocyclic analogues of fluorene

For carbazole, dibenzofuran, and dibenzothiophene—heterocyclic analogues of fluorene containing N-H, O, and S groups, respectively—the transition dipole moments P ₀₀ ⁱ for the transitions ³ B ₂→S ₀ and ³ A ₁→S ₀ from the sublevels i=z, y, x of the triplet electronic ππ* states, which are caused by intramolecular spin-orbit (SO) interactions, are calculated. The effect that the SO coupling between the S ₀ state and highest triplet states has on the calculation results is considered. The effects exerted on the value of P ₀₀ ⁱ by such specific features of the molecular structure as the position of a heteroatom on the symmetry axis, its valence, and different constants of SO coupling in heteroatoms are discussed. The reason for the weak influence of the quantity ?_HA on the rate constant of radiative deactivation of the lowest T state is ascertained.     

The Rank-One Separable Interaction Kernel for Nucleons with Scalar Propagator

In the paper the covariant kernel of the nucleon-nucleon interaction of particles with scalar propagators is analyzed. The Bethe–Salpeter equation for the T matrix is considered in the rank-one separable kernel. The parameters of the kernel for the specific partial-wave channels explicitly connect with the observables low energy scattering parameters and phase shifts, deuteron binding energy. Covariant separable kernels for the partial-wave channels with total angular momentum J = 0 (¹S₀, ³P₀) and J =1 (³S₁ ? ³D₁, ¹P₁, ³P₁) are constructed.     

Mechanism of charge transfer in <Emphasis Type="Italic">n</Emphasis>-CdS/<Emphasis Type="Italic">p</Emphasis>-CdTe heterojunctions

The capacitance-voltage and current-voltage characteristics of the n-CdS/p-CdTe heterosystem are investigated. Analysis of these characteristics demonstrates that the CdTe_1?x S _x solid solution formed at the n-CdS/p-CdTe heterointerface is inhomogeneous in both the conductivity and composition. The thickness of solid solutions is estimated from the capacitance-voltage characteristics. It is shown that, for the n-CdS/p-CdTe heterosystem, the current-voltage characteristic in the current density range 10^?8-10^?5 A cm^?2 is governed by the thermal electron emission, whereas the current in the heterostructure at current densities in the range 10^?4-10^?2 A cm^?2 is limited by recombination of charge carriers in the electroneutral region of the CdTe_1?x S _x solid solution. The lifetime and the diffusion length of minority charge carriers in the CdTe_1?x S _x solid solution and the surface recombination rate at the interface between the CdS layer and the CdTe_1?x S _x solid solution are determined. It is demonstrated that the n-CdS/p-CdTe heterostructure operates as a p-i-n structure in which CdTe is a p layer, CdTe_1?x S _x is an i layer, and CdS is an n layer.     

Screening of strongly charged macroparticles in liquid electrolyte solutions

A modified Poisson-Boltzmann model has been proposed which makes it possible to describe the screening of strongly charged macroparticles in liquid electrolyte Z: Z solutions in the case when parameter B= ZeQ₀/εRT?1(Q₀ is the surface electric charge, T is the temperature, ε is the solution permittivity, and Z is the valence of ions) provided that the solution is dilute: κR ≡ (8πZ²e²n_i0/εT)^1/2R?1 (n_i0 is the equilibrium number density of ions). It is assumed that the charge Q₀ of a macroparticle appears as a result of adsorption of ions of a certain polarity on its surface. Quantitative criteria of division of dissolved ions into capable and incapable of adsorption are formulated. For aqueous solutions, the adsorption mechanism always leads to values of B ? 1. It is shown that the charge inversion effect predicted by other authors on the basis of different models must be observed for such solutions for all Z ≥ 1. The effect of Brownian movement of macroparticles on their screening is considered. It is shown that viscous forces emerging during such movement lead to peripheral destruction (“washing out”) of the screening ionic shell of macroparticles and, as a result, to violation of their electroneutrality. This results in the emergence of two types of oppositely charged compound particles with small radii close to R and with radii much larger than R, the charge polarity of the latter being opposite to the polarity of Q₀. It is found that both types of ions of compound particles obey the “law of distribution” of the mean energy of their electric field, expressed by formula (29). The problem of ionic screening of gas bubbles accompanied by the formation of bubstons (bubbles stabilized by ions) is considered separately. It is shown that the bubston radius R in pure water and in aqueous solutions of electrolytes is equal to 14 nm irrespective of the ion number density n_i0. The value of n_i0 determines the number density n _b of bubstons themselves, which are formed spontaneously under equilibrium conditions.     

Polarization of phosphorescence transitions and probabilities of intramolecular nonradiative deactivation of the lowest triplet state of aromatic molecules

This study continues the experimental testing of the validity of the inductive resonance theory of dipole-dipole energy transfer from the T ₁→S ₀ transition dipole to stretching vibrations of intramolecular CH bonds of naphthalene and its hydroxy derivatives. To this end, in the series of compounds under study, the range of variation of the geometrical parameter [Φ(CH)]² of the Förster theory, which accounts for the mutual orientation of the energy donor and acceptor, is estimated. Preliminarily, the angles between the transition dipole moments of the radiative and absorptive electronic transitions (T ₁→S ₀ and S ₀→S ₁; T ₁→S ₀ and S ₀→S ₂; S ₁→S ₀ and S ₀ →S ₁; and S ₁→S ₀ and S ₀→S ₂) are measured at 77 K by the method of polarization photoselection. From the polarization measurements, the angles between the phosphorescence transition dipole moment and the plane of a molecule are determined. It was found that, upon passage from naphthalene to its β derivatives, the orientation of the dipole moment of the radiative T ₁→S ₀ transition relative to the plane of a molecule markedly changes, with the in-plane component of the dipole moment being increased by an order of magnitude. The experimentally determined rate constants of nonradiative deactivation of the T ₁ state averaged over the CH groups of the naphthalene ring system, k _nr(CH), are compared with the rate constants [Φ(CH)]² of the inductive resonance energy transfer from the dipole of the T ₁→S ₀ transition to the dipole of the CH vibrations polarized in the plane of a molecule, calculated with regard to the orientational factor [Φ(CH)]². This comparison showed that, in the series of compounds under study, a change in the orientation of the dipole moment of the radiative T ₁→S ₀ transition relative to the plane of a molecule does not affect the rate of the nonradiative T ₁?S ₀ transition. This inference is confirmed by the absence of a correlation between the rate constants k _dd(CH) calculated by us (with regard to [Φ(CH)]²) and the well-known rate constants k _nr(CH) of individual sublevels of the T ₁ state measured at T≤1.35 K for a number of organic molecules. The possible sources of discrepancy between the experimental data that k _nr(CH) is independent of [Φ(CH)]² and the predictions of the theory are considered. A conclusion is made that the electronic-vibrational energy transfer between electric dipoles is the most probable mechanism of the T ₁?S ₀ transitions, but the rate constant of the dipole-dipole energy transfer upon interaction of the electronic and vibrational dipoles in a molecule does not depend on their orientations.     

Calculation of the diffusion coefficient in acoustic turbulence

The first (Born) approximation commonly used to calculate the diffusion coefficient D_T of a passive scalar in acoustic turbulence is shown to be insufficient. Even for a small main parameter—the Mach number, M?1—the next approximation gives a larger contribution to D_T than does the first approximation, but negative in sign. We present a procedure for correctly calculating D_T based on the solution of a nonlinear DIA (direct interaction approximation) equation for the mean Green’s function of the problem. We include an additional term in the general formula for D_T that directly describes the compressibility of acoustic turbulence. This term has not been known previously and has been disregarded even in the Born approximation. A positive value was obtained for D_T=CM³u₀/p₀. The spectrum E(x) was assumed to be smooth at distances Δ x～M²?1.     

Thermodynamic study of compounds of the Nd-Ba-Cu-O system

Standard enthalpies of formation for solid solutions of composition Nd_{1 + x} Ba_{2 ? x} Cu₃O _y (x = 0–0.8, y = 6.65–7.24) from oxides were determined by solution calorimetry. The heat capacity of NdBa₂Cu₃O_6.87 phase was measured in the range 5–320 K by low-temperature adiabatic calorimetry. The absolute entropy S ^o(T), the difference of enthalpies H ^o(T)-H ^o(0 K), and the reduced Gibbs energy Φ^o(T) = S ^o(T)–[H ^o(T)–H ^o(0)]/T were calculated on the basis of smoothed dependence C _p (T) in the 0–320 K range. An assessment was made for the heat capacities and the absolute entropies of solid solutions Nd_1+x Ba_2?x Cu₃O _y . The obtained set of thermodynamic parameters can be used for the calculation of phase equilibria in the Nd-Ba-Cu-O system.     

Finite size and surface effects on the magnetic properties of cobalt ferrite nanoparticles

Cobalt ferrite, CoFe₂O₄, nanoparticles in the size range 2–15 nm have been prepared using a non-aqueous solvothermal method. The magnetic studies indicate a superparamagnetic behavior, showing an increase in the blocking temperatures (ranging from 215 to more than 340 K) with the particle size, D _TEM. Fitting M versus H isotherms to the saturation approach law, the anisotropy constant, K, and the saturation magnetization, M _S, are obtained. For all the samples, it is observed that decreasing the temperature gives rise to an increase in both magnetic properties. These increases are enhanced at low temperatures (below ~160 K) and they are related to surface effects (disordered magnetic moments at the surface). The fit of the saturation magnetization to the T ² law gives larger values of the Bloch constant than expected for the bulk, increasing with decreasing the particle size (larger specific surface area). The saturation magnetization shows a linear dependence with the reciprocal particle size, 1/D _TEM, and a thickness of 3.7 to 5.1 Å was obtained for the non-magnetic or disordered layer at the surface using the dead layer theory. The hysteresis loops show a complex behavior at low temperatures (T ≤ 160 K), observing a large hysteresis at magnetic fields H > ~1000 Oe compared to smaller ones (H ≤ ~1000 Oe). From the temperature dependence of the ac magnetic susceptibility, it can be concluded that the nanoparticles are in magnetic interaction with large values of the interaction parameter T ₀, as deduced by assuming a Vogel–Fulcher dependence of the superparamagnetic relaxation time. Another evidence of the presence of magnetic interactions is the almost nearly constant value below certain temperatures, lower than the blocking temperature T _b, observed in the FC magnetization curves.     

Ion dynamics in methylcellulose–LiBOB solid polymer electrolytes

A polymer electrolyte system comprising methylcellulose (MC) as the host polymer and lithium bis(oxalato) borate (LiBOB) as the lithium ion source has been prepared via the solution cast technique. The electrolyte with the highest conductivity of 2.79 μS cm^?1 has a composition of 75 wt% MC–25 wt% LiBOB. The mobile ion concentration (n) in this sample was estimated to be 5.70?×?10²⁰ cm^?3. A good correlation between ionic conductivity, dielectric constant, and free ion concentration has been observed. The ratio of mobile ion number density (n) at a particular temperature to the concentration n ₀ of free ions at T?=?∞ (n/n ₀) and the power law exponents (s) exhibit opposite trends when varied with salt concentration.     

Spin-Wave Resonance in Ge : Mn Thin Films with Percolation Magnetic Ordering

The mechanism of excitation and propagation of spin waves in Ge: Mn thin films with different nominal manganese concentrations (2, 4, and 8 at % Mn) with percolation magnetic ordering is explored. Concentration dependencies of Curie temperature T_C(n) and spin wave rigidity D(n) are determined, which enables to find the index of correlation distance. An exotic percolation magnetic state of samples of Ge: Mn thin films is confirmed by rectifying experimental dependences D(n) and D/T_C(n) in coordinates accepted in the percolation theory.     

Colormagnetic confinement in the quark–gluon thermodynamics

Nonperturbative effects in the quark–gluon thermodynamics are studied in the framework of vacuum correlator method. It is shown, that for T > T ₀ = 175 MeV two correlators: colorelectric D ₁ ^E (x) and colormagnetic D ^H (x), provide the Polyakov line and the colormagnetic confinement in the spatial planes respectively. As a result, both effects produce the realistic behavior of p(T) and I(T), being in good agreement with numerical lattice data.     

Precision measurements of optical excitation functions for the cadmium atom

An experimental setup and a technique for the investigation of excitation of atoms by ultramonoenergetic electrons are described. The optical excitation functions are given for 14 spectral lines of the cadmium atom originating from the n ¹ S ₀, 5¹ P ₁, n ³ S ₁, 5³ P ₁, and n ³ D _j levels. More than 150 specific features are found in the energy dependences of the effective excitation cross sections measured from the excitation threshold to 16 eV. The most pronounced of these features are in good agreement with the fine structure observed previously. The main mechanisms of the initial-level population, namely, the direct transition of an electron from the ground atomic state to the initial level of a spectral line, the population of the initial levels due to the decay of short-lived states of a negative ion, and the cascade population, are separated. In the excitation functions of the lines originating from the n ¹ S ₀ levels, in the energy range from 10.9 to 12.4 eV, we observed for the first time an effect of postcollision interactions of emitted and scattered electrons in the vicinity of the thresholds of four autoionization states of the cadmium atom.     

Role of initial correlation in coarsening of a ferromagnet

We study the dynamics of ordering in ferromagnets via Monte Carlo simulations of theIsing model, employing the Glauber spin-flip mechanism, in space dimensionsd = 2 and3, on square and simplecubic lattices. Results for the persistence probability and the domain growth arediscussed for quenches to various temperatures (T _f ) below the criticalone (T _c ), from differentinitial temperatures T _i ≥T _c . In long timelimit, for T _i >T _c ,the persistence probability exhibits power-law decay with exponents θ ? 0.22 and? 0.18 in d = 2 and 3, respectively. For finite T _i , the early timebehavior is a different power-law whose life-time diverges and exponent decreases asT _i →T _c . The two steps areconnected via power-law as a function of domain length and the crossover to the secondstep occurs when this characteristic length exceeds the equilibrium correlation length atT =T _i . T _i =T _c is expected toprovide a new universality class for which we obtain θ ≡θ _c ? 0.035 ind = 2 and?0.105 in d = 3. The time dependenceof the average domain size ?, however, is observed to be rather insensitive tothe choice of T _i .