Effects of applied DC/AC fields in electrical fixing process with SBN:60

We present experimental investigations of electrical fixing techniques in Ce:SBN:60. The effect of crystal fatigue on the diffraction efficiency of electrically fixed photorefractive gratings is studied. We observed that applying an ac field to the crystal eliminated crystal fatigue and improved diffraction efficiency. A controllable diffraction efficiency of a photorefractive grating is presented. A reproducible diffraction efficiency of up to 75% is obtained using a write-reveal grating technique with high-voltage pulses of opposite polarity. We also show that the diffraction efficiency can be controlled by varying the intensity of the writing beams incident to the crystal during the recording process. A method of determining the hysteresis loop using the domain-fixing technique is proposed. The dependence of the diffraction efficiency on the direction of the applied electric field while writing the hologram is studied. Our experiments show that, during writing, when the electric field is applied opposite to the c axis the grating can be successfully revealed with both positive and negative dc voltages. However, when the grating is written with a field parallel to the c axis, the grating can be revealed only with a field applied in the opposite direction. Received: 28 October 2002 / Revised version: 28 February 2003 / Published online: 14 May 2003 RID="*" ID="*"Corresponding author. Fax: +1-812/872-6167, E-mail: azad.siahmakoun@rose-hulman.edu     

Crystal structure, morphology, depth profile of elements and mid-infrared optical constants of ‘mild’ lead telluride film

The characterizations of a so-called ‘mild’ PbTe layer thermal-evaporated from an excess of Te (<1 mol.%) evaporable materials are reported. The results reveal that the film obtained is polycrystalline and has a single-phase NaCl-type PbTe crystal structure. It is also demonstrated that the film has a homogeneous surface morphology and a high degree of homogeneous distribution of Te-rich components along the layer. The study of mid-infrared optical constants of a surface-polished film indicates that the influence of surface scattering on optical properties is very small. Received: 3 July 2002 / Accepted: 7 August 2002 / Published online: 4 December 2002 RID="*" ID="*"Corresponding author. Fax: +86-21/6516-9946, E-mail: lbincome@yahoo.com     

High-power laser interactions with nanostructured materials

We use short-pulse high-power lasers to selectively modify the structure of nanolaminates and nanocrystals. It is demonstrated that femtosecond pulses can achieve excellent results for microscopic thin film removal. Laser pulses can also be used to modify the crystal structure of thin films. It is also demonstrated that coherent laser excitation promotes a selective modification of nanocrystals, resulting in changes of size, shape, and crystal structure. Received: 7 October 2002 / Accepted: 20 January 2003 / Published online: 28 May 2003 RID="*" ID="*"Corresponding author. Fax: +1-414/229-5589, E-mail: yakovlev@uwm.edu     

Second-order grazing-angle scattering in uniform wide holographic gratings

Grazing-angle scattering (GAS) is a type of Bragg scattering in slanted wide periodic gratings. It occurs when the diffracted order satisfying the Bragg condition (scattered wave) propagates at a grazing angle to the grating boundaries. Previous research has been concerned only with first-order GAS, which has been shown to be a highly unusual type of scattering characterised by a strong resonant increase of amplitudes of the scattered and incident waves in the grating. In this paper, a rigorous numerical study of second-order GAS is presented for the case of bulk TE electromagnetic waves in planar holographic gratings. A highly unusual pattern of strong resonances in the grating, which is strongly different from that for first-order GAS, is predicted, described, and discussed. Physical interpretations of the predicted results are presented. In particular, a special new type of eigenmodes in a slanted wide periodic grating with large amplitude is predicted. These eigenmodes are shown to be guided by the grating alone without any conventional guiding effect in the structure. The typical field structure in such eigenmodes is investigated and discussed. Received: 16 September 2002 / Revised version: 4 November 2002 / Published online: 22 January 2003 RID="*" ID="*"Corresponding author. Fax: +61-7/3864-9079, E-mail: d.pile@osa.org     

Preparation of one-dimensional porous silicon photonic quantum-well structures

One-dimensional porous silicon (PSi) photonic quantum-well structures have been electrochemically fabricated and spectroscopically characterized. The photonic well in the structure is a photonic crystal (PC) consisting of alternately stacked high- and low-refractive-index PSi layers. Discrete states are observed in both reflectance and transmission spectra. It is found that the number of confined states appearing in the photonic bandgap of the photonic barrier depends on the number of periods adopted in the well PC. Thus, increased confined photonic states can be created simply by increasing the number of periods of the well PC in the structures. Received: 26 February 2002 / Accepted: 17 May 2002 / Published online: 4 December 2002 RID="*" ID="*"Corresponding author. Fax: +86-21/6510-4949, E-mail: xyhou@fudan.edu.cn     

Multiply scattered component of lidar returns

The results of statistical simulation of the spatiotemporal structure of the multiply scattered component of lidar returns by the Monte Carlo method are discussed for the case of monostatic sensing geometry. The spatial characteristics of the region of the medium where occurs the last scattering of photon before arriving at the reciever. This region of the medium is called the instantaneous brightness body of multiply scattered radiation. It is demonstrated that the instantaneous brightness body of multiply scattered radiation that propagates toward the receiver may occupy a large volume that does not necessarily coincide with the region of formation of the singly scattered component. The main factors influencing the spatial and brightness characteristics of this volume source are established. The effect of scattering order on the spatiotemporal structure of lidar returns is analyzed for the case of sensing of aerosol haze and advective and radiative fogs with optical thickness 2<τ<8. Received: 2 August 2001 / Revised version: 7 January 2002 / Published online: 25 September 2002 RID="*" ID="*"Corresponding author. Fax: +7-38/2225-8026, E-mail: belov@iao.ru     

Influence of stress relief on hysteretic magnetoimpedance in Co-rich amorphous ribbons at the relaxation frequency

The magnetoimpedance response shown by amorphous and nanostructured ultrasoft magnetic materials is a very promising effect suitable for application in a great variety of fields, as magnetic stress, strain or torsion sensors. However, magnetoimpedance hysteresis, which is related to irreversibilities in transverse magnetization processes, is an undesired effect for technological devices. Various thermal treatments were performed on Co-rich amorphous alloys to obtain quasi-reversible magnetoimpedance. Stress-relief-like treatments were found to reduce in a very significant way the hysteretic behaviour. Moreover, this improvement was analysed at the relaxation frequencies of the samples, where the magnetoimpedance has its maximum value. An attempt to understand the origin of this hysteresis reduction is given in this paper. The proposed explanation is based on the improvement of the reversibility in the magnetization processes, as a consequence of the decrease in the anelastic component of the induced anisotropy and the removal of wall pinning centres. Received: 2 October 2002 / Accepted: 7 October 2002 / Published online: 15 January 2003 RID="*" ID="*"Corresponding author. Fax: +34-98/510-3324, E-mail: grande@pinon.ccu.uniovi.es     

Wetting and scanning force microscopy on rough polymer surfaces: Wenzel’s roughness factor and the thermodynamic contact angle

The influence of the surface roughness of polypropylene on the contact angle hysteresis is investigated by means of ethylene glycol drops in order to estimate the true Young’s equilibrium contact angle. A new relationship between the contact angle hysteresis and Wenzel’s contact angle is derived. In addition, the determination of Wenzel’s roughness factor by means of scanning force microscopy opens an alternative way to obtaining Young’s equilibrium contact angle without any surface manipulation. The experimental results presented verify this new approach. Received: 2 September 2002 / Accepted: 2 September 2002 / Published online: 5 March 2003 RID="*" ID="*"Corresponding author. Fax: +49-3328/352-452, E-mail: helmut.kamusewitz@gkss.de     

Interaction of two light beams with different polarizations in TGS

By ellipsometric measurements we have observed the polarization variations of the primary light beam, with wavelength λ₁=5145 ?, interacting with the secondary light beam of controlled variable polarization, transmitted through a TGS crystal layer. We present a theoretical explanation based on the second-order optical nonlinearity of TGS. Received: 4 December 2001 / Revised version: 28 May 2002 / Published online: 25 October 2002 RID="*" ID="*"Corresponding author. Fax: +48-22/660-5447, E-mail: petyk@if.pw.edu.pl     

Statistical modeling of imaging process in active night vision systems with gate-light detection

Characteristics of object images observed through scattering media with an active vision system operating in the mode of spatial selection are estimated using the Monte Carlo method. The effect of optical and geometrical conditions of observation on the contrast in images of reflecting objects is considered. Interpretation is given to the obtained dependences. Received: 11 February 2002 / Revised version: 31 May 2002 / Published online: 25 October 2002 RID="*" ID="*"Corresponding author. Fax: +7-38/2225-9086, E-mail: belov@iao.ru     

Property study of Si + -ion-implanted Nd:YVO 4 waveguides

Planar waveguides were formed in Nd:YVO₄ crystals by 3.0-MeV Si⁺-ion implantation at doses of 1×10¹³–1.5×10¹⁵ ions/cm² at room temperature. The effective refractive indices of the waveguide propagation modes were measured by using a prism-coupling method. It was found that the number of the propagation modes is dependent on the doses for the waveguides in Nd:YVO₄. The atom displacement in the near-surface region (about 2 μm beneath the surface) of the Nd:YVO₄ crystal induced by the implantation was simulated by using the TRIM 98 (transport and range of ions in matter) code. The possible reasons for the waveguide formation are discussed in a primary way. Received: 17 July 2002 / Revised version: 20 September 2002 / Published online: 11 December 2002 RID="*" ID="*"Corresponding author. Fax: +86-531-8565167, E-mail: drfchen@sdu.edu.cn     

In situ synthesis of mesoporous CdS nanoparticles in ternary cubic phase lyotropic liquid crystal

An in situ technique for the synthesis of CdS nanoparticles in a ternary lyotropic cubic phase liquid crystal has been carried out. The extremely viscous cubic phase liquid-crystal system consists of poly(oxyethylene)₁₀ nonyl phenol ether as non-ionic surfactant, octane as oil phase and an aqueous phase containing reactant ions (Cd²⁺ and S^2-). Thioacetamide (TAA) has been utilized as a source for slow release of sulfur in the in situ synthesis of CdS. Rheological results show that CdS nanoparticle growth did not disrupt the structure of the cubic phase liquid-crystal system. This indicates that homogenous synthesis of CdS in the liquid crystal had been achieved. The final products were characterized using X-ray photoelectron spectroscopy, thermal gravimetric analysis, transmission electron microscopy and UV-visible spectroscopy. It was found that the CdS nanoparticles formed have a mesoporous structure with a size dependent on the TAA decomposition aging time. Received: 29 March 2002 / Accepted: 4 September 2002 / Published online: 17 December 2002 RID="*" ID="*"Corresponding author. Fax: +603-8921/3257, E-mail: shahidan@pkrisc.cc.ukm.my     

Ordered thin films of alkyloxy-substituted benzaldehydes on a graphite surface studied by scanning tunneling microscopy

The molecular assembly of three different trialkyloxy-substituted benzaldehydes on graphite has been studied using scanning tunneling microscopy (STM). It is found that these benzaldehydes, which do not have intermolecular hydrogen bonding, could form a lamella arrangement in which the headgroups are aligned side by side. The effect due to the alkyl chain length on the lamella structure is also presented. Received: 21 January 2002 / Accepted: 22 March 2002 / Published online: 10 September 2002 RID="*" ID="*"Corresponding author. Fax: +86-10/6255-7908     

Analysis of the concentration of C60 fullerenes in single wall carbon nanotubes

Single wall carbon nanotubes filled with C₆₀ were analyzed using resonance Raman scattering and electron energy loss spectroscopy. In order to obtain concentrations of the fullerene molecules inside the tubes, the scattering intensity from the fullerenes relative to that from the tubes was used. Since the scattering intensity from the tubes is subject to strong fluctuations, the determination of the concentrations is shown to require averaging of results from different lasers and from all observable Raman lines. The fluctuations are shown to be intrinsic and a consequence of photoselective resonance scattering. Calibration of absolute concentrations can be obtained from electron energy loss spectroscopy performed on the same samples. Samples with three different diameters were analyzed and good agreement between the fullerene concentrations measured by the two methods was obtained. Received: 20 September 2002 / Accepted: 4 November 2002 / Published online: 10 March 2003 RID="*" ID="*"Corresponding author. Fax: +43-1/4277-51375, E-mail: kuzman@ap.univie.ac.at     

Elastic modulus-density relationship for amorphous boron suboxide thin films

Boron suboxide thin films have been deposited on Si(100) substrates by reactive RF magnetron sputtering of a sintered B target in an Ar/O₂ atmosphere. Elastic recoil detection analysis was applied to determine the film composition and density. Film structure was studied by X-ray diffraction and transmission electron microscopy. The elastic modulus, measured by nanoindentation, was found to decrease as the film density decreased. The relationship was affected by tuning the negative substrate bias potential and the substrate temperature during film growth. A decrease in film density, by a factor of 1.55, caused an elastic modulus reduction by a factor of 4.5, most likely due to formation of nano-pores containing Ar. It appears evident that the large scattering in the published data on elastic properties of films with identical chemical composition can readily be understood by density variations. These results are important for understanding the elastic properties of boron suboxide, but may also be qualitatively relevant for other B-based material systems. Received: 22 February 2002 / Accepted: 11 April 2002 / Published online: 10 September 2002 RID="*" ID="*"Corresponding author. Fax: +46-13/288-918, E-mail: denmu@ifm.liu.se     

Thermal lensing measurements and thermal conductivity of Yb:YAB

By using holographic shear interferometry, we have measured the thermal lens in a diode-pumped Yb:YAB crystal, under lasing and non-lasing conditions, as a function of absorbed power. From these purely optical measurements we estimate the fractional thermal loading and the thermal conductivity of Yb:YAB. Knowledge of these thermal parameters is essential for the optimisation of Yb:YAB laser cavity designs. Received: 5 February 2002 / Final version: 22 November 2002 / Published online: 26 February 2003 RID="*" ID="*"Corresponding author. Fax +61-2/9850-8915, E-mail: Judith@ics.mq.edu.au     

Extremely asymmetrical scattering in gratings with weak dissipation: some physical analogies

A detailed analysis of new effects related to extremely asymmetrical scattering (EAS) of bulk and guided weakly dissipating electromagnetic waves in oblique periodic gratings is presented. A very important role of the previously determined critical grating width is demonstrated for EAS in dissipative gratings. Incident and scattered wave amplitudes inside and outside the grating are analysed as functions of dissipation coefficient, grating width, grating amplitude, etc. Strong differences in the patterns of scattering in gratings that are narrower and wider than the critical width are demonstrated and discussed. Deep analogies between EAS and other resonant optical effects, such as attenuated total reflection, Fabry–Pérot interferometry, etc. are revealed and discussed. A physical interpretation of the obtained results is presented. Received: 19 February 2002 / Revised version: 28 June 2002 / Published online: 22 November 2002 RID="*" ID="*"Corresponding author. Fax: +61-7/3864-9079, E-mail: d.gramotnev@qut.edu.au     

High-repetition-rate eye-safe optical parametric oscillator intracavity pumped by a diode-pumped Q-switched Nd:YVO<Subscript>4</Subscript> laser

A high-repetition-rate eye-safe optical parametric oscillator (OPO), using a non-critically phase-matched KTP crystal intracavity pumped by an acousto-optically (AO) Q-switchedNd:YVO₄ laser, is experimentally demonstrated. It is found that the average OPO signal power at 1573 nm can be efficiently increased by increasing the pulse repetition rate. Moreover, the intracavity OPO process effectively shortens the pulse width so that it is in the range 5∼8 ns for pulse repetition rates of 10 to 80 kHz. As a result of the relatively short pulse, the peak power at 1573 nm is higher than 2 kW at a pulse repetition rate of 80 kHz. Received: 10 July 2002 / Published online: 26 February 2003 RID="*" ID="*"Corresponding author. Fax: +886-35/729-134, E-mail: yfchen@cc.nctu.edu.tw     

Extended defects in shallow implants

Extended defects are often found after ion implantation and annealing of silicon and they are known to affect dopant diffusion. The article reviews the structure and energetics of the most often found extended defects and describes the mechanisms by which all these defects grow in size and transform during annealing. Defects grow by interchanging the Si atoms they are composed of and thus maintain large supersaturations of free Si interstitials in the region. A model has been developped to describe such an evolution in presence of a free surface. It is shown that after low energy implantation, the surface of the wafer may recombine large amounts of these free Si interstitials, driving defects into dissolution before transformation into more stable forms. Received: 21 August 2002 / Accepted: 21 August 2002 / Published online: 12 February 2003 RID="*" ID="*"Corresponding author. Fax: +33-56/2257-999, E-mail: claverie@cemes.fr     

The interplay between geometry,electronic structure,and reactivity of Cu-Ni bimetallic (111) surfaces

The mutual influence of surface geometry (e.g. lattice parameters, morphology) and electronic structure is discussed for Cu-Ni bimetallic (111) surfaces. It is found that on flat surfaces the electronic d-states of the adlayer experience very little influence from the substrate electronic structure which is due to their large separation in binding energies and the close match of Cu and Ni lattice constants. Using carbon monoxide and benzene as probe molecules, it is found that in most cases the reactivity of Cu or Ni adlayers is very similar to the corresponding (111) single crystal surfaces. Exceptions are the adsorption of CO on submonolayers of Cu on Ni(111) and the dissociation of benzene on Ni/Cu(111) which is very different from Ni(111). These differences are related to geometric factors influencing the adsorption on these surfaces. Received: 26 August 2002 / Accepted: 4 September 2002 / Published online: 5 February 2003 RID="*" ID="*"Corresponding author. Fax: +44-1223/76-2829, E-mail: gh10009@cam.ac.uk [+1pt] Present address: University of Cambridge, Lensfield Road, Department of Chemistry, Cambridge CB2 1EW, UK