Shear Band Formation in Fe–Cr–Mo–V–B–Si Amorphous Alloy under Nanoindentation

The formation of shear bands in Fe–Cr–Mo–V–B–Si amorphous alloy under nanoindentation Is studied. The indentation process is considered against the background of shear band formation in the amorphous material.     

Direct measurement of static yield properties of cohesive suspensions

A technique of yield stress investigation based upon the combined use of two devices (an applied stress rheometer and an instrument for measuring the propagation velocity of small amplitude, torsional shear waves) is described. Investigations into the low shear rate rheological properties of illitic suspensions are reported for shear rates, typically, in the range 10^–4— 10^–1 s^–1 under applied stresses in the range 0.01 — 10 Nm^–2 and involving shear strains between 10^–1 and 10^–4. Results are presented which demonstrate that the technique does not invoke the excessive structural disruption of material associated with applied shear rate based methods (direct and otherwise) and the widely encountered problem of wall slip at the surface of rotational measuring devices is avoided using miniature vane geometries. Results are compared with those obtained using smooth-walled cyclindrical measuring devices in both applied stress and applied shear rate instruments.Yield measurements are considered in relation to the structural properties of the undisturbed material state and shear moduli obtained by studying the propagation of small amplitude (10^–5 rad), high frequency (~ 300 Hz) torsional shear waves through the test materials are reported. Experimental techniques and instrument modifications to permit these measurements are described.     

Modeling of blood rheological behavior in unsteady-state shearing flows

Issues of blood flow modeling under unsteady-state conditions at moderate shear rates are considered using a blood rheological model accounting both for the viscoelastic properties and the thixotropy caused by erythrocyte aggregation. The resulting shear stress versus time relations for single shear rate steps and the dependence of the complex viscosity components on the shear rate amplitude in oscillating shear flow show good qualitative correspondence with the experimental data reported in the literature.Moscow. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 6, pp. 26–30, November–December, 1995.     

Molecular theory for moderately concentrated polymer solutions in shear flow

A molecular theory for the rheological properties of moderately concentrated polymer solutions is developed on the basis of a model of interacting dumbbells. The interaction is treated in a mean field approximation, leading to an effective one-particle potential and a Gaussian stationary distribution function. Various rheological functions such as birefringence, shear viscosity and first normal-stress coefficient for simple shear flow and the Trouton viscosity for simple extensional flow are calculated. Good qualitative agreement with experimental observations is found, especially at intermediate flow rates. It is predicted, for example, that the birefringence increases approximately linearly with shear rate at intermediate shear rates and that the concentration dependence of the gradient varies asc ^1/2. The typical non-Newtonian behaviour is obtained for the shear viscosity. For small concentrations the onset of shear rate dependence decreases asc ^–1/2. At intermediate shear rates an apparent power law is obtained with an exponent between – 0.5 and – 1.0, decreasing with concentration.     

Viscosity of some clay-based coating colors at high shear rates

The shear viscosity of clay-based coating colors containing latex and carboxymethyl cellulose (CMC) has been measured over a relatively large shearrate region. In the shear-rate range of 50–1500 s^–1 the measurements were performed using a rotational viscometer and, at higher shear rates extending into the region 10⁵ – 10⁶ s^–1, a high pressure capillary viscometer was employed. The viscosity of the clay colors increased with increasing CMC-concentration, but the influence of the CMC-content was less pronounced at higher shear rates. The apparent shear-thinning behavior of the investigated colors could, in part, be attributed to the shear-thinning of the corresponding polymer (CMC) solution constituting the liquid phase of the color, but the influence of another factor was also indicated. At low shear rates, the interaction between the color components can produce relatively high viscosity levels, but in the high shear rate region these interactions appear to be less important for the viscosity level. It is also of interest to note that the viscosity dependence on the solids content in the high shear-rate region could be described with reasonable accuracy using an empirical equation neglecting interactions between the color components.     

New laboratory tests to measure rheological properties of paper coatings in transient and steady-state flows

The paper describes pertinent laboratory tests to characterize the rheological properties of paper coatings with regard to blade coating over a very wide range of shear rates in both transient and steady-state shear flows. Shear rates as high as 10⁶ s^–1 can be reached by means of a gas-driven capillary rheometer. Examples for the evaluation of end effects, wall effects, and coating thixotropy are given. A stiff and fast Couette rheometer is used to determine flow curves and the shear stress overshoot in step shear rate tests. The primary normal stress difference can be measured up to 10⁴ s^–1 by means of a high shear cone-plate rheometer with piezo transducer. A correct evaluation of the measurements has to take into account inertia contributions to the normal force. First results using a sinusoidal modulation of the shear rate are presented.Paper presented at: International Symposium on Pigment Coating Structure and Rheology, Helsinki, Febr. 8–9, 1989     

Viskositätsmessungen bei kleinen Schergefällen

Zusammenfassung Große, stark strukturierte Moleküle können Konformationswechselzeiten haben, die in der Größenordnung der Deformationsperiode bei der Scherung der Moleküle in Lösung liegen, wenn das Geschwindigkeitsgefälle kleine Werte annimmt. Es werden einige Viskosimeter beschrieben, die zur Untersuchung verdünnter Lösungen in einem Geschwindigkeitsgefälle-Intervall von 10^–2–10⁴ sec^–1 geeignet sind. Anhand von Messungen an DNA wird gezeigt, daß bei Geschwindigkeitsgefällen von 10 sec^–1 noch starke Strukturviskosität auftreten kann.

---

Summary Large strongly structured molecules may have change of constellation times comparable to the deformation period in shearing the molecules in solution, if the shear rate assumes low values. Several viscometers are described, which are suitable for the investigation of diluted solutions in a shear rates range of 10^–2–10⁴ sec^–1. With the help of measurements with DNA, it is shown that strong shear dependence is observed for shear rates of 10 sec^–1.

---

---

Vorgetragen auf der Rheologen-Tagung in Darmstadt am 7. und 8. Juni 1971

---

Diese Arbeiten wurden von der DFG im Rahmen des SFB 41 Mainz-Darmstadt unterstützt, wofür wir herzlich danken.     

The behaviour of field-responsive fluids during shear start-up

The application of an external field (magnetic or electric) to suspensions of particles in a carrier liquid often causes a dramatic increase in the flow resistance. The transient stress response of these systems during the start-up of shear flow was studied as a function of the shear rate, using a system of carbonyl iron particles dispersed in paraffinic spindle oil under magnetic flux densities up to 0.57 T. It was found that initially the stress increased in proportion to the applied strain, reaching a plateau value at a characteristic strain of 0.2. Similar strain dependence of the transient stress behaviour was observed for shear rates spanning the range 0.01 s^–1 to 10 s^–1, suggesting that strain-governed deformation and rupture of the particle aggregates in the fluid was the main contribution to the response. In addition, the steady state flow curves of these fluids were obtained over the shear rate range 0.1 to 100 s^–1.     

Shear flows of a liquid with a power-type rheological law in the presence of a constant transverse velocity component

Plane shear flows of dilatant liquids are considered in the presence of a constant transverse velocity component of the liquid; this component arises from uniform injection (or suction) at the bounding surfaces. It is shown that the presence of transverse drift in the liquid influences the rate of propagation of the leading edge of the shear waves, and this has a number of effects on the flows.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 4, pp. 15–21, July–August, 1973.     

Experimental study of shear flow instability

The results of experiments carried out in order to study the instability of a free shear layer of rotating barotropic fluid at high Reynolds numbers are presented.Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No.3, pp. 167–173, May–June, 1992.     

Hexagonal Defect Array Formed under Steady Shear Flow in Water-in-Cholesteric Liquid Crystal Emulsions

The relation between the liquid crystalline textures and the steady shear viscosity has been investigated in cholesteric emulsions, composed of water, surfactants, and cholesteric liquid crystals. Both at the substrate surface and at the surfactant-coated droplet surface, a homeotropic anchoring is enforced to the adjacent liquid crystal. Under a steady shear flow with the shear rate below 100 s^–1, we observed that point defects spontaneously appear, and tend to adopt a regular hexagonal arrangement in the low shear-rate range of 1–20 s^–1. In viscosity measurements, the shear-thinning behavior was found, showing a clear correspondence to the texture change. We estimated the height of point defects in the hexagonal array from the viscosity increase in the shear-thinning, assuming that the shear-thinning behavior is caused by the reduction of the effective gap between cone and plate, owing to the presence of the hexagonal array anchored on the plate. The relation between the estimated height and the measured lateral size of point defects agreed with that of the quadrilateral array, which is formed after termination of the shear. This agreement informs that the shape of a point defect is preserved in both defect arrays, independently of shearing conditions.     

Effect of the acoustic regularization of initial perturbations on the development of ordered structures

Mechanisms are considered by which acoustic oscillations influence the structure of subsonic shear flows. Analysis of the experimental data [1–7] confirms the assumption made in [6] that the regularization of initial perturbations, which causes a higher degree of ordering and an increase in the life of vortices formed because of the development of instability waves or interaction of acoustic oscillations with the edge of the nozzle, is one of the mechanisms by which acoustics influences various shear flows. Photographs are given which show the regularizing effect of acoustics on the development of vortices in the wake behind the edge.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 1, pp. 171–174, January–February, 1986.     

Dislocation Model of Polysynthetic Shear Bands in Amorphous Materials

A dislocation model for a polysynthetic shear band in an amorphous material is proposed. The stress fields near the polysynthetic shear band are calculated. The distribution of impurities in an amorphous binary Fe–B medium containing a polysynthetic shear band is determined.     

Re-examined principles of thrust generation by a track on soft ground

Dr. Bekker’s first book Theory of land locomotion offers in fact two different concepts of thrust generation on soft ground with respect to the slip: (a) as the push of grousers causing horizontal soil “distortion” and (b) as the shear force in the failure plane linked with the shear deformation. Bekker preferred the second concept and backed it up by the unique shear-ring measuring technique. To clear up the matter, the author decided to re-examine the thrust generation by a track plate experimentally in field conditions. The tests have shown that the initial stage of thrust generation in compressible ground is always horizontal soil compression by grousers, which divides the soil under a track into separate blocks initially at rest. This compression increases at least to the transition point, when a block is sheared off simultaneously at the bottom and in both lateral planes and starts sliding along the channel formed by the preceding grouser. The analysis of these measurements enabled to define the compressive displacement of the face of the soil block (travel of the grouser) appurtenant to the mentioned transition point, useful to define the thrust–slip curve. The case may also be described by the conventional shear stress–shear displacement relationship, imagined to take place in the bottom failure plane, however, namely the “shear displacement” is rather an unusual quantity.     

Active slip-band separation and the energetics of slip in single crystals

This research supports recent efforts to provide an energetic approach to the prediction of stress–strain relations for single crystals undergoing single slip and to give precise formulations of experimentally observed connections between hardening of single crystals and separation of active slip-bands. Non–classical, structured deformations in the form of two-level shears permit the formulation of new measures of the active slip-band separation and of the number of lattice cells traversed during slip. A formula is obtained for the Helmholtz free energy per unit volume as a function of the shear without slip, the shear due to slip, and the relative separation of active slip-bands in a single crystal. This formula is the basis for a model, under preparation by the authors, of hardening of single crystals in single slip that is consistent with the Portevin-Le Chatelier effect and the existence of a critical resolved shear stress.     

Gravitational sedimentation of aggregating particles in a shear flow

A theoretical model describing the sedimentation of aggregating particles under the influence of gravity in Couette shear flow is proposed. The relation between the parameters characterizing the dependence of the sedimentation properties on the shear rate and the parameters characterizing the aggregation of the particles is traced.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 95–98, March–April, 1989.The authors wish to thank S. A. Regirer for useful discussions.     

Response of flexure–torsion coupled composite thin-walled beams with closed cross-sections to random loads

A study of the flexure–torsion coupled random response of the composite beams with solid or thin-walled closed-sections subjected to various types of concentrated and distributed random excitations is dealt with in this paper. The effects of flexure–torsion coupling, shear deformation and rotary inertia are included in the present formulations. The random excitations are assumed to be stationary, ergodic and Gaussian. Analytical expressions for the displacement response of the composite beams are obtained by using normal mode superposition method combined with frequency response function method. The present method can produce the effective solutions for the composite Timoshenko beams with circumferentially antisymmetric (CAS) configuration and more general beam assemblages of connected beams. The influences of flexure–torsion coupling, shear deformation and rotary inertia on the random response of an appropriately chosen composite beam from the literature are demonstrated and discussed.     

Large thermal deflections of Timoshenko beams under transversely non-uniform temperature rise

Geometrically non-linear deformation of axially extensional Timoshenko beams subjected mechanical as well thermal loadings were characterized by a system of 7 coupled and highly non-linear ordinary differential equations, which results in a complicated two-point boundary-value problem. By using shooting method this kind of problem can be numerically solved efficiently. Based on the above-mentioned mathematical formulation and numerical procedure, analysis of large thermal deflections for Timoshenko beams, subjected transversely non-uniform temperature rise and with immovably pinned–pinned as well as fixed–fixed ends, is presented. Characteristic curves showing the relationships between the beam deformation and temperature rise are illustrated. Especially, the effects of shear deformation on the bending and buckling response are quantitatively investigated. The numerical results show, as we know, that shear deformation effects become significant with the decrease of the slenderness and with the increase of the shear flexibility.     

Shear dependence of viscosity for perfluoropolyether fluids

The shear dependence of the bulk viscosities of two structurally different types of perfluoropolyether fluids was determined by two different techniques. The first involved direct measurement in a high shear Couette viscometer, the second utilized the time-temperature superposition principle to establish master curves from viscosity determinations at low shear rates and temperature; the results are comparable. Both fluids begin to show non-Newtonian behavior at shear rates above 10,000 s^–1.