Study of material agglomeration during nozzle injection of multiviscosity liquid into a fluidized bed reactor by the electric conductance method

Fluidized bed agglomeration is an important and challenging problem for thermal cracking in fluid cokers. A low coker temperature can be problematic because the bitumen is injected into the fluidized bed with a different viscosity, resulting in formation of agglomerates of varying sizes, which slows the cracking reactions. In the present study, the bed material agglomeration process during nozzle injection of multiviscosity liquid was investigated in a fluidized bed operated at different mass ratios of the atomization gas to the liquid jets (GLR = 1%–3.5%) and gas velocities (3.9U_mf and 5.9U_mf) based on a conductance method using a water–sand system to simulate the hot bitumen–coke system at room temperature. During the tests of liquid-jet dispersion throughout the bed, different agglomeration stages are observed at both gas velocities. The critical amount of tert-butanol in the liquid jets that could lead to severe agglomeration of the bed materials (poor fluidization) at GLR = 1% is about 10 wt% at the low fluidizing gas velocity (3.9U_mf) and 18 wt% at the high gas velocity (5.9U_mf). This study provides a new approach for on-line monitoring of bed agglomeration during liquid injection to guarantee perfect contact between the atomized liquid and the bed particles.     

Fluid-dynamics evaluation in a conical spouted bed and characterization of foxtail millet seeds

Foxtail millet (Setaria italica) is one of the most valuable species in economic terms in the genus Setaria and plays an important role in human nutrition, animal feed, and agriculture. The present study described chemical, physical, and quality aspects of seeds of foxtail millet. Furthermore, the fluid-dynamic behavior of the seeds was evaluated in a conical spouted bed, which has advantages in terms of promoting the cyclic and regular movement of the seed particles. Dynamic parameters of spouting (minimum spouting velocity, stable and peak pressure drop) were determined and compared with those obtained from empirical correlations available in the literature. The results obtained from physical characterization showed that the seeds can be classified as belonging to Group D of Geldart, having a non-rough surface, mean diameter of 1.75 mm, and sphericity of 0.74. Fluid-dynamics analysis showed that the seeds are suitable for processing in a spouted bed, which is in agreement with the results of particle physical characterization.     

Modified correlation for minimum fluidization velocity of low-density particles in inverse liquid–solid fluidized beds

The minimum fluidization velocity (U_mf) is a key parameter for the scale-up of inverse liquid–solid fluidized beds. Theoretical predictions using common correlations were compared against experimental minimum fluidization velocity measurements of low density (28–638 kg/m³), 0.80–1.13 mm Styrofoam particles in a fluidized bed with a height of 4.5 m and 0.2 m diameter. The average absolute relative deviation for the predicted minimum fluidization velocity for particles below 300 kg/m³ was above 40% using the studied common correlations. A modified Wen and Yu correlation was thus proposed based on novel and past measurements with low-density and small-diameter particles, expanding the range for predicting U_mf. The new correlation predicted U_mf with deviations below 15% for ST028, ST122 and ST300. This modified correlation also improved U_mf predictions for comparable particles from a previous study, demonstrating its validity for a larger range of low-density particles.     

Effect of Gaussian size distribution width on minimum fluidization velocity in tapered gas–solid fluidized beds

This paper investigated the effect of Gaussian distribution width, average particle diameter, particle loading, and the tapered angle on minimum fluidization velocity (U_mf) by conducting extensive experiments in tapered fluidized beds. Three powders with Gaussian size distribution and different distribution widths were used in the experiments. An increase in U_mf with increasing the average particle diameter, particle loading, and the tapered angle was observed. There was also a nonmonotonic behavior of U_mf as the Gaussian distribution width increased. An empirical correlation including dimensionless groups for predicting U_mf in tapered beds was developed in which the effect of distribution width was considered. The proposed correlation predictions were in good agreement with the experimental data, with a maximum deviation of 16.5% and average and standard deviations of, respectively, 6.4% and 7.4%. The proposed correlation was also compared with three earlier models, and their accuracy was discussed.     

CFD-DEM simulation of spouting of corn-shaped particles

Three dimensionally coupled computational fluid dynamics (CFD) and discrete element method (DEM) were used to investigate the flow of corn-shaped particles in a cylindrical spouted bed with a conical base. The particle motion was modeled by the DEM, and the gas motion by the k-? two-equation turbulent model. A two-way coupling numerical iterative scheme was used to incorporate the effects of gas–particle interactions in terms of momentum exchange. The corn-shaped particles were constructed by a multi-sphere method. Drag force, contact force, Saffman lift force, Magnus lift force, and gravitational force acting on each individual particle were considered in establishing the mathematical modeling. Calculations were carried out in a cylindrical spouted bed with an inside diameter of 200 mm, a height of 700 mm, and a conical base of 60°. Comparison of simulations with experiments showed the availability of the multi-sphere method in simulating spouting action with corn-shaped particles, but it depended strongly on the number and the arrangement of the spherical elements. Gas–solid flow patterns, pressure drop, particle velocity and particle concentration at various spouting gas velocity were discussed. The results showed that particle velocity reaches a maximum at the axis and then decreases gradually along the radial direction in the whole bed. Particle concentration increases along the radial direction in the spout region but decreases in the fountain region, while it is nearly constant in the annulus region. Increasing spouting gas velocity leads to larger pressure drop, remarkably increased speed of particle moving upward or downward, but decreased particle concentration.     

Experimental study on the effect of drag reducing polymer on flow patterns and drag reduction in a horizontal oil–water flow

In this study, a HMW anionic co-polymer of 40:60 wt/wt NaAMPS/acrylamide was used as a drag reducing polymer (DRP) for oil–water flow in a horizontal 25.4 mm ID acrylic pipe. The effect of polymer concentration in the master solution and after injection in the main water stream, oil and water velocities, and pipe length on drag reduction (DR) was investigated. The injected polymer had a noticeable effect on flow patterns and their transitions. Stratified and dual continuous flows extended to higher superficial oil velocities while annular flow changed to dual continuous flow. The results showed that as low as 2 ppm polymer concentration was sufficient to create a significant drag reduction across the pipe. DR was found to increase with polymer concentration increased and reached maximum plateau value at around 10 ppm. The results showed that the drag reduction effect tends to increase as superficial water velocity increased and eventually reached a plateau at U_sw of around 1.3 m/s. At U_sw > 1.0 m/s, the drag reduction decreased as U_so increased while at lower water velocities, drag reduction is fluctuating with respect to U_so. A maximum DR of about 60% was achieved at U_so = 0.14 m/s while only 45% was obtained at U_so = 0.52 m/s. The effectiveness of the DRP was found to be independent of the polymer concentration in the master solution and to some extent pipe length. The friction factor correlation proposed by Al-Sarkhi et al. (2011) for horizontal flow of oil–water using DRPs was found to underpredict the present experimental pressure gradient data.     

Evaluation of the dimensionless groups based scale-up of gas–solid spouted beds

In this work, the scale-up methodology of He et al. (1997) that is based on maintaining similar or close dimensionless groups in gas–solid spouted beds has been evaluated. Two geometrically similar spouted beds of 0.152 m and 0.076 m diameter have been used. It has been demonstrated experimentally, that there is non-similarity in the local hydrodynamic parameters such as solids holdup and dimensionless solids velocity, when all the dimensionless groups have been matched or close to each other in the two studied spouted beds. This confirms that the global hydrodynamic parameters should not be used to confirm the validity of or to evaluate the dimensionless groups scale-up based methodologies.     

High photocatalytic efficiency of spouting reactor compared with fluidized bed with top irradiation source

The removal of volatile organic compounds by photocatalytic degradation is one of the safest and most effective ways of removing pollutants from the air. This process is highly affected by the type of reactor, light exposure, and hydrodynamics. For scale up purposes, continuous reactors with high capacity are required for treating large amounts of feedstock. In this work, two types of reactors based on different hydrodynamics, fluidized and spouted reactors, were designed to work under light irradiation inside the reactor. The efficiency of the reactors for volatile organic compound removal from high flow rates of air under Hg lamp irradiation using N–F-TiO₂ photocatalyst was investigated. The performance of the fluidized bed and spouted bed were evaluated and compared at the same weight hourly space velocity of feed stream through the reactor. The results revealed that 80% of the initial acetaldehyde was removed in the fluidized bed after about 200 min, while in the spouted bed the acetaldehyde was totally removed after about 120 min.     

Flow evolution of a turbulent submerged two-dimensional rectangular free jet of air. Average Particle Image Velocimetry (PIV) visualizations and measurements

The paper presents average flow visualizations and measurements, obtained with the Particle Image Velocimetry (PIV) technique, of a submerged rectangular free jet of air in the range of Reynolds numbers from Re = 35,300 to Re = 2200, where the Reynolds number is defined according to the hydraulic diameter of a rectangular slot of height H. According to the literature, just after the exit of the jet there is a zone of flow, called zone of flow establishment, containing the region of mixing fluid, at the border with the stagnant fluid, and the potential core, where velocity on the centerline maintains a value almost equal to the exit one. After this zone is present the zone of established flow or fully developed region. The goal of the paper is to show, with average PIV visualizations and measurements, that, before the zone of flow establishment is present a region of flow, never mentioned by the literature and called undisturbed region of flow, with a length, L_U, which decreases with the increase of the Reynolds number. The main characteristics of the undisturbed region is the fact that the velocity profile maintains almost equal to the exit one, and can also be identified by a constant height of the average PIV visualizations, with length, L_CH, or by a constant turbulence on the centerline, with length L_CT. The average PIV velocity and turbulence measurements are compared to those performed with the Hot Film Anemometry (HFA) technique. The average PIV visualizations show that the region of constant height has a length L_CH which increases from L_CH = H at Re = 35,300 to L_CH = 4–5H at Re = 2200. The PIV measurements on the centerline of the jet show that turbulence remains constant at the level of the exit for a length, L_CT, which increases from L_CT = H at Re = 35,300 to L_CT = 4–5H at Re = 2200. The PIV measurements show that velocity remains constant at the exit level for a length, L_U, which increases from L_U = H at Re = 35,300 to L_U = 6H at Re = 2200 and is called undisturbed region of flow. In turbulent flow the length L_U is almost equal to the lengths of the regions of constant height, L_CH, and constant turbulence, L_CT. In laminar flow, Re = 2200, the length of the undisturbed region of flow, L_U, is greater than the lengths of the regions of constant height and turbulence, L_CT = L_CH = 4–5H. The average PIV and HFA velocity measurements confirm that the length of potential core, L_P, increases from L_P = 4–5H at Re = 35,300 to L_P = 7–8H at Re = 2200, and are compared to the previous experimental and theoretical results of the literature in the zone of mixing fluid and in the fully developed region with a good agreement.     

Hydrodynamic behaviour of Cellets™ (Ph.Eur./USP) in a spouted bed using image processing method

The hydrodynamic behaviour of the spouted bed in the pharmaceutical industries has been found to be less addressed. The present paper has focused on the hydrodynamic characteristics of a spouted bed where the Cellets™ (Ph.Eur./USP) is adopted as the bed material. Experiments are carried out with three different static bed heights (H₀) of shallow depth (2D_i ≤ H₀ < 3D_i) using two different particle sizes. The spouted bed employed with D_i/D₀ of 5 has given the experimental information on external spouting (U_es) by mapping the pressure drop, and fountain height (H_f) against the superficial gas velocity (U_g) is represented with the image contours, which show the intrinsic behaviour. All the 1000 μm and 700 μm particles have been found to exhibit symmetric and asymmetric spouting. With increasing U_g, the fully suspended particles are limited to a certain height in the freeboard region due to the gas-solid cross-flow, which implies the clusters have identified with the image processing method.     

Influence of single rectangular groove on the flow past a circular cylinder

In the present study, flow control mechanism of single groove on a circular cylinder surface is presented experimentally using Particle image velocimetry (PIV). A square shaped groove is patterned longitudinally on the surface of the cylinder with a diameter of 50 mm. The flow characteristics are studied as a function of angular position of the groove from the forward stagnation point of the cylinder within 0° ≤ θ ≤ 150°. In the current work, instantaneous and time-averaged flow data such as vorticity, ω streamline, Ψ streamwise, u/U_o and transverse, v/U_o velocity components, turbulent kinetic energy, TKE and RMS of streamwise, u_rms and transverse, v_rms velocity components are utilized in order to present the results of quantitative analyses. Furthermore, Strouhal numbers are calculated using Karman vortex shedding frequency, f_k obtained from single point spectral analysis. It is concluded that a critical angular position of the groove, θ = 80° is observed. The flow separation is controlled within 0° ≤ θ < 80°. At θ = 80°, the flow separation starts to occur in the upstream direction. The instability within the shear layer is also induced on grooved side of the cylinder with frequencies different than Karman vortex shedding frequency, f_k.     

Effects of rotation on flow in an asymmetric rib-roughened duct: LES study

We report on large-eddy simulations (LES) of fully-developed asymmetric flow in a duct of a rectangular cross-section in which square-sectioned, equally-spaced ribs oriented perpendicular to the flow direction, were mounted on one of the walls. The configuration mimics a passage of internal cooling of a gas-turbine blade. The duct flow at a Reynolds number Re = 15,000 (based on hydraulic diameter D_h and bulk flow velocity U₀) was subjected to clock-wise (stabilising) and anti-clock-wise (destabilising) orthogonal rotation at a moderate rotational number Ro = ΩD_h/U₀ = 0.3, where Ω is the angular velocity. The LES results reproduced well the available experimental results of Coletti et al. (2011) (in the mid-plane adjacent to the ribbed wall) and provided insight into the whole duct complementing the reference PIV measurement. We analyzed the effects of stabilising and destabilising rotation on the flow, vortical structures and turbulence statistics by comparison with the non-rotating case. The analysis includes the identification of depth of penetration of the rib-effects into the bulk flow, influence of flow three-dimensionality and the role of secondary motions, all shown to be strongly affected by the rotation and its direction.     

Flow regimes in wet conical spouted beds using glass bead mixtures

Using a high-viscosity Newtonian fluid, glycerol, an experimental investigation was carried out to evaluate the stable spouting regime in conical spouted beds using four particle mixtures： a reference （monoparticles）, a binary mixture, two ternary mixtures with flat and Gaussian distributions respectively. The mixtures were selected for particle diameters （dp） ranging from 1.09 to 4.98 mm and particle diameter ratios （dpL/dps） ranging from 1.98 to 4.0. Experimental data show that pressure fluctuation signals of the bed, as indicated by changes in their standard deviations, provide suitable information to identify the range of operational conditions for stable spouting. However, the analysis of skewness of curves of pressure fluctuation as a function of air velocity appears not sufficient to identify a particular flow regime. For glycerol in the spouting regime, the standard deviation is noted to increase with increasing glycerol concentration due to the growth of interparticle forces. The implications of these research findings on the drying of suspensions in conical spouted beds using glass bead mixtures are also discussed.     

CFD modelling and wind tunnel validation of airflow through plant canopies using 3D canopy architecture

The efficiency of pesticide application to agricultural fields and the resulting environmental contamination highly depend on atmospheric airflow. A computational fluid dynamics (CFD) modelling of airflow within plant canopies using 3D canopy architecture was developed to understand the effect of the canopy to airflow. The model average air velocity was validated using experimental results in a wind tunnel with two artificial model trees of 24 cm height. Mean air velocities and their root mean square (RMS) values were measured on a vertical plane upstream and downstream sides of the trees in the tunnel using 2D hotwire anemometer after imposing a uniform air velocity of 10 m s^?1 at the inlet. 3D virtual canopy geometries of the artificial trees were modelled and introduced into a computational fluid domain whereby airflow through the trees was simulated using Reynolds-Averaged Navier–Stokes (RANS) equations and k-ε turbulence model. There was good agreement of the average longitudinal velocity, U between the measurements and the simulation results with relative errors less than 2% for upstream and 8% for downstream sides of the trees. The accuracy of the model prediction for turbulence kinetic energy k and turbulence intensity I was acceptable within the tree height when using a roughness length (y₀ = 0.02 mm) for the surface roughness of the tree branches and by applying a source model in a porous sub-domain created around the trees. The approach was applied for full scale orchard trees in the atmospheric boundary layer (ABL) and was compared with previous approaches and works. The simulation in the ABL was made using two groups of full scale orchard trees; short (h = 3 m) with wider branching and long (h = 4 m) with narrow branching. This comparison showed good qualitative agreements on the vertical profiles of U with small local differences as expected due to the spatial disparities in tree architecture. This work was able to show airflow within and above the canopy in 3D in more details.     

A note on a boundary condition for spouted beds

The boundary condition, zero solids pressure at the top of a particle bed of maximum spoutable height, Hm, is shown to eliminate any resort to empiricism in the derivation of the fluid velocity in the annulus of a spouted bed for which both viscous and inertial effects are taken into account. The same boundary condition fails when applied to a spouted bed for which the bed height H 〈 Hm, especially when H 〈 0.8Hm.     

A solids mixing rate correlation for small scale fluidized beds

A new first degree solids mixing rate is proposed to evaluate the mixing of solids in small scale fluidized beds. Particle mixing experiments were carried out in a 2D fluidized bed with a cross-section of 0.02 m × 0.2 m and a height of 1 m. White and black particles with average diameters of 850 and 450 μm were used in our experiments. Image processing was used to measure the concentration of the tracers at different times. The effects of four representative operating parameters (superficial gas velocity, ratio of tracer particles to bed particles, tracer particle position, and particle size) on mixing are discussed with reference to the mixing index. We found that the Lacey index depends on the concentration of the tracers. The position of the tracers affects the initial mixing rate but not the final degree of mixing. However, the new mixing rate equation does not depend on the initial configuration of the particles because this situation is considered to be the initial condition. Using the data obtained in this work and that found in literature, an empirical correlation is proposed to evaluate the mixing rate constant as a function of dimensionless numbers (Archimedes, Reynolds, and Froude) in small scale fluidized beds. This correlation allows for an estimation of the mixing rate under different operating conditions and for the detection of the end point and/or the time of mixing.     

Flow structures and heat transfer on dimples in a staggered arrangement

Vortex structures and heat transfer enhancement mechanism of turbulent flow over a staggered array of dimples in a narrow channel have been investigated using Large Eddy Simulation (LES), Laser Doppler Velocimetry (LDV) and pressure measurements for Reynolds numbers Re_H = 6521 and Re_H = 13,042.The flow and temperature fields are calculated by LES using dynamic mixed model applied both for the velocity and temperature. Simulations have been validated with experimental data obtained for smooth and dimpled channels and empiric correlations. The flow structures determined by LES inside the dimple are chaotic and consist of small eddies with a broad range of scales where coherent structures are hardly to detect. Proper Orthogonal Decomposition (POD) method is applied on resolved LES fields of pressure and velocity to identify spatial–temporal structures hidden in the random fluctuations. For both Reynolds numbers it was found that the dimple package with a depth h to diameter D ratio of h/D = 0.26 provides the maximum thermo-hydraulic performance. The heat transfer rate could be enhanced up to 201% compared to a smooth channel.     

Spatiotemporal variations of PM2.5 and PM10 concentrations between 31 Chinese cities and their relationships with SO2, NO2, CO and O3

The variations of mass concentrations of PM_2.5, PM₁₀, SO₂, NO₂, CO, and O₃ in 31 Chinese provincial capital cities were analyzed based on data from 286 monitoring sites obtained between March 22, 2013 and March 31, 2014. By comparing the pollutant concentrations over this length of time, the characteristics of the monthly variations of mass concentrations of air pollutants were determined. We used the Pearson correlation coefficient to establish the relationship between PM_2.5, PM₁₀, and the gas pollutants. The results revealed significant differences in the concentration levels of air pollutants and in the variations between the different cities. The Pearson correlation coefficients between PMs and NO₂ and SO₂ were either high or moderate (PM_2.5 with NO₂: r = 0.256–0.688, mean r = 0.498; PM₁₀ with NO₂: r = 0.169–0.713, mean r = 0.493; PM_2.5 with SO₂: r = 0.232–0.693, mean r = 0.449; PM₁₀ with SO₂: r = 0.131–0.669, mean r = 0.403). The correlation between PMs and CO was diverse (PM_2.5: r = 0.156–0.721, mean r = 0.437; PM₁₀: r = 0.06–0.67, mean r = 0.380). The correlation between PMs and O₃ was either weak or uncorrelated (PM_2.5: r = −0.35 to 0.089, mean r = −0.164; PM₁₀: r = −0.279 to 0.078, mean r = −0.127), except in Haikou (PM_2.5: r = 0.500; PM₁₀: r = 0.509).     

Heat transfer and fluid dynamics of air–water two-phase flow in micro-channels

Heat transfer, pressure drop, and void fraction were simultaneously measured for upward heated air–water non-boiling two-phase flow in 0.51 mm ID tube to investigate thermo–hydro dynamic characteristics of two-phase flow in micro-channels. At low liquid superficial velocity j_l frictional pressure drop agreed with Mishima–Hibiki’s correlation, whereas agreed with Chisholm–Laird’s correlation at relatively high j_l. Void fraction was lower than the homogeneous model and conventional empirical correlations. To interpret the decrease of void fraction with decrease of tube diameter, a relation among the void fraction, pressure gradient and tube diameter was derived. Heat transfer coefficient fairly agreed with the data for 1.03 and 2.01 mm ID tubes when j_l was relatively high. But it became lower than that for larger diameter tubes when j_l was low. Analogy between heat transfer and frictional pressure drop was proved to hold roughly for the two-phase flow in micro-channel. But satisfactory relation was not obtained under the condition of low liquid superficial velocity.