Large-scale synthesis of hierarchical MnO2 for benzene catalytic oxidation

Hierarchical sea-urchin-shaped manganese oxide microspheres were synthesized via a facile method based on the reaction between KMnO₄ and MnSO₄ in HNO₃ solution at 50 °C. The average diameter of the microspheres is ∼850 nm. The microspheres consist of a core of diameter of ∼800 nm and nanorods of width ∼50 nm. The nanorods exist at the edge of the core. The Brunauer–Emmett–Teller surface area of the sea-urchin-shaped microspheres is 259.4 m²/g. A possible formation mechanism of the hierarchical sea-urchin-shaped microspheres is proposed. The temperature for 90% conversion of benzene (T_90%) on the hierarchical urchin-shaped MnO₂ microspheres is about 218 °C.     

Controlled synthesis of Ce(OH)CO3 flowers by a hydrothermal method and their thermal conversion to CeO2 flowers

Highly uniform Ce(OH)CO₃ flowers were successfully prepared in large quantities using a facile hydrothermal approach from the reaction of Ce(NH₄)(NO₃)₄ with CO(NH₂)₂ at 160 °C in a water–N₂H₄ complex. The influences of the N₂H₄ content and temperature on flower formation were discussed. CeO₂ flowers were prepared by thermal conversion of Ce(OH)CO₃ flowers at 500 °C in air. Both Ce(OH)CO₃ and CeO₂ flowers were characterized by X-ray powder diffraction (XRD), and scanning electron microscopy (SEM). The UV–vis adsorption spectrum of the CeO₂ flowers showed that the band gap energy (E_g) is 2.66 eV, which is lower than that of bulk ceria.     

Flow boiling heat transfer of R134a,R236fa and R245fa in a horizontal 1.030 mm circular channel

This research focuses on acquiring accurate flow boiling heat transfer data and flow pattern visualization for three refrigerants, R134a, R236fa and R245fa in a 1.030 mm channel. We investigate trends in the data, and their possible mechanisms, for mass fluxes from 200 to 1600 kg/m²s, heat fluxes from 2.3 kW/m² to 250 kW/m² at T_sat = 31 °C and ΔT_sub from 2 to 9 K. The local saturated flow boiling heat transfer coefficients display a heat flux and a mass flux dependency but no residual subcooling influence. The changes in heat transfer trends correspond well with flow regime transitions. These were segregated into the isolated bubble (IB) regime, the coalescing bubble (CB) regime, and the annular (A) regime for the three fluids. The importance of nucleate boiling and forced convection in these small channels is still relatively unclear and requires further research.     

Microwave-assisted polyol synthesis of LiMnPO4/C and its use as a cathode material in lithium-ion batteries

We synthesized LiMnPO₄/C with an ordered olivine structure by using a microwave-assisted polyol process in 2:15 (v/v) water–diethylene glycol mixed solvents at 130 °C for 30 min. We also studied how three surfactants—hexadecyltrimethylammonium bromide, polyvinylpyrrolidone k30 (PVPk30), and polyvinylpyrrolidone k90 (PVPk90)—affected the structure, morphology, and performance of the prepared samples, characterizing them by using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, charge/discharge tests, and electrochemical impedance spectroscopy. All the samples prepared with or without surfactant had orthorhombic structures with the Pnmb space group. Surfactant molecules may have acted as crystal-face inhibitors to adjust the oriented growth, morphology, and particle size of LiMnPO₄. The microwave effects could accelerate the reaction and nucleation rates of LiMnPO₄ at a lower reaction temperature. The LiMnPO₄/C sample prepared with PVPk30 exhibited a flaky structure coated with a carbon layer (∼2 nm thick), and it delivered a discharge capacity of 126 mAh/g with a capacity retention ratio of ∼99.9% after 50 cycles at 1C. Even at 5C, this sample still had a high discharge capacity of 110 mAh/g, demonstrating good rate performance and cycle performance. The improved performance of LiMnPO₄ likely came from its nanoflake structure and the thin carbon layer coating its LiMnPO₄ particles. Compared with the conventional polyol method, the microwave-assisted polyol method had a much lower reaction time.     

Influence of temperature on a carbon–fibre epoxy composite subjected to static and fatigue loading under mode-I delamination

In this paper, interlaminar crack initiation and propagation under mode-I with static and fatigue loading of a composite material are experimentally assessed for different test temperatures. The material under study is made of a 3501-6 epoxy matrix reinforced with AS4 unidirectional carbon fibres, with a symmetric laminate configuration [0°]_16/S. In the experimental programme, DCB specimens were tested under static and fatigue loading. Based on the results obtained from static tests, fatigue tests were programmed to analyse the mode-I fatigue behaviour, so the necessary number of cycles was calculated for initiation and propagation of the crack at the different temperatures. G–N curves were determined under fatigue loading, N being the number of cycles at which delamination begins for a given energy release rate. G_ICmax–a, a–N and da/dN–a curves were also determined for different G_cr rates (90%, 85%, 75%, etc.) and different test temperatures: 90 °C, 50 °C, 20 °C, 0 °C, ?30 °C and ?60 °C.     

Influence of single rectangular groove on the flow past a circular cylinder

In the present study, flow control mechanism of single groove on a circular cylinder surface is presented experimentally using Particle image velocimetry (PIV). A square shaped groove is patterned longitudinally on the surface of the cylinder with a diameter of 50 mm. The flow characteristics are studied as a function of angular position of the groove from the forward stagnation point of the cylinder within 0° ≤ θ ≤ 150°. In the current work, instantaneous and time-averaged flow data such as vorticity, ω streamline, Ψ streamwise, u/U_o and transverse, v/U_o velocity components, turbulent kinetic energy, TKE and RMS of streamwise, u_rms and transverse, v_rms velocity components are utilized in order to present the results of quantitative analyses. Furthermore, Strouhal numbers are calculated using Karman vortex shedding frequency, f_k obtained from single point spectral analysis. It is concluded that a critical angular position of the groove, θ = 80° is observed. The flow separation is controlled within 0° ≤ θ < 80°. At θ = 80°, the flow separation starts to occur in the upstream direction. The instability within the shear layer is also induced on grooved side of the cylinder with frequencies different than Karman vortex shedding frequency, f_k.     

Synthesis and phase evolution of LiNb0.6Ti0.5O3 powder via a sol–gel method

A simple sol–gel route was demonstrated for the synthesis of LiNb_0.6Ti_0.5O₃ (M-phase) powder, using cheap and manageable starting materials at a relatively low temperature. The phase transitions in both chemical and solid-state processes were studied by X-ray diffraction (XRD) in detail. The results showed that in the sol–gel process the anatase TiO₂ phase first appeared at 400 °C and then LiNbO₃ solid solution (LiNbO₃ ss) emerged at 500 °C. When calcined to 600 °C, the M-phase started to appear along with the decrease of TiO₂ and LiNbO₃ ss. Single M-phase could be formed at 700 °C, which is 300 °C lower than that by the traditional solid-state method. A plausible evolution mechanism of the as-synthesized powder in calcination was proposed. The produced powder has potential applications in microelectronics systems.     

The effect of incidence angle on the mean wake of surface-mounted finite-height square prisms

The mean wake of a surface-mounted finite-height square prism was studied experimentally in a low-speed wind tunnel to explore the combined effects of incidence angle (α) and aspect ratio (AR). Measurements of the mean wake velocity field were made with a seven-hole pressure probe for finite square prisms of AR = 9, 7, 5 and 3, at a Reynolds number of Re = 3.7 × 10⁴, for incidence angles from α = 0° to 45°. The relative thickness of the boundary layer on the ground plane, compared to the prism width, was δ/D = 1.5. As the incidence angle increases from α = 0° to 15°, the mean recirculation zone shortens and the mean wake shifts in the direction opposite to that of the mean lift force. The downwash is also deflected to this side of the wake and the mean streamwise vortex structures in the upper part of the wake become strongly asymmetric. The shortest mean recirculation zone, and the greatest asymmetry in the mean wake, is found at the critical incidence angle of α_critical ≈ 15°. As the incidence angle increases from α = 15° to 45°, the mean recirculation zone lengthens and the mean streamwise vortex structures regain their symmetry. These vortices also elongate in the wall-normal direction and become contiguous with the horseshoe vortex trailing arms. The mean wake of the prism of AR = 3 has some differences, such as an absence of induced streamwise vorticity near the ground plane, which support its classification as lying below the critical aspect ratio for the present flow conditions.     

Wavelet decomposition method decoupled boiling/evaporation oscillation mechanisms over two to three timescales: A study for a microchannel with pin fin structure

Boiling/evaporation heat transfer in a microchannel with pin fin structure was performed with water as the working fluid. Simultaneous measurements of various parameters were performed. The chip wall temperatures were measured by a high spatial-time resolution IR image system, having a sensitivity of 0.02 °C. The flow pattern variations synchronously changed wall temperatures due to ultra-small Bi number. The wavelet decomposition method successfully identified the noise signal and decoupled various temperature oscillations with different amplitudes and frequencies. Three types of temperature oscillations were identified according to heat flux q and mass flux G. The first type of oscillation occurred at q/G < 0.62 kJ/kg. The approximation coefficient of wavelet decomposition decided the dominant cycle period which was ∼3 times of the fluid residence time in the microchannel, behaving the density wave oscillation characteristic. The detail coefficients of wavelet decomposition decided the dominant cycle period, which matched the flow pattern transition determined value well, representing the flow pattern transition induced oscillation. For the second type of oscillation, the wavelet decomposition decoupled the three oscillation mechanisms. The pressure drop oscillation caused the temperature oscillation amplitudes of 5–10 °C and cycle periods of 10–15 s. The density wave oscillation and flow pattern transition induced oscillation are embedded with both the pressure rise and decrease stages of the pressure drop oscillation. The third type of oscillation happened at q/G > 1.13 kJ/kg, having the density wave oscillation coupled with the varied liquid film evaporation induced oscillation. The liquid island, retention bubble induced nucleation sites and cone-shape two-phase developing region are unique features of microchannel boiling with pin fin structure. This study illustrated that pressure drop oscillation and density wave oscillation, usually happened in large size channels, also take place in microchannels. The flow pattern transition and varied liquid film evaporation induced oscillations are specific to microchannel boiling/evaporation flow.     

Hydrothermal synthesis of ultrathin hexagonal nickel hydroxide nanosheets

Nickel hydroxide, Ni(OH)₂ is widely used in electrodes of nickel-based alkaline secondary batteries. Ultrathin hexagonal Ni(OH)₂ nanosheets of space group P-3m1 were hydrothermally prepared at 200 °C for 10 h. Their diameter and thickness were 200–300 and 3–5 nm, respectively. Their formation was attributed to the oriented assembly of growing particles, which was assisted by surfactant molecules. The specific surface area of the Ni(OH)₂ nanosheets was 8.66 m²/g. Their magnetization curve exhibited linear paramagnetic behavior across the entire measurement region.     

Synthesis of potassium sodium niobate powders using an EDTA/citrate complexing sol–gel method

Potassium sodium niobate (KNN) powders were synthesized by a modified sol–gel method, using as starting chemicals potassium carbonate, sodium carbonate, and niobium hydroxide, and, as esterification and chelating agents, respectively, ethylene glycol (EG) and ethylene diamine tetraacetic acid (EDTA)/citrate. The effects of citric acid (CA), EG, and EDTA on the stability of the precursor sol were systemically investigated. The powders and gels were characterized by X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis-differential scanning calorimetry (TGA-DSC). The results indicated that a stable precursor sol was formed when n(CA):n(Mⁿ⁺) = 3:1, n(EDTA):n(NH₄OH) = 1:3.5, and n(CA):n(EG) = 1:2. The xerogel was calcined at 500–950 °C to prepare the KNN powder. Pure KNN perovskite phase with a cube-like structure was synthesized at 850 °C from the precursor sol for a K/Na molar ratio of 1.2. The formation mechanism of the KNN perovskite phase was also discussed.     

Surface characteristics of spruce veneers and shear strength of plywood as a function of log temperature in peeling process

The objective of this study was to determine the effect of temperature of spruce (Picea orientalis L.) logs during peeling process on surface roughness, adhesive wettability, colour variation of veneer, and shear strength of plywood made from these veneer sheets. Veneer samples were manufactured from the logs after they were kept for 3 h and 24 h to reach to average temperatures of 52 °C and 32 °C, respectively. A fine stylus method was used for surface roughness evaluation of the veneer produced from two types of the logs and it was found that the samples peeled from the logs with a temperature of 52 °C had significantly better roughness values than those of manufactured from the logs with 32 °C at a 95% confidence level. Wettability of veneer samples was determined with contact angle measurements according to the sessile drop method. Urea formaldehyde (UF) and phenol formaldehyde (PF) resin drops were used in contact angle measurements. Contact angles of PF resin drops on veneers were similar for each peeling temperature while the contact angles of UF glue resin on veneers produced from the logs with 32 °C were lower than those of produced from the logs with 52 °C. Small colour difference was measured (indicated by a low ΔE value) on veneer samples depending on the log temperature. The highest shear strength value was determined for the plywood manufactured from veneers obtained from the logs with 52 °C by using UF glue.     

Catalytic oxidation of benzene over Ce–Mn oxides synthesized by flame spray pyrolysis

Flame spray pyrolysis (FSP) was utilized to synthesize Ce–Mn oxides in one step for catalytic oxidation of benzene. Cerium acetate and manganese acetate were used as precursors. The materials synthesized were characterized using X-ray diffraction (XRD), N₂ adsorption, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), Raman spectroscopy, and H₂-temperature programmed reduction (H₂-TPR) and their benzene catalytic oxidation behavior was evaluated. Mn ions were evidenced in multiple chemical states. Crystalline Ce–Mn oxides consist of particles with size <40 nm and specific surface areas (SSA) of 20–50 m²/g. Raman spectrums and H₂-TPR results indicated the interaction between cerium and manganese oxides. Flame-made 12.5%-Ce–Mn oxide exhibited excellent catalytic activity at relatively low temperatures (T₉₅ about 260 °C) compared to other Ce–Mn oxides with different cerium-to-manganese ratios. Redox mechanism and strong interaction conform to structure analysis that Ce–Mn strong interaction formed during the high temperature flame process and the results were used to explain catalytic oxidation of benzene.     

Improved performance of aluminum pigments encapsulated in hybrid inorganic–organic films

An organic silane acrylate resin (PMBK) was synthesized by free-radical solution polymerization using methyl methacrylate, butyl acrylate and (3-methacryloxypropyl)trimethoxysilane as monomers. Aluminum (Al) particles were then encapsulated in inorganic–organic hybrid films that were prepared by hydrolysis and condensation of PMBK and tetraethyl orthosilicate (TEOS) on the surface of Al pigments. Characterization results showed that PMBK and TEOS could simultaneously hydrolyze and condense with hydroxyl groups on the surface of the Al particles to form composite Al particles coated with inorganic–organic hybrid films. Compared with raw Al particles, the corrosion resistance and adhesive properties of paint films containing the composite Al particles were improved greatly, while the glossiness of the paint films decreased slightly, from 48.6° to 47.0°. In alkaline media (pH 11), the volume of evolved H₂ of composite Al particles was only 3.5 mL, whereas that of raw Al was 83.5 mL. The glossiness of paint films containing composite Al particles decreased by 1.66% after immersion in alkaline media for 24 h, whereas that of raw Al decreased by 14.82%. Peel-off tests of the paint films showed that the composite particles moved slightly away from the paint films. In contrast, the raw Al particles were seriously desquamated, suggesting encapsulation of hybrid films can greatly improve the adhesive properties of Al particles in paint films.     

Effect of calcining temperature and time on the characteristics of Sb-doped SnO2 nanoparticles synthesized by the sol–gel method

Spherical Sb-doped SnO₂ (ATO) nanoparticles were synthesized by the sol–gel route, employing SnCl₄·5H₂O and SbCl₃ as precursors in an ethanol solution. The influences of the calcining temperature and calcining time on the crystallite size, crystallinity, lattice parameters, lattice distortion ratio and the resistivity of the ATO nanoparticles were synthetically investigated. The results suggested that the ATO nanoparticles were crystallized in a tetragonal cassiterite structure of SnO₂ with a highly (1 1 0)-plane-preferred orientation. The calcining temperature had a dominating effect on the crystallite size, crystallinity, lattice distortion ratios and resistivity of the ATO. As the calcining temperature increased, the average crystallite size increased, the crystallinity was promoted accompanied by a decrease in the lattice distortion ratio and a corresponding decrease in the resistivity of the ATO. X-ray diffraction (XRD) and Fourier transform infrared spectrophotometer (FTIR) analysis revealed that Sb ions could not entirely supplant the Sn ions in the SnO₂ lattice for a calcining time of less than 0.5 h, even at a calcining temperature of 1000 °C. The ATO nanoparticles calcined at 1000 °C for 3.0 h possessed the lowest resistivity of 10.18 Ω cm.     

Experimental study on turbulent mixing of spray droplets in crossflow

Centrifugal spray injected at various angles in gas crossflow has been studied experimentally using PIV visualization system and image-processing techniques. Experiments were carried out inside a rectangular duct (95 mm × 95 mm in cross-section) at ambient temperature and pressure, with different gas Reynolds numbers (vary from 12,900 to 45,000) and three injection angles (60°, 90° and 120°). The spray angle of the centrifugal nozzle is 80°, with D₃₂ of 80 μm. The instantaneous images of droplets distribution and the values of the line-averaged D₃₂ at different positions on the cross-sections along the flow field for each condition were obtained, and their flow field configurations were achieved. Quantitative assessments of mixing degree between two phases for different injection angles were determined using a spatial unmixedness parameter. It is found that the addition of droplets into the gas crossflow enhanced the turbulence intensity of the gas crossflow and caused different-scale vortices. The flow field structure, to a great extent, is dependent on the injection angle. The entrainment and centrifugal force of large vortex lead to uneven droplet distribution and moreover influence the mixing of droplets and gas crossflow. A better mixing result can be obtained with the injection angle of nozzles of 60°.     

Emission of organic carbon,elemental carbon and water-soluble ions from crop straw burning under flaming and smoldering conditions

Emissions from major agricultural residues were measured using a self-designed combustion system. Emission factors (EFs) of organic carbon (OC), elemental carbon (EC), and water-soluble ions (WSIs) (K⁺, NH₄⁺, Na⁺, Mg²⁺, Ca²⁺, Cl⁻, NO₃⁻, SO₄^2–) in smoke from wheat and rice straw were measured under flaming and smoldering conditions. The OC₁/TC (total carbon) was highest (45.8% flaming, 57.7% smoldering) among carbon fractions. The mean EFs for OC (EF_OC) and EC (EF_EC) were 9.2 ± 3.9 and 2.2 ± 0.7 g/kg for wheat straw and 6.4 ± 1.9 and 1.1 ± 0.3 g/kg for rice straw under flaming conditions, while they were 40.8 ± 5.6 and 5.8 ± 1.0 g/kg and 37.6 ± 6.3 and 5.0 ± 1.4 g/kg under smoldering conditions, respectively. Higher EC ratios were observed in particulate matter (PM) mass under flaming conditions. The OC and EC for the two combustion patterns were significantly correlated (p < 0.01, R = 0.95 for wheat straw; p < 0.01, R = 0.97 for rice straw), and a higher positive correlation between OC₃ and EC was observed under both combustion conditions. WSIs emitted from flaming smoke were dominated by Cl⁻ and K⁺, which contributed 3.4% and 2.4% of the PM mass for rice straw and 2.2% and 1.0% for wheat straw, respectively. The EFs of Cl⁻ and K⁺ were 0.73 ± 0.16 and 0.51 ± 0.14 g/kg for wheat straw and 0.25 ± 0.15 and 0.12 ± 0.05 g/kg for rice straw under flaming conditions, while they were 0.42 ± 0.28 and 0.12 ± 0.06 g/kg and 0.30 ± 0.27 and 0.05 ± 0.03 g/kg under smoldering conditions, respectively. Na⁺, Mg²⁺, and NH₄⁺ were vital components in PM, comprising from 0.8% (smoldering) to 3.1% (flaming) of the mass. Strong correlations of Cl⁻ with K⁺, NH₄⁺, and Na⁺ ions were observed in rice straw and the calculated diagnostic ratios of OC/EC, K⁺/Na⁺ and Cl⁻/Na⁺ could be useful to distinguishing crop straw burning from other sources of atmospheric pollution.     

Controllable hydrothermal synthesis of star-shaped Sr3Fe2(OH)12 assemblies and their thermal decomposition and magnetic properties

Pure phase star-shaped hydrogarnet Sr₃Fe₂(OH)₁₂ assemblies were synthesized by a mild hydrothermal method (210 °C, 12 h), and the effects of the preparation conditions on the phase composition of the product were investigated. It was found that the impurity phases could be decreased or eliminated by increasing the molar ratio of Sr²⁺ to Fe³⁺, and that high temperatures favored the formation of Sr₃Fe₂(OH)₁₂ and reduced the concentration of CO₃^2–-containing byproducts. The thermal decomposition of the star-shaped Sr₃Fe₂(OH)₁₂ assemblies was examined, and the results showed that the dehydration process at higher temperatures is accompanied by the formation of SrFeO_3–δ. Above 655 °C, a solid state reaction between the SrFeO_3–δ and Sr(OH)₂ or SrCO₃ results in the formation of Sr₄Fe₃O_10–δ.The magnetic properties of the as-synthesized Sr₃Fe₂(OH)₁₂ and of samples calcined at different temperatures were assessed. A sample calcined at 575 °C exhibited greatly enhanced ferromagnetic properties, with a remanent magnetization of 1.28 emu/g and a coercivity of 4522.1 Oe at room temperature.