COMBINED EFFECTS OF SUBCOOLING AND SURFACE ORIENTATION ON POOL BOILING OF HFE-7100 FROM A SIMULATED ELECTRONIC CHIP

The effects of orientation and subcooling on pool boiling of the HFE-7100 dielectric liquid near atmospheric pressure (0.085 MPa) from a 10 × 10 mm smooth copper surface are investigated experimentally. Results are obtained for inclination angles θ = 0° (upward-facing), 30°, 60°, 90°, 120°, 150°, and 180° (downward-facing) and liquid subcoolings ΔT_sub = 0, 10, 20, and 30 K. Increasing θ decreases the saturation nucleate boiling heat flux at high surface superheats (ΔT_sat > 20 K), but increases it only slightly at lower surface superheats. The critical heat flux (CHF) decreases slowly with increasing θ from 0° to 90°, and then deceases faster with increasing θ to 180°. CHF increases linearly with increased subcooling, but the rate increases from 0.016 K^?1 at 0° to 0.048 K^?1 at 180°. At θ = 0° and ΔT_sub = 30 K, CHF is ～ 36 W/cm² and 24.45 W/cm² for saturation boiling, while at θ = 180° CHF = 10.85 W/cm² at ΔT_sub = 30 K and only 4.30 W/cm² at saturation. The developed correlation for CHF of HFE-7100, as a function of θ and ΔT_sub, is within ±10% of the present data. The recorded still photographs of the boiling surface in the experiments illustrate the effects of liquid subcooling and surface orientation at different nucleate boiling heat fluxes and surface superheats on vapor bubble accumulation and/or induced mixing at the surface.     

Methane hydrate crystal growth in a porous medium filled with methane-saturated liquid water

The nucleation, growth and ageing of methane hydrate crystals were observed visually in a porous medium filled with liquid water presaturated with methane. The pore space dimensions of the porous medium were 1.0?×?10²?µm. The pressure?temperature conditions at which hydrate formation was initiated corresponded to system subcoolings of 3.4?K, 6.7?K, 12.3?K and 14.1?K, respectively, where the system subcooling denotes the difference of the system temperature from the triple methane?hydrate?water equilibrium temperature under a given pressure. Faceted (skeletal) hydrate crystals grew and bridged the pore spaces without intervention of a liquid water layer when the subcoolings were equal or smaller than 6.7?K. The faceted crystals may form a physical bonding with the walls of the porous medium. At the higher subcoolings, the dispersive formation of dendritic crystals and subsequent morphological change into particulate crystals were observed. The bridging of the dendritic crystals is unlikely in the absence of a large amount of additional methane supply due to the dispersive spatial distribution of the dendritic crystals that have dimensions smaller than those of the pore spaces. As a result of the interpretation of the observed variation in the crystal morphology of the methane hydrate formed in liquid water, the dependence of the crystal morphology on the magnitude of the mass transfer of methane molecules in liquid water observed in the porous medium was consistent with that previously observed in a bulk methane–water system.     

整体煤气化联合循环合成气水合物法分离CO2的分子动力学模拟

利用分子动力学（MD）模拟方法研究整体煤气化联合循环（IGCC）合成气（CO₂/H₂）水合物法分离CO₂的分离机理,系统研究了CO₂水合物、H₂水合物以及合成气水合物法一级分离所得CO₂/H₂混合气体水合物的微观结构及性质.模拟分析n个CO₂或H₂与水合物笼状结构的整体结合能ΔE关键词： 水合物法分离 分子动力学模拟 整体煤气化联合循环合成气 2分离')" href="#">CO₂分离     

Phase transitions in orthorhombic oxyfluoride (NH4)2MoO2F4

(NH₄)₂MoO₂F₄ single crystals were grown and studied using polarization-optical methods, and the birefringence was measured in the temperature range 90–350 K. The following sequence of phase transitions is revealed: G ₀ ? G ₁ ? G ₂. It is established that the phase transition at T ₀₁ ≈ 267 K is of the first order and exhibits thermal hysteresis δT ₀₁ ≈ 0.6 K. A weak anomaly is found in Δn(T) at T ₀₂ ≈ 180 K. The crystals are shown to retain the orthorhombic symmetry during the phase transitions.     

Effect of γ irradiation on the thermochromic phase transition in [(C<Subscript>2</Subscript>H<Subscript>5</Subscript>)<Subscript>2</Subscript>NH<Subscript>2</Subscript>]<Subscript>2</Subscript>CuCl<Subscript>4</Subscript> crystals (as derived from heat capacity measurements)

The heat capacity of [(C₂H₅)₂NH₂]₂CuCl₄ crystals, both nonirradiated and γ-irradiated to a dose of 10⁷R, was studied in the temperature interval 90–330 K by adiabatic calorimetry. The temperature dependence of C_p(T) was found to have a peak-shaped anomaly in the region of the thermochromic phase transition (PT) at T = 322.7 K. Smoothened experimental heat capacity data were used to calculate the changes in the thermodynamic functions. The changes in the entropy and enthalpy of the thermochromic PT were determined to be ΔS = 42 J K^?1 mol^?1 and ΔH = 13653 J mol^?1 for the nonirradiated crystals and ΔS = 39 J K^?1 mol^?1 and ΔH = 12120 J mol^?1 for the irradiated crystals, respectively. Irradiation of a [(C₂H₅)₂NH₂]₂CuCl₄ crystal by γ rays to a dose of 10⁷ R was shown to shift the PT point toward lower temperatures by ΔT ≈ 1.7 K.     

Calorimetric fragility of maltitol

The heat capacity of maltitol has been measured with an adiabatic calorimeter for the crystal from 100 K to 425 K (T _m = 420 K), for the glass from 249 K to T _g (around 311 K) and for the liquid from T _g to 400 K. The heat of melting is 55.068 kJ/mol. The calorimetric glass transition occurs at about T _g = 311 K with a sudden jump of the heat capacity ΔC _p (T _g ) of about 243.6 J/(K mol). The excess entropy between the undercooled liquid and the crystal was calculated from the heat capacity data and was used to estimate the Kauzmann temperature T _K which was found 50 K below T _g . ΔC _p (T _g ) and T _K for maltitol were compared to other compounds like sugars, polyol and hydrogen bonded liquids. It has been found that the glass former maltitol is a "fragile" liquid on the thermodynamic point of view.     

Calorimetric investigation of (TEA)2MnCl4 crystals

Temperature dependencies of the specific heat in a temperature range of 14–260?K are presented for the crystals (TEA)₂MnCl₄. Two anomalies typical for the first order phase transition at T ₁?=?224?K and T ₂?=?231?K with entropy jumps of 15?J?mol^?1?K^?1 and 12?J?mol^?1?K^?1 were observed. The temperature dependence of the lattice heat was approximated by a linear combination of Debye and Einstein functions. Basing on the results an effective wave number of phonons with an essential contribution to the lattice oscillation energy was determined. Since phase transition sequence observed in (TEA)₂MnCl₄ and (TEA)₂CuCl₄ is similar and similar is the chemical composition one can suppose that the low temperature phase transition observed in (TEA)₂MnCl₄ crystals is an isostructural transition.     

Effect of substrate temperature on structure and electrical resistivity of laser-ablated IrO2 thin films

IrO₂ thin films were prepared on Si(1 0 0) substrates by laser ablation. The effect of substrate temperature (T_sub) on the structure (crystal orientation and surface morphology) and property (electrical resistivity) of the laser-ablated IrO₂ thin films was investigated. Well crystallized and single-phase IrO₂ thin films were obtained at T_sub = 573-773 K in an oxygen partial pressure of 20 Pa. The preferred orientation of the laser-ablated IrO₂ thin films changed from (2 0 0) to (1 1 0) and (1 0 1) depending on T_sub. With the increasing of T_sub, both the surface roughness and crystallite size increased. The room-temperature electrical resistivity of IrO₂ thin films decreased with increasing T_sub, showing a low value of (42 ± 6) × 10⁻⁸ Ω m at T_sub = 773 K.     

Silicon substrate temperature effects on surface roughness induced by ultrafast laser processing

We report the effect of substrate temperature (T_sub) in the range 300-900 K on the surface roughness of silicon wafer resulted from femtosecond laser ablation. The surface roughness observed at the laser fluences less then 0.3 J/cm² increases with increasing T_sub. However, the surface roughness decreases with increasing T_sub for the laser fluences between 0.5 and 1.0 J/cm². If the laser fluence is higher than 2.0 J/cm², the surface roughness is independent of T_sub. The effect of T_sub on the surface roughness can be understood in terms of the temperature dependence of optical absorption coefficient of silicon substrate, which eventually alters a mechanism underlying the fs-laser-material ablation process between optical penetration and thermal diffusion processes.     

Application of low field NMR T2 measurements to clathrate hydrates

Low field (2 MHz) Nuclear Magnetic Resonance (NMR) proton spin–spin relaxation time (T₂) distribution measurements were employed to investigate tetrahydrofuran (THF)—deuterium oxide (D₂O) clathrate hydrate formation and dissociation processes. In particular, T₂ distributions were obtained at the point of hydrate phase transition as a function of the co-existing solid/liquid ratios. Because T₂ of the target molecules reflect the structural arrangements of the molecules surrounding them, T₂ changes of THF in D₂O during hydrate formation and dissociation should yield insights into the hydrate mechanisms on a molecular level. This work demonstrated that such T₂ measurements could easily distinguish THF in the solid hydrate phase from THF in the coexisting liquid phase. To our knowledge, this is the first time that T₂ of guest molecules in hydrate cages has been measured using this low frequency NMR T₂ distribution technique. At this low frequency, results also proved that the technique can accurately capture the percentages of THF molecules residing in the solid and liquid phases and quantify the hydrate conversion progress. Therefore, an extension of this technique can be applied to measure hydrate kinetics. It was found that T₂ of THF in the liquid phase changed as hydrate formation/dissociation progressed, implying that the presence of solid hydrate influenced the coexisting fluid structure. The rotational activation measured from the proton response of THF in the hydrate phase was 31 KJ/mole, which agreed with values reported in the literature.     

Linear birefringence studies of incommensurate systems: II. KFeF4

Abstract

The temperature dependence of the linear birefringence (LB), Δn _c , is measured in the range 5 K ? T ? 500 K on samples of KFeF₄, which originate from hydrothermal, flux and Bridgman growth techniques. Pronounced anomalies are found at the orthorhombic-orthorhomic phase transition at T _c ∽ 400 K. It is weakly discontinuous with a near-tricritical exponent β ∽ 0.2. Weak anomalies near T _i ∽ T _c + (25 … 40 K) seem to indicate a transition into an intermediate incommensurate phase. Its XY-model character is reflected by the critical LB exponent β = 0.8 ± 0.1. A smooth LB anomaly below 200 K is due to 2-dimensional ferromagnetic spin-order.     

Magnetic and transport properties of UBi2 and USb2 single crystals

The thermoelectric power, S(T), of USb₂ and UBi₂, which are tetragonal, uniaxial antiferromagnets below T _N?=?202?K and 180.8?K, respectively, have been examined between 0.4?K and 300?K. The values of S(T), up to now known above 70?K for USb₂ and unknown for UBi₂, are positive along the a-axis for both compounds in the whole examined temperature range. The S(T) data for the c-axis (the easy magnetization axis) are positive near room temperature for USb₂ and UBi₂ but becomes negative below 120?K and 170?K, respectively, with two very deep minima in S(T) dependence for USb₂. In the latter compound the Fermi surface, known from literature, is composed of the only cylindrical sheets that are slightly corrugated and parallel to the c-axis. UBi₂, the Fermi surface of which is composed of one spherical and two cylindrical sheets, shows corresponding minima although less pronounced than those in USb₂. Having at disposal the highest purity single crystals in comparison to those for which the resistivity, ρ(T), has been reported in literature, the ρ(T) anisotropy was re-examined for these two systems. Magnon and phonon contributions to their total electrical resistivity have been determined and the critical fluctuation behaviour of the resistivity near T _N for both dipnictides has been analysed. Although the magnetic susceptibilities of UBi₂ and USb₂ reveal a similarity, their transport properties are significantly different due to the difference in the Fermi surface topology.     

Direct evidence of two superconducting gaps in FeSe<Subscript>0.5</Subscript>Te<Subscript>0.5</Subscript>: SnS-Andreev spectroscopy and the lower critical field

We present direct measurements of the superconducting order parameter in nearly optimal FeSe Te single crystals with the critical temperature T _C ≈ 14 K. Using the intrinsic multiple Andreev reflection effect (IMARE) spectroscopy and measurements of the lower critical field, we directly determined two superconducting gaps, Δ_L ≈ 3.3?3.4 meV and Δ_S ≈ 1 meV, and their temperature dependences. We show that a twoband model fits well the experimental data. The estimated electron–boson coupling constants indicate a strong intraband and a moderate interband interaction.     

Multiple andreev reflections spectroscopy of superconducting LiFeAs single crystals: Anisotropy and temperature behavior of the order parameters

The superconducting state of LiFeAs single crystals with the maximum critical temperature T _c ≈ 17 K in the 111 family has been studied in detail by multiple Andreev reflections (MAR) spectroscopy implemented by the break-junction technique. The three superconducting gaps, Δ_Γ = 5.1–6.5 meV, Δ_L = 3.8–4.8 meV, and Δ_S = 0.9–1.9 meV (at T ? T _c), as well as their temperature dependences, have been directly determined in a tunneling experiment with these samples. The anisotropy degrees of the order parameters in the k space have been estimated as <8, ～12, and ～20%, respectively. Andreev spectra have been fitted within the extended Kümmel-Gunsenheimer-Nikolsky model with allowance for anisotropy. The relative electron-boson coupling constants in LiFeAs have been determined by approximating the Δ(T) dependences by the system of the two-band Moskalenko and Suhl equations. It has been shown that the densities of states in bands forming Δ_Γ and Δ_L are approximately the same, intraband pairing dominates in this case, and the interband coupling constants are related as λ_ΓL ≈ λ_LΓ ? λ_SΓ, λ_SL.     

块体非晶合金的黏度与玻璃形成能力的关系

基于经典结晶理论讨论了非晶合金的晶化动力学因素和晶化热力学因素对玻璃形成能力（GFA）的影响.分析表明,合金的等温转变（TTT）曲线“鼻尖”温度T_n对应的黏度与晶化阻力因子成正比;重新加热时晶化开始温度T_x对应的黏度与晶化驱动力因子成反比.由此得到了新的GFA参数ω₀=（T_g-T₀）/（T_x-T₀）-（T_g-T₀）/（T_n-T₀）,其中T_g为玻璃转变温度,T₀为理想玻璃转变温度.统计结果显示,ω₀与临界冷却速率具有较高的相关性,R²高达09626.进一步分析表明：新提出的ω₀参数可以合理地解释过冷熔体的黏度、脆性、液相稳定性、热稳定性以及T_rg、ΔT_x、γ、γ_m、ΔT_rg、α、β、δ和φ等参数与GFA的关系. 关键词： 块体非晶合金 黏度 脆性 玻璃形成能力     

Polarization properties of Li2−x Na x Ge4O9 (0.2 ≤ x ≤ 0.3) crystals

The polarization switching in sinusoidal fields and the pyroelectric properties of Li_2?x Na _x Ge₄O₉ (0.2 ≤ x ≤ 0.3) crystals are measured in the temperature range T _c ?T ≤ 40 K. The behavior of the P?E hysteresis loops with variations in temperature is investigated for crystals with phase transition temperatures T _c < 300 K and T _c > 300 K. It is shown that, for crystals with phase transition temperatures T _c < 300 K, the temperature dependence of the hysteresis loop exhibits a behavior typical of crystals with second-order phase transitions. The crystals with phase transition temperatures T _c > 300 K are characterized by double hysteresis loops in the temperature range T _c ?T ₁ ≈ 30 K. The correlation between the polarization properties and possible structural transformations of the Li_2?x Na _x Ge₄O₉ crystals due to the change in the concentration ratio of Na and Li ions is discussed.     

Ferromagnetism in a new dilute magnetic semiconductor Sb<Subscript>2−<Emphasis Type="Italic">x</Emphasis></Subscript>Cr<Subscript>x</Subscript>Te<Subscript>3</Subscript>

Magnetic and galvanomagnetic properties of single crystals of a new dilute magnetic semiconductor p-Sb_2?xCr_xTe₃ (x = 0, 0.0115, 0.0215) are investigated in a temperature range of 1.7–300 K. A ferromagnetic phase with a Curie temperature of T_C ≈ 5.8 (x = 0.0215) and 2.0 K (x = 0.0115) is detected. The easy magnetization axis is parallel to the C₃ crystallographic axis. Analysis of the Shubnikov-de Haas effect observed in these crystals in strong magnetic fields leads to the conclusion that the hole concentration decreases as a result of doping with Cr. Negative magnetoresistance and the anomalous Hall effect are observed in Cr-doped samples at liquid helium temperature.     

Anisotropy of the transport properties of single-crystal Bi2 Te3 disordered by electron bombardment

Using single-crystal samples of Bi₂Te₃ bombarded by 5-MeV electrons at a temperature of 250 K, we study the electrical resistivity and the Hall effect in the temperature range 1.7–370 K and the Shubnikov-de Haas effect at T=4.2 K in magnetic fields up to 14 T. We find that electron bombardment of Bi₂Te₃ crystals results in a transition from the metallic p-type state to the metallic state with a Fermi surface. Annealing at 350 K eliminates the radiation defects and restores the p-type metallic conductance. Zh. éksp. Teor. Fiz. 113, 1787–1798 (May 1998)     

Magnetic and electric studies of a new Co(II) perovskite-like material

Structural phase transitions in the perovskite-like material [(CH₄)₁₂(NH₃)₂]CoCl₄ have been observed using differential thermal scanning. The material shows an order-disorder transition at T ₁ = 396 ± 5 K with entropy, (ΔS ₁) = 12.8 J/mole/K. A "chain melting" transition with a major endothermic peak at T ₂ = 337 ± 3 K and a minor one at T ′ = 316 ± 2 K, has total entropy ΔS = 28 J/mole/K. At low temperatures, the transitions at T ₃ = 288 ± 3 K and at T ₄ = 188 ± 3 K, have entropies of ΔS ₃ = 14.4 J/mole/K and ΔS ₄ = 2.6 J/mole/K respectively. AC magnetic susceptibility in the temperature range 78-290 K, in a magnetic field of 160 A/m and at a frequency of 320 Hz is presented. The results indicate changes in symmetry at 188 K. Dielectric permittivity has been studied as a function of temperature in the range 300-430 K and frequency range (60 Hz-100 kHz), confirming the observed transitions. The dielectric permittivity reflects rotational and conformational transition for the material. The variation of the real part of the conductivity with temperature is thermally activated with different activation energies in the range of ionic hopping. The temperature dependence of the dc conductivity and that of the ions hopping rate have indicated that the concentration of mobile ions is independent of temperature. The dependence of the conductivity on frequency follows the universal power law, <artwork name="GPHT31040ei1"> in the temperature range 340 K<T<390 K. Values 0 <s ₁ <1 dominate at low frequency and correspond to translational hopping motion and values 1<s ₂<2 dominate at high frequencies and correspond to well localized hopping and/or reorientational motion. For T > 396 K, the AC conductivity was fitted to <artwork name="GPHT31040ei2"> with 0<s<1. Comparison with the corresponding Cu-containing material is discussed.     

Far infrared and phase transitions in ferroelectric materials

Abstract

A number of far infrared absorption bands are found in molecular and hydrogen-bonded crystals when there are several formula units in the primitive cell. They are very sensitive to the crystal structure and constitute a convenient probe for looking at small changes in the structure, especially at low temperatures where there is a lack of X-Ray data. As well known examples, the case of LTT (Lithium Thallium Tartrate) where the absorption band observed at 21 cm^?1 at room temperature softens down to 8 cm^?1 at the Curie temperature (T_c = 12 K), and LiNH₄SO₄ which has a phase transition at 26 K, will be considered.

It is less known that some ferroelectric crystals can be studied as very thick single crystal plates (thickness t up to 10 mm) at 4 K, and they show in some cases a far IR transmission that is much higher than expected from the study of thin plates (i.e. t = 20 μm). In fact the transmission does not decrease very much when thickness is higher than some specific value t ₀/2. The crystal is not homogeneous at 4 K. A model with a far IR absorbing surface layer (thickness t ₀/2) and a transparent bulk is a good first approximation.

At some temperature T ₀ located between liquid helium and liquid nitrogen temperatures, the center of the bulk undergoes a phase transition from the absorbing phase into the transparent one. When temperature is still lowered, the transparent phase is extended towards the surface with an incommensurate phase between the surface and the bulk.