B(E2) upward arrow measurements for radioactive neutron-rich ge isotopes: reaching the N=50 closed shell

The B(E2;0(+)(1)-->2(+)(1)) values for the radioactive neutron-rich germanium isotopes (78,80)Ge and the closed neutron shell nucleus 82Ge were measured at the HRIBF using Coulomb excitation in inverse kinematics. These data allow a study of the systematic trend between the subshell closures at N=40 and 50. The B(E2) behavior approaching N=50 is similar to the trend observed for heavier isotopic chains. A comparison of the experimental results with a shell model calculation demonstrates persistence of the N=50 shell gap and a strong sensitivity of the B(E2) values to the effective interaction.     

(68)(28)Ni(40): Magicity versus superfluidity

The neutron-rich (66,68)Ni have been produced at GANIL via interactions of a 65.9A MeV 70Zn beam with a 58Ni target. Their reduced transition probability B(E2;0(+)(1)-->2+) has been measured for the first time by Coulomb excitation in a (208)Pb target at intermediate energy. The B(E2) value for (68)Ni(40) is unexpectedly small. An analysis in terms of large scale shell model calculations stresses the importance of proton core excitations to reproduce the B(E2) values and indicates the erosion of the N = 40 harmonic-oscillator subshell by neutron-pair scattering.     

Lowest excitations in 56Ti and the predicted N=34 shell closure

Recent experimental characterization of the subshell closure at N=32 in the Ca, Ti, and Cr isotones has stimulated shell-model calculations that indicated the possibility that the N=34 isotones of these same elements could exhibit characteristics of a shell closure, namely, a high energy for the first excited 2(+) level. To that end, we have studied the decay of 56Sc produced in fragmentation reactions and identified new gamma rays in the daughter N=34 isotone 56Ti. The first 2(+) level is found at an energy of 1127 keV, well below the expected position that would indicate the presence of an N=34 shell closure in 56Ti.     

(Au)_核(Ag)_壳纳米微粒-火焰原子吸收光谱法测定过氧化氢

在90 ℃水浴条件下,以粒径为10 nm的纳米金做晶种,用柠檬酸三钠还原硝酸银,制备了平均粒径为30 nm的（Au）核（Ag）壳纳米微粒,用高速离心纯化除去过量的柠檬酸三钠获得了较纯的（Au）核（Ag）壳纳米微粒。在pH 3.8的HAc-NaAc缓冲溶液中,Fe2＋催化H2O2反应产生的羟基自由基可氧化（Au）核（Ag）壳纳米微粒生成银离子。离心后,离心液中的银离子可用火焰原子吸收光谱法在328.1 nm波长处测量。随着H2O2浓度增大,离心液中银离子浓度增加,其吸光度值增加。H2O2浓度在2.64～42.24 μmol·L-1范围内与上清液中银离子的原子吸收值ΔA呈良好的线性关系,回归方程为ΔA=0.014c-0.013 1, 相关系数为0.998 4,检出限为0.81 μmol·L-1 H2O2。当用于水样中H2O2的测定,获得了满意的结果。     

An investigation of competition on the dynamic magnetic properties of the core/shell nanowire

In this study, we investigate the dynamic magnetic properties of Ising-type core/shell nanowires (NW) for different spin systems. The model of NW X_(Spin-1/2)@Y with Y = Spin-1/2, Spin-1 and Spin-3/2 are considered for discussing an effect of the nature of shell particle on the dynamic properties. The mean-field theory and Glauber-type stochastic dynamics have been successfully applied to this, and the results of the dynamic magnetic properties for the core/shell NW are obtained. Different shell spin states are employed to the analysis of dynamic magnetic behavior for core/shell NW. Results of numerical calculation for the magnetization and coercivity curves are discussed for the effect of shell particles, shell interaction and oscillating field frequency. All results present that dynamic magnetic properties of the NW strongly dependent on the shell particle and the shell interaction.     

Large-scale shell model calculations for odd-odd <Superscript>58-62</Superscript>Mn isotopes

Large-scale shell model calculations have been carried out for odd-odd ^58-62Mn isotopes in two different model spaces. The first set of calculations has been carried out in full fp shell valence space with two recently derived fp shell interactions namely GXPF1A and KB3G treating ⁴⁰Ca as core. The second set of calculations has been performed in the fpg _9/2 valence space with the fpg interaction treating ⁴⁸Ca as core and imposing a truncation by allowing up to a total of six particle excitations from the 0f _7/2 orbital to the upper fp orbitals for protons and from the upper fp orbitals to the 0g _9/2 orbital for neutrons. For low-lying states in ⁵⁸Mn , KB3G and GXPF1A both predict good results and for ⁶⁰Mn , KB3G is much better than GXPF1A. For negative-parity and high-spin positive-parity states in both isotopes the fpg interaction is required. Experimental data on ⁶²Mn is sparse and therefore it is not possible to make any definite conclusions. More experimental data on negative-parity states is needed to ascertain the importance of 0g _9/2 and higher orbitals in neutron-rich Mn isotopes.     

Air stability and magnetic properties of GdN, TiN, and (Gd,Ti)N nanoparticles

GdN, TiN, and (Gd,Ti)N nanoparticles were prepared by arc evaporating Gd, Ti, and Gd-Ti alloys in N₂, respectively. Most of these nanoparticles show narrow size distribution with average diameter of 20 nm. Shell/core structure was observed in the (Gd,Ti)N nanoparticles, in which the shell was formed by surface reaction with air. (Gd,Ti)N nanoparticles are more stable than GdN nanoparticles in air due partially to the formation of the protective shell. The Curie temperature of GdN nanoparticles is lower than that of the bulk GdN. Both GdN and (Gd, Ti)N nanoparticles are difficult to reach magnetic saturation and show zero coercivity.     

The reactions 50,52Cr(d, 6Li) 46,48Ti at Ed = 651 MeV

The ^50,52Cr(d, ⁶Li) ^46,48Ti reactions have been studied at E_d = 65 MeV bombarding energy. Angular distributions of outgoing Li particles were measured for final states in ^46,48Ti nuclei from 15° to 50° (lab). These were compared with zero-range and finite-range DWBA calculations in an α-cluster pick-up approximation to obtain relative α-spectroscopic factors.     

核壳结构磁性复合纳米材料的可控合成与性能

具有核/壳结构的磁性复合纳米材料是十分重要的功能材料,其综合物性受材料微结构的影响,而这很大程度上又取决于复合体系的可控合成.本文综述了近二十年来有关核/壳磁性复合纳米材料的制备、表征及性能研究方面的进展,讨论的体系主要有：铁氧体基永磁/软磁（反铁磁）复合纳米材料、非磁性体包覆磁性核而成的复合纳米材料、用磁性颗粒催化合成的碳基复合纳米材料、基于交换偏置效应而设计的复合纳米材料、核-壳同轴结构的一维复合纳米材料和核/壳/壳三元结构的磁性复合纳米材料等.构建复合体系的组分包括M型永磁铁氧体、3d过渡金属（及其合金、氧化物、碳化物）、多铁化合物、非磁性体（比如绝缘体、半导体、有机分子）和碳材料等,着重分析了复合纳米材料的热稳定性、光致发光性能、光电催化能力、电化学特性、微波吸收性能、磁电阻效应、永磁体性能、高频软磁特性、交换偏置效应及其相关现象.最后,对核/壳结构磁性复合纳米材料的未来发展趋势进行了展望,并在基础研究和改性应用方面提出了一些建议.     

Upon a magnetic composite preparation based on magnetite and poly(succinimide)-b-poly(ethylene glycol) shell

Taking into account that magnetic particles with suitable surface characteristics have a high potential for the use in a lot of in vitro and in vivo applications, in the study is presented the in situ preparation of a core-shell magnetic composite based on the magnetite core and the shell composed from the poly(succinimide)-b-poly(ethylene glycol) copolymer. The average particle size of the synthesized magnetic microspheres is in the range of 6.5-8.8 μm with a magnetite content of around 11%. The saturation magnetization of the microspheres was found 26.8 emu/g, the magnetic microspheres being characterized by superparamagnetic properties. The particles have combined properties of high magnetic saturation and biocompatibility and interactive functions at the surface through the block copolymer shell. The surface of the magnetic particles has also the possibility for further functionalization or the attachment of various bioactive molecules after the hydrolysis of the succinimide cycle and the resulting carboxylic group.     

Synthesis and Raman signature for the formation of CdO/MnO2 (core/shell) nanostructures

In the present report, bare CdO and CdO/MnO₂ core/shell nanostructures of various cores and different shell sizes were synthesized using co‐precipitation method. The phase, size, shape and structural details of the bare CdO and CdO/MnO₂ nanostructures were investigated by X‐ray diffraction, transmission electron microscopy (TEM), and Raman spectroscopy measurements. TEM micrographs confirm the formation of core/shell nanostructures. The presence of CdO (core) and MnO₂ (shell) crystal phases was determined by analyzing the Raman data of bare CdO and CdO/MnO₂ core/shell nanostructures. The Raman spectra of bare CdO nanostructures contain one broad intense convoluted envelop of three bands in the spectral range of 200–500 cm⁻¹ and a weaker band located at ~940 cm⁻¹. The intensity of these two Raman bands is decreased with the increase of shell size and disappeared completely for the shell size 5.3 ± 1 nm. Further, two new Raman bands appeared at ~451 and ~665 cm⁻¹ for the shell size 1.3 ± 0.1 nm. These two Raman bands are assigned to the deformation of Mn–O–Mn and Mn–O stretching modes of MnO₂. The intensity of these two Raman bands is enhanced with the increase of shell size and attains a maximum value for the shell size 5.3 ± 1 nm. The disappearance of characteristics Raman bands of CdO phase and the appearance of characteristics Raman bands corresponding to MnO₂ phase for nanostructures of shell size 5.3 ± 1 nm authenticate the presence of CdO as core and MnO₂ as shell in the core/shell nanostructures. Copyright © 2014 John Wiley & Sons, Ltd.     

1 states and the 1f-2p shell model

The observed 1⁺ cross sections from (³He, p) reactions on even Ca, Ti, Cr and Fe targets are analyzed in terms of an approximate sum rule. It is shown that the summed 1⁺ cross sections in a qualitative way depend on the proton and neutron number of the target as predicted from the shell model.     

Magnetoexcitons in core/shell quantum dots

The ground-state energies of the “bright” and “dark” excitons formed by an electron and a hole localized in a thin spherical shell subjected to a high magnetic field are calculated. This model corresponds to a core/shell quantum dot. The high-field condition implies that the magnetic length is much shorter than the radius of the sphere. It is found that the ground-state energy of the bright exciton exhibits an unusual magnetic-field dependence: E ₀ ～ H ^2/3.     

Effect of Configuration Mixing and Core Excitation on Predominantly (f 7/2)n States in the Lower fp Shell Nuclei

Shell model calculations in the lower fp shell region, (for ^44,45Ca and ⁴⁷Sc nuclei) have been performed, with different model spaces, to probe the effect of configuration mixing from the p^3/2, p^1/2 and f_5/2 orbitals on the predominantly (f_7/2)ⁿ states and the contribution arising from the excitation of the N = Z = 16 core. Our calculations indicate that excitation of nucleons across the N = Z = 16 magic shell closure do contribute significantly towards the wavefunctions of the observed level structures of ^44,45Ca nuclei. However the inclusion of these configurations did not result in a better agreement for the observed level structure of ⁴⁷Sc nulcei. A plaussible explaination for this phenomena could be attributed to the two-body matrix elements used and calls for a detailed micro-scopic calculations involving fundamental interactions substantiated by additional spectroscopic data such as lifetime measurements to have an unambigious understanding of the intrinsic configurations of nuclei in this region.     

On the extended basis shell model and two-nucleon transfer

The enhancement of two-nucleon transfer reactions predicted by the extended basis shell-model (EBSM) calculations of Feng, Ibarra and Vallieres and other theorists, is shown to be a higher order manifestation of the pairing effects in nuclei. A simple schematic model is introduced which illustrates the constructive interference of the contributions from the highly excited shell-model states included in the EBSM. The model can be used to estimate the effect of ground-state correlations of the closed-shell core. The results indicate that the assumption of an inert core in EBSM calculations introduces negligible error in cases in which the addition of a nucleon pair to a closed shell is treated. However, in the case of two-nucleon removal from a closed shell, including the effects of correlations may significantly enhance the cross section. A suggestion is made for including these effects in EBSM calculations.     

Dynamic magnetic and hysteretic properties of the different type core/shell nanostructures: the effect of geometry of wire shape

In the present study, we examine by comparison the dynamic magnetic and hysteretic properties of nanostructures with different magnetic core/shell particles confined within a shape structure of the wire. The model of nanostructures with core?=?spin-1 and shell?=?spin-3/2, namely cylindrical, cubic and hexagonal nanowire, is proposed for studying the effect of the geometry of wire shape on the magnetic and hysteretic properties. The results were obtained by mean-field theory as well as Glauber-type stochastic dynamics, and focused the response to thermal and hysteretic behaviours of systems. All results display dynamic magnetic properties of the nanostructure strongly dependent on the geometry of wire shape. Moreover, temperature and crystal field are proposed as the important factors affecting the dynamic properties of wire systems.     

Magnetic dipole moments near Sn: Measurement on isomeric 11/2 states in odd-A Te and Te by NMR/ON

On-line low temperature nuclear orientation (OLNO) experiments have been performed on the odd-A Te isotopes ¹³¹Te and ¹³³Te using the technique of nuclear magnetic resonance on oriented nuclei (NMR/ON). The magnetic moments of the isomeric 11/2⁻ states have been measured extending the known data on these states in the Te isotopes up to the neutron shell closure at N = 82. The contribution to the 11/2⁻ magnetic moment in ¹³³Te due to core polarisation is calculated using an RPA shell model as well as corrections to the magnetic dipole operator caused by mesonic exchange currents. The neutron number dependence of the magnetic moments of the 11/2⁻ isomers in heavy Te isotopes is discussed in terms of particle-core coupling model (PCM) calculations.     

Ab initio study of 40Ca with an importance-truncated no-core shell model

We propose an importance truncation scheme for no-core shell model or configuration interaction approaches, which enables converged calculations for nuclei well beyond the p shell. It is based on an a priori measure for the importance of individual basis states constructed by means of many-body perturbation theory. Only the physically relevant states of the no-core model space are considered, which leads to a dramatic reduction of the basis dimension. We analyze the validity and efficiency of this truncation scheme using different realistic nucleon-nucleon interactions and compare to conventional no-core shell model calculations for 4He and 16O. Then, we present first converged calculations for the ground state of 40Ca within no-core model spaces including up to 16 PlanckOmega excitations using realistic low-momentum interactions. The scheme is universal and can be easily applied to other quantum many-body problems.     

Facile synthesis and characterization of glass/cobalt core/shell composite spheres with tunable shell morphologies

Polyhedral cobalt microcrystals assembled on hollow glass spheres are successfully synthesized by a facile and easy-control hydrothermal reduction process, and thus hierarchical glass/cobalt core/shell composite hollow spheres are fabricated with low-density (0.96 g cm⁻³). By properly tuning the process conditions and the component of the reaction solution, a series of composite spheres with gradient in morphologies of the shell layer can be prepared. Based on a series of contrast experiments, the probable formation mechanism of the core/shell hierarchical structures is proposed. The magnetic properties of the products are studied and the results demonstrate that the composite spheres present ferromagnetic properties related to the special shell morphologies. The composite hollow spheres thus obtained may have some promising applications in the fields of low-density magnetic materials, conduction, and catalysis, etc. This work provides an additional strategy to prepared core/shell composite spheres with tailored shell morphology and magnetic properties.