Mullins Effect for a Cylinder Subjected to Combined Extension and Torsion

We study the Mullins effect for a circular cylinder of incompressible, isotropic material under loading cycles of combined extension and torsion. The analysis is based on the constitutive model recently proposed in De Tommasi et al. (J. Rheol. 50: 495–512, 2006). This model assumes that the mechanical response at each material point results as a homogenized effect of a mixture of different materials with variable activation and breaking thresholds. We show the feasibility of this approach to treat complex, inhomogeneous deformations. In particular, we obtain for the generic loading path the analytical expressions of the stress field, of the axial force, and of the twisting moment. The proposed model exhibits the Mullins stress softening effect in the case of simple extension, simple torsion, and combined extension and torsion. We analyze in detail the path dependent behavior and the preconditioning effects.      

Hysteresis cycles and fatigue criteria using anelastic models based on fractional derivatives

The constitutive equation and the fatigue of anelastic media are described by using fractional order derivatives. The stress–strain relation, based on a generalization of the Kelvin–Voigt model, describes typical hysteresis cycles with the stress increasing as the number of cycles increases, a phenomenon known as cyclic hardening and observed in many materials such as, for instance, steel. Criteria are established to find the number of cycles which may cause fatigue for a strain with a given amplitude and frequency. They are based on the yield and fatigue stresses, on the melting temperature through the dissipated energy, and on the strain energy. In all the cases, it is seen that the number of cycles to failure is inversely proportional to the amplitude and to the frequency of the applied strain. Comparison to experimental data indicates that the model satisfies, at least qualitatively, the behavior of real materials under cyclic loading.     

Coupled nonlinear constitutive models for rarefied and microscale gas flows: subtle interplay of kinematics and dissipation effects

The constitutive relations of gases in a thermal nonequilibrium (rarefied and microscale) can be derived by applying the moment method to the Boltzmann equation. In this work, a model constitutive relation determined on the basis of the moment method is developed and applied to some challenging problems in which classical hydrodynamic theories including the Navier–Stokes–Fourier theory are shown to predict qualitatively wrong results. Analysis of coupled nonlinear constitutive models enables the fundamentals of gas flows in thermal nonequilibrium to be identified: namely, nonlinear, asymmetric, and coupled relations between stresses and the shear rate; and effect of the bulk viscosity. In addition, the new theory explains the central minimum of the temperature profile in a force-driven Poiseuille gas flow, which is a well-known problem that renders the classical hydrodynamic theory a global failure.     

A 3D finite strain phenomenological constitutive model for shape memory alloys considering martensite reorientation

Most devices based on shape memory alloys experience both finite deformations and non-proportional loading conditions in engineering applications. This motivates the development of constitutive models considering finite strain as well as martensite variant reorientation. To this end, in the present article, based on the principles of continuum thermodynamics with internal variables, a three-dimensional finite strain phenomenological constitutive model is proposed taking its basis from the recent model in the small strain regime proposed by Panico and Brinson (J Mech Phys Solids 55:2491–2511, 2007). In the finite strain constitutive model derivation, a multiplicative decomposition of the deformation gradient into elastic and inelastic parts, together with an additive decomposition of the inelastic strain rate tensor into transformation and reorientation parts is adopted. Moreover, it is shown that, when linearized, the proposed model reduces exactly to the original small strain model.     

A constrained theory for single crystal shape memory wires with application to restrained recovery

The theory of thin wires developed in Dret and Meunier (Comptes Rendus de l’Académie des Sciences. Série I. Mathématique 337:143–147, 2003) is adapted to phase-transforming materials with large elastic moduli in the sense discussed in James and Rizzoni (J Elast 59:399–436, 2000). The result is a one-dimensional constitutive model for shape memory wires, characterized by a small number of material constants. The model is used to analyze self-accommodated and detwinned microstructures and to study superelasticity. It also turns out that the model successfully reproduces the behavior of shape memory wires in experiments of restrained recovery (Tsoi et al. in Mater Sci Eng A 368:299–310, 2004; Tsoi in 50:3535–3544, 2002; S̆ittner et al. in Mater Sci Eng A 286:298–311, 2000; vokoun in Smart Mater Struct 12:680–685, 2003; Zheng and Cui in Intermetallics 12:1305–1309, 2004; Zheng et al. in J Mater Sci Technol 20(4):390–394, 2004). In particular, the model is able to predict the shift to higher transformation temperatures on heating. The model also captures the effect of prestraining on the evolution of the recovery stress and of the martensite volume fraction.     

A unified model for polystyrene–nanorod and polystyrene–nanoplatelet melt composites

We present a unified constitutive model capable of predicting the steady shear rheology of polystyrene (PS)–nanoparticle melt composites, where particles can be rods, platelets, or any geometry in between, as validated against experimental measurements. The composite model incorporates the rheological properties of the polymer matrix, the aspect ratio and characteristic length scale of the nanoparticles, the orientation of the nanoparticles, hydrodynamic particle–particle interactions, the interaction between the nanoparticles and the polymer, and flow conditions of melt processing. We demonstrate that our constitutive model predicts both the steady rheology of PS–carbon nanofiber composites and the steady rheology of PS–nanoclay composites. Along with presenting the model and validating it against experimental measurements, we evaluate three different closure approximations, an important constitutive assumption in a kinetic theory model, for both polymer–nanoparticle systems. Both composite systems are most accurately modeled with a quadratic closure approximation.     

A Phenomenological Constitutive Model for Describing Thermo-Viscoplastic Behavior of Al-Zn-Mg-Cu Alloy Under Hot Working Condition

In order to predict the high-temperature deformation behavior of Al-Zn-Mg-Cu alloy, the hot compression tests were conducted in the strain rate range of (0.001–0.1)s⁻¹ and the forming temperature range of (573–723) K. Based on the experimental results, Johnson-Cook model was found inadequate to describe the high-temperature deformation behavior of Al-Zn-Mg-Cu alloy. Therefore, a new phenomenological constitutive model is proposed, considering the coupled effects of strain, strain rate and forming temperature on the material flow behavior of Al-Zn-Mg-Cu alloy. In the proposed model, the material constants are presented as functions of strain rate. The proposed constitutive model correlates well with the experimental results confirming that the proposed model can give an accurate and precise estimate of flow stress for the Al-Zn-Mg-Cu alloy investigated in this study.     

Codimension-two bifurcation analysis in two-dimensional Hindmarsh–Rose model

In this paper, we analyze the codimension-2 bifurcations of equilibria of a two-dimensional Hindmarsh–Rose model. By using the bifurcation methods and techniques, we give a rigorous mathematical analysis of Bautin bifurcation. The main result is that no more than two limit cycles can be bifurcated from the equilibrium via Hopf bifurcation; sufficient conditions for the existence of one or two limit cycles are obtained. This paper also shows that the model undergoes a Bogdanov–Takens bifurcation which includes a saddle-node bifurcation, an Andronov–Hopf bifurcation, and a homoclinic bifurcation. In some case, the globally asymptotical stability is discussed.     

Constitutive modeling of shape memory alloy wire with non-local rate kinetics

A constitutive modeling approach for shape memory alloy (SMA) wire by taking into account the microstructural phase inhomogeneity and the associated solid–solid phase transformation kinetics is reported in this paper. The approach is applicable to general thermomechanical loading. Characterization of various scales in the non-local rate sensitive kinetics is the main focus of this paper. Design of SMA materials and actuators not only involve an optimal exploitation of the hysteresis loops during loading–unloading, but also accounts for fatigue and training cycle identifications. For a successful design of SMA integrated actuator systems, it is essential to include the microstructural inhomogeneity effects and the loading rate dependence of the martensitic evolution, since these factors play predominant role in fatigue. In the proposed formulation, the evolution of new phase is assumed according to Weibull distribution. Fourier transformation and finite difference methods are applied to arrive at the analytical form of two important scaling parameters. The ratio of these scaling parameters is of the order of 10⁶ for stress-free temperature-induced transformation and 10⁴ for stress-induced transformation. These scaling parameters are used in order to study the effect of microstructural variation on the thermo-mechanical force and interface driving force. It is observed that the interface driving force is significant during the evolution. Increase in the slopes of the transformation start and end regions in the stress–strain hysteresis loop is observed for mechanical loading with higher rates.      

Numerical Modeling of Hydraulic Hysteresis in Unsaturated Soils

This article presents the implementation of the constitutive model of Wheeler (Geotechnique 53(1):41–54, 2003) for coupling of hydraulic hysteresis and mechanical behavior of unsaturated soils in a fully coupled transient hydro-mechanical finite element (FE) model (computer code UNSATEX) developed by the authors. The constitutive model considers the effects of irreversible changes of degree of saturation on stress–strain behavior and the influence of plastic volumetric strains on the water retention behavior. The mathematical framework and the numerical implementation of the constitutive model are presented and discussed. The FE model is verified and validated against analytical predictions [obtained using the model of Wheeler (Geotechnique 53(1):41–54, 2003] as well as experimental results from the literature involving unsaturated soils undergoing various combinations of drying, wetting, loading, unloading, and reloading paths. Comparison of the results shows that the developed FE model can be used to predict various aspects of the behavior of unsaturated soils under drying and wetting as well as loading and unloading paths. The merits and limitations of the FE model are highlighted.     

Isotropic hardening in micropolar plasticity

Experimental evidence for length scale effects in plasticity has been provided, e.g., by Fleck et al. (Acta Metall. Mater. 42:475–487, 1994). Results from torsional loadings on copper wires, when appropriately displayed, indicated that, for the same shear at the outer radius, the normalized torque increased with decreasing specimen radius. Modeling of the constitutive behavior in the framework of micropolar plasticity is a possibility to account for length scale effects. The present paper is concerned with this possibility and deals with the theory developed by Grammenoudis and Tsakmakis (Contin. Mech. Thermodyn. 13:325–363, 2001; Int. J. Numer. Methods Eng. 62:1691–1720, 2005; Proc. R. Soc. 461:189–205, 2005). Both isotropic and kinematic hardening are present in that theory, with isotropic hardening being captured in a unified manner. Here, we discuss isotropic hardening composed of two parts, responsible for strain and gradient effects, respectively.     

On the thermodynamics of some generalized second-grade fluids

The generalized second-grade fluids, which have been used for modeling the creep of ice and the flow of coal-water and coal-oil slurries, are among the simplest non-Newtonian fluid models that can describe shear-thinning/thickening and exhibit normal stress effects. In this article, we conduct thermodynamic analysis on a class of generalized second-grade fluids, one distinguishing feature of which is the existence of a constitutive function Φ that describes frictional heating. We work within the framework of Serrin’s original formulation of neoclassical thermodynamics, where internal energy and entropy functions, if they exist for a continuous body at all, are to be derived from the classical First Law and (quantitatively reformulated) Second Law of thermodynamics for cycles. For the class of generalized second-grade fluids in question, we show from the First Law that an internal energy density u exists, and we derive the equation of energy balance; from the Second Law, we demonstrate the existence of an entropy density s and derive the Clausius–Duhem inequality that it satisfies. We obtain explicit expressions for u, s and the frictional heating Φ, and derive thermodynamic restrictions on the material functions of temperature μ, α ₁, and α ₂ that appear in the constitutive relation for the Cauchy stress. For the special case of second-grade fluids, our expressions for u and s agree with those which Dunn and Fosdick [6] derived under the theoretical framework of the rational thermodynamics of Coleman and Noll.     

Rice Local Phase Angle Study for a Delamination Problem Between a Shape Memory Alloy and an Elastic Material

The present study is an extension of a recent paper of Freed et al. (J Mech Phys Solids 56:3003–3020, 2008). The final aim is to describe the transformation toughening behavior of a static crack along an interface between a shape memory alloy (SMA) and a linear elastic isotropic material. With an SMA as an equivalent Huber–Von Mises stress model (hypothesis of symmetric behavior between tension and compression), Freed et al. determine the initiation (ending) phase transformation yield surfaces in terms of the local phase angle introduced by Rice et al. (Metal ceramic interfaces, Pergamon Press, New York, pp 269–294, 1990). In this paper we give the general framework to determine this angle for a model integrating the asymmetry between tension and compression (experimentally measured: Vacher and Lexcellent in Proc ICM 6:231–236, 1991; Orgéas and Favier in Acta Mater 46(15):5579–5591, 2000), the Huber–Von Mises model being only a particular case. We demonstrate the local phase angle existence in an appropriate framing domain and give a sufficient hypothesis for its uniqueness and an algorithm to obtain it. Estimates are obtained in terms of physical quantities such as the Young modulus ratio, the bimaterial Poisson modulus values and also the choice of the yield loading functions. Finally, we illustrate this theoretical study by an application linking the asymmetry intensity on the width and the shape on predicted phase transformation surfaces and by a comparison with the symmetric case.     

Development of a local continuous sampling probe for the equivalence air–fuel ratio measurement. Application to spark ignition engine

This paper is a contribution to the development of an original technique for measuring the in-cylinder equivalence air–fuel ratio. The main objective was to construct an instrument able to furnish instantaneous values of hydrocarbon concentration for many consecutive cycles at a definite location, especially at the spark plug location. The probe is based on a hot-wire-like apparatus, but involves catalytic oxidation on the wire surface in order to be sensitive to the hydrocarbon concentration. In this paper, we present the different steps needed to develop and validate the probe. The first step focuses on the geometric configuration to simplify as much as possible the mass transfer phenomena on the wire. The second step is a parametric study to evaluate the sensitivity, confidence and lifetime of the wire. By physical analysis, we propose a relationship between the electrical signal and the air–fuel equivalence ratio of the sampled gases. The third step is the application of the probe to in-cylinder motored engine measurements, which confirms the ability of the technique to characterise, quantitatively, the homogeneity of the air–fuel mixture, especially during the compression stroke. This work points out that the global sensitivity is estimated at 4 V per unit of equivalence air–fuel ratio and the response time is estimated at about 400 μs. The equivalence air–fuel ratio range is from pure air to 1.2. Experiments show that it is necessary to calibrate the system before use because of the existence of multiple catalysis states. The probe presents advantages associated with its simplicity, its low cost and its direct engine application without any modifications. Received: 1 November 2000 / Accepted: 30 May 2001     

Nonlinear damping in a micromechanical oscillator

Nonlinear elastic effects play an important role in the dynamics of microelectromechanical systems (MEMS). A Duffing oscillator is widely used as an archetypical model of mechanical resonators with nonlinear elastic behavior. In contrast, nonlinear dissipation effects in micromechanical oscillators are often overlooked. In this work, we consider a doubly clamped micromechanical beam oscillator, which exhibits nonlinearity in both elastic and dissipative properties. The dynamics of the oscillator is measured in both frequency and time domains and compared to theoretical predictions based on a Duffing-like model with nonlinear dissipation. We especially focus on the behavior of the system near bifurcation points. The results show that nonlinear dissipation can have a significant impact on the dynamics of micromechanical systems. To account for the results, we have developed a continuous model of a geometrically nonlinear beam-string with a linear Voigt–Kelvin viscoelastic constitutive law, which shows a relation between linear and nonlinear damping. However, the experimental results suggest that this model alone cannot fully account for all the experimentally observed nonlinear dissipation, and that additional nonlinear dissipative processes exist in our devices.     

Rheological characterization and constitutive modeling of bread dough

Bread dough (a flour–water system) has been rheologically characterized using a parallel-plate, an extensional, and a capillary rheometer at room temperature. Based on the linear and nonlinear viscoelastic and viscoplastic data, two constitutive equations have been applied, namely a viscoplastic Herschel–Bulkley model and a viscoelastoplastic K–BKZ model with a yield stress. For cases where time effects are unimportant, the viscoplastic Herschel–Bulkley model can be used. For cases where transient effects are important, it is more appropriate to use the K-BKZ model with the addition of a yield stress. Finally, the wall slip behavior of dough was studied in capillary flow, and an appropriate slip law was formulated. These models characterize the rheological behavior of bread dough and constitute the basic ingredients for flow simulation of dough processing, such as extrusion, calendering, and rolling.     

Viscoelastic properties of phosphoric and oxalic acid-based chitosan hydrogels

In a previous work, we have shown that chitosan true physical gelation occurs in some organic and inorganic acids (Hamdine et al. 2004). Two systems presenting similar gelation mechanisms were characterized furthermore in order to investigate the sol–gel transition: the chitosan–phosphoric acid and the chitosan–oxalic acid systems. By performing rheological measurements in the framework of linear viscoelasticity, we have investigated the effect of time, temperature, and polymer concentration on the gelation evolution. For both acid-based systems, gelation occurred above a critical polymer concentration around 5% w/v (g/100 ml) of chitosan. Isothermal time sweep experiments showed that the gelation occurs in three stages: (i) incubation; (ii) rapid increase of G′; and (iii) a last stage where G′ slowly reached its equilibrium value due to slow molecular diffusion. At the gel point, G′ and G′′ scaled with ω ⁿ , with n=0.55 for both acid-based systems and a fractal dimension d _f of 1.9. Cooling–heating cycles revealed that the gels showed thermoreversibility after one sequence, but became permanent during subsequent cycles.This revised version was published online in October 2005 with corrections to the author's name.     

A thermodynamics framework and numerical aspects for transformation-induced plasticity at large strains

In this work, we present a macroscopic material model for simulation transformation-induced plasticity, which is an important phenomenon in metal forming processes. The model is formulated within a thermodynamic framework at large strains. In order to account for both, phase transformation and plasticity, yield functions are related to these effects. Then, applying the concept of maximum dissipation evolution equations are obtained for the inelastic strains, the transformation strains, a hardening variable and the volume fraction of martensite. Furthermore the numerical implementation of the constitutive equations into a finite element program is described. In a numerical example we investigate the austenite-to-martensite phase transformation in a shaft subjected to thermo-mechanical loading in a hybrid-forming process.     

Stability of a fluid interface under tangential vibrations

The stability of the interface between two immiscible fluids of different density which occupy a plane horizontal layer performing harmonic horizontal oscillations is considered. Within the framework of the ideal fluid model a transformation reducing the problem of small plane perturbations to the Mathieu equation is found. Resonance instability domains associated with the formation of capillary-gravitational waves are investigated. A model which takes into account dissipation processes due to the presence of viscous friction is constructed. The role of the viscous dissipation in suppressing resonance instability is discussed. Perm’. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 3, pp. 25–31, May–June, 1998. The work was carried out with partial support from the Russian Foundation for Basic Research (project No. 95-01-00386).     

Immiscible Displacement in the Interacting Capillary Bundle Model Part II. Applications of Model and Comparison of Interacting and Non-Interacting Capillary Bundle Models

In the first part of this work (Dong et al., Transport Porous Media, 59, 1–18, 2005), an interacting capillary bundle model was developed for analysing immiscible displacement processes in porous media. In this paper, the second part of the work, the model is applied to analyse the fluid dynamics of immiscible displacements. The analysis includes: (1) free spontaneous imbibition, (2) the effects of injection rate and oil–water viscosity ratio on the displacement interface profile, and (3) the effect of oil–water viscosity ratio on the relative permeability curves. Analysis of a non-interacting tube bundle model is also presented for comparison. Because pressure equilibration between the capillaries is stipulated in the interacting capillary model, it is able to reproduce the behaviour of immiscible displacement observed in porous media which cannot be modelled by using non-interacting tube bundle models.