Impulse breakdown characteristics of the plane-to-plane electrode system with a needle-shaped protrusion in SF6

This paper presents the impulse pre-breakdown and breakdown characteristics of the plane-to-plane electrode system with a needle-shaped protrusion in SF₆ gas. The breakdown voltage–time (V–t) characteristics and the breakdown voltage–gas pressure (V–p) characteristics of a highly non-uniform SF₆ gas gap under positive and negative lightning impulse voltages are investigated in the pressure range between 0.1 and 0.5 MPa. The pre-breakdown developments are examined by the corona current and light emission measurements with high time resolution. As a result, the dielectric strengths versus time-to-breakdown of SF₆ gas gap under positive lightning impulse voltages were nearly independent of the gas pressure. The first streamer corona was initiated at the tip of the needle electrode, and the streamer corona pulses developed with a stepwise propagation. The discharge paths were zigzag, and the branches of the discharge channel for positive polarity were created. On the other hand, the leader channel in the negative polarity was thicker and brighter than that in the positive polarity.     

Abnormal polarity effect in nanosecond-pulse breakdown of SF6 and nitrogen

The breakdown of gas gaps in an inhomogeneous electric field at subnanosecond and nanosecond voltage pulse rise times are studied, and the famous polarity effect in point-to-plane gaps is investigated. It is shown that at a voltage pulse rise time of ∼0.5 ns, the inversion of polarity effect takes place not only in electronegative gases such as SF₆, but also occurs in electropositive nitrogen. The inversion of polarity effect is related to a delay of electron emission from the plane cathode on arrival of the ionization wave front anode to the cathode. It is found that with a voltage pulse rise time of ∼0.5 ns, the inversion of polarity effect occurs at SF₆ and SF₆–N₂ pressures of 0.25 MPa and lower, and with a voltage pulse rise time of 15 ns, at a SF₆ pressure lower than 0.12 MPa.     

Selection of the Time Parameters of Oscillating Impulse Voltages for On-Site Testing of Gas Insulated Switchgears (GIS)

GIS for operation voltages ≧ 245 kV can be tested with oscillating impulse voltages on site advantageously, because this H. V. test can be performed with easily mountable impulse generators. The IEC recommendation for on-site testing of GIS which is now under discussion doesn't fix the time parameters of the oscillating impulse voltages, but these influence the breakdown behaviour of slightly non-uniform fields with disturbances (sharpe edges, fixed or free-moving particles) in SF₂. For the mentioned GIS (≧ 245 kV) fixed disturbances are more dangerous than free-moving particles. Therefore the breakdown voltages of model insulations with a disturbance at the H.V. electrode (needle with length l=0…5 mm) in SF₆ (p₂₀=0.1…0.4 MPa) were investigated at oscillating lightning (OLI) and oscillating switching (OSI) impulse voltages with different times to crest. From the results, which were compared with those at aperiodic lightning (LI) or switching (SI) impulse voltages, permissible time parameters for OLI and OSI can be derived. On the basis of these parameters an impulse generator was designed which enables on-site testing for a wide range of the capacity of the tested GIS.     

Stochastic and Relaxation Processes in Argon by Measurements of Dynamic Breakdown Voltages

Statistically based measurements of breakdown voltages U _b and breakdown delay times td and their variations in transient regimes of establishment and relaxation of discharges are a convenient method to study stochastic processes of electrical breakdown of gases, as well as relaxation kinetics in afterglow. In this paper the measurements and statistical analysis of the dynamic breakdown voltages U _b for linearly rising (ramp) pulses in argon at 1.33 mbar and the rates of voltage rise k up to 800 V s ^–1 are presented. It was found that electrical breakdowns by linearly rising (ramp) pulses is an inhomogeneous Poisson process caused by primary and secondary ionization coefficients α , γ and electron yield Y variations on the voltage (time). The experimental breakdown voltage distributions were fitted by theoretical distributions by applying approximate analytical and numerical models. The afterglow kinetics in argon was studied based on the dependence of the initial electron yield on the relaxation time Y ₀ (τ ) derived from fitting of distributions. The space charge decay was explained by the surface recombination of nitrogen atoms present as impurities. The afterglow kinetics and the surface recombination coefficients on the gas tube and cathode were determined from a gas‐phase model. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Some Investigations of the Ignition and Development of Breakdown in Cylindrical Hollow Cathode Glow Discharges

The breakdown behaviour of a hollow cathode glow discharge is investigated in a cylindrical, hollow cathode structure having an internal diameter of 2 cm. The anode is a plane electrode across one end of the cathode cylinder. Pressures of argon between 20 and 107 Pa were used (0.15 to 0.80 torr), and applied voltages between 800 and 2500 V. It is shown that the statistical time lag for breakdown is in the range of ～ 1 ms and depends on the applied voltage, the gas pressure, and the history of operation of the discharge tube. The rise time of the discharge current ranges from about 10 ns at high pressure and voltage to about 200 ns at the lowest pressure and voltage used. The discharge propagates along the cathode axis at a speed of about 10⁸ cm s^?1. From the obtained data, a qualitative model of the first stage of the discharge is derived. Based on this model, a simple calculation gives values of Townsend modified first coefficient η at high values of E/N, 10⁴ < E/N < 8 · 10⁴ Td which fit well at the lowest E/N, where they approach the data of PENNING and KRUITHOF in argon. In contrast to the extremely short initial current-rise times, in the submicrosecond range, the discharge currents reach steady-state values only after about 300 μs.     

The sensitivity and dynamic response of field ionization gas sensor based on ZnO nanorods

Field ionization gas sensors based on ZnO nanorods (50–300 nm in diameter, and 3–8 μm in length) with and without a buffer layer were fabricated, and the influence of the orientation of nano-ZnO on the ionization response of devices was discussed, including the sensitivity and dynamic response of the ZnO nanorods with preferential orientation. The results indicated that ZnO nanorods as sensor anode could dramatically decrease the breakdown voltage. The XRD and SEM images illustrated that nano-ZnO with a ZnO buffer layer displayed high c-axis orientation, which helps to significantly reduce the breakdown voltage. Device A based on ZnO nanorods with a ZnO buffer layer could distinguish toluene and acetone. The dynamic responses of device A to the NO _x compounds presented the sensitivity of 0.045 ± 0.007 ppm/pA and the response speed within 17–40 s, and indicated a linear relationship between NO _x concentration and current response at low NO _x concentrations. In addition, the dynamic responses to benzene, isopropyl alcohol, ethanol, and methanol reveals that the device has higher sensitivity to gas with larger static polarizability and lower ionization energy.     

Statistical Property of Breakdown between Electrode and Shield in High-Voltage Vacuum Interrupter

Statistical property of the breakdown between stainless or copper electrode and stainless arc shield is studied by applying (250 × 2000)-?s switching impulses to model vacuum interrupters. Higher breakdown voltages are obtained in negative polarity than in positive polarity. The effective area of breakdown which takes the electric-field distribution on the anode surface into account is introduced to explain the polarity effect of breakdown voltage using Weibull statistics.     

A non-equilibrium atmospheric pressure Capacitively-Coupled-Plasma (CCP) driven at VHF (162 MHz) for plasma catalysis of CO2 into CO

The design of a Very-High-Frequency (VHF) 162 MHz driven atmospheric-pressure Capacitively-Coupled-Plasma (CCP), with top and bottom electrodes operated in push-pull configuration, powered via a Power-Splitting-Transmission-Line-Driver (PSTLD), is presented. Application to the reprocessing of carbon dioxide into carbon-monoxide in this "high” VHF atmospheric plasma is presented, demonstrating some behaviour of the plasma source. rf power in the system is characterized using measured current (~ 1′s Amps peak) and voltage (~ 10′s Volts peak) waveforms at the electrode; Both are sinusoidal confirming a glow-discharge operational condition. Analysis of Optical Emission Spectra results find a highly non-equilibrium plasma, with high vibrational temperatures (from N₂) in the range ~4000 K, while gas temperature, monitored by a thermocouple at the gas outlet, remains low ~300 K, and confirmed by analysis of the N₂ rotational bands. The relative density of CO produced, as a by-product of CO₂ dissociation, is measured optically using N₂ as an actinometer. The CO density increases with rf power and longer gas residence times in the plasma volume. The high VHF atmospheric plasma is found to operate in pure CO₂ flows (no helium) with minimal gas heating for the full range of power densities (specific energy input of 0.4–2 eV per molecule) investigated.     

Formation of Discharges between Glass Insulated Electrodes in Ne + 1% N2 Mixtures. II. Frequency Dependence and Discharge Modes

Discharges between glazed electrodes for p = 2.67 kPa Ne + 1% N₂ and pd = 1.3 kPa cm (p = gas pressure, d = electrode distance) are investigated. They are sustained by a sine wave voltage of variable frequency f. Measurements of the space time structure of the radiation emission provide information of the build up and quenching of discharges and of the structure of the fully developed ac-discharge. It is shown that the discharge types for the different values of frequency and amplitude of the sine wave sustaining voltage are dynamically developed Townsend and glow discharges. For f ≦ 4 kHz the optical structure and its temporal behaviour largely depends on the increment of the sustaining voltage. For f ≧ 20 kHz the axial structure of radiation emission is modified by the influence of consecutive discharges due to residual ions (f ≌ 20 kHz) and metastable Ne(³P₂)-atoms (f > 20 kHz) existing for several periods of sine wave. The Penning effect of metastable Ne-atoms with N₂ molecules then produces start electrons for each discharge in a sequence which improve the initial conditions for the breakdown. Relations between space time structure and breakdown voltage as a function of frequency f are discussed.     

The influence of vibrational excitation on the burning voltage of a pulsed electric discharge in HF laser working media

The burning voltages of an intermediate pressure self-sustained volume discharge (SSVD) in SF₆ and SF₆-C₂H₆ mixtures irradiated by a 10.6 μm pulse TEA CO₂ laser, have been measured on varying the laser fluences over a wide range. The delay between the voltage application and the laser pulse onset is 4 μs, and the laser pulse lasts ∼3 μs. The considerable rise observed in the discharge voltages with increasing absorbed specific laser radiation energy, is due to electron attachment to vibrationally excited molecules of SF₆. Different processes of relaxation of the vibrational energy stored in SF₆ molecules are analyzed and the relevant characteristic times are numerically assessed. The gas heating process owing to vibration-translation energy exchange is qualitatively described in terms of the “thermal explosion”. The relation between the “explosion” and delay times determines the peculiarities of electron attachment to vibrationally excited SF₆ molecules. The burning voltages of a submicrosecond non-irradiated SSVD in the above-mentioned media versus the specific electric energy deposited are also measured. They are compared to those of a laser-illuminated SSVD at commensurable specific laser energy depositions. It is concluded that electron attachment to the discharge-produced vibrationally excited SF₆ molecules is not capable of noticeably affecting the discharge voltages of a submicrosecond non-irradiated SSVD. PACS 42.55 Ks; 52.80     

Role of the volume and surface breakdown in a formation of microdischarges in a steady-state DBD

The results of an experimental study on a spatial-time behavior of microdischarges (MDs) in steady-state dielectric barrier discharge (DBD) are presented. MDs of DBD have a spatial “memory”, i.e. every subsequent MD appears exactly at the same place that was occupied by the preceding MD. In most cases each MD appears at its fixed place only once by every half-period (HP). Spatial “memory” is derived from slow recombination of plasma in the MDs channels for a period between two neighbor HPs. In steady-state DBD each plasma column was formed only one-time due to local avalanche-streamer breakdown in the very first (initial) gas gap breakdown under inception voltage U^*U^*. After that DBD is sustained under voltage lower than U^*U^*. For the plane-to-plane DBD having the restricted electrode area there is a critical voltage U ₁: DBD is in a steady-state if U > U ₁ but the DBD decays slowly at voltages below U ₁. The decay takes many HPs and occurs due to decreasing the number of MDs inside the gap because of their Brownian motion from central region to the outside of the discharge area. In steady-state DBD there is no correlation between an appearance of alone MD and phase of the applied voltage – each MD has a great scatter in its appearance at the HP. This scatter is attributed to the dispersion in a threshold voltage for local surface breakdowns around the MD base. So, in steady-state DBD the MD volume plasma is responsible for an existence of spatial “memory” (i.e. where the MD appears) but the surface charge distribution around MD is responsible for MD time dispersion (i.e. when the MD appears).     

Fabrication of gas ionization sensor based on titanium oxide nanotube arrays

Gas sensors have been fabricated based on field ionization from titanium oxide nanotubes grown on titanium foil. Ordered nanaotube arrays of titanium oxides were grown by the anodization method. We measured breakdown voltages and discharge currents of the device for various gases. Our gas ionization sensors (GIS) presented good sensitivity, selectivity, and short response time. The GISs based on TiO₂ nanotube arrays showed lower breakdown voltage, higher discharge current, and good selectivity. An excellent response observed for Ar compared to other gases. Besides, by introducing 2 % CO and 4 % H₂ to N₂ flow gas, the amount of breakdown voltage shifts about 20 and 70 volts to the lower values, respectively. The GIS works at room temperature and has the ability of detect inert gases with high stability and good linearity. Besides, short response time of about 1 second for the GISs based on TiO₂ nanotube arrays makes them excellent for gas sensing applications. Sharp edges of the nanotubes, through enhancing the applied electric field, reduce operating voltage to the reasonable values and power consumption.     

Optical emission spectroscopy of point-plane corona and back-corona discharges in air

Results of spectroscopic investigations and current-voltage characteristics of corona discharge and back discharge on fly-ash layer, generated in point-plane electrode geometry in air at atmospheric pressure are presented in the paper. The characteristics of both discharges are similar but differ in the current and voltage ranges of all the discharge forms distinguished during the experiments. Three forms of back discharge, for positive and negative polarity, were investigated: glow, streamer and low-current back-arc. In order to characterize ionisation and excitation processes in back discharge, the emission spectra were measured and compared with those obtained for normal corona discharge generated in the same electrode configuration but with fly ash layer removed. The emission spectra were measured in two discharge zones: near the tip of needle electrode and near the plate. Visual forms of the discharge were recorded with digital camera and referred to current-voltage characteristics and emission spectra. The measurements have shown that spectral lines emitted by back discharge depend on the form of discharge and the discharge current. From the comparison of the spectral lines of back and normal discharges an effect of fly ash layer on the discharge morphology can be determined. The recorded emission spectra formed by ionised gas and plasma near the needle electrode and fly ash layer are different. It should be noted that in back arc emission, spectral lines of fly ash layer components can be distinguished. On the other hand, in needle zone, the emission of high intensity N₂ second positive system and NO _γ lines can be noticed. Regardless of these gaseous lines, also atomic lines of dust layer were present in the spectrum. The differences in spectra of back discharge for positive and negative polarities of the needle electrode have been explained by considering the kind of ions generated in the crater in fly ash layer. The aim of these studies is to better understand the discharge processes encountered in electrostatic precipitators.     

Ascent of open-circuit voltage on diamond-like carbon photovoltaic cell by infrared heating-assisted pulsed-laser deposition

Phosphorus-doped diamond-like carbon (DLC) films were deposited on quartz and p-type silicon (p-Si) substrates by pulsed-laser deposition. Open-circuit voltage (V _oc) and short-circuit density (I _sc/cm²) from a heating process converted from one type of electrode to another and the two types of electrode pattern are shown by the V–I characteristics. The first heating process was by a ceramic heater, and the other was by an infrared heater. We adopted two electrode patterns, from a bipectinate electrode and a plot pattern electrode, to measure electric photovoltaic characteristics. We were able to upgrade V _oc and I _sc/cm² to 35∼45 mV, and 0.24 μA/cm², respectively, under infrared heating. V _oc by the plot pattern electrode was over 2 V under infrared heating and ceramic heating did not match this on deposition by the PLD method.     

Radiation damage effects on power VDMOS devices with composite SiO2–Si3N4 films

Total dose effects and single event effects on radiation-hardened power vertical double-diffusion metal oxide semiconductor (VDMOS) devices with composite SiO₂-–Si₃N₄ film gate are investigated. The relationships among the important electrical parameters of the samples with different thickness SiO₂-–Si₃N₄ films, such as threshold voltage, breakdown voltage, and on-state resistance in accumulated dose, are discussed. The total dose experiment results show that the breakdown voltage and the on-state resistance barely change with the accumulated dose. However, the relationships between the threshold voltages of the samples and the accumulated dose are more complex, not only positive drift, but also negative drift. At the end of the total dose experiment, we select the group of samples which have the smaller threshold voltage shift to carry out the single event effect studies. We find that the samples with appropriate thickness ratio SiO₂-–Si₃N₄ films have a good radiation-hardening ability. This method may be useful in solving both the SEGR and the total dose problems with the composite SiO₂-–Si₃N₄ films.     

Effects of trench oxide and field plates on the breakdown voltage of SOI LDMOSFET

To improve the breakdown voltage, we propose a SOI-based LDMOSFET with a trench structure in the drift region. Due to the trench oxide and underneath boron implanted layer, the surface electric field in the drift region effectively reduced. These effects resulted in the increment of breakdown voltage for the trenched LDMOS more than 100 V compared with the conventional device. However, the specific on-resistance, which has a trade-off relationship, is slightly increased. In addition to the trench oxide on the device performance, we also investigated the influence of n− drift to n+ drain junction spacing on the off-state breakdown voltage. The measured breakdown voltages were varied more than 50 V with different n− to n+ design spaces and achieved a maximum value at L_DA = 2.0 μm. Moreover, the influence of field plate on the breakdown voltage of trench LDMOSFET was investigated. It is found that the optimum drain field plate over the field oxide is 8 μm.     

Control of electric field in 4H-SiC UMOSFET: Physical investigation

In this paper, we show how breakdown voltage (V_BR) and the specific on-resistance (R_on) can be improved simply by controlling of the electric field in a power 4H-SiC UMOSFET. The key idea in this work is increasing the uniformity of the electric field profile by inserting a region with a graded doping density (GD region) in the drift region. The doping density of inserted region is decreased gradually from top to bottom, called Graded Doping Region UMOSFET (GDR-UMOSFET). The GD region results in a more uniform electric field profile in comparison with a conventional UMOSFET (C-UMOSFET) and a UMOSFET with an accumulation layer (AL-UMOSFET). This in turn improves breakdown voltage. Using two-dimensional two-carrier simulation, we demonstrate that the GDR-UMOSFET shows higher breakdown voltage and lower specific on-resistance. Our results show the maximum breakdown voltage of 1340 V is obtained for the GDR-UMOSFET with 10 µm drift region length, while at the same drift region length and approximated doping density, the maximum breakdown voltages of the C-UMOSFET and the AL-UMOSFET structures are 534 V and 703 V, respectively.     

N24B24分子结的电子传输

利用GW近似和非平衡格林函数结合的方法 研究了耦合到两个金属触点的N₂₄B₂₄分子的电子传输性. 计算结果表明,在单个和多个原子触点的态密度曲线上分别出现四个和三个谐振隧峰. 在I-V特性曲线上出现断路状态和微分负阻效应. 对于一、四、六、八原子的触点在电压分别在 ∓4.5、∓4、∓4.6、∓4.3 V表现出微分负阻效应行为. I-V特性在以低电压断开状态,呈独立的触点类型. I-V曲线取决于触点类型,并且表明N₂₄B₂₄分子呈现半导体的特性.     

Experimental observation of negative differential characteristic of corona discharge in ultraviolet spectrum

Corona discharge is a self-sustained discharge which appears at electrodes with a small radius curvature in gas insulation. An almost invisible glow occurs just above the inception voltage. Corona phenomenon is mainly used in electro-technological processes to obtain space charge for electrostatic precipitation, separation of different particles, electrostatic liquid or solid coating, neutralization of space charge, etc. All of these processes rely on a strong nonhomogeneous electric field generated by a point – plate electrode system. When the critical value of the applied voltage is reached, the ionization processes near the point electrode start and give rise to the current between two electrodes. If the pointed electrode is positive, it is possible to observe an anomaly of the current – voltage (I-U) characteristic for the point-plate space. It means that while the voltage is raising the current density decreases in a narrow voltage area (2–3 kV). The anomaly was technically named as negative differential conductivity (dI/dU < 0). Unstable current can have a negative influence on electro-technological processes. The anomaly was detected for different shapes and materials of the electrode as well as for various temperatures and distances between electrodes. An oxidation layer, which appears on the metal electrode, also influences the ionization processes near the pointed electrode and causes a decrease of a current. In this paper measuring of the discharge activity in a point – plate electrode system is presented. Ionization of gas atoms and molecules in a high electric field and the following recombination of electrons and positive ions in the corona region can give rise to high-energy photons which produce new electrons in the field of discharge. Corona discharges are detected by DayCor Corona camera which can register UV emission generated by corona in a day light. The experiment was conducted with various shapes of the pointed electrode and distances between the high voltage and the grounded electrode under applied direct voltage with positive and negative polarity.     

Stilbene-Like Molecules as Fluorescent Probes Applied for Monitoring of Polymerization Process

2-(p-N,N-dimethylaminostyryl)benzoxazole (OS), 2-(p-N,N-dimethylaminostyryl)-benzothiazole (SS) and 2-(p-N,N-dimethylaminostyryl)naphtiazole (PS) were prepared and their absorption and fluorescence spectra were measured in various solvents at room temperature. On the basis of the solvatochromic behavior the ground state (μ_g) and excited state (μ_e) dipole moments of these pN,N-dimethylaminostyryl derivatives were evaluated. The dipole moments (μ_g and μ_e) were estimated from solvatochromic shifts of absorption and fluorescence spectra as function of the dielectric constant (ɛ) and refractive index (n) of applied solvents. The absorption spectra only slightly are affected by the solvent polarity in contrast to the fluorescence spectra that are highly solvatochromic and display a large Stokes shift. The analysis of the solvatochromic behavior of the fluorescence spectra as function of Δf (ɛ, n) revealed that the emission occurs from a high polarity excited state. The large dipole moment change along with the strongly red-shifted fluorescence, as the solvent polarity is increased, demonstrate the formation of an intramolecular charge transfer state (ICT). Compounds under the study were used as fluorescence probes for monitoring the kinetics of polymerization. The study on the changes in fluorescence intensity and spectroscopic shifts of studied compounds were carried out during thermally initiated polymerization of methyl methacrylate (MMA) and during photoinitiated polymerization of 2-ethyl-2-(hydroxymethyl)propane-1,3-diol triacrylate (TMPTA).