Influence of \text{ CF }_{3}\text{ H } and \text{ CCl }_{4} additives on acetylene detonation

The influence of $\text{ CF }_{3}\text{ H }$ and $\text{ CCl }_{4}$ admixtures (known as detonation suppressors for combustible mixtures) on the development of acetylene detonation was experimentally investigated in a shock tube. The time-resolved images of detonation wave development and propagation were registered using a high-speed streak camera. Shock wave velocity and pressure profiles were measured by five calibrated piezoelectric gauges and the formation of condensed particles was detected by laser light extinction. The induction time of detonation development was determined as the moment of a pressure rise at the end plate of the shock tube. It was shown that $\text{ CF }_{3}\text{ H }$ additive had no influence on the induction time. For $\text{ CCl }_{4}$ , a significant promoting effect was observed. A simplified kinetic model was suggested and characteristic rates of diacetylene $\text{ C }_{4}\text{ H }_{2}$ formation were estimated as the limiting stage of acetylene polymerisation. An analysis of the obtained data indicated that the promoting species is atomic chlorine formed by $\text{ CCl }_{4}$ pyrolysis, which interacts with acetylene and produces $\text{ C }_{2}\text{ H }$ radical, initiating a chain mechanism of acetylene decomposition. The results of kinetic modelling agree well with the experimental data.     

La30Ce30Al15Co25金属玻璃应力松弛行为

作为潜在的工程材料, 金属玻璃在材料科学和凝聚态物理等领域引起广泛的研究兴趣. 金属玻璃结构与性能的关系表明, 金属玻璃的动态非均匀性与其黏弹性和塑性紧密相关. 然而, 宏观应力松弛行为与动态弛豫之间的物理图像并不清晰. 与传统金属材料不同, 金属玻璃的变形机理非常复杂. 应力松弛是一种表征玻璃体系黏弹性和塑性变形机制的有效手段, 从而探索结构和动态非均匀性. 本研究以La₃₀Ce₃₀Al₁₅Co₂₅金属玻璃为模型体系, 在较宽的温度窗口研究了其应力松弛行为. 研究结果表明, 与传统金属玻璃不同, La₃₀Ce₃₀Al₁₅Co₂₅金属玻璃具有明显的β弛豫行为. 基于Kohlarausch-Willams-Watts (KWW)方程的分析表明, 金属玻璃应力松弛为动态不均匀过程; 热动力学分析发现La₃₀Ce₃₀Al₁₅Co₂₅金属玻璃应力松弛存在显著的双阶段行为, 即从高应力条件下应力驱动为主导的松弛行为, 向低应力下热激活为主导的松弛行为发生转变. 通过激活能谱模型分析表明, 应力松弛单元的激活并非均匀, 而是存在能量上的起伏, 金属玻璃对于外力响应是一个渐进过程, 具有动力学不均匀性. 本研究进一步构建了金属玻璃的结构和动态非均匀性之间的关联, 为研究金属玻璃的α弛豫和β弛豫提供了强有力的支撑.      

通过表面机械加工调控Zr52.5Cu17.9Ni14.6Al10Ti5非晶合金的结构和韧性

作为一种新型结构材料, 非晶态合金的韧性需要进一步提高. 提高非晶态合金韧性的方法有引入枝晶相、调整其成分改变其泊松比影响其剪切带衍生、裂纹扩展等.本文通过表面机械加工的方法来调控非晶态合金的微观结构及韧性. 我们采用真空电弧熔炼、亚稳态薄板离心浇铸系统制备了Zr_52.5Cu_17.9Ni_14.6Al₁₀Ti₅ (原子百分比) (Vit105)非晶合金板,并用表面机械研磨处理方法(surface mechanical attrition treatment, SMAT), 在Vit105板上形成纳米尺度局域类晶体序结构. 基于差示扫描量热分析、纳米压痕实验, 我们发现SMAT处理后的Vit105合金板表面附近弛豫焓更低, 微观结构更加均匀、稳定. 通过显微维氏硬度计测试, 发现SMAT处理后样品的表面附近硬度增大,硬度值分布也更均匀. 通过三点弯断裂实验, 可得到SMAT处理后合金板缺口韧度值从70.7 ± 4.7 MPa·m1/2提高到112.8 ± 3.7 MPa·m1/2. SMAT处理后合金板断裂后, 缺口前端剪切带密度比未处理的更大. Vit105合金板韧性的提高源于SMAT处理对剪切带萌生的促进作用. 该研究表明,表面机械加工可以在非晶态合金中形成局域类晶体有序结构, 影响其结构均匀性, 增大其硬度, 促进剪切带萌生, 提高其韧性. 表面机械加工作为一种新型的改变材料性能的手段, 具有广阔的应用前景.      

Semianalytical Solution for \text{ CO}_{2} Plume Shape and Pressure Evolution During \text{ CO}_{2} Injection in Deep Saline Formations

The injection of supercritical carbon dioxide ( $\text{ CO}_{2})$ in deep saline aquifers leads to the formation of a $\text{ CO}_{2}$ rich phase plume that tends to float over the resident brine. As pressure builds up, $\text{ CO}_{2}$ density will increase because of its high compressibility. Current analytical solutions do not account for $\text{ CO}_{2}$ compressibility and consider a volumetric injection rate that is uniformly distributed along the whole thickness of the aquifer, which is unrealistic. Furthermore, the slope of the $\text{ CO}_{2}$ pressure with respect to the logarithm of distance obtained from these solutions differs from that of numerical solutions. We develop a semianalytical solution for the $\text{ CO}_{2}$ plume geometry and fluid pressure evolution, accounting for $\text{ CO}_{2}$ compressibility and buoyancy effects in the injection well, so $\text{ CO}_{2}$ is not uniformly injected along the aquifer thickness. We formulate the problem in terms of a $\text{ CO}_{2}$ potential that facilitates solution in horizontal layers, with which we discretize the aquifer. Capillary pressure is considered at the interface between the $\text{ CO}_{2}$ rich phase and the aqueous phase. When a prescribed $\text{ CO}_{2}$ mass flow rate is injected, $\text{ CO}_{2}$ advances initially through the top portion of the aquifer. As $\text{ CO}_{2}$ is being injected, the $\text{ CO}_{2}$ plume advances not only laterally, but also vertically downwards. However, the $\text{ CO}_{2}$ plume does not necessarily occupy the whole thickness of the aquifer. We found that even in the cases in which the $\text{ CO}_{2}$ plume reaches the bottom of the aquifer, most of the injected $\text{ CO}_{2}$ enters the aquifer through the layers at the top. Both $\text{ CO}_{2}$ plume position and fluid pressure compare well with numerical simulations. This solution permits quick evaluations of the $\text{ CO}_{2}$ plume position and fluid pressure distribution when injecting supercritical $\text{ CO}_{2}$ in a deep saline aquifer.     

Well-Posedness of Nematic Liquid Crystal Flow in {L^{3}_{\rm uloc}(\mathbb{R}^3)}

In this paper, we establish the local well-posedness for the Cauchy problem of a simplified version of hydrodynamic flow of nematic liquid crystals in ${\mathbb{R}^3}$ for any initial data (u ₀, d ₀) having small ${L^{3}_{\rm uloc}}$ -norm of ${(u_{0}, \nabla d_{0})}$ . Here ${L^{3}_{\rm uloc}(\mathbb{R}^3)}$ is the space of uniformly locally L ³-integrable functions. For any initial data (u ₀, d ₀) with small ${\|(u_0, \nabla d_0)\|_{L^{3}(\mathbb{R}^3)}}$ , we show that there exists a unique, global solution to the problem under consideration which is smooth for t > 0 and has monotone deceasing L ³-energy for ${t \geqq 0}$ .     

Heat Flow of Harmonic Maps Whose Gradients Belong to L^{n}_{x}L^{\infty}_{t}

For any compact n-dimensional Riemannian manifold (M, g) without boundary, a compact Riemannian manifold without boundary, and 0 < T ≦ +∞, we prove that for n ≧ 4, if u : M × (0, T] → N is a weak solution to the heat flow of harmonic maps such that , then u ∈C ^∞(M × (0, T], N). As a consequence, we show that for n ≧3, if 0 < T < +∞ is the maximal time interval for the unique smooth solution u ∈C ^∞(M × [0, T), N) of (1.1), then blows up as t ↑ T.     

CONTROL OF THE PROPERTIES OF Ba $$_{x}$$ Sr $$_{1-x}$$ TiO $$_{3}$$ FERROELECTRIC FILMS

Journal of Applied Mechanics and Technical Physics - A method is proposed to control the properties of thin ferroelectric films under forced strain due to the differences in crystal lattice...     

Dynamics of stochastic non-Newtonian fluids driven by fractional Brownian motion with Hurst parameter H ∈ （1/4,1/2）

A two-dimensional (2D) stochastic incompressible non-Newtonian fluid driven by the genuine cylindrical fractional Brownian motion (FBM) is studied with the Hurst parameter $H \in \left( {\tfrac{1} {4},\tfrac{1} {2}} \right)$ under the Dirichlet boundary condition. The existence and regularity of the stochastic convolution corresponding to the stochastic non-Newtonian fluids are obtained by the estimate on the spectrum of the spatial differential operator and the identity of the infinite double series in the analytic number theory. The existence of the mild solution and the random attractor of a random dynamical system are then obtained for the stochastic non-Newtonian systems with $H \in \left( {\tfrac{1} {2},1} \right)$ without any additional restriction on the parameter H.     

Isochronicity for a $$\varvec{Z_{2}}$$ Z 2 -equivariant cubic system

Nonlinear Dynamics - This paper is concerned with the bi-isochronous centers problem for a cubic systems in $${Z}_2$$ -equivariant vector field. Being based on bi-centers condition, we compute the...     

Nonlinear Differential Equations in {\mathcal{B}(\mathcal{H})} Motivated by Learning Models

We study a system of ordinary differential equations in B(H){\mathcal{B}(\mathcal{H})} , the space of all bounded linear operators on a separable Hilbert space H{\mathcal{H}} . The system considered is a natural generalization of the Oja–Cox–Adams learning models. We establish the local existence of solutions and solve explicitly the system for a class of initial conditions. For such cases, we also characterize the asymptotic behavior of solutions.     

A $$ \mathcal{U}\mathcal{V} $$-decomposed method for solving an MPEC problem

uv-decomposition method for solving a mathematical program with equilibrium constraints （MPEC） problem with linear complementarity constraints is presented. The problem is first converted into a nonlinear programming one. The structure of subdifferential a corresponding penalty function and results of its uv-decomposition are given. A conceptual algorithm for solving this problem with a superUnear convergence rate is then constructed in terms of the obtained results.     

Theoretical analysis for the mechanical behavior caused by an electromagnetic cycle in ITER $$\hbox {Nb}_{3}\hbox {Sn}$$ cable-in-conduit conductors

The central solenoid (CS) is one of the key components of the International Thermonuclear Experimental Reactor (ITER) tokamak and which is often considered as the heart of this fusion reactor. This solenoid will be built by using \(\hbox {Nb}_{3}\hbox {Sn}\) cable-in-conduit conductors (CICC), capable of generating a 13 T magnetic field. In order to assess the performance of the \(\hbox {Nb}_{3}\hbox {Sn}\) CICC in nearly the ITER condition, many short samples have been evaluated at the SULTAN test facility (the background magnetic field is of 10.85 T with the uniform length of 400 mm at 1% homogeneity) in Centre de Recherches en Physique des Plasma (CRPP). It is found that the samples with pseudo-long twist pitch (including baseline specimens) show a significant degradation in the current-sharing temperature (Tcs), while the qualification tests of all short twist pitch (STP) samples, which show no degradation versus electromagnetic cycling, even exhibits an increase of Tcs. This behavior was perfectly reproduced in the coil experiments at the central solenoid model coil (CSMC) facility last year. In this paper, the complex structure of the \(\hbox {Nb}_{3}\hbox {Sn}\) CICC would be simplified into a wire rope consisting of six petals and a cooling spiral. An analytical formula for the Tcs behavior as a function of the axial strain of the cable is presented. Based on this, the effects of twist pitch, axial and transverse stiffness, thermal mismatch, cycling number, magnetic distribution, etc., on the axial strain are discussed systematically. The calculated Tcs behavior with cycle number show consistency with the previous experimental results qualitatively and quantitatively. Lastly, we focus on the relationship between Tcs and axial strain of the cable, and we conclude that the Tcs behavior caused by electromagnetic cycles is determined by the cable axial strain. Once the cable is in a compression situation, this compression strain and its accumulation would lead to the Tcs degradation. The experimental observation of the Tcs enhancement in the CS STP samples should be considered as a contribution of the shorter length of the high field zone in SULTAN and CSMC devices, as well as the tight cable structure.     

Existence and Regularity of the Reflector Surfaces in {\mathbb{R}^{n+1}}

In this paper we study the problem of constructing reflector surfaces from the near field data. The light is transmitted as a collinear beam and the reflected rays illuminate a given domain on the fixed receiver surface. We consider two types of weak solutions and prove their equivalence under some convexity assumptions on the target domain. The regularity of weak solutions is a very delicate problem and the positive answer depends on a number of conditions characterizing the geometric positioning of the reflector and receiver. In fact, we show that there is a domain \({\mathcal{D}}\) in the ambient space such that the weak solution is smooth if and only if its graph lies in \({\mathcal{D}}\) .     

Effect of Fuel Stratification on OH and $${\mathrm {CH}}_{2}\hbox {O}$$ CH 2 O PLIF Multiplication of Turbulent Hydrogen-Enriched Flames

Multiplication of hydroxyl and formaldehyde planar laser-induced fluorescence signals for turbulent hydrogen-enriched methane–air flames with compositionally inhomogeneous mixtures is investigated experimentally. Hydrogen-enriched methane–air flames with a global fuel–air equivalence ratio of 0.8 and hydrogen-enrichment percentage of 60% are examined. Two nozzles, each containing 4 fuel/air injection lobes are used in the experiments. The lobes of the first nozzle are straight, while those of the second nozzle are not, generating a swirling motion. The fuel is injected through several small diameter holes into the lobes. The amount of injected fuel flow rate varies between the lobes, generating stratified conditions. For each nozzle, two mean bulk flow velocities of 5 and 25 m/s are tested. Simultaneous hydroxyl and formaldehyde planar laser-induced fluorescence as well as separate stereoscopic particle image velocimetry are performed for the tested reacting conditions. For non-reacting flow tests, separate particle image velocimetry and acetone planar laser-induced fluorescence experiments are conducted to study the background turbulent flow characteristics and fuel/air mixing, respectively. The results show that stratification can lead to fragmentation of the flames and generation of islands with noticeable multiplication of hydroxyl and formaldehyde planar laser-induced fluorescence signals. Due to their significantly large number of occurrences, such flame structure can generate relatively large integral of the PLIF signals multiplication.

     

An iterative \mathit{GL}(n,\mathbb{R}) method for solving non-linear inverse vibration problems

For the inverse vibration problem, a differential-algebraic equation (DAE) method is proposed to simultaneously estimate the time-dependent damping and stiffness coefficients by using two sets of displacement and velocity as input data. We combine the equations of motion and the supplemental data into a set of DAEs. We develop an implicit $\mathit{GL}(n,\mathbb{R})$ scheme and a Newton iterative algorithm to stably solve the DAEs to find the unknown structural coefficients. The unknown force is also recovered by the present method. A linear oscillator and a non-linear Duffing oscillator are used as testing examples. The estimated results are rather accurate and robust against random noise; hence, the new method can be used in the solutions of non-linear inverse vibration problems.