Influence of surfactants on pool boiling of aqueous polyacrylamide solutions

The influence of a surfactant, sodium lauryl sulfate (SLS), on the pool boiling behavior of aqueous polyacrylamide solutions has been investigated. The basic test section is a heated horizontal platinum wire submerged in a saturated pool of liquid at atmospheric pressure. Results are reported for six combinations of deionized water, polyacrylamide and surfactant. Measurements of surface tension and steady shear apparent viscosity are reported for each working solution.The boiling heat transfer performance of deionized water containing concentrations of 250 and 1000 (parts per million by weight) wppm of the surfactant did not differ significantly from the values found for deionized water. For the 250 wppm aqueous polyacrylamide solution the boiling performance is poorer than that found for water alone. However, the addition of 250 wppm of SLS to the aqueous polyacrylamide solution resulted in a significant improvement in the boiling heat transfer performance compared to water. An increase in the surfactant concentration to 1000 wppm to the aqueous polymer solution revealed even greater improvement in the boiling performance. At a heat flux of 50 W/cm², increases in the heat transfer coefficient were as much as 50% for the 250 wppm AP-30 — 250 wppm SLS solution and 100% the for 250 wppm AP-30 — 1000 wppm SLS solution as compared to deionized water alone.On the basis of these results, it appears that the influence of surfactants on the boiling heat transfer performance of aqueous polymer solutions may be more significant than in the case where surfactants are added to Newtonian fluids.

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Einfluß von grenzflächenaktiven Stoffen auf das Sieden von Polyacrylamid-Lösungen

Zusammenfassung Es wurde der Einfluß des grenzflächenaktiven Stoffes Sodium-Lauryl-Sulfat (SLS) auf das Verhalten des freien Behältersiedens von Polyacrylamid-Lösungen untersucht. Die Testeinheit besteht aus einem beheizten Platindraht, der in einem mit Flüssigkeit (Umgebungsdruck) gefüllten Behälter eingetaucht ist. Ergebnisse wurden für sechs Kombinationen von vollentsalztem Wasser, Polyacrylamid-Lösungen und grenzflächenaktiven Stoffen untersucht. Messungen der Oberflächenspannung und Viskosität wurden für jedes Gemisch durchgeführt.Der Wärmetransport beim Sieden von vollentsalztem Wasser mit einem Anteil an SLS von 250 bis 1000 wppm (parts per million by weight) unterscheidet sich nicht von dem bei reinem, vollentsalztem Wasser. Bei einer Lösung mit 250 wppm Polyacryl ist das Sieden schwächer als bei reinem Wasser. Bei einer Zugabe von 250 wppm SLS zur Polyacryl-Lösung ist eine signifikante Zunahme des Wärmetransportes beim Sieden festzustellen. Ein Erhöhen der SLS-Konzentration auf 1000 wppm verstärkt nochmals diese Zunahme. Bei einem Wärmefluß von 50 W/cm² erhöht sich der Wärmetransportkoeffizient bei der AP-30 — 250 wppm SLS Lösung um 50% und bei der AP-30 — 1000 wppm SLS Lösung um 100% im Vergleich zum vollentsalzten Wasser.Mit diesen Ergebnissen wird deutlich, daß der Einfluß von grenzflächenaktiven Stoffen auf den Wärmetransport beim Sieden von polymeren Lösungen signifikanter als im Falle von Newtonschen Fluiden ist.

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Nomenclature q heat flux, (W/cm²) - T fluid temperature, (°C) - T _sat saturation temperature of the fluid, (°C) - T _w surface wall temperature, (°C) - T =T _w–T _sat, (°C) - steady shear apparent viscosity, (poise) - shear rate, (sec^–1) - surface tension, (dyne/cm) Dedicated to Prof. Dr.-Ing. U. Grigull's 80th birthday     

Local heat transfer from a hot plate to a water jet

Jet impingement boiling is very efficient in cooling of hot surfaces as a part of the impinging liquid evaporates. Because of its importance to many cooling procedures, investigations on basic mechanisms of jet impingement boiling heat transfer are needed. Until now, most of the experimental studies, carried out under steady-state conditions, used a heat flux controlled system and were limited by the critical heat flux (CHF). The present study focuses on steady-state experiments along the entire boiling curve for hot plate temperatures of up to 700°C. A test section has been built up simulating a hot plate. It is divided into 8 independently heated modules of 10 mm length to enable local heat transfer measurements. By means of temperature controlled systems for each module local steady-state experiments in the whole range between single phase heat transfer and film boiling are possible. By solving the two dimensional inverse heat conduction problem, the local heat flux and the corresponding wall temperature on the surface of each module can be computed. The measurements show important differences between boiling curves measured at the stagnation line and those obtained in the parallel flow region. At the stagnation line, the transition boiling regime is characterised by very high heat fluxes, extended to large wall superheats. Inversely, boiling curves in the parallel flow region are very near to classical ones obtained for forced convection boiling. The analysis of temperature fluctuations measured at a depth of 0.8 mm from the boiling surface enables some conclusions on the boiling mechanism in the different boiling regimes.     

Boiling heat transfer,pressure drop,and flow pattern in a horizontal square minichannel

This study experimentally investigated the flow boiling heat transfer, pressure drop, and flow pattern in a horizontal square minichannel with a hydraulic diameter of 2.0 mm, and the effects of mass flux, vapor quality, heat flux, and refrigerant properties on the flow boiling characteristics were clarified. The heat transfer coefficient and pressure drop of R32 and R1234yf were measured in a mass flux range of 50–400 kgm⁻²s⁻¹ at a saturation temperature of 15 °C. The flow pattern of the square minichannel outlet was observed and was classified as plug, wavy, churn, and annular flows. The heat transfer coefficients in the square minichannel were larger than those in the circular minichannel with a similar hydraulic diameter at low mass flux conditions. The heat transfer coefficients of R32 indicated higher values compared with those of R1234yf at same mass flux and qualities. An empirical heat transfer model taking into account the forced convection, nucleate boiling, and thin liquid film evaporation was developed for horizontal square and circular minichannels. The frictional pressure drop of R32 was 1.5–2 times higher than that of R1234yf at same mass flux and vapor quality condition, and the effect of channel shape on the frictional pressure drop was small unlike the boiling heat transfer.     

Nucleate boiling heat transfer in aqueous solutions with carbon nanotubes up to critical heat fluxes

In this study, pool boiling heat transfer coefficients (HTCs) and critical heat fluxes (CHFs) are measured on a smooth square flat copper heater in a pool of pure water with and without carbon nanotubes (CNTs) dispersed at 60 °C. Tested aqueous nanofluids are prepared using multi-walled CNTs whose volume concentrations are 0.0001%, 0.001%, 0.01%, and 0.05%. For the dispersion of CNTs, polyvinyl pyrrolidone polymer is used in distilled water. Pool boiling HTCs are taken from 10 kW/m² to critical heat flux for all tested fluids. Test results show that the pool boiling HTCs of the aqueous solutions with CNTs are lower than those of pure water in the entire nucleate boiling regime. On the other hand, critical heat flux of the aqueous solution is enhanced greatly showing up to 200% increase at the CNT concentration of 0.001% as compared to that of pure water. This is related to the change in surface characteristics by the deposition of CNTs. This deposition makes a thin CNT layer on the surface and the active nucleation sites of the surface are decreased due to this layer. The thin CNT layer acts as the thermal resistance and also decreases the bubble generation rate resulting in a decrease in pool boiling HTCs. The same layer, however, decreases the contact angle on the test surface and extends the nucleate boiling regime to very high heat fluxes and reduces the formation of large vapor canopy at near CHF. Thus, a significant increase in CHF results in.     

The influence of oil on nucleate pool boiling heat transfer

The influence of various oil contents in R134a is investigated for nucleate pool boiling on copper tubes either sandblasted or with enhanced heating surfaces (GEWA-B tube). Polyolester oils (POE) (Reniso Triton) with medium viscosity 55 cSt (SE55) and high viscosity 170 cSt (SE170) were used. Heat transfer coefficients were obtained for boiling temperatures between −28.6 and +20.1°C. The oil content varied from 0 to 5% mass fraction. For the sandblasted tube and the SE55 oil the heat transfer coefficients for the refrigerant/oil-mixture can be higher or lower than those for the pure refrigerant, depending on oil mass fraction, boiling temperature and heat flux. In some cases the highest heat transfer coefficients were obtained at a mass fraction of 3%. For the 170 cSt oil there is a clear decrease in heat transfer for all variations except for a heat flux 4,000 W/m² and −10.1°C at 0.5% oil content. The heat transfer coefficients are compared to those in the literature for a smooth stainless steel tube and a platinum wire. For the enhanced tube and 55 cSt oil the heat transfer coefficients are clearly below those for pure refrigerant in all cases. The experimental results for the sandblasted tube are compared with the correlation by Jensen and Jackman. The calculated values are within +20 and −40% for the medium viscosity oil and between +50% and −40% for the high viscosity oil. A correlation for predicting oil-degradation effects on enhanced surfaces does not exist.     

Compositive effects of orientation and contact angle on critical heat flux in pool boiling of water

An experimental study was carried out to investigate the effects of heat transfer surface orientation and the solid–liquid contact angle on the boiling heat transfer and critical heat flux (CHF) in water pool boiling using a smooth heat-transfer surface under atmospheric pressure. The orientation angle was ranged from 0° (up-facing horizontal position) to 180° (down-facing horizontal position) with a pace of 45°. The three kinds of heat transfer surfaces having different solid–liquid contact angles were the normal surface with a contact angle of 55°, the hydrophilic surface with a contact angle of 30° and the superhydrophilic surface with a contact angle of 0°. The experimental results indicate that orientation and contact angle have complex, coupling effects on heat transfer and CHF. A predicting correlation for the CHF which takes the effects of both orientation and contact angle into account is established. The predicting correlation agrees reasonably well with the experimental data.     

Investigation of heat transfer by means of pool film boiling on vertical cylinders in gravity

In this study, the heat transfer by means of pool film boiling on immersed vertical cylindrical rods was investigated. For this purpose, the rods with various dimensions, which have been heated up to 600°C, were immersed in a pure water pool in the different temperatures. The centre temperature and water temperature versus operation time were measured by K type thermocouples at the atmospheric pressure. After experimental studies, the surface temperatures of rods and heat transfer coefficients were calculated by means of Lumped method from the measured temperatures. Consequently, an empirical equation was developed between the Nusselt, Grashof, Prandtl and Jakob numbers. The experimental results showed that the specimens having the same characteristic lengths exhibited the same heat transfers performance although the specimen’s diameters and lengths differed considerably.     

An experimental study of the evaporation characteristics of emulsified liquid droplets

This paper presents the results of an experimental investigation, into the effect of water in diesel and kerosene emulsions, on the evaporation time of a single droplet, on hot surfaces (stainless-steel and aluminum). Experiments are performed at atmospheric pressure, and initial water volume concentrations of 10, 20, 30, and 40%. The wall temperatures ranging from 100–460 °C, to cover the entire spectrum of heat transfer characteristics from evaporation to film boiling. Results show that, qualitatively, the shapes of emulsion evaporation curves are very similar to that of pure liquids. Quantitavely, there are significant differences. The total evaporation time, for the emulsion droplets is lower than that for diesel and kerosene fuels, and decreased as water initial concentration increases, up to surface temperatures less than the critical temperature. The value of the critical surface temperature (maximum heat transfer rate), decreases as initial concentration of water increases. In the film-boiling region, the evaporation time for the emulsion droplets is higher than for diesel and kerosene droplets, at identical conditions.List of Symbols h_fg latent heat of vaporization, KJ/kg - m mass of the droplet, gm - T_b boiling temperature, °C - T_c critical temperature, °C - T_L Leidenfrost temperature, °C - T_s initial surface temperature of the hot surface, °C     

On the quenching of steel and zircaloy spheres in water-based nanofluids with alumina,silica and diamond nanoparticles

The quenching curves (temperature vs time) for small (∼1 cm) metallic spheres exposed to pure water and water-based nanofluids with alumina, silica and diamond nanoparticles at low concentrations (?0.1 vol%) were acquired experimentally. Both saturated (ΔT_sub = 0 °C) and highly subcooled (ΔT_sub = 70 °C) conditions were explored. The spheres were made of stainless steel and zircaloy, and were quenched from an initial temperature of ∼1000 °C. The results show that the quenching behavior in nanofluids is nearly identical to that in pure water. However, it was found that some nanoparticles accumulate on the sphere surface, which results in destabilization of the vapor film in subsequent tests with the same sphere, thus greatly accelerating the quenching process. The entire boiling curves were obtained from the quenching curves using the inverse heat transfer method, and revealed that alumina and silica nanoparticle deposition on the surface increases the critical heat flux and minimum heat flux temperature, while diamond nanoparticle deposition has a minimal effect on the boiling curve. The possible mechanisms by which the nanoparticles affect the quenching process were analyzed. It appears that surface roughness increase and wettability enhancement due to nanoparticle deposition may be responsible for the premature disruption of film boiling and the acceleration of quenching. The basic results were also confirmed by quench tests with rodlets.     

Effect of heater size on ultrasonic enhancement of boiling in water and surfactant solutions

Experiments were performed to study enhancement of heat transfer from the wire of d = 50 µm and the tube of d = 1.5 mm in subcooled pool boiling by ultrasonic waves. The working fluids are clean water and Alkyl (8-16) Glucoside surfactant solutions of different concentrations and bulk temperature 30 °C. The wire resistance was translated to the temperature, using the calibration data, the temperature of the tube was measured by thermocouple. The differences between effect of ultrasonic field on boiling in water for heaters of d = 50 µm and d = 1.5 mm may be summarized as follows: for boiling on the wire of d = 50 µm in subcooled water, T_b = 30 °C, enhancement of heat transfer coefficient due to applied ultrasonic field is about 70% and 20% at heat flux q = 620 kW/m² and q = 1350 kW/m², respectively. For boiling in surfactant solutions at the same boiling conditions enhancement of heat transfer coefficient is in the range of 5–10% at heat flux q = 620 kW/m² and 10–16% at heat flux q = 1350 kW/m² depending on solution concentration. For boiling on the tube of d= 1.5 mm in subcooled water, T_b= 30 ℃, enhancement of heat transfer coefficient due to applied ultrasonic field is about 50% and 45% at heat flux q = 500 kW/m² and q = 2500 kW/m², respectively. The same values are obtained for boiling in surfactant solution of concentration C = 250 ppm. For the wire of d = 50 µm the heat transfer enhancement due to acoustic vibrations in surfactant solutions is not as strong as in water. This fact may be considered as evidence of significant role of relationship between jet flow and ultrasonic field.     

Experimental investigation of micro-scale temperature transients in sub-cooled flow boiling on a horizontal heater

Surface temperature fluctuations that occur locally underneath departing bubbles in pool boiling are shown to result in local heat transfer coefficients ranging from 1 to 10 kW/cm². These estimates were reported in the literature involved both numerical and experimental approaches. Significantly higher heat fluxes are associated with flow boiling than pool boiling under similar conditions of wall superheat and liquid subcooling (e.g. at boiling inception and at critical heat flux). These enhancements are primarily caused by the convective transport, acceleration/distortion of the bubble departure process as well as the resultant potential enhancement of the local surface temperature fluctuations.In this study we measure the surface temperature fluctuations using temperature micro/nano-sensors fabricated on a silicon wafer during flow boiling on the silicon wafer which is heated from below. The silicon wafer is clamped on a constant heat flux type calorimeter consisting of a vertical copper cylinder with embedded cartridge heaters and K-type thermocouples. Micro/nano-thermocouples (thin film thermocouples or “TFT”) are fabricated on the surface of the silicon wafer. High speed data acquisition apparatus is used to record temperature data from the TFT at 1 kHz. A fluorinert was used as the test fluid (PF-5060, manufacturer: 3M Co.). The calorimeter and surface temperature measurement apparatus is housed in a test section with glass walls for visual observation. The liquid is pumped from a constant temperature bath to maintain a fixed subcooling during the experiments under steady state conditions. The transient temperature data from the FFT array during flow boiling on the silicon wafer is analyzed using fast Fourier transform (FFT). The FFT data is analyzed as a function of the wall heat flux and wall superheat. The number of temperature peaks in the FFT data is observed to increase with increase in wall heat flux and the peaks are found to cover a wider spectrum with peaks at higher frequencies with enhancement of heat flux. The surface temperature fluctuations, especially at small length and time scales, are perturbed potentially by the coupled hydrodynamic and thermal transport processes, resulting in enhanced local and global heat flux values. Boiling incipience condition and the flow boiling data are compared with correlations reported in the literature.     

Theoretical analyses on boiling critical heat flux with porous media

Porous media has been widely applied to enhance boiling heat transfer in industry, especially for increasing the value of critical heat flux (CHF). Two cases were considered in the paper: boiling within porous bed and boiling above on porous coatings. For boiling within porous bed, simplified Rayleigh–Taylor stability was analyzed and parametric effects of porous media on boiling critical heat flux were revealed. For boiling above on porous coatings, a simple new critical heat flux model was proposed basing on the analysis of liquid film stability and parametric effect of porous coatings on CHF was elaborated.     

Local jet impingement boiling heat transfer with R113

An experimental study was performed to characterize the boiling heat transfer of impinging circular submerged jets on simulated microelectronic chips with a nominal area of 5 mm × 5 mm. The heat transfer modes included natural convection, partially developed nucleate boiling, fully developed nucleate boiling and critical heat flux. The study included the effects of jet parameters and fluid subcooling on the nucleate boiling. The results showed that the nucleate boiling data varied only with fluid subcooling regardless of jet parameters and that both the pool and impingement nucleate boiling curves at the same subcooling condition were well correlated. The high heat flux portions of the boiling curves with jet exit velocities greater than 10 m/s were corrected for the elevated saturation temperature. A new expression was developed with an interpolation method to construct the partially developed nucleate boiling curve.     

Boiling heat transfer region with independence of the wall temperature

 Extensive measurements of the intensive cooling of hot-rolled wires with temperatures between 1000 ^°C and 1100 ^°C are analysed. The analysis proves the existence of a convection-controlled boiling region, which has been previously observed by few authors in the case of high mass fluxes and high liquid subcooling. This region is characterised by an independence of the heat flux of the surface temperature. The heat flux depends essentially on the Reynolds number, the main influence parameter of the single phase convection, and on the liquid subcooling. Received on 13 September 1999     

Numerical simulation of flow boiling for organic fluid with high saturation temperature in vertical porous coated tube

A semi-analytical model is developed for the prediction of flow boiling heat transfer inside vertical porous coated tubes. The model assumes that the forced convection and nucleate boiling coexist together in the annular flow regime. Conservations of mass, momentum, and energy are used to solve for the liquid film thickness and temperature. The heat flux due to nucleate boiling consists of those inside and outside micro-tunnels. To close the equations, a detailed analysis of various forces acting on the bubble is presented to predict its mean departure diameter. The active nucleation site density of porous layer is determined from the pool boiling correlation by introducing suppression factor. The flow boiling heat transfer coefficients of organic fluid (cumene) with high saturation temperature in a vertical flame-spraying porous coated tube are studied numerically. It is shown that the present model can predict most of the experimental values within ±20%. The numerical results also indicate that the nucleate boiling contribution to the overall heat transfer coefficient decreases from 50% to 15% with vapor quality increasing from 0.1 to 0.5.     

Pool boiling performance of finned surfaces in R-113

Performance of horizontal copper heaters with a transverse fin structure was investigated for pool boiling heat transfer and critical heat flux limits. Data were obtained for 5.1 and 7.6 cm diameter structured cooper and brass heaters in saturated R-113 boiling at pressures ranging between 0.037 and 1 atm. The fin structure consisted of 0.16 cm×0.16 cm×0.32 cm high square fins with an interfin spacing of 0.16 cm. Following a similar methodology to Haley and Westwater¹, a numerical analysis of the heat transfer phenomenon was performed by solving the one-dimensional fin conduction equation with a non-linear heat transfer boundary condition obtained from the previously reported data for R-113 boiling on plain surfaces. The predictions agreed with the data at the 1 atm pressure levels but showed deviations at the low pressure levels. The results showed that, compared with plain surface heaters of the same diameters the finned structured surfaces investigated: (a) decreased the wall temperature differences for a given heat flux and saturated pool boiling conditions, thus improving the nucleate boiling heat transfer coefficients, and (b) increased the critical heat flux limits, calculated as the power input divided by the heater projected area, by a factor of 2–2.5.     

Ultra fast cooling of hot steel plate by air atomized spray with salt solution

In the present study, the applicability of air atomized spray with the salt added water has been studied for ultra fast cooling (UFC) of a 6 mm thick AISI-304 hot steel plate. The investigation includes the effect of salt (NaCl and MgSO₄) concentration and spray mass flux on the cooling rate. The initial temperature of the steel plate before the commencement of cooling is kept at 900 °C or above, which is usually observed as the “finish rolling temperature” in the hot strip mill of a steel plant. The heat transfer analysis shows that air atomized spray with the MgSO₄ salt produces 1.5 times higher cooling rate than atomized spray with the pure water, whereas air atomized spray with NaCl produces only 1.2 times higher cooling rate. In transition boiling regime, the salt deposition occurs which causes enhancement in heat transfer rate by conduction. Moreover, surface tension is the governing parameter behind the vapour film instability and this length scale increases with increase in surface tension of coolant. Overall, the achieved cooling rates produced by both types of salt added air atomized spray are found to be in the UFC regime.     

Visualization of boiling phenomena in inclined rectangular gap

An experimental study was performed to investigate the pool boiling critical heat flux (CHF) in one-dimensional inclined rectangular channels by changing the orientation of a copper test heater assembly. In a pool of saturated water under the atmospheric pressure, the test parameters included the gap sizes of 1, 2, 5, and 10 mm, and the surface orientation angles from the downward-facing position (180°) to the vertical position (90°). Tests were conducted on the basis of the visualization of boiling phenomena in the narrowly confined channel and open periphery utilizing a high-speed digital camera. To prevent the heat loss from the water pool and copper test heater, a state-of-the-art vacuum pumping technique was introduced. It was observed that the CHF generally decreased as the surface inclination angle increased and as the gap size decreased. In the downward-facing position (180°), however, the vapor movement was enhanced by the gap structure, which produced the opposing result; that is, the CHF increased as the gap size decreased. Phenomenological characteristics regarding the interfacial instability of vapor layer were addressed in terms of visualization approaching the CHF. It was found that there exists a transition angle, around which the CHF changes with a rapid slope.     

Effect of inclination angle on the pool boiling heat transfer of ultra-light copper foams

Effect of inclination angles on the pool boiling heat transfer on ultra-light copper foam covers was studied using acetone as the working fluid. The inclination angle was from 0° to 90°. It is found that copper foam covers decrease the surface superheat at the onset of nucleate boiling and extend the operation ranges of surface superheats and heat fluxes, significantly. Boiling curves are crossed between low and high inclination angles. Heat transfer coefficients are increased, attain maximum values, and then are decreased with continuous increases in heat fluxes. The thermal performance is very insensitive to inclination angles at low pool liquid temperatures. The thermal performance is better for the saturation pool boiling heat transfer at small surface superheats, but it is better for the subcooled pool boiling heat transfer at high surface superheats. The Nusselt number is well correlated using the 812 data points, with the maximum error of 20%.     

Periodic boiling in parallel micro-channels at low vapor quality

Based on experimental investigations the present study evaluates instability and heat transfer phenomenon under condition of periodic flow boiling of water and ethanol in parallel triangular micro-channels. Tests were performed in the range of hydraulic diameter 100–220 μm, mass flux 32–200 kg/m² s, heat flux 120–270 kW/m², vapor quality x = 0.01–0.08. The period between successive events depends on the boiling number and decreases with an increase in the boiling number. The initial film thickness decreases with increasing heat flux. When the liquid film reached the minimum initial film thickness CHF regime occurred. Temporal variations of pressure drop, fluid and heater temperatures were periodic. Oscillation frequency is the same for the pressure drop, for the fluid temperature at the outlet manifold, and for the mean and maximum heater temperature fluctuations. All these fluctuations are in phase. The CHF phenomenon is different from that observed in a single channel of conventional size. A key difference between micro-channel heat sink and single conventional channel is amplification of parallel-channel instability prior to CHF. The dimensionless experimental values of the heat transfer coefficient are presented as the Nusselt number dependence on the Eotvos number and the boiling number.