Optical detection of an electric field in a GaAs/AlGaAs <Emphasis Type=Italic>n</Emphasis>-<Emphasis Type=Italic>i</Emphasis>-<Emphasis Type=Italic>n</Emphasis> heterostructure with double quantum wells

Processes occurring when a static transverse electric field is applied to a GaAs/AlGaAs n-i-n heterostructure with single quantum wells and asymmetric tunnel-coupled double quantum wells have been investigated by optical methods. The difference between the energies of exciton transitions for quantum wells of different widths makes it possible to attribute the observed photoluminescence peaks to particular pairs of wells or particular single quantum wells. The local electric field for each quantum well has been determined in terms of the Stark shift and splitting of exciton lines in a wide range of external voltage. A qualitative model has been proposed to explain the nonmonotonic distribution of the electric field over the depth of the heterostructure.     

Cosmology based on <Emphasis Type=Italic>f</Emphasis>(<Emphasis Type=Italic>R</Emphasis>) gravity with <Emphasis Type=Italic>O</Emphasis>(1)eV sterile neutrino

We confront different up to date cosmological data with different gravity models of the Universe with one additional massive sterile neutrino [1].     

A New Fluorescent Sensor Based on 1H-pyrazolo[3,4-b]quinoline Skeleton. Part 2

A novel fluorescent dye bis-(pyridin-2-yl-methyl)-(1,3,4-triphenyl-1H-pyrazolo[3,4-b]quinolin-6-ylmethyl)-amine (P1) has been synthesized and investigated by means of steady state and time-resolved fluorescence techniques. This compound acts as sensor for fluorescence detection of small inorganic cations (lithium, sodium, barium, magnesium, calcium, and zinc) in highly polar solvents such as acetonitrile. The mechanism which allows application of this compound as sensor is an electron transfer from the electron-donative part of molecule (amine) to the acceptor part (pyrazoloquinoline derivative), which is retarded upon complexation of the electro-donative part by inorganic cations. The binding constants are strongly dependent on the charge density of the analyzed cations. The 2/1 complexes of P1 with Zn(++) and Mg(++) cations posses large binding constants. Moreover, in the presence of these cations a significant bathochromic shift of fluorescence is observed. The most probable explanation of such behaviour is the formation of intramolecular excimer. This is partially supported by the quantum chemical calculations.     

Synthesis of 1<Emphasis Type="Italic">H</Emphasis>-imidazo[1,2-<Emphasis Type="Italic">b</Emphasis>]-1,2,4-triazol-6-amines via multicomponent reaction

A simple and effective method for the synthesis of bioactive imidazo[1,2,4]triazole analogues has been developed utilizing the MCR technique, which involved the reaction of aminotriazoles, isocyanides and aldehydes. The products were characterized by ¹H, ¹³C NMR spectroscopy, MS and elemental analysis. Interestingly, compounds 19d, 21a, 21b and 21h displayed good cytotoxic activities at 10⁻⁴ M concentration in the inhibition of tumor cell growth as evaluated by the MTT method.     

<Emphasis Type=Italic>Y</Emphasis> and <Emphasis Type=Italic>Z</Emphasis> luminescence of polycrystalline cadmium telluride

The properties of polycrystalline CdTe with a grain size of 5–30 μm have been investigated using the microphotoluminescence methods of spectral analysis and topography. This material has been prepared by direct synthesis in a vapor flow of components at a low temperature. The dominance of the Y and Z bands in the spectra reflects a nonequilibrium character of the crystallization processes. The superlinear dependences of the luminescence intensity on the level of the band-to-band excitation indicate the exciton nature of the corresponding transitions. The activation energies for temperature quenching of luminescence in the temperature range T = 100–150 K are found to be 120 meV for the Y luminescence and 180 meV for the Z luminescence, which correspond to the dissociation of excitons bound to defects with the transition of charge carriers to the conduction and valence bands. The monochromatic topography data indicate that Y and Z defects have different material bases.     

Current-phase relation in SFS Josephson junctions in the presence of <Emphasis Type=Italic>s</Emphasis>-<Emphasis Type=Italic>d</Emphasis> scattering

The analytical equations for the current-phase relation (CPR) coefficients for Josephson junctions with a ferromagnetic interlayer in the model where the scattering from s- to d-band is considered to be the main type scattering of charge carrier in a ferromagnet are obtained. It is shown that the magnitude of the coefficients oscillates and decays with an increase of the interlayer thickness. Both the oscillation period and the decay length for the first and the second harmonics differ by two times. The temperature dependence of the critical current demonstrating 0-π temperature transitions is obtained. The possibility of design a flux qubit based on such Josephson junctions is demonstrated.     

Static spherically symmetric solutions in <Emphasis Type=Italic>F</Emphasis>(<Emphasis Type=Italic>R</Emphasis>) gravity

A Lagrangian derivation of the Equations of Motion (EOM) for static spherically symmetric metrics in F(R) modified gravity is presented. For a large class of metrics, our approach permits one to reduce the EOM to a single equation and we show how it is possible to construct exact solutions in F(R)-gravity. All known exact solutions are recovered. We also exhibit a new non-trivial solution with non-constant Ricci scalar.     

Ionic liquid-promoted multi-component reaction: novel and efficient preparation of pyrazolo[3,4-<Emphasis Type="Italic">b</Emphasis>]pyridinone,pyrazolo[3,4-<Emphasis Type="Italic">b</Emphasis>]-quinolinone and their hybrids with pyrimidine nucleoside

The utilization of an ionic liquid, [bmim][BF₄] as both reaction medium and promoter for a multi-component reaction of aldehyde (1) and 5-amino-3-methyl-1-phenylpyrazole (2) with Meldrum acid (3) or dimedone (5) is studied. From this reaction, pyrazolo[3,4-b]pyridinone (4) and pyrazolo[3,4-b]quinolinone (6) derivatives were prepared in high yields. This novel procedure showed such advantages as environmentally benign nature, enhanced efficiency, simple operation process, and mild reaction conditions. As an application, the procedure was successfully used in the preparation of a set of pyrimidine nucleoside–pyrazolo[3,4-b]pyridine and pyrazolo[3,4-b]quinolinone hybrids with potential biological activities.