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基于由纯苯环稠合的稠环芳烃的所有碳原子以sp2杂化不存在额外氢的事实,建议废除对由纯苯环稠合的稠环芳烃额外氢的标明;建议将稠环烃编号从右上方第一个环最上方的自由角开始修改为从右上方第一个环最左方的自由角开始;对文中一些例子命名错误给予了纠正。 相似文献
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]本文提出高效液相色谱法分离测定土壤中的多环芳烃。方法简便,快速,基本过程是将土壤样品用二氯甲烷索氏提取,提取液浓缩后,经硅酸镁-微细硅胶薄层纯化,以除去色素、极性物及其它杂质。薄板在254nm紫外光下观察,收集荧光带区域内的吸附剂,用二氯甲烷洗脱,浓缩后进行高效液相色谱分析。该法对几种代表性多环芳烃的回收率为75.0-100%。用苯并(a)芘为代表物作了高效液相色谱法与荧光法比较,结果也很近似。 相似文献
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固相萃取-高效液相色谱法测定水中的多环芳烃 总被引:3,自引:0,他引:3
建立了固相萃取-一高效液相色谱法测定水中多环芳烃的方法。水样经L-18固相萃取柱吸附后用二氯甲烷洗脱,氮吹干后换甲醇溶剂。反相C18柱为色谱柱;水、甲醇为流动相进行梯度洗脱,流速为1.0mL/min;柱温为30℃;检测器为荧光检测器、紫外检测器。方法的检出限为0.00006-0.03μg/L,回收率为80%~110%,测定结果的相对标准偏差为0.1%~3.6%(n=5)。方法适合于水中16种多环芳烃的测定。 相似文献
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褐煤超临界流体抽提产物中芳烃的组成特征 总被引:3,自引:2,他引:3
用柱色谱分离、GC/MS分析云南先锋和金所褐煤甲苯(或二甲苯)超临界流体抽提(SCFE)产物油段分中芳烃馏分的组成结构,鉴定出联苯、联苄型结构及它们的烷基衍生物为主要组成部分,菲、芴、芘、荧蒽、苯并芘等多环缩合芳烃的量较少,有较丰富的芳构化五环萜类,包括从三环至五环芳构化的化合物。这些结果反映了多环芳烃成煤过程中的演变情况,可为煤化学研究提供重要的信息。 相似文献
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土壤中多环芳烃的高效液相色谱测定研究及应用 总被引:3,自引:0,他引:3
本文用高效液相色谱方法分离测定土壤中的多环芳烃,通过改变不同的流动相组成使15种多环芳烃完全分离,并分别得到15种物质的最低检出限和线性范围,被试验的4种多环度烃的回收率为96%-112%,本文最后对深圳河的实际土壤样品进行了测度定,一些多环节芳烃被检出。 相似文献
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气相色谱质谱法测定化妆品中9种多环芳烃 总被引:1,自引:0,他引:1
建立了气相色谱质谱法测定化妆品中9种多环芳烃的分析方法。化妆品中的萘、苯并[a]蒽、、苯并[b]荧蒽、苯并[j]荧蒽、苯并[k]荧蒽、苯并[e]芘、苯并[a]芘、二苯并[a,h]蒽等9种多环芳烃用甲醇超声提取后,用环己烷液-液萃取后浓缩,经硅胶-中性氧化铝柱净化后,采用气相色谱-质谱测定。多环芳烃浓度在0.05~2 mg/L范围内,质量浓度与其峰面积呈良好的线性关系。在低、中、高3个添加水平下,9种多环芳烃化合物的平均回收率为81.6%~100.2%,相对标准偏差为1.3%~5.8%。方法可用于化妆品中多环芳烃的检测。 相似文献
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Naoya Kishikawa Ayuko Ihara Masae Shirota Mitsuhiro Wada Yoshihito Ohba Nobuyuki Sera Kenichiro Nakashima Naotaka Kuroda 《Analytical sciences》2005,21(12):1467-1470
Thirteen polycyclic aromatic hydrocarbons (PAHs) and four nitropolycyclic aromatic hydrocarbons (NPAHs) on the surfaces of airborne particulates, which were collected at an industrial area of a western site of Japan during periods from 1976 to 1998, were retrospectively analyzed. PAHs and NPAHs were extracted from airborne particulates using hexane with ultrasonication, and then analyzed by HPLC systems with fluorescence detection and chemiluminescence detection, respectively. The total concentrations (mean +/- SD, n = 34) were 15.54 +/- 21.24 ng/m3 for PAHs and 5.85 +/- 8.16 pg/m3 for NPAHs. The concentrations of PAHs and NPAHs were found to be highest during the period between 1979 and 1982, and then reduced. The annual concentrations of PAHs and NPAHs were highly correlated with those of air pollutants from motor vehicle origin, such as carbon monoxide, suspended particulates and non-methane hydrocarbons. The results suggested that motor vehicle emissions were one of the predominant sources of atmospheric PAHs and NPAHs. 相似文献
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Galano A 《The journal of physical chemistry. A》2007,111(9):1677-1682
Physisorption and chemisorption processes of thiophene on coronene and 2Si-coronene have been studied using density functional theory and MP2 methods. These systems have been chosen as the simplest models to describe the adsorption of thiophene-like compounds on polycyclic aromatic hydrocarbons (PAHs). The calculated data suggest that the presence of silicon atoms in PAHs could favor their interaction with thiophene and similar compounds. Small stabilization energies have been found for several physisorbed complexes. The thiophene chemisorption on coronene seems very unlikely to occur, while that on 2Si-coronene leads to addition products which are very stable, with respect to the isolated reactants. These chemisorption processes were found to be exoergic (DeltaG < 0) in the gas phase and in the nonpolar liquid phase. The results reported in this work suggest that silicon defects on extended polycyclic aromatic hydrocarbons, such as graphite, soot, and large-diameter carbon nanotubes, could make them useful in the removal processes of aromatic sulfur compounds from oil hydrocarbons. 相似文献
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聚丙烯酸树脂涂层HS-SPME-GC-MS监测城市污水中的芳香烃化合物 总被引:2,自引:0,他引:2
采用聚丙烯酸树脂涂层-固相微萃取-气相色谱-质谱(PA—SPME—GC—MS)联用技术,在优化的萃取条件下检测了城市污水中的苯系物和多环芳烃等芳香烃化合物.该方法的最低检出限达12ng/L水平,相对标准偏差为1.7%~9.8%. 相似文献
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A. S. Lindsey J. J. Belliardo P. J. Wagstaffe 《Fresenius' Journal of Analytical Chemistry》1989,333(6):599-606
Summary Monitoring of the concentration levels of certain environmental organic pollutants which pose potential health hazards is examined. The use of reference materials in the quantitative measurement of common pollutants such as polycyclic aromatic hydrocarbons (PAHs), polycyclic heteroaromatic compounds, nitro-polycyclic aromatic hydrocarbons, and polychlorinated biphenyls (PCBs) is reviewed within the context of achieving optimum precision sand accuracy of the measurements.
Verwendung zertifizierter Referenzmaterialien bei der Messung von Umweltverunreinigungen (PAHs, Nitro-PAHs, PCBs)相似文献
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That polystyrene and benzene as additives to gasoline increase the amount of polycyclic aromatic hydrocarbons (PAHs) has been studied previously in our laboratory. This paper describes the use of carbon disulfide as the solvent instead of benzene brings a marked reduction of the formation of polycyclic aromatic hydrocarbons. 相似文献
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Solid-phase extraction (SPE) is an established sample-preparation technique for clean-up procedures of polycyclic aromatic hydrocarbons (PAHs). The suitability of monofluorinated polycyclic aromatic hydrocarbons (F-PAHs) as a novel set of internal standards, was tested for two widely used SPE sorbents, octyl-bonded silica and styrene-divinylbenzene copolymer. The elution profiles of eight F-PAHs and their parent PAHs, taken from the priority pollutant list of the US-Environmental Protection Agency, were compared for demineralized water and waste water. In both instances, the match of the elution profiles was exceptionally close. The eight F-PAHs and the corresponding PAHs were determined by reversed-phase liquid chromatography using acetonitrile-water gradient elution with UV detection at 254 nm. The UV spectra of the F-PAHs show a small bathochromic shift compared with the parent PAHs. 相似文献
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J. F. Fernndez-Snchez A. Segura Carretero J. M. Benítez-Snchez C. Cruces-Blanco A. Fernndez-Gutirrez 《Analytica chimica acta》2004,510(2):183-187
This paper presents an optosensor for screening of four polycyclic aromatic hydrocarbons: anthracene (ANT), benzo[a]pyrene (BaP), fluoranthene (FLT), and benzo[b]fluoranthene (Bbf) using a photomultiplier device with an artificial neural network as transducer. The optosensor is based on the on-line immobilization on a non-ionic resin (Amberlite XAD-4) solid support in a continuous flow. The determination was performed in 15 mM H2PO4−/HPO42− buffer solution at pH 7 and 25% of 1,4-dioxane. Feed forward neural networks (multiplayer perceptron) have been trained to quantify the considered Polycyclic aromatic hydrocarbons (PAHs) in mixtures under optimal conditions. The optosensor proposed was also applied satisfactorily to the determination of the considered PAHs in water samples in presence of the other 12 EPA–PAHs. 相似文献
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Polycyclic aromatic hydrocarbons (PAHs) and geochemical biomarkers are good environmental markers to study the origin and evolution of an oil spill. To have access to the greatest number of molecular ratios, no fractionation of oil into aliphatic and aromatic compounds is made. Three analytical MS approaches are tested to analyze markers in this total hydrocarbon fraction: classical quadrupole GC-MS, high resolution GC-MS (HR GC-MS) and metastable reaction monitoring GC-MS-MS (MRM GC-MS-MS). This analytical approach is used to follow the evolution of PAHs in petroleum polluted mangrove soils over 8 years by using molecular ratios between polycyclic aromatic hydrocarbons and tri- and tetracyclic terpanes. 相似文献