Experimental investigations and theoretical determination of thermal conductivity and viscosity of Al2O3/water nanofluid

Experimental investigations and theoretical determination of effective thermal conductivity and viscosity of Al₂O₃/H₂O nanofluid are reported in this paper. The nanofluid was prepared by synthesizing Al₂O₃ nanoparticles using microwave assisted chemical precipitation method, and then dispersing them in distilled water using a sonicator. Al₂O₃/water nanofluid with a nominal diameter of 43 nm at different volume concentrations (0.33–5%) at room temperature were used for the investigation. The thermal conductivity and viscosity of nanofluids are measured and it is found that the viscosity increase is substantially higher than the increase in thermal conductivity. Both the thermal conductivity and viscosity of nanofluids increase with the nanoparticle volume concentration. Theoretical models are developed to predict thermal conductivity and viscosity of nanofluids without resorting to the well established Maxwell and Einstein models, respectively. The proposed models show reasonably good agreement with our experimental results.     

Experimental investigation on thermal conductivity and viscosity of aluminum nitride nanofluid

Aluminum nitride nanoparticles (AlNs) have been found to be a good additive for enhancing the thermal conductivity of traditional heat exchange fluids.At a volume fraction of 0.1,the thermal conductivity enhancement ratios are 38.71% and 40.2%,respectively,for ethylene glycol and propylene glycol as the base fluids.Temperature does not have much influence on the enhanced thermal conductivity ratios of the nanofluids,though a volume fraction of 5.0% appears to signify a critical concentration for rheology:fo...     

Experimental investigation of TiO2/water nanofluid laminar forced convective heat transfer through helical coiled tube

Coiled tubes and nanofludics are two significant techniques to enhance the heat transfer ability of thermal equipments. The forced convective heat transfer and the pressure drop of nanofluid inside straight tube and helical coiled one with a constant wall heat flux were studied experimentally. Distilled water was used as a host fluid and Nanofluids of aqueous TiO₂ nanoparticles (50 nm) suspensions were prepared in various volume concentrations of 0.25–2 %. The heat transfer coefficient of nanofluids is obtained for different nanoparticle concentrations as well as various Reynolds numbers. The experiments covered a range of Reynolds number of 500–4,500. The results show the considerable enhancement of heat transfer rate, which is due to the nanoparticles present in the fluid. Heat transfer coefficient increases by increasing the volume concentration of nanoparticles as well as Reynolds number. Moreover, due to the curvature of the tube when fluid flows inside helical coiled tube instead of straight one, both convective heat transfer coefficient and the pressure drop of fluid grow considerably. Also, the thermal performance factors for tested nanofluids are greater than unity and the maximum thermal performance factor of 3.72 is found with the use of 2.0 % volume concentration of nanofluid at Reynolds number of 1,750.     

Numerical simulation of the nanoparticle diameter effect on the thermal performance of a nanofluid in a cooling chamber

The thermal performance of a nanofluid in a cooling chamber with variations of the nanoparticle diameter is numerically investigated. The chamber is filled with water and nanoparticles of alumina (Al₂O₃). Appropriate nanofluid models are used to approximate the nanofluid thermal conductivity and dynamic viscosity by incorporating the effects of the nanoparticle concentration, Brownian motion, temperature, nanoparticles diameter, and interfacial layer thickness. The horizontal boundaries of the square domain are assumed to be insulated, and the vertical boundaries are considered to be isothermal. The governing stream-vorticity equations are solved by using a secondorder central finite difference scheme coupled with the mass and energy conservation equations. The results of the present work are found to be in good agreement with the previously published data for special cases. This study is conducted for the Reynolds number being fixed at Re = 100 and different values of the nanoparticle volume fraction, Richardson number, nanofluid temperature, and nanoparticle diameter. The results show that the heat transfer rate and the Nusselt number are enhanced by increasing the nanoparticle volume fraction and decreasing the Richardson number. The Nusselt number also increases as the nanoparticle diameter decreases.     

The role of several heat transfer mechanisms on the enhancement of thermal conductivity in nanofluids

A modelling of the thermal conductivity of nanofluids based on extended irreversible thermodynamics is proposed with emphasis on the role of several coupled heat transfer mechanisms: liquid interfacial layering between nanoparticles and base fluid, particles agglomeration and Brownian motion. The relative importance of each specific mechanism on the enhancement of the effective thermal conductivity is examined. It is shown that the size of the nanoparticles and the liquid boundary layer around the particles play a determining role. For nanoparticles close to molecular range, the Brownian effect is important. At nanoparticles of the order of 1–100 nm, both agglomeration and liquid layering are influent. Agglomeration becomes the most important mechanism at nanoparticle sizes of the order of 100 nm and higher. The theoretical considerations are illustrated by three case studies: suspensions of alumina rigid spherical nanoparticles in water, ethylene glycol and a 50/50w% water/ethylene glycol mixture, respectively, good agreement with experimental data is observed.     

Experimental investigation of the Cu/R141b nanofluids on the evaporation/boiling heat transfer characteristics for surface with capillary micro-channels

An experimental study was conducted to investigate the heat transfer characteristic of a vertical copper plate with rectangular micro-channels. In this research, Cu/R141b nanofluids were used as the working fluid. Three different volume concentrations—0.001, 0.01, and 0.1 %—of Cu nanoparticles with an average diameter of 20 nm dispersed in R141b were prepared. Experiments were performed to measure thermal resistance of the microchannel surface under a steady operating pressure range of 0.86 × 10⁵ Pa to 2 × 10⁵ Pa. Thermal resistance weakened with addition of nanoparticles into the base fluid. The maximum reduction effect of the thermal resistance was 50 %, which corresponds to 0.01 % volume concentration of nanofluid at low operating pressure. The operating pressure significantly affects thermal performance of the microchannel surface. This paper also studied heat transfer characteristics for a Cu nanoparticle-coated surface with rectangular microchannels, which were produced by heating in different volume concentrations from 0.001 to 0.1 %. Nanoparticle layer on the micro-channel surface is responsible for enhanced heat transfer of nanofluids with 0.001 and 0.01 % volume concentrations.     

Experimental study to obtain the viscosity of CuO-loaded nanofluid: effects of nanoparticles’ mass fraction,temperature and basefluid’s types to develop a correlation

In this study, the impacts of temperature, nanoparticles mass fraction, and basefluid types were investigated on the dynamic viscosity of CuO-loaded nanofluids. The nanoparticles were dispersed in deionized water, ethanol, and ethylene glycol as basefluids separately and the measurements were performed on samples with nanoparticles loads ranging from 0.005 to 5 wt%, and the temperature range of 25 to 70 °C. TEM analysis were performed on dried nanoparticles and the results showed the average mean diameter of CuO nanoparticles ranged from 10 to 50 nm. The results of DLS analysis confirmed the results of nanoparticles size obtained by TEM analysis in mentioned basefluids and Zeta-Potential tests exhibited the high stability of the nanoparticles in the basefluids environment. The results indicate that by adding tiny amount of CuO nanoparticles to basefluids, relative viscosity of nanofluid increases. By the increase in nanoparticles load higher than 0.1 wt% the effect of both nanoparticles mass fraction and temperature would be more tangible, while for nanoparticles mass fraction lower than 0.1 wt% no significant change in viscosity was observed. In addition, the results declare that viscosity of nanofluid remains constant at various applied shear rates indicating Newtonian behavior of nanofluid at various nanoparticles load and temperature. According to experimental data, it is also evident that with the increase in temperature, the value of relative dynamic viscosity decreases significantly. Also it is concluded that for CuO/ethanol nanofluid, more interfacial interaction is resulted that causes higher relative dynamic viscosity while for CuO/water lower interfacial interaction between nanoparticles surface and water molecules are resulted which leads to the lower values for this parameter. The results of this study implied that with increase the temperature from 25 to 70 °C at the condition where nanoparticles mass fraction was chosen to be 5 wt%, the value of dynamic viscosity of CuO/ethanol, CuO/deionized water, CuO/ethylene glycol declined 69%, 66%, and 65% respectively. Finally, a correlation was proposed for the relative dynamic viscosity of nanofluid based on the CuO nanoparticles mass fraction and temperature of the basefluid and nanoparticles.     

Measurement of temperature-dependent thermal conductivity and viscosity of TiO2-water nanofluids

Nanofluid is an innovative heat transfer fluid with superior potential for enhancing the heat transfer performance of conventional fluids. Many attempts have been made to investigate its thermal conductivity and viscosity, which are important thermophysical properties. No definitive agreements have emerged, however, about these properties. This article reports the thermal conductivity and dynamic viscosity of nanofluids experimentally. TiO₂ nanoparticles dispersed in water with volume concentration of 0.2–2 vol.% are used in the present study. A transient hot-wire apparatus is used for measuring the thermal conductivity of nanofluids whereas the Bohlin rotational rheometer (Malvern Instrument) is used to measure the viscosity of nanofluids. The data are collected for temperatures ranging from 15 °C to 35 °C. The results show that the measured viscosity and thermal conductivity of nanofluids increased as the particle concentrations increased and are higher than the values of the base liquids. Furthermore, thermal conductivity of nanofluids increased with increasing nanofluid temperatures and, conversely, the viscosity of nanofluids decreased with increasing temperature of nanofluids. Moreover, the measured thermal conductivity and viscosity of nanofluids are quite different from the predicted values from the existing correlations and the data reported by other researchers. Finally, new thermophysical correlations are proposed for predicting the thermal conductivity and viscosity of nanofluids.     

Effect of temperature on the effective thermal conductivity of n-tetradecane-based nanofluids containing copper nanoparticles

Nanofluids were prepared by dispersing Cu nanoparticles(~20nm) in n-tetradecane by a two-step method.The effective thermal conductivity was measured for various nanoparticle volume fractions(0.0001-0.02) and temperatures(306.22-452.66 K).The experimental data compares well with the Jang and Choi model.The thermal conductivity enhancement was lower above 391.06 K than for that between306.22 and 360.77 K.The interfacial thermal resistance increased with increasing temperature.The effective thermal conductivity enhancement was greater than that obtained with a more viscous fluid as the base media at 452.66 K because of nanoconvection induced by nanoparticle Brownian motion at high temperature.     

Effective thermal conductivity of CdS/ZnS nanoparticles embedded polystyrene nanocomposites

CdS/PS and ZnS/PS nanocomposites have been prepared by solution casting method with different wt% of cadmium sulphide (CdS) and zinc sulphide (ZnS) nanoparticles and characterized through X-ray diffraction and transmission electron microscope measurements. The effective thermal conductivity of polymer nanocomposites has been measured by transient plane source method over the temperature range from room to 150 °C. The experimental results showed that the thermal conductivity has been found to increase up to 4 wt% of CdS/ZnS nanoparticles and then decrease for 6 and 8 wt% of nanoparticles.     

Effects of walls temperature variation on double diffusive natural convection of Al2O3–water nanofluid in an enclosure

The effect of wall temperature variations on double diffusive natural convection of Al₂O₃–water nanofluid in a differentially heated square enclosure with constant temperature hot and cold vertical walls is studied numerically. Transport mechanisms of nanoparticles including Brownian diffusion and thermophoresis that cause heterogeneity are considered in non-homogeneous model. The hot and cold wall temperatures are varied, but the temperature difference between them is always maintained 5 °C. The thermophysical properties such as thermal conductivity, viscosity and density and thermophoresis diffusion and Brownian motion coefficients are considered variable with temperature and volume fraction of nanoparticles. The governing equations are discretized using the control volume method. The results show that nanoparticle transport mechanisms affect buoyancy force and cause formation of small vortexes near the top and bottom walls of the cavity and reduce the heat transfer. By increasing the temperature of the walls the effect of transport mechanisms decreases and due to enhanced convection the heat transfer rate increases.     

Experimental studies on heat transfer and friction factor characteristics of CuO/water nanofluid under turbulent flow in a helically dimpled tube

An experimental investigation on the convective heat transfer and friction factor characteristics in the plain and helically dimpled tube under turbulent flow with constant heat flux is presented in this work using CuO/water nanofluid as working fluid. The effects of the dimples and nanofluid on the Nusselt number and the friction factor are determined in a circular tube with a fully developed turbulent flow for the Reynolds number in the range between 2500 and 6000. The height of the dimple/protrusion was 0.6 mm. The effect of the inclusion of nanoparticles on heat transfer enhancement, thermal conductivity, viscosity, and pressure loss in the turbulent flow region were investigated. The experiments were performed using helically dimpled tube with CuO/water nanofluid having 0.1%, 0.2% and 0.3% volume concentrations of nanoparticles as working fluid. The experimental results reveal that the use of nanofluids in a helically dimpled tube increases the heat transfer rate with negligible increase in friction factor compared to plain tube. The experimental results showed that the Nusselt number with dimpled tube and nanofluids under turbulent flow is about 19%, 27% and 39% (for 0.1%, 0.2% and 0.3% volume concentrations respectively) higher than the Nusselt number obtained with plain tube and water. The experimental results of isothermal pressure drop for turbulent flow showed that the dimpled tube friction factors were about 2-10% higher than the plain tube. The empirical correlations developed for Nusselt number and friction factor in terms of Reynolds number, pitch ratio and volume concentration fits with the experimental data within ±15%.     

Influence of heating load on heat transfer characteristics in micro-pin-fin arrays

Experimental investigations were carried out to explore the convective heat transfer in micro pin-fins with different aspect ratios, and the influence of heating load on Nusselt numbers in micro pin-fins with liquid water as working fluid were investigated. The mechanism of convective heat transfer in micro pin-fins at different heating load were studied by 3-D numerical investigations, and the relationships of thermal physical properties change, the end wall effect and axial thermal conduction with Nu numbers in micro pin-fins were analysed. It was found that the thickness of boundary layer was decreased as much as 33.3 % attributed to the destructive effect of thermal physical properties change, and convective heat transfer in the micro pin-fin channel was more than 20 % enhanced by the flow disturbance caused by the increase of temperature difference. The discrepancy of Nu in micro pin-fin channel with different aspect ratios reached 34.59 %, and this discrepancy was reduced by the increase of heating load. The maximum value of impact factors of dynamic viscosity and thermal conductivity on the Nu in micro-pin-fins reached 25.02 and 7.68 %, respectively.     

Viscosity of alumina nanoparticles dispersed in car engine coolant

The present paper, describes our experimental results on the viscosity of the nanofluid prepared by dispersing alumina nanoparticles (<50 nm) in commercial car coolant. The nanofluid prepared with calculated amount of oleic acid (surfactant) was tested to be stable for more than 80 days. The viscosity of the nanofluids is measured both as a function of alumina volume fraction and temperature between 10 and 50 °C. While the pure base fluid display Newtonian behavior over the measured temperature, it transforms to a non-Newtonian fluid with addition of a small amount of alumina nanoparticles. Our results show that viscosity of the nanofluid increases with increasing nanoparticle concentration and decreases with increase in temperature. Most of the frequently used classical models severely under predict the measured viscosity. Volume fraction dependence of the nanofluid viscosity, however, is predicted fairly well on the basis of a recently reported theoretical model for nanofluids that takes into account the effect of Brownian motion of nanoparticles in the nanofluid. The temperature dependence of the viscosity of engine coolant based alumina nanofluids obeys the empirical correlation of the type: log (μ_nf) = A exp(BT), proposed earlier by Namburu et al.     

Role of interfacial layer and clustering on the effective thermal conductivity of CuO-gear oil nanofluids

Copper oxide nanoparticles (∼40 nm) are dispersed in gear oil (IBP Haulic-68) at different volume fractions (0.005-0.025) with oleic acid added as a surfactant to stabilize the system. Prepared nanofluids are characterized by Fourier Transform Infrared spectroscopy (FTIR) and Dynamic light scattering (DLS) measurements. DLS data confirmed the presence of agglomerated nanoparticles in the prepared nanofluids. Thermal conductivity measurements are performed both as a function of CuO volume fraction and temperature between 5 and 80 °C. An enhancement in thermal conductivity at 30 °C of 10.4% with 0.025 volume fraction of CuO nanoparticle loading is observed. Measured volume fraction dependence of the thermal conductivity enhancement at room temperature is predicted fairly well considering contributions from both nanolayer at the solid-liquid interface and particle agglomeration in the suspension, as visualized by Feng et al.     

The effect of real viscosity on the heat transfer of water based Al2O3 nanofluids in a two-sided lid-driven differentially heated rectangular cavity

The heat transfer and fluid flow behavior of water based Al₂O₃ nanofluids are numerically investigated inside a two-sided lid-driven differentially heated rectangular cavity. Physical properties which have major effects on the heat transfer of nanofluids such as viscosity and thermal conductivity are experimentally investigated and correlated and subsequently used as input data in the numerical simulation. Transport equations are numerically solved with finite volume approach using SIMPLEC algorithm. It was found that not only the thermal conductivity but also the viscosity of nanofluids has a key role in the heat transfer of nanofluids. The results show that at low Reynolds number, increasing the volume fraction of nanoparticles increases the viscosity and has a deteriorating effect on the heat transfer of nanofluids. At high Reynolds number, the increase in the viscosity is compensated by force convection and the increase in the volume fraction of nanoparticles which results in an increase in heat transfer is in coincidence with experimental results.     

Effect of temperature on the effective thermal conductivity of n-tetradecane-based nanofluids containing copper nanoparticles

Nanofluids were prepared by dispersing Cu nanoparticles (∼20 nm) in n-tetradecane by a two-step method. The effective thermal conductivity was measured for various nanoparticle volume fractions (0.0001–0.02) and temperatures (306.22–452.66 K). The experimental data compares well with the Jang and Choi model. The thermal conductivity enhancement was lower above 391.06 K than for that between 306.22 and 360.77 K. The interfacial thermal resistance increased with increasing temperature. The effective thermal conductivity enhancement was greater than that obtained with a more viscous fluid as the base media at 452.66 K because of nanoconvection induced by nanoparticle Brownian motion at high temperature.     

Heat- and mass-transport in aqueous silica nanofluids

Using the transient hot wire and pulsed field gradient nuclear magnetic resonance methods we determined the thermal conductivity and the solvent self-diffusion coefficient (SDC) in aqueous suspensions of quasi-monodisperse spherical silica nanoparticles. The thermal conductivity was found to increase at higher volume fraction of nanoparticles in accordance with the effective medium theory albeit with a smaller slope. On the other hand, the SDC was found to decrease with nanoparticle volume fraction faster than predicted by the effective medium theory. These deviations can be explained by the presence of an interfacial heat-transfer resistance and water retention by the nanoparticles, respectively. We found no evidence for anomalous enhancement in the transport properties of nanofluids reported earlier by other groups.     

Laminar convective heat transfer of non-Newtonian nanofluids with constant wall temperature

Nanofluids are obtained by dispersing homogeneously nanoparticles into a base fluid. Nanofluids often exhibit higher heat transfer rate in comparison with the base fluid. In the present study, forced convection heat transfer under laminar flow conditions was investigated experimentally for three types of non-Newtonian nanofluids in a circular tube with constant wall temperature. CMC solution was used as the base fluid and γ-Al₂O₃, TiO₂ and CuO nanoparticles were homogeneously dispersed to create nanodispersions of different concentrations. Nanofluids as well as the base fluid show shear thinning (pseudoplastic) rheological behavior. Results show that the presence of nanoparticles increases the convective heat transfer of the nanodispersions in comparison with the base fluid. The convective heat transfer enhancement is more significant when both the Peclet number and the nanoparticle concentration are increased. The increase in convective heat transfer is higher than the increase caused by the augmentation of the effective thermal conductivity.     

Influence of temperature dependent conductivity of a nanofluid in a vertical rectangular duct

Natural convective heat transfer and fluid flow in a vertical rectangular duct filled with a nanofluid is studied numerically assuming the thermal conductivity to be dependent on the fluid temperature. The transport equations for mass, momentum and energy formulated in dimensionless form are solved numerically using finite difference method. Particular efforts have been focused on the effects of the thermal conductivity variation parameter, Grashof number, Brinkman number, nanoparticles volume fraction, aspect ratio and type of nanoparticles on the fluid flow and heat transfer inside the cavity. It is found that the flow was enhanced for the increase in Grashof number, Brinkman number and aspect ratio for any values of conductivity variation parameter and for regular fluid and nanofluid. The heat transfer rate for regular fluid is less than that for the nanofluid for all governing parameters.