Power-law creep and residual stresses in a carbopol gel

We report on the interplay between creep and residual stresses in a carbopol microgel. When a constant shear stress σ is applied below the yield stress σ _y, the strain is shown to increase as a power law of time, γ(t) = γ ₀ + (t/τ) ^α , with an exponent α = 0.39 ± 0.04 that is strongly reminiscent of Andrade creep in hard solids. For applied shear stresses lower than some typical value σ _c ? 0.2σ _y, the microgel experiences a more complex, anomalous creep behavior, characterized by an initial decrease of the strain, that we attribute to the existence of residual stresses of the order of σ _c that persist after a rest time under a zero shear rate following preshear. The influence of gel concentration on creep and residual stresses are investigated as well as possible aging effects. We discuss our results in light of previous works on colloidal glasses and other soft glassy systems.     

Newtonian,power law,and infinite shear flow characteristics of concentrated slurries using percolation theory concepts

There is a strong interest today in concentrated particulate-filled dispersion and slurries in both polymeric and Newtonian fluids. This paper reviews and extends theoretical approaches using percolation theory concepts to characterize the rheological behavior of fluids filled with particulate solids. First, a previously proposed limiting, zero shear viscosity model based on percolation theory concepts is reviewed. This model has been primarily tested with rigid fillers in a Newtonian carrier and polymeric fluids. Second, all Newtonian fluid-based slurries that have a high concentration of filler become pseudoplastic, shear-thinning slurries at some threshold shear rate. A new theory is reviewed and new data are evaluated that correlate the power law constant, n, to cluster formation of the fillers suspended in the fluids in shear flow. Slurry systems reported here cover a size range from 58 nm to 200 μm. Third, this cluster percolation-based rheological analysis is then extended to a newly proposed model for the calculation of the ratio of infinite shear, η_∞, to the zero shear viscosity, η₀. Using literature data, it is demonstrated that measurements of the viscosity ratio, η_∞/η₀, correlate with the power law through the use of an energy dissipation-based model for Bingham rheological fluids.     

Filling the gap between transient and steady shear rheology of aqueous graphene oxide dispersions

Even though the rheological behavior of aqueous graphene oxide (G-O) dispersions has been shown to be strongly time-dependent, only few transient measurements have been reported in the literature. In this work, we attempt to fill the gap between transient and steady shear rheological characterizations of aqueous G-O dispersions in the concentration range of 0.004 < ? <?3.5 wt%, by conducting comprehensive rheological measurements, including oscillatory shear flow, transient shear flow, and steady shear flow. Steady shear measurements have been performed after the evaluation of transient properties of the G-O dispersions, to assure steady-state conditions. We identify the critical concentration ? _c =?0.08 wt% (where G-O sheets start to interact) from oscillatory shear experiments. We find that the rheology of G-O dispersions strongly depends on the G-O concentration ?. Transient measurements of shear viscosity and first normal stress difference suggest that G-O dispersions behave like nematic polymeric liquid crystals at ?/? _c =?25, in agreement with other work reported in the literature. G-O dispersions also display a transition from negative to positive values of the first normal stress difference with increasing shear rates. Experimental findings of aqueous graphene oxide dispersions are compared and discussed with models and experiments reported for nematic polymeric liquid crystals, laponite, and organoclay dispersions.     

Spray-Flame Dynamics in a Rich Droplet Array

We numerically study spray-flame dynamics. The initial state of the spray is schematized by alkane droplets located at the nodes of a face-centered 2D-lattice. The droplets are surrounded by a gaseous mixture of alkane and air. The lattice spacing s reduced by the combustion length scale is large enough to consider that the chemical reaction occurs in a heterogeneous medium. The overall spray equivalence ratio is denoted by ?_T, with ?_T = ?_L + ?_G, where ?_G corresponds to the equivalence ratio of the gaseous surrounding mixture at the initial saturated partial pressure, while ?_L is the so-called liquid loading. To model such a heterogenous combustion, the retained chemical scheme is a global irreversible one-step reaction governed by an Arrhenius law, with a modified heat of reaction depending on the local equivalence ratio. ?_T is chosen in the range 0.9 ≤ ?_T ≤ 2. Three geometries (s = 3, s = 6, s = 12) and four liquid loadings, ?_L = 0.3, ?_L = 0.5, ?_L = 0.7, ?_L = 0.85 are studied. In the rich sprays, our model qualitatively retrieves the recent experimental measurements: the rich spray-flames can propagate faster than the single-phase flames with the same overall equivalence ratio. To analyse the conditions for this enhancement, we introduce the concept of “spray Peclet number”, which compares the droplet vaporization time with the combustion propagation time of the single-phase flame spreading in the fresh surrounding mixture.     

Effects of the Reynolds number on a scale-similarity model of Lagrangian velocity correlations in isotropic turbulent flows

A scale-similarity model of a two-point two-time Lagrangian velocity correlation(LVC) was originally developed for the relative dispersion of tracer particles in isotropic turbulent flows(HE, G. W., JIN, G. D., and ZHAO, X. Scale-similarity model for Lagrangian velocity correlations in isotropic and stationary turbulence. Physical Review E, 80, 066313(2009)). The model can be expressed as a two-point Eulerian space correlation and the dispersion velocity V. The dispersion velocity denotes the rate at which one moving particle departs from another fixed particle. This paper numerically validates the robustness of the scale-similarity model at high Taylor micro-scale Reynolds numbers up to 373, which are much higher than the original values(R_λ = 66, 102). The effect of the Reynolds number on the dispersion velocity in the scale-similarity model is carefully investigated. The results show that the scale-similarity model is more accurate at higher Reynolds numbers because the two-point Lagrangian velocity correlations with different initial spatial separations collapse into a universal form compared with a combination of the initial separation and the temporal separation via the dispersion velocity.Moreover, the dispersion velocity V normalized by the Kolmogorov velocity V_η≡η/τ_η in which η and τ_η are the Kolmogorov space and time scales, respectively, scales with the Reynolds number R_λ as V/V_η∝ R_λ~(1.39) obtained from the numerical data.     

Mechanical Properties of Hard W-C Coating on Steel Substrate Deduced from Nanoindentation and Finite Element Modeling

Mechanical properties of a hard and stiff W-C coating on steel substrate have been investigated using nanoindentation combined with finite element modeling (FEM) and extended FEM (XFEM). The significant pile-up observed around the indents in steel substrate caused an overestimation of hardness and indentation modulus. A simple geometrical model, considering the additional contact surfaces due to pile-up, has been proposed to reduce this overestimation. The presence of W-C coating suppressed the pile-up in the steel substrate and a transition to sink-in behavior occurred. The FEM simulations adequately reproduced the surface topography of the indents in the substrate and coating/substrate systems as well. The maximum principal stresses of the indented W-C/steel coated system were tensile; they were always located in the coating and evolved in 3 stages. Cohesive cracking occurred during loading in the sink-in zone (stage III) when the ultimate tensile strength (σ _max ) of the coating was reached. The obtained hardness (H _c ), indentation modulus (E _c ), yield stress (Y) and strength (σ _max ) of the W-C coating were H _c ? =?20 GPa, E _c ? =?250 GPa, Y?=?9.0 GPa and σ _max ? =?9.35 GPa, respectively. XFEM resulted in fracture energy of the W-C coating of G?=?38.1 J?·?m^-2 and fracture toughness of K _IC ? =?3.5 MPa?·?m^0.5.     

From linear viscoelasticity to the architecture of highly branched polyethylene

In this work, the linear viscoelastic behavior of some low-density polyethylene in the melt is used to obtain their architecture. In this way, the number of branches per molecule and long chain branching (LCB) content is determined. For this purpose, a method based on the molecular dynamics of simple star-shaped molecules is presented. It allows one to infer the topology of an average molecule through a set of 2N _c parameters {C ⁿ _i , the number concentration of a level i} and {M _bi , the mass of a segment of level i} representing an irregular Cayley tree with N _c levels. The inverse problem uses the complex shear modulus as a function of the frequency data along with a minimization algorithm. Results from the present method are compared with NMR and SEC measurements of the level of branching. It appears that SEC and rheology leads to similar results on the determination of LCB while NMR overestimate the number of branch points per molecule. Moreover, rheology allows one to go further than the basic evaluation of LCB content and shows a picture of the structure of the molecules that is in agreement with the kinetics of free radical polymerization of polyethylene.     

Quantitative Scanning Probe Microscopy for Nanomechanical Forensics

Atomic force microscopy (AFM) was used to assess the indentation modulus M _s and pull-off force F _po in four case studies of distinct evidence types, namely hair, questioned documents, fingerprints, and explosive particle-surface interactions. In the hair study, M _s decreased and F _po increased after adding conditioner and bleach to the hair. For the questioned documents, M _s and F _po of two inks were markedly different; ballpoint pen ink exhibited smaller variations relative to the mean value than printer ink. The fingerprint case study revealed that both maximum height and F _po decreased over a three-day period. Finally, the study on explosive particle-surface interactions illustrated that two fabrics exhibited similar M _s, but different F _po. Overall, it was found that AFM addresses needs in forensic science as defined by several federal agencies, in particular an improved ability to expand the information extracted from evidence and to quantify its evidentiary value.     

Torsional rigidity of a bar with multiple fibers

The classical problem of torsion is newly considered with the complex fast multipole method used to determine the torsional rigidity of a bar with multiple fibers. New analytical formulas are given for the rigidity in the case of circular contours of the fibers and the bar. It is shown that the method ensures the results which, up to three significant digits, agree well with the solutions obtained by series expansions. For a fixed concentration of a great many (up to 540) thin fibers whose shear modulus is significantly (30 times) greater than the shear modulus of the matrix, the torsional rigidity weakly depends on the diameter and the distance between the fibers. The torsional rigidity G becomes 2.5 times larger as the fiber concentration c increases from 0 to 0.16 for a very small concentration interval (0 ≤ c ≤ 0.03), where the dependence G(c) is linear. The inverse quantity 1/G (torsional compliance) varies linearly in a much wider range of concentrations (0 ≤ c ≤ 0.16).     

Turbulent Drag Reduction by a Near Wall Surface Tension Active Interface

In this work we study the turbulence modulation in a viscosity-stratified two-phase flow using Direct Numerical Simulation (DNS) of turbulence and the Phase Field Method (PFM) to simulate the interfacial phenomena. Specifically we consider the case of two immiscible fluid layers driven in a closed rectangular channel by an imposed mean pressure gradient. The present problem, which may mimic the behaviour of an oil flowing under a thin layer of different oil, thickness ratio h₂/h₁ =?9, is described by three main flow parameters: the shear Reynolds number Re _τ (which quantifies the importance of inertia compared to viscous effects), the Weber number We (which quantifies surface tension effects) and the viscosity ratio λ = ν₁/ν₂ between the two fluids. For this first study, the density ratio of the two fluid layers is the same (ρ₂ = ρ₁), we keep Re _τ and We constant, but we consider three different values for the viscosity ratio: λ =?1, λ =?0.875 and λ =?0.75. Compared to a single phase flow at the same shear Reynolds number (Re _τ =?100), in the two phase flow case we observe a decrease of the wall-shear stress and a strong turbulence modulation in particular in the proximity of the interface. Interestingly, we observe that the modulation of turbulence by the liquid-liquid interface extends up to the top wall (i.e. the closest to the interface) and produces local shear stress inversions and flow recirculation regions. The observed results depend primarily on the interface deformability and on the viscosity ratio between the two fluids (λ).     

Operator method for solving the plane elasticity problem for a strip with periodic cuts

In the present paper, we use the conformal mapping z/c = ζ?2a sin ζ (a, c?const, ζ = u + iv) of the strip {|v| ≤ v ₀, |u| < ∞} onto the domain D, which is a strip with symmetric periodic cuts. For the domain D, in the orthogonal system of isometric coordinates u, v, we solve the plane elasticity problem. We seek the biharmonic function in the form F = C ψ ₀ + S ψ*₀ + x(C ψ ₁ ? S ψ ₂) + y(C ψ ₂ + S ψ ₁), where C(v) and S(v) are the operator functions described in [1] and ψ ₀(u), …, ψ ₂(u) are the desired functions. The boundary conditions for the function F posed for v = ±v ₀ are equivalent to two operator equations for ψ ₁(u) and ψ ₂(u) and to two ordinary differential equations of first order for ψ ₀(u) and ψ*₀(u) [2]. By finding the functions ψ _j (u) in the form of trigonometric series with indeterminate coefficients and by solving the operator equations, we obtain infinite systems of linear equations for the unknown coefficients. We present an efficient method for solving these systems, which is based on studying stable recursive relations. In the present paper, we give an example of analysis of a specific strip (a = 1/4, v ₀ = 1) loaded on the boundary v = v ₀ by a normal load of intensity p. We find the particular solutions corresponding to the extension of the strip by the longitudinal force X ^∞ and to the transverse and pure bending of the strip due to the transverse force Y ^∞ and the constant moment M ^∞, respectively. We also present the graphs of normal and tangential stresses in the transverse cross-section x = 0 and study the stress concentration effect near the cut bottom.     

Self-similar solutions in the problem of generalized vortex diffusion

The analysis of the group properties and the search for self-similar solutions in problems of mathematical physics and continuum mechanics have always been of interest, both theoretical and applied [1–3]. Self-similar solutions of parabolic problems that depend only on a variable of the type η = x/√t are classical fundamental solutions of the one-dimensional linear and nonlinear heat conduction equations describing numerous physical phenomena with initial discontinuities on the boundary [4]. In this study, the term “generalized vortex diffusion” is introduced in order to unify the different processes in mechanics modeled by these problems. Here, vortex layer diffusion and vortex filament diffusion in a Newtonian fluid [5] can serve as classical hydrodynamic examples. The cases of self-similarity with respect to the variable η are classified for fairly general kinematics of the processes, physical nonlinearities of the medium, and types of boundary conditions at the discontinuity points. The general initial and boundary value problem thus formulated is analyzed in detail for Newtonian and non-Newtonian power-law fluids and a medium similar in behavior to a rigid-ideally plastic body. New self-similar solutions for the shear stress are derived.     

Numerical Study of Turbulent Channel Flow over Surfaces with Variable Spanwise Heterogeneities: Topographically-driven Secondary Flows Affect Outer-layer Similarity of Turbulent Length Scales

Wall-bounded turbulent flows over surfaces with spanwise heterogeneous surface roughness – that is, spanwise-adjacent patches of relatively high and low roughness – exhibit mean flow phenomena entirely different to what would otherwise exist in the absence of spanwise heterogeneity. In the outer layer, mean counter-rotating rolls occupy the depth of the flow, and are positioned such that “upwelling” and “downwelling” occurs above the low and high roughness, respectively. It has been comprehensively shown that these secondary flows are Prandtl’s secondary flow of the second kind (Anderson et al., J. Fluid Mech. 768, 316–347 2015). This behaviour indicates that spanwise spacing, s _y , between adjacent patches of high and low roughness is, itself, a problem parameter; in this study, we have systematically assessed how s _y affects turbulence structure in high Reynolds number channel flows via two-point correlations. “High roughness” is imposed with streamwise-aligned pyramid elements with height, h, selected to be ≈ 5% of the channel half height, H. For \(s_{y}/H \gtrsim 1\), we find that the aforementioned domain-scale mean circulations exist and the surface may be regarded as a topography. For s _y /H ? 0.2, turbulence statistics show characteristics very similar to a homogeneous roughness and thus the surface may be regarded as a roughness. For 0.2 ? s _y /H ? 2, the spatial extent of the counter-rotating rolls is controlled by proximity to adjacent rows, and we define such surfaces as being intermediate. We refer to such surfaces as intermediate state.     

Mixing and Bimolecular Reaction Kinetics in a Plane Poisseulle Flow

Mixing and a nonlinear bimolecular chemical reaction (reactant A + reactant B → product; reaction rate r?=?κc ₁ c ₂) in laminar shear flow are investigated. It is found that asymptotically the dominant balance between the rates of production and dissipation of the mean-squared concentration fluctuations \((\sigma_{c_1 }^2 ,\sigma_{c_2 }^2)\) and cross-covariance of concentration fluctuations \((\overline {c_1 c_2 })\) occurs under nonreactive and reactive conditions. Longitudinal dispersion of the cross-sectional averages (C ₁, C ₂), and variances and the cross-covariance of reactant concentrations can be asymptotically quantified by the classic Taylor dispersion coefficient (D) even under reactive conditions. The characteristic time-scale (τ) over which molecular diffusion dissipates concentration variance and the cross-covariance of reactant concentrations is also shown to be the same under nonreactive and reactive conditions. A variational estimate of τ is shown to be close to the values inferred from detailed numerical simulation. The production-dissipation balance implies that the cross-sectional averaged reaction rate follows \(\overline r =\kappa_{eff} C_1 C_2 \) and \(\kappa _{eff} \approx \kappa \left[ {1+2D\tau \left( {{\partial \ln C_1 } \mathord{\left/ {\vphantom {{\partial \ln C_1 } {\partial x}}} \right. \kern-\nulldelimiterspace} {\partial x}} \right)\left( {{\partial \ln C_2 } \mathord{\left/ {\vphantom {{\partial \ln C_2 } {\partial x}}} \right. \kern-\nulldelimiterspace} {\partial x}} \right)} \right]\). The effective reaction rate parameter (κ _eff ) is higher than that of well-mixed batch test reaction rate constant (κ) for initially overlapping species and κ _eff is smaller than κ for initially non-overlapping species.     

Suspensions of titania nanoparticle networks in nematic liquid crystals: rheology and microstructure

We study the influence of confinement on the rheology and structure of nematic liquid crystals (NLCs). NLCs get confined in networks of titania (TiO₂, primary particle size = 21 nm) nanoparticles in suspensions of TiO₂ and NLC, N-(4-methoxybenzylidene)-4-butylaniline (MBBA). Suspensions with TiO₂ nanoparticle volume fraction (?) of 0.006–0.017, form viscoelastic solids with low elastic modulus (G′) of 10¹ Pa–10² Pa and short relaxation times. Increase in TiO₂ nanoparticle ? leads to a rise in G′ with TiO₂ nanoparticles forming a percolating network at a critical volume fraction (? _c) = 0.023, and G′ of ~10³ Pa. TiO₂/MBBA NLC suspensions at and above ? _c = 0.023 show G′ ~ ω ^x?1 scaling, where ω is the angular frequency and the minimum in loss modulus (G′′) with ω. The effective noise temperature, x decreases and approaches 1 with the increase in the TiO₂ nanoparticle ? from 0.023–0.035, is indicative of an increase in the glassy dynamics. Through the polarized light microscopy and differential scanning calorimetry experiments, we propose that the progressive addition of TiO₂ nanoparticles introduces a quenched random disorder (QRD) in the NLC medium which disturbs the nematic order. This results in metastable TiO₂/MBBA NLC suspensions in which NLC domains get confined in the network of flocs of TiO₂ nanoparticles. We also show that the salient rheological signatures of soft glassy rheology develop only in the presence of NLC MBBA and are absent in the isotropic phase of MBBA.     

Pre-Chamber Ignition Mechanism: Simulations of Transient Autoignition in a Mixing Layer Between Reactants and Partially-Burnt Products

The structure of autoignition in a mixing layer between fully-burnt or partially-burnt combustion products from a methane-air flame at ? = 0.85 and a methane-air mixture of a leaner equivalence ratio has been studied with transient diffusion flamelet calculations. This configuration is relevant to scavenged pre-chamber natural-gas engines, where the turbulent jet ejected from the pre-chamber may be quenched or may be composed of fully-burnt products. The degree of reaction in the jet fluid is described by a progress variable c (c = taking values 0.5, 0.8, and 1.0) and the mixing by a mixture fraction ξ (ξ = 1 in the jet fluid and 0 in the CH₄-air mixture to be ignited). At high scalar dissipation rates, N₀, ignition does not occur and a chemically-frozen steady-state condition emerges at long times. At scalar dissipation rates below a critical value, ignition occurs at a time that increases with N₀. The flame reaches the ξ = 0 boundary at a finite time that decreases with N₀. The results help identify overall timescales of the jet-ignition problem and suggest a methodology by which estimates of ignition times in real engines may be made.     

Direct Numerical Simulation and Theory of a Wall-Bounded Flow with Zero Skin Friction

We study turbulent plane Couette-Poiseuille (CP) flows in which the conditions (relative wall velocity ΔU _w ≡ 2U _w , pressure gradient dP/dx and viscosity ν) are adjusted to produce zero mean skin friction on one of the walls, denoted by APG for adverse pressure gradient. The other wall, FPG for favorable pressure gradient, provides the friction velocity u _τ , and h is the half-height of the channel. This leads to a one-parameter family of one-dimensional flows of varying Reynolds number Re ≡ U _w h/ν. We apply three codes, and cover three Reynolds numbers stepping by a factor of two each time. The agreement between codes is very good, and the Reynolds-number range is sizable. The theoretical questions revolve around Reynolds-number independence in both the core region (free of local viscous effects) and the two wall regions. The core region follows Townsend’s hypothesis of universal behavior for the velocity and shear stress, when they are normalized with u _τ and h; on the other hand universality is not observed for all the Reynolds stresses, any more than it is in Poiseuille flow or boundary layers. The FPG wall region obeys the classical law of the wall, again for velocity and shear stress. For the APG wall region, Stratford conjectured universal behavior when normalized with the pressure gradient, leading to a square-root law for the velocity. The literature, also covering other flows with zero skin friction, is ambiguous. Our results are very consistent with both of Stratford’s conjectures, suggesting that at least in this idealized flow turbulence theory is successful like it was for the classical logarithmic law of the wall. We appear to know the constants of the law within a 10% bracket. On the other hand, that again does not extend to Reynolds stresses other than the shear stress, but these stresses are passive in the momentum equation.     

Assessment of Five SGS Models for Low-Rem MHD Turbulence

Assessment of three regularization-based and two eddy-viscosity-based subgrid-scale (SGS) turbulence models for large eddy simulations (LES) are carried out in the context of magnetohydrodynamic (MHD) decaying homogeneous turbulence (DHT) with a Taylor scale Reynolds number (Re_λ) of 120 and a MHD transition-to-turbulence Taylor-Green vortex (TGV) problems with a Reynolds number of 3000, through direct comparisons to direct numerical simulations (DNS). Simulations are conducted using the low-magnetic Reynolds number approximation (Re_m<<1). LES predictions using the regularization-based Leray- α,LANS- α, and Clark- α SGS models, along with the eddy viscosity-based non-dynamic Smagorinsky and the dynamic Smagorinsky models are compared to in-house DNS for DHT and previous results for TGV. With regard to the regularization models, this work represents their first application to MHD turbulence. Analyses of turbulent kinetic energy decay rates, energy spectra, and vorticity fields made between the varying magnetic field cases demonstrated that the regularization models performed poorly compared to the eddy-viscosity models for all MHD cases, but the comparisons improved with increase in magnitude of magnetic field, due to a decrease in the population of SGS eddies within the flow field.     

Effect of the mode of gas-surface interaction on intensive monatomic gas evaporation

The direct Monte Carlo simulation method is used for investigating the effect of the thermal accommodation coefficient α _E on the relations on the Knudsen layer boundary in the presence of intensive evaporation. The model of mirror reflection of molecules from the surface is considered. It is shown that diffuse reflection with α _E = 0 leads to almost the same relations on the Knudsen layer boundary as mirror reflection. The accuracy of the moment method is estimated in application to the problems of intensive evaporation with diffuse and mirror reflection from the surface.     

Two-component modeling for non-Newtonian nanofluid slip flow and heat transfer over sheet: Lie group approach

The present paper deals with the multiple solutions and their stability analysis of non-Newtonian micropolar nanofluid slip flow past a shrinking sheet in the presence of a passively controlled nanoparticle boundary condition. The Lie group transformation is used to find the similarity transformations which transform the governing transport equations to a system of coupled ordinary differential equations with boundary conditions. These coupled set of ordinary differential equation is then solved using the RungeKutta-Fehlberg fourth-fifth order(RKF45) method and the ode15 s solver in MATLAB.For stability analysis, the eigenvalue problem is solved to check the physically realizable solution. The upper branch is found to be stable, whereas the lower branch is unstable. The critical values(turning points) for suction(0 sc s) and the shrinking parameter(χc χ 0) are also shown graphically for both no-slip and multiple-slip conditions. Multiple regression analysis for the stable solution is carried out to investigate the impact of various pertinent parameters on heat transfer rates. The Nusselt number is found to be a decreasing function of the thermophoresis and Brownian motion parameters.