Dynamic crushing of sandwich panels with prismatic lattice cores

The dynamic out-of-plane compressive response of stainless steel corrugated and Y-frame sandwich cores have been investigated for impact velocities ranging from quasi-static to 200 ms⁻¹. Laboratory-scale sandwich cores of relative density 2.5% were manufactured and the stresses on the front and rear faces of the dynamically compressed sandwich cores were measured using a direct impact Kolsky bar. Direct observational evidence is provided for micro-inertial stabilisation of both topologies against elastic buckling at impact velocities below 30 ms⁻¹. At higher impact velocities, plastic waves within the core members result in the front face stresses increasing with increasing velocity while the rear face stresses remain approximately constant. While the finite element calculations predict the rear face stresses and dynamic deformation modes to reasonable accuracy, the relatively slow response time of the measurement apparatus results in poor agreement between the measured and predicted front face stresses. The finite element calculations also demonstrate that material strain-rate effects have a negligible effect upon the dynamic compressive response of laboratory-scale and full-scale sandwich cores.     

Preparation of nano-sized Al2O3–2SiO2 powder by sol–gel plus azeotropic distillation method

Nano-sized amorphous Al₂O₃–2SiO₂ powder was prepared by a sol–gel method coupled with azeotropic distillation. The structure of the powder was investigated by DTS, BET, TEM, FT-IR, TG-DTA and XRD, showing that n-butanol azeotropic distillation could effectively remove water from the aluminosilicate gels and prevent the formation of hard agglomerates in the drying process. The average particle diameter of the powder was about 70 nm. The largest BET specific surface area of the powder was 669 m²/g. To examine the alkali-activation reactivity of the powder, alkali-activation tests were performed with the powder reacting with sodium silicate solution. The synthetic powder was found to be highly reactive.     

Hydrothermal synthesis of Mn-Zn ferrites from spent alkaline Zn-Mn batteries

Nanocrystalline Mn-Zn ferrites （Mno.GZno.4Fe204） with particle size of 12 nm were synthesized hydrotherreally using spent alkaline Zn-Mn batteries, and accompanied by a study of the influencing factors. The nanocrystals were examined by powder X-ray diffraction （XRD） for crystalline phase identification, and scanning electron microscopy （SEM） for grain morphology. The relationship between concentration of Fe（II）, Mn（II）, and Zn（II） and pH value was obtained through thermodynamic analysis of the Fe（II）-Mn（II）-Zn（II）-NaOH-H2O system. The results showed that all ions were precipitated completely at a pH value of 10-11. The optimal preparation conditions are： co-precipitation pH of 10.5, temperature of 200 ℃ and time of 9 h.     

Fabrication of nano-sized Ca(OH)2 with excellent adsorption ability for N2O4

Uniform nano-sized calcium hydroxide (Ca(OH)₂) monocrystal powder was synthesized from calcium oxide in a surfactant solution via a digestion method by decreasing the surface tension of the reaction system to control the growth of crystalline Ca(OH)₂. The Ca(OH)₂ monocrystal powder samples were characterized by means of scanning electron microscopy (SEM), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), and Fourier transform-infrared spectroscopy (FT-IR). The NO_x adsorption ability of the samples was evaluated, and the influence of various types and concentrations of surfactants on powder agglomeration and then the specific surface area in the precipitation process were studied. The specific surface area of the samples was found as high as 58 m²/g and 92 m²/g and the particle size, 300–400 nm and 200–300 nm in the presence of 10 wt% PEG600 and 0.086 mL/L SDS at a reaction time of 5 h, respectively. The product has an exceptionally strong adsorption ability for NO_x, which makes it a highly promising adsorbent for emission control and air purification.     

Interaction between Weibull parameters and mechanical strength reliability of industrial-scale water gas shift catalysts

A fundamental step in the production of an industrial catalyst is its crushing strength assessment. Limited literature exists in which the strength reliability of supported catalysts is investigated from production to their application in a reactor. In this work, cylindrical supports were prepared by pelletizing high porosity γ-alumina powder, and Cu–Zn/γ-Al₂O₃ catalysts were prepared by impregnation of the pelletized γ-alumina supports with an aqueous solution of copper and zinc nitrates. The support-forming variables, such as binder concentration, compaction pressure, calcination temperature, and drying procedure were investigated. The Weibull method was used to analyze the crushing strength data of the supports, and the fresh and used catalysts before and after the low-temperature water gas shift reaction. Support formation at a 50 wt% binder concentration, 1148 MPa compaction pressure, 500 °C calcination temperature, and rapid drying (100 °C, 8 h) led to the maximum support mechanical reliability. The most reliable catalyst with respect to simultaneous appropriate catalytic performance and mechanical strength was prepared from a support with the lowest mean crushing strength (26.25 MPa). This work illustrates the importance of the Weibull modulus as a useful mechanical reliability index in manufacturing a supported solid catalyst.     

Dry modification of electrode materials by roller vibration milling at room temperature

For the first time dry roller vibration milling at room temperature was used to prepare active carbon （AC） nano-particles and to modify MnO2 powder as electrode materials. In 30 min AC was milled to a mean particle size of 30-50 nm with increased crystallinity and higher specific surface area, predominantly mesoporous and with improved pore diameter distribution. Then, AC nano-particles were incorporated with MnO2 or bismuth-doped MnO2 nano-particles synthesized by sol-gel methods to prepare nano-composite electrode materials for studying their electrochemical performance. The AC nano-particles combined with 10 wt.% bismuth-doped MnO2 nano-particles were found to possess excellent electrochemical property with specific capacitance up to 308 F/g and without obvious attenuation with increasing current. Our method seems to ooen a new way to imorove AC based electrode materials used for clean energy such as suner capacitors.     

Soil compaction and tires for harvesting and transporting sugarcane

Four tire types (A, block-shape tread; B, rib-shape tread; C, low-lug tread; D, high-lug tread) used to harvest and transport sugarcane were compared regarding the compaction induced to the soil. Tires were tested at three inflation pressures (207, 276, 345 kPa) and six loads ranging from 20 to 60 kN/tire. Track impressions were traced, and 576 areas were measured to find equations relating inflation pressure, load, contact surface and pressure. Contact surface increased with increasing load and decreasing inflation pressure; however, the contact pressure presented no defined pattern of variation, with tire types A and B generating lower contact pressure. The vertical stresses under the tires were measured and simulated with sensors and software developed at the Colombian Sugarcane Research Center (Cenicaña). Sensors were placed at 10, 30, 50 and 70 cm depth. Tire types A and B registered vertical stresses below 250 kPa at the surface. These two tires were better options to reduce soil compaction. The equations characterizing the tires were introduced into a program to simulate the vertical stress. Simulated and measured stresses were adjusted in an 87–92% range. Results indicate a good correlation between the tire equations, the vertical stress simulation and the vertical stress measurement.     

Optimized synthesis and photovoltaic performance of TiO2 nanoparticles for dye-sensitized solar cell

This paper presents response surface methodology （RSM） as an efficient approach for modeling and optimizing TiO2 nanoparticles preparation via co-precipitation for dye-sensitized solar cell （DSSC） perfor- mance. Titanium （IV） bis-（acetylacetonate） di-isopropoxide （DIPBAT）, isopropanol and water were used as precursor, solvent and co-solvent, respectively. Molar ratio of water, aging temperature and calcina- tion temperature as preparation factors with main and interaction effects on particle characteristics and performances were investigated, Particle characteristics in terms of primary and secondary sizes, crys- tal orientation and morphology were determined by X-ray diffractometry （XRD） and scanning electron microscopy （SEM）. Band gap energy and power conversion efficiency of DSSCs were used for perfor- mance studies. According to analysis of variance （ANOVA） in response surface methodology （RSM）, all three independent parameters were statistically significant and the final model was accurate. The model predicted maximum power conversion efficiency （0.14%） under the optimal condition of molar ratio of DIPBAT-to-isopropanol-to-water of 1 ： 10：500, aging temperature of 36 C and calcination temperature of 400 ℃. A second set of data was adopted to validate the model at optimal conditions and was found to be 0.14 ± 0.015%, which was very close to the predicted value. This study proves the reliability of the model in identi（ving the optimal condition for maximum performance.     

Numerical simulation of a supersonic gas–solid flow over a blunt body: The role of inter-particle collisions and two-way coupling effects

A supersonic dusty gas flow over a blunt body is considered. The mathematical model of the two-phase gas–particle flow takes into account the inter-particle collisions and the two-way coupling effects. The carrier gas is treated as a continuum, the averaged flow field of which is described by the complete Navier–Stokes equations with additional source terms modeling the reverse action of the dispersed phase. The dispersed phase is treated as a discrete set of solid particles, and its behavior is described by a kinetic Boltzmann-type equation. Particles impinging on the body surface are assumed to bounce from it. Numerical analysis is carried out for the cross-wise flow over a cylinder. The method of computational simulation represents a combination of a CFD-method for the carrier gas and a Monte Carlo method for the “gas” of particles. The dependence of the fine flow structure of the continuous and dispersed phases upon the free stream particle volume fraction α_p∞ and the particle radius r_p is investigated, particularly in the shock layer and in the boundary layer at the body surface. The particle volume fraction α_p∞ is varied from a negligibly low value to the value α_p∞ = 3 × 10⁵ at which inter-particle collisions and two-way coupling effects are simultaneously essential. Particular attention has been given to the particles of radii close to the critical value r_p1, because in this range of particle size the behavior of the particles and their effect on the carrier gas flow are not yet completely understood. An estimate of the turbulent kinetic energy produced by the particles in the shock layer is obtained.     

Stress and fatigue life analyses of a five-piece rim and the proposed optimization with a two-piece rim

A five-piece rim and a two-piece bolt-connected rim were investigated to examine stress levels and fatigue lives on critical regions. The finite element models of the rim/tire assemblies were developed and validated through tire engineering data and previously validated modelling approaches. The rim/tire assemblies were simulated under two conditions, (1) application of a 23,100 kg static load followed by a 24.14 km/h travelling speed and an 82° wheel angle, and (2) application of a 26,900 kg static load followed by an 8.05 km/h travelling speed and an 82° wheel angle. The results revealed that travelling and steering speeds were the key factors in causing high stresses and bolt tension forces. Compared to the five-piece rim, the two-piece rim decreased the maximum stresses by over 30% for both loading conditions; consequently the fatigue lives were increased by over two orders of magnitude. The maximum bolt forces for the two-piece rim were estimated to be 195,680 N and 111,360 N separately.     

Modification of ADP extinguishing powder by siliconization in spray drying

Superfine spherical fire-extinguishing powder, ammonium dihydrogen phosphate (ADP, NH₄H₂PO₄), was prepared by spray drying and modified in situ with methyl hydrogen silicone oil (MHSO) emulsion and the fluorinated surfactant FK-510. The influences of the MHSO mass ratio on the hydrophobicity, surface composition, surface morphology, dispersion and particle-size distribution of the NH₄H₂PO₄ were studied, and the influence of the drying air temperature on the decomposition of the NH₄H₂PO₄ was also researched. The results indicate that the MHSO and FK-510 congregate on the particle surfaces and then form a hydrophobic shell. This shell improves the particle hydrophobicity and leads to a fine dispersion of the particles. During the process of preparing the precursor solution, 3 wt% (based on the weight of NH₄H₂PO₄) was chosen as the optimum value of the MHSO mass ratio. During the spray drying, a low absolute humidity of the air should be maintained, and it is very important to keep the exit-air temperature below 100 °C to avoid decomposition.     

Microstructure and mechanical properties of ZrO2 (Y2O3)–Al2O3 nanocomposites prepared by spark plasma sintering

Zirconia (yttria)–alumina ceramic nanocomposites were fabricated from different powders by spark plasma sintering (SPS). One powder was a commercially available nanocomposite powder TZP-3Y20A, consisting of 3 mol% yttria-stabilized zirconia (3-YSZ) reinforced with 20 wt% alumina, and the other, used as a comparison, was a conventional mechanically mixed powder 3YSZ-20A, a blend made of 3 mol% yttria-stabilized zirconia powder ZrO₂ (3Y) and 20 wt% α-alumina powder. The effect of the sintering temperature on the densification, the sintering behavior, the mechanical properties and the microstructure of the composites was investigated. The results showed that the density increased with increasing sintering temperature, and thus, the mechanical properties were strengthened because of the increased densification. The nanocomposite powder TZP-3Y20A was easily sintered, and good mechanical properties were achieved as compared with the powder from the conventional mechanically mixed method, the maximum flexural strength and fracture toughness of which were 967 MPa and 5.27 MPa m^1/2, respectively.     

Synthesis and phase evolution of LiNb0.6Ti0.5O3 powder via a sol–gel method

A simple sol–gel route was demonstrated for the synthesis of LiNb_0.6Ti_0.5O₃ (M-phase) powder, using cheap and manageable starting materials at a relatively low temperature. The phase transitions in both chemical and solid-state processes were studied by X-ray diffraction (XRD) in detail. The results showed that in the sol–gel process the anatase TiO₂ phase first appeared at 400 °C and then LiNbO₃ solid solution (LiNbO₃ ss) emerged at 500 °C. When calcined to 600 °C, the M-phase started to appear along with the decrease of TiO₂ and LiNbO₃ ss. Single M-phase could be formed at 700 °C, which is 300 °C lower than that by the traditional solid-state method. A plausible evolution mechanism of the as-synthesized powder in calcination was proposed. The produced powder has potential applications in microelectronics systems.     

Technique for quantitative mapping of three-dimensional liquid–gas phase boundaries in microchannel flows

A diagnostic technique capable of characterizing interfaces between transparent, immiscible fluids is developed and demonstrated by investigating the morphology of liquid–gas interfaces in an adiabatic two-phase flow through a microchannel of 500 μm × 500 μm square cross section. Water seeded with 0.5 μm-diameter fluorescent polystyrene particles is pumped through the channel, and the desired adiabatic two-phase flow regime is achieved through controlled air injection. The diagnostic technique relies on obtaining particle position data through epifluorescent imaging of the flow at excitation and emission wavelengths of 532 nm and 620 nm, respectively. The particle position data are then used to resolve interface locations to within ±1 μm in the focal plane. By mapping the interface within individual focal planes at various depths within the channel, it is possible to determine the complete liquid–gas interface geometry across the channel cross section in a dynamic flow environment. Utilizing this approach, the liquid–gas phase boundaries of annular flows within a microchannel have been successfully characterized.     

Experimental investigation on flow asymmetry in solid entrance region of a square circulating fluidized bed

To study the influence of back feeding particles on gas-solid flow in the riser, this paper investigated the flow asymmetry in the solid entrance region of a fluidized bed by particle concentration/velocity measurements in a cold square circulating fluidized beds （CFB）. The pressure drop distribution along the riser and the saturation carrying capacity of gas for Geldart-B type particles were first analyzed. Under the condition of u0 = 4 m/s and Gs = 21 kg/（m^2 s）, the back feeding particles were found to penetrate the lean gas-solid flow near the entrance （rear） wall before reaching the opposite （front） wall, thus leading to a relatively denser region near the front wall in the bottom bed. Higher solid circulation rate （u0 =4 m/s, Gs = 33 kg/（m^2 s）） resulted in a higher particle concentration in the riser. However the back feeding particles with higher momentum increased the asymmetry of the particle concentration/velocity profile in the solid entrance region. Lower air velocity （u0 =3.2 m/s） and Gs =21 kg/（m2 s）, beyond the saturation carrying capacity of gas, induced an S-shaped axial solid distribution with a denser bottom zone. This limited the penetration of the back feeding particles and forced the flnidizing air to flow in the central region, thus leading to a higher solid holdup near the rear wall. Under the conditions of uo = 4 m/s and Gs = 21 kg/（m^2 s）, addition of coarse particles （dp= 1145 μm） into the bed made the radial distribution of solids more symmetrical.     

Size and shape effects on magnetic properties of Ni nanoparticles

Pure Ni nanoparticles ranging in size from 24 to 200 nm are prepared via thermal decomposition of nickel acetylacetonate in oleylamine. The as-prepared Ni particles change from spherical to dendritic or starlike with increasing precursor concentration. The particles are stable because the organic coating occurs in situ. Magnetic measurement reveals that all the Ni nanoparticles are ferromagnetic and show ferromagnetic–paramagnetic transitions at their Curie points. The saturation magnetization M_s is size-dependent, with a maximum value of 52.01 and 82.31 emu/g at room temperature and 5 K, respectively. The coercivity decreases at first and then increases with increasing particle size, which is attributed to the competition between size effect and shape anisotropy. The Curie temperature T_c is 593, 612, 622, 626 and 627 K for the 24, 50, 96, 165 and 200 nm Ni nanoparticles, respectively. A theoretical model is proposed to explain the size-dependence of Ni nanoparticle Curie temperature.     

Preparation and gas sensing performances of palladium surface-modified flower-like SnO2 nanopowders

Flower-like SnO2 nanopowders prepared by a hydrothermal method were surface modified with palla- dium via impregnation. The crystal structure, morphology, and surface chemistry states of the samples were characterized by means of X-ray diffraction （XRD）, scanning electron microscopy （SEM）, and X-ray photoelectron spectroscopy （XPS）, respectively. The gas sensing performances were also investigated. For a hydrothermal temperature of 220 ℃, flower-like SnO2 nanoparticles consist of nanorods with diameters of 40 nm and lengths of 100 nm. The XPS and XRD results reveal that palladium exists in the Pd0 chemical state but the crystal is too small to be detected. The 0.3 wt% Pd modified SnO2 sensor shows better sensi- tivity, up to 21, for 70 μL/L ethanol gas at an optimal working temperature of 250 ℃. The quick response time （3 s） and fast recovery time （-20 s） are the main characteristics of this sensor.     

Dual-element directional shock wave attenuators

This study explores the interaction between shock waves and dual-element porous plates used to ameliorate the hazardous effects of these waves. Tests were performed in a shock tube to determine the effects that a pair of porous plates with directional resistance properties had on the initial peak pressure and impulse amelioration experienced by an end wall. Mild steel test specimens, ranging in porosity values from 6.6% to 41.1%, were mounted two at a time at different spacings in the test section. Each plate had directional properties, i.e. resistance to flow was different for flow coming from either side. Four plates were used, and 48 plate configurations were tested. Side wall and end wall pressure measurements and schlieren photographs were taken of the interactions. Tests were run at Mach numbers of 1.23, 1.35 and 1.42. The separation distances between the plate specimens were varied between 30 mm and 60 mm; however, the distance between the downstream plate and the end wall was kept constant at 140 mm for all tests.Both the initial peak pressure and impulse amelioration values were found to be dependant on the plate combination porosity. As the porosity of the combination increased, the amelioration values decreased. Complementary plate combinations produced differing results as different wave interactions occur when plate positions were interchanged. The porosity of the combined plates was found to have an overriding influence on the end wall peak pressure and impulse amelioration values when compared to the effect that plate arrangement (i.e. geometrical influences) had. Impulse amelioration values were found to increase as the separation distance between plates were increased. The amplitude of the end wall pressure trace was found to increase as the incident Mach number was increased. The significant attenuation of the incident shock wave obtained during this study is attributed to the system of multiple reflected and transmitted waves that are produced by the presence of the plate specimens in series. This increases the frequency of shock wave and barrier interactions, when compared to just using a single barrier.     

Direct reduction of hematite powders in a fluidized bed reactor

Ultrafine hematite powder was reduced to produce ultrafine iron powder in a 50%Ar–50%H₂ atmosphere at 450–550 °C in a fluidized bed reactor. The ultrafine hematite powder shows the typical agglomerating fluidization behavior with large agglomerates fluidized at the bottom of the bed and small agglomerates fluidized at the upper part of the bed. It was found that defluidization occurred even at the low temperature of 450 °C with low metallization rate. Defluidization was attributed mainly to the sintering of the newly formed iron particles. Granuation was employed to improve the fluidization quality and to tackle the defluidization problem, where granules fluidized like a Geldart's group A powder. Granulation was found to effectively reduce defluidization during reduction, without however sacrificing reduction speed. The as-reduced iron powders from both the ultrafine and the granulated hematite exhibited excellent sintering activity, that is, fast sintering at temperature of as low as ～580 °C, which is much superior as compared to that of nano/ultrafine iron powders made by other processes.     

Microwave-assisted polyol synthesis of LiMnPO4/C and its use as a cathode material in lithium-ion batteries

We synthesized LiMnPO₄/C with an ordered olivine structure by using a microwave-assisted polyol process in 2:15 (v/v) water–diethylene glycol mixed solvents at 130 °C for 30 min. We also studied how three surfactants—hexadecyltrimethylammonium bromide, polyvinylpyrrolidone k30 (PVPk30), and polyvinylpyrrolidone k90 (PVPk90)—affected the structure, morphology, and performance of the prepared samples, characterizing them by using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, charge/discharge tests, and electrochemical impedance spectroscopy. All the samples prepared with or without surfactant had orthorhombic structures with the Pnmb space group. Surfactant molecules may have acted as crystal-face inhibitors to adjust the oriented growth, morphology, and particle size of LiMnPO₄. The microwave effects could accelerate the reaction and nucleation rates of LiMnPO₄ at a lower reaction temperature. The LiMnPO₄/C sample prepared with PVPk30 exhibited a flaky structure coated with a carbon layer (∼2 nm thick), and it delivered a discharge capacity of 126 mAh/g with a capacity retention ratio of ∼99.9% after 50 cycles at 1C. Even at 5C, this sample still had a high discharge capacity of 110 mAh/g, demonstrating good rate performance and cycle performance. The improved performance of LiMnPO₄ likely came from its nanoflake structure and the thin carbon layer coating its LiMnPO₄ particles. Compared with the conventional polyol method, the microwave-assisted polyol method had a much lower reaction time.