Analysis of spectral characteristics of scattering of evanescent waves

The spectral scattering characteristics of nanoscale particles exhibited in the field of evanescent waves are analyzed using the method of discrete sources. The effect of various parameters on the behavior of the scattering characteristics is studied. The material of the particles is shown to have the most substantial effect on the scattering cross section.     

金属丝的杨氏模量测定实验的改进

对金属丝杨氏模量测定仪重新设计.将金属丝水平放置,在中点处悬挂重物,通过测量金属丝伸长后的转角,进而测量金属丝的杨氏模量.     

Determination of the of rate cross slip of screw dislocations

The rate for cross slip of screw dislocations during annihilation of screw dipoles in copper is determined by molecular dynamics simulations. The temperature dependence of the rate is seen to obey an Arrhenius behavior in the investigated temperature range: 225-375 K. The activation energy and the effective attempt frequency can therefore be extracted from the simulations. The transition state energy for the annihilation process is calculated by identifying the transition state using the nudged elastic band path technique. The two activation energies agree very well, indicating that transition state theory is applicable for this type of process.     

Analysis of diffraction of a plane wave on a grating consisting of impedance bodies of revolution

The problem of wave scattering by a grating consisting of coaxial impedance bodies of revolution is solved. The efficient numerical algorithm based on the modified null field method is offered. The method is applied both to scalar and vector formulations of the problem. The numerical results are obtained for various geometries of the grating elements.     

The effect of the crystalline perfection of quartz on the rotation of the plane of polarization of light

The wavelength dependence of the specific rotation of the plane of polarization of light by quartz crystals is experimentally studied. The chirality coefficients determined from the plots δ(1/λ²) are found to be different for different crystals. The differences between these plots are associated with the perfection of the crystal structure of quartz. The rotation of the plane of polarization is more sensitive to imperfection of the medium and makes it possible to reveal this imperfection without additional irradiation of crystalline quartz by γ quanta.     

The Characterisation of the Products of Reduction of Chinkombe Ilmenite

The characterisation of iron-containing species in Chinkombe ilmenite and its reduction products was undertaken using Mössbauer Spectroscopic techniques. The ore was reduced by graphite in an inert atmosphere. The effects of such variables as quantity of reductant, temperature and preoxidation were investigated. The ore was completely reduced to alpha-iron and titanium dioxide with 20% carbon for a period of one hour at 1373 K. Chemical mechanisms are proposed for the reduction and oxidation of Chinkombe ilmenite. In the processing of ilmenite to obtain synthetic rutile, the ultimate desire is to separate the Fe phase from the TiO₂. Mössbauer Spectroscopy has unambiguously confirmed the desired transformation of the iron phase according to thermodynamic predictions. The information gained would be used to choose the conditions of the reduction process. The alpha-iron could be separated physically or chemically from the completely reduced product mass to obtain synthetic titanium dioxide suitable for the paint industry.     

Mechanisms of the oxidation of defect-free surfaces of carbon nanostructures: the influence of surface curvature

This work is concerned with reaction paths in the interaction of carbon defect-free nanostructures with different surface curvatures (graphene, tubulenes, and fullerene C₆₀) with atomic and molecular oxygen. The interaction energies of atoms were calculated by the density functional theory method using the basis set of plane waves and the VASP package. The potential surface of reactions with molecular oxygen was studied by the nudged elastic band method. The energy parameters of the reaction (released energy and barrier) strongly depended on the curvature of carbon structure surfaces. The interaction of atomic oxygen in the ground state with the surface of carbon nanostructures is an exothermic reaction. The barrier to the reaction with molecular oxygen (0.5–2.5 eV) decreases as the curvature of nanostructure surfaces increases. The calculation results are in agreement with the experimental data and other ab initio calculations.     

Equation of state of metallic helium

The effective ion-ion interaction, free energy, pressure, and electric resistance of metallic liquid helium have been calculated in wide density and temperature ranges using perturbation theory in the electron-ion interaction potential. In the case of conduction electrons, the exchange interaction has been taken into account in the random-phase approximation and correlations have been taken into account in the local-field approximation. The solid-sphere model has been used for the nuclear subsystem. The diameter of these spheres is the only parameter of this theory. The diameter and density of the system at which the transition of helium from the singly ionized to doubly ionized state occurs have been estimated by analyzing the pair effective interaction between helium atoms. The case of doubly ionized helium atoms has been considered. Terms up to the third order of perturbation theory have been taken into account in the numerical calculations. The contribution of the third-order term is significant in all cases. The electric resistance and its temperature dependence for metallic helium are characteristic of simple divalent metals in the liquid state. The thermodynamic parameters—temperature and pressure densities-are within the ranges characteristic of the central regions of giant planets. This makes it possible to assume the existence of helium in the metallic state within the solar system.     

混合菁染料J-聚集体的光谱性能研究

对2种混合菁染料吸附在溴化银颗粒表面形成的J-聚集体的反射光谱及感光性能与对应菁染料单独吸附在溴化银颗粒表面进行了对比研究。用紫外-可见分光光计测定了菁染料吸附在溴化银颗粒表面形成J-聚集体的反射光谱。结果表明:2种混合菁染料吸附在溴化银颗粒表面形成的J-聚集体的反射光谱分别具有2个最大峰值波长,并且与对应菁染料单独使用时的峰值波长相一致。2种混和菁染料的感光性能比对应菁染料单独使用时有较大提高。     

Study of the process of formation of excited states of krypton atomic ions via electron-stimulated desorption of excited molecular ions

The processes of population of excited levels of a krypton atomic ion via electron-stimulated desorption are studied. The radiation yield per single exciting electron in the corresponding krypton spectral lines is measured by the optical time-of-flight mass spectrometric method. The efficiency of the processes studied is compared with that of electron-impact excitation of the same levels.     

Features of isotherms of the surface tension of a bentonite water suspension

The results from experimental studies of the concentration and temperature dependence of the surface tension of aqueous suspensions of bentonite are presented. The studies are conducted using the pendant drop method on a DSA-100 tensiometer. The maximum error of measuring the surface tension is 1%. The characteristics of isotherms of the surface tension of aqueous suspensions are analyzed. An attempt is made to explain the nature of low surface tension isotherms of a suspension.     

SEM study of the influence of microstructure wettability on the character of the oil saturation of the porous space of rocks

The influence of microstructure wettability on the oil distribution in pores is studied for oil-saturated deposits with highly viscous oil. The character of the oil distribution in the pores, depending on the degree of their hydrophobicity, is shown for carbonate rocks with different oil saturation. The given data indicate the relation between the character of the oil distribution in the pores and the microstructure wettability.     

闪光照相系统成像重复性的测量

为了更直观利用照像图像信息考察照相系统的重复性,提出了利用等光程条件下的黑密度分布曲线对成像重复性进行测量的方法,通过两次成像的黑密度分布曲线的线性拟合参数来评估成像系统的成像重复性。实验测量了有无后锥条件下的闪光照相系统的重复性以及底片接收系统的成像重复性,实验结果表明:后锥的存在对成像重复性没有明显影响,底片接收时闪光照相系统的成像重复性约为5%,底片本身引入的成像重复误差约为1.6%。     

Thickness dependence of temperature coefficient of resistance of MnBi films

In-situ measurements of the temperature coefficient of resistance of electron-beam evaporated MnBi films are reported for the thickness range 30–180 nm. The thickness dependence of the temperature coefficient of resistance curves are plotted for different weight ratios, annealing times and substrate temperatures. The temperature coefficient of resistance shows marked size effect, and is negative for lower thicknesses (<100nm) and positive for higher thicknesses. The experimental data is in good agreement with the Mayadas-Shatzkes theory. The thickness dependence of the Curie temperature also indicates marked size effect.     

大视场空间相机轻型遮光罩的研制

空间相机遮光罩既能遮挡杂光进入相机镜头,又可利用遮光罩长度和遮光罩内的光栅及表面材料特性,吸收已进入遮光罩的杂散光,能够保证相机获得较高的信噪比。具有优良性能指标的碳纤维复合材料应用于空间相机中能够满足空间相机的结构设计指标,并能大大降低相机的重量。针对某空间相机进行了遮光罩的设计,通过利用有限元模拟仿真分析与试验验证相结合的方法,验证了碳纤维作为遮光罩材料的可行性和是否能够提高光学系统的信噪比。结果表明,碳纤维复合材料应用于空间相机遮光罩的设计是完全可行的。     

Concentration quenching of fluorescence of colloid quantum dots of cadmium sulfide

The influence of the concentration of cadmium sulfide nanoparticles in a colloid aqueous solution on its optical properties has been investigated. The band gap of cadmium sulfide nanoparticles is calculated based on the optical absorption spectra of solutions with different concentrations. The band gap coincides for all the samples irrespective of their concentration and is equal to 2.63 eV. It is found that the intensity of fluorescence substantially depends on the solution concentration. The fluorescence intensity considerably decreases in a wavelength range from 665 to 720 nm as the concentration increases above 3.25 mM. This concentration is the threshold of the concentration quenching for CdS nanoparticles.     

Calculation of photoelectron spectra of the trihalides of group v elements

The SCF-Xα-SW method is applied to calculate the ionization energies of the trihalides of all of the Group V elements. The calculated orbital energies agree very well with reported experimental ionization energies. The molecular-orbital orderings obtained coincide with recent experimental orbital assignments. The results are also compared with previous ab initio, semiempirical and Xα calculations for NF₃, PF₃, PCl₃ and PBr₃. The comparison indicates that the present results show improved agreement with experiment and clarify certain ambiguities in the earlier molecular-orbital assignments.     

Simulation of the superlinearity of dose characteristics of thermoluminescence of anion-defective aluminum oxide

The specific features revealed in the superlinearity of dose dependences of thermoluminescence of anion-defective aluminum oxide single crystals have been considered theoretically in terms of the model of an interactive trap system. The model explains the decrease in the degree of superlinearity at a low heating rate, as well as with an increase in the dose increment, the occupancy of deep traps, and the sensitivity of the crystals to radiation due to the increase in the concentration of luminescence centers. The obtained results indicate a widening of the possibilities of the model for interpreting experimental data in the investigation of the dose characteristics of thermoluminescence of the studied crystals.     

单个鼻咽癌细胞的拉曼光谱分析的研究

利用激光镊子拉曼光谱系统研究了鼻咽癌细胞株和正常人鼻咽部气道上皮细胞株的单个细胞的拉曼光谱,对于每个细胞在不同部位测3个点。结果显示：正常细胞和癌细胞的平均拉曼光谱有显著差异：正常的细胞光谱强度比癌细胞的明显要高;正常细胞的1304和1336 cm-1处峰的强度比值为1.05,癌细胞的为1.22。用PCA主成分分析和DFA判别分析分别对单个细胞的平均光谱和不同位置所取得的单独光谱进行分析,结果发现：PCA和DFA均可以把癌细胞和正常细胞正确区分,对于单独光谱,DFA的效果更好一些。同时还发现同一个细胞中不同的光谱位置对PCA和DFA的区分度影响不是很大;PCA和DFA的图中还表明癌细胞的均匀度要比正常细胞的差。以上的研究均表明：激光镊子拉曼光谱可以成为区别正常鼻咽细胞和鼻咽癌细胞的有效手段。