Nonbonding oxygen holes and spinless scenario of magnetic response in doped cuprates

Both theoretical considerations and experimental data point to a more complicated nature of the valence hole states in doped cuprates than is predicted by the Zhang-Rice model. Actually, we deal with a competition of a conventional hybrid \({\text{Cu}} {\text{3}}d-{\text{O}} {\text{2}}p b{1g} \propto d{x^2-y^2} \) state and purely oxygen nonbonding state with e _u x, y∝p _{x, y} symmetry. The latter reveals a nonquenched Ising-like orbital moment that gives rise to a novel spinless purely oxygen scenario of the magnetic response in doped cuprates with the oxygen localized orbital magnetic moments of the order of tenths of Bohr magneton. We consider the mechanism of ^{63, 65}Cu-O 2p transferred orbital hyperfine interactions due to the mixing of the oxygen O2p orbitals with Cu3p semicore orbitals. Quantitative estimates point to a large magnitude of the respective contributions to both the local field and electric field gradient, and their correlated character.     

g-factors of rotational states in176Hf,177Hf,and180Hf

g-factors of rotational states in¹⁷⁶Hf and¹⁸⁰Hf were measured with the twelve detector IPAC-apparatus of our laboratory [1]. The natural radioactivity 3.78·10¹⁰y¹⁷⁶Lu and the 5.5 h isomer^180mHf were used which populate the ground-state rotational bands of¹⁷⁶Hf and¹⁸⁰Hf. The integral rotations ofγ-γ directional correlations in strong external magnetic fields and in static hyperfine fields of (Lu→Hf)Fe₂ and HfFe₂ were observed. The following results were obtained: $$\begin{array}{l} ^{176} Hf: g\left( {4_1^ + } \right) = + 0.334\left( {38} \right) \\ ^{180} Hf: g\left( {2_1^ + } \right) = + 0.305\left( {14} \right) \\ g\left( {4_1^ + } \right) = + 0.358\left( {43} \right) \\ {{ g\left( {6_1^ + } \right)} \mathord{\left/ {\vphantom {{ g\left( {6_1^ + } \right)} {g\left( {4_1^ + } \right)}}} \right. \kern-\nulldelimiterspace} {g\left( {4_1^ + } \right)}} = + 0.95\left( {12} \right) \\ \end{array}$$ . The hyperfine field in (Lu→Hf)Fe₂ was calibrated by observing the integral rotation of the 9/2^? first excited state of¹⁷⁷Hf populated in the decay of 6.7d¹⁷⁷Lu. Theg-factor of this state was redetermined in an external magnetic field as $$^{177} Hf: g\left( {{9 \mathord{\left/ {\vphantom {9 {2^ - }}} \right. \kern-\nulldelimiterspace} {2^ - }}} \right) = + 0.228\left( 7 \right)$$ . Finally theg-factor of the 2 ₁ ⁺ state of¹⁷⁶Hf was derived from the measuredg(2 ₁ ⁺ ) of¹⁸⁰Hf by use of the precisely known ratiog(2 ₁ ⁺ ,¹⁷⁶Hf)/g(2 ₁ ⁺ ,¹⁸⁰Hf) [2] as $$^{176} Hf: g\left( {2_1^ + } \right) = + 0.315\left( {30} \right)$$ .     

Non-spherical magnetic moment in MnAlGe

The magnetic structure factors of MnAlGe (space groupP4/nmm) measured with polarised neutrons have been expressed in terms of the magnetic moment of the Mn atom (site symmetry tetrahedral with tetragonal distortion), the Bessel transforms 〈j _n〉 of the Mn radial functions and the fractional occupancies of the moment density in the various crystal field orbitals. The measured structure factors were least-squares fitted with the theoretical expression involving 〈j _n〉 appropriate to the Mn⁰, Mn⁺ and Mn²⁺ atoms. The best fit was got using Mn⁰ transforms, yielding 1·45µ _B as the Mn magnetic moment. The fractional occupancies of the moment density in the crystal field orbitalsA _1g,B _1g E _g andB _2g were obtained. This analysis shows the magnetic moment to be highly non-spherical with a large fractional occupancy (38%) in theA _1g orbital directed along the tetragonal axis while the fractional occupancies ofB _1g andB _2g are found to be 31% and 30% respectively. The fractional occupancy of the moment in theE _g orbital directed towards the Ge and Al atoms is very low (1%). The spatially averaged moment density of Mn in MnAlGe is more diffuse than that of Mn I and Mn II in isostructural Mn₂Sb.     

Singlet-triplet pseudo Jahn-Teller centers in copper oxides

One of the most interesting attributes of a hole CuO ₄ ⁵ center in doped cuprates is the complexity of the ground state as a result of electronic pseudodegeneracy. An extra hole injected into the initial CuO ₄ ⁶ cluster with a b _1g hole can occupy not only the very same hybrid Cu 3d-O 2p orbital state, producing a Zhang-Rice A _1g singlet, but also the pure oxygen e _u state, generating a singlet or triplet ^1,3 E _u term, with close energies. The pseudo Jahn-Teller effect induced by pseudodegeneracy of the singlet ¹ A _1g and ¹ E _u terms is analyzed in detail. Fiz. Tverd. Tela (St. Petersburg) 40, 1795–1804 (October 1998)     

Empirical two-point correlation functions

Let A ₁ , A ₂ , A ₃ A ₄ be four observables, the compatible observables among them being (A ₁ , A ₃ ), (A ₁ , A ₄ ), (A ₂ , A ₃ ), (A ₂ , A ₄ ). In order that the empirical data be reproducible by a quantum or a classical theory, the two-point correlation functions $$\{ C_{ij} = \left\langle {A_i A_j } \right\rangle :i,j a compatible pair\} $$ must necessarily satisfy $$|X_{13} X_{14} - X_{23} X_{24} | \leqslant \left( {1 - X_{13} ^2 } \right)^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} \left( {1 - X_{14} ^2 } \right)^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} + \left( {1 - X_{23} ^2 } \right)^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} \left( {1 - X_{24} ^2 } \right)^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} (*)$$ where X_ij=C_ijC _ii ^?1/2 C _jj ^?1/2 . In the case ofGaussian data, this inequality is alsosufficient; If (*) holds, there is a Gaussian joint distribution for A ₁ , A ₂ , A ₃ , A ₄ which reproduces the Gaussian data for compatible pairs. It follows that Bell's inequality is satisfied by all true-false propositions about the Gaussian data. A further consequence of the analysis is thatquantum Gaussian fields satisfy Bell's inequality for all true-false propositions aboutfield measurements. The maximum violation of (*) corresponds to Rastall's example in the case of two-valued observables.     

Polarized ARPES spectra of undoped cuprates

The spectral density (SD) in the ARPES spectra of antiferromagnetic (AFM) dielectrics Sr₂CuO₂Cl₂ and Ca₂CuO₂Cl₂ along the principal symmetry directions of the Brillouin zone was studied by the generalized tight binding method. At the valence band top of these undoped cuprates in the AFM state, there is a pseudogap of magnetic nature with E _s(k)～0–0.4 eV between a virtual level and the valence band proper. The observed similarity of dispersion along the Γ-M and X-Y directions can be explained by the proximity of the ³ B _1g triplet and the Zhang-Rice singlet levels. The value of parity of the polarized ARPES spectra at the Γ, M, and X points calculated for the AFM phase of undoped cuprates with an allowance for the partial contributions is even. The conditions favoring observation of the partial contributions in polarized ARPES spectra are indicated. Due to the spin fluctuations, the virtual level acquires dispersion and possesses a small spectral weight. Probably, this level cannot be resolved on the background of the main quasi-particle peak as a result of the damping effects.     

Gyromagnetic ratio of the 2+ rotational state of184W and observation of a large hyperfine anomaly with respect to183Wg in iron

Theg-factor of the 2⁺ rotational state of¹⁸⁴W was redetermined by an IPAC measurement in an external magnetic field of 9.45 (5)T as: $$g_{2^ + } (^{184} W) = + 0.289(7).$$ In the evaluation the remeasured half-life of the 2⁺ state: $$T_{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} (2^ + ) = 1.251(12)ns$$ was used. TDPAC-measurements with a sample of carrierfree¹⁸⁴Re in high purity iron gave the hyperfine fields: $$B_{300 K}^{hf} (^{184} W_2 + \underline {Fe} ) = 70.1(21)T$$ and $$B_{40 K}^{hf} (^{184} W_{2^ + } \underline {Fe} ) = 71.8(22)T.$$ A comparison with the hyperfine field known from a spin echo experiment with¹⁸³W _g Fe leads to the hyperfine anomaly: $$^{184} W_{2^ + } \Delta ^{183} W_g = + 0.145(36).$$ The hyperfine splitting observed in a Mössbauer source experiment with another sample of carrierfree^184m Re in high purity iron indicates that the smaller splitting, measured previously by a Mössbauer absorber experiment is due to the high tungsten concentration in the absorber. The new value for theg-factor of the 2⁺ state together with the result of the Mössbauer experiment allow an improved calibration for our recent investigation of theg _R -factors of the 4⁺ and 6⁺ rotational states. The recalculated values are: $$g_{4^ + } (^{184} W) = + 0.293(23)$$ and $$g_{6^ + } (^{184} W) = + 0.299(43).$$ The remeasured 792-111 keVγ-γ angular correlation $$W(\Theta ) = 1 - 0.034(4) \cdot P_2 + 0.325(6) \cdot P_4 $$ gives for the mixing ratio of theK-forbidden 792keV transition: $$\delta ({{E2} \mathord{\left/ {\vphantom {{E2} {M1}}} \right. \kern-\nulldelimiterspace} {M1}}) = - \left( {17.6\begin{array}{*{20}c} { + 1.8} \\ { - 1.5} \\ \end{array} } \right).$$ A detailed investigation of the attenuation ofγ-γ angular correlations in liquid sources of¹⁸⁴Re and^184m Re revealed the reason for erroneous results of early measurements of the 2⁺ g _R -factor: The time dependence of the perturbation is not of a simple exponential type. It contains an unresolved strong fast component.     

Time evolution of the Infrared Laser Induced Breakdown Spectroscopy of DNA bases Guanine and Adenine

Laser-Induced Breakdown Spectroscopy (LIBS) of DNA bases Guanine and Adenine was studied using a high-power CO₂ pulsed laser (λ=10.591 μm, τ _FWHM=64 ns and fluences ranging from 25 to 70 J/cm²). The strong emission of the adenine and guanine plasma, collected using a high-resolution spectrometer, at medium-vacuum conditions (4 Pa) and at 1 mm from the target, exhibits excited molecular bands of CN (B² Σ ⁺–X² Σ ⁺) and excited neutral H and ionized N⁺ and C⁺. The medium-weak emission is due to excited species C²⁺, C³⁺, N, O, O⁺, O²⁺ and molecular band systems of $\mathrm{C}_{2}(\mathrm{d}^{3}\varPi_{\mathrm{g}}\mbox{--}\mathrm{a}^{3}\varPi_{\mathrm{u}};\ \mathrm{D}^{1}\varSigma_{\mathrm{u}}^{+}\mbox{--}\mathrm{X}^{1}\varSigma_{\mathrm{g}}^{+})$ , OH(A² Σ ⁺–X² Π), NH(A³ Π–X³ Σ ^?), CH(A² Π–X² Π), $\mathrm{N}_{2}^{+}(\mathrm{B}^{2}\varSigma_{\mathrm{u}}^{+}\mbox{--} \mathrm{X}^{2}\varSigma_{\mathrm{g}}^{+})$ and N₂(C³ Π _u–B³ Π _g). We focus our attention on the temporal evolution of different atomic/ionic and molecular species. The velocity distributions for various (different) species were obtained from time-of-flight (TOF) measurements. Intensities of some lines from C⁺ were used for determining electron temperature and their Stark-broadened profiles were employed to estimate the temporal evolution of electron density.     

Calculations of the Spin-Hamiltonian Parameters for the Trigonal Cr3+ and Mn4+ Centers in Ca3Ga2Ge3O12 (CGGG) Garnet Crystal

The spin-Hamiltonian parameters (zero-field splitting D, g-factors g _//, g _⊥ and hyperfine structure constants A _//, A _⊥) of Cr³⁺ and Mn⁴⁺ ions at the trigonal Ga³⁺ site of Ca₃Ga₂Ge₃O₁₂ (CGGG) garnet crystals are calculated from the high-order perturbation formulas based on the two-mechanism model. In the model, besides the contributions to spin-Hamiltonian parameters from the crystal-field (CF) mechanism in the frequently applied CF theory, those from the charge-transfer (CT) mechanism (which is neglected in CF theory) are taken into account. The calculated results are in reasonable agreement with the experimental values. The defect structures of Cr³⁺ and Mn⁴⁺ impurity centers in CGGG crystals are also obtained from the calculations. The calculations show that the relative importance of CF mechanism (characterized by $ \left| {{{Q^{\text{CT}} } \mathord{\left/ {\vphantom {{Q^{\text{CT}} } {Q^{\text{CF}} }}} \right. \kern-0pt} {Q^{\text{CF}} }}} \right| $ , where $ Q = D,\;\Delta g_{\rm{//}} ,\;\Delta g_{ \bot } ,\;A_{\rm{//}}^{(2)} or\;A_{ \bot }^{(2)} $ ) for Mn⁴⁺ center in CGGG is larger than that for Cr³⁺ center. So, for the high valence state dⁿ ions in crystals, the reasonable calculations of spin-Hamiltonian parameters should consider the contributions due to both the CF and CT mechanisms.     

Nuclear orientation and NMR/ON of205,207Po

^205,207Po have keen implanted with an isotope separator on-line into cold host matrices of Fe, Ni, Zn and Be. Nuclear magnetic resonance of oriented²⁰⁷Po has been observed in Fe and Ni, of²⁰⁵Po in Fe. The resonance frequencies for zero external field are $$\begin{gathered} v_L (^{207} Po\underline {Fe} ) = 575.08(20)MHz \hfill \\ v_L (^{207} Po\underline {Ni} ) = 160.1(8)MHz \hfill \\ v_L (^{205} Po\underline {Fe} ) = 551.7(8)MHz. \hfill \\ \end{gathered} $$ From the dependence of the resonance frequency on external magnetic field theg-factor of²⁰⁷Po was derived as $$g(^{207} Po) = + 0.31(22).$$ Using this value the magnetic hyperfine fields of Po in Fe and Ni were obtained as $$\begin{gathered} B_{hf} (Po\underline {Fe} ) = + 238(16)T \hfill \\ B_{hf} (Po\underline {Ni} ) = 66.3(4.6)T. \hfill \\ \end{gathered}$$ Theg-factor of²⁰⁵Po follows as $$g(^{205} Po) = + 0.304(22).$$ From the temperature dependence of the anisotropies ofγ-lines in the decay of^205,207Po the multipole mixing of several transitions was derived. The electric interaction frequenciesv _Q=eQV_zz/h in the hosts Zn and Be were measured as $$\begin{gathered} v_Q (^{207} Po\underline {Zn} ) = + 42(3)MHz \hfill \\ v_Q (^{207} Po\underline {Be} ) = - 70(20)MHz \hfill \\ v_Q (^{205} Po\underline {Be} ) = - 42(17)MHz. \hfill \\ \end{gathered}$$      

Characterising WIMPs at a future e + e − linear collider

We investigate the prospects for detecting and measuring the parameters of WIMP dark matter in a model-independent way at the International Linear Collider. The signal under study is direct WIMP pair production with associated initial state radiation e ⁺ e ^?→χχγ. The analysis accounts for the beam energy spectrum of the ILC and the dominant machine induced backgrounds. The influence of the detector parameters are incorporated by full simulation and event reconstruction within the framework of the ILD detector concept. We show that by using polarised beams, the detection potential is significantly increased by reduction of the dominant SM background of radiative neutrino production $e^{+}e^{-} \rightarrow \nu \bar {\nu }\gamma The light-by-light contribution from the lightest neutral pseudoscalar and scalar mesons to the anomalous magnetic moment of muon is calculated in the framework of the nonlocal SU(3)×SU(3) quark model. The model is based on chirally symmetric four-quark interaction of the Nambu?CJona-Lasinio type and Kobayashi?CMaskawa?C??t?Hooft U _A (1) breaking six-quark interaction. Full kinematic dependence of vertices with off-shell mesons and photons in intermediate states in the light-by-light scattering amplitude is taken into account. The small positive contributions from the scalar mesons stabilize the total result with respect to change of model parameters and reduces to $a_{\mu}^{\mathrm{LbL},\mathrm{PS}+\mathrm{S}}=(6.25\pm0.83)\cdot10^{-10}$ .     

The temperature dependence of the hyperfine interaction of the transition metal osmium in a gadolinium host matrix

Integral perturbed angular correlations of the 931-155keVγγ-cascade of¹⁸⁸Os in Gd have been measured. With this technique the combined magnetic and electric hyperfine interaction of the 155 keV level of¹⁸⁸Os as an impurity in a Gd host has been studied as a function of temperature. The result for the electric field gradient of Os in Gd at 300 K is: $$\left| {V_{zz} \left( {Os:\underline {Gd} } \right)} \right| = \left( {12.8_{ - 1.9}^{ + 3.1} } \right) \cdot 10^{17} {V \mathord{\left/ {\vphantom {V {cm^2 }}} \right. \kern-\nulldelimiterspace} {cm^2 }}.$$ For the magnetic hyperfine field at 4.2 K the value $$H_{hf} \left( {Os:\underline {Gd} } \right) = - 134\left( {26} \right)kG$$ was obtained. Sign and magnitude of the magnetic hyperfine field suggest the existence of a localized moment of about ?0.4 µ _B at the site of Os in Gd. With increasing temperature the magnetic hyperfine field decreases much stronger than the magnetization of the host. Possible explanations for this anomalous temperature dependence are discussed.     

Electron scattering from trans 1,3-butadiene molecule: cross-sections, oscillator strength and VUV photoabsorption cross-sections

Electron energy-loss spectra for the butadiene molecule were measured in the scattering angular range of 2.0° to 8.0°, in an energy-loss range from 2 to 50 eV, using 1000 eV incident electrons. The absolute generalized oscillator strength (GOS) and inelastic cross section have been determined for the \hbox{$\tilde{\rm X}^{1}$}?X1A _g  → 1¹B _u transition. The absolute elastic differential cross section was also determined spanning an angular range from 2.0° to 40.0°. From a small angle electron energy-loss spectrum, the optical oscillator distribution (photoabsorption spectrum) for the butadiene molecule was obtained in the 2 to 100 eV photon energy range. Accurate ab initio calculations have been performed, within the First Born Approximation, for generalized oscillator strength (GOS) and excitation energies for the \hbox{$\tilde{\rm X}^{1}$}?X1A _g  → 1¹B _u and \hbox{$\tilde{\rm X}^{1}$}?X1A _g  → 2¹A _g transitions. Our results emphasize the importance of using highly correlated wavefunctions and accurate methodologies in the calculation of the GOS for electron impact-induced electronic transitions in molecules.     

Two-Channel Effective Range Expansion and Bound-State Properties

The S matrix and the f matrix amplitudes are considered for the case of two coupled elastic scattering channels, which differ in values of orbital angular momenta. Matrix elements of S and f matrices are parametrized in terms of scattering phases ?? _i (i?=?1, 2) and a mixing parameter ${\epsilon}$ and are expressed in terms of matrix elements c _ij = (K ^?1) _ij where K is the reaction K matrix. Quantities ${g_{ij}(k)=k^{l_i+l_j+1}c_{ij}(k)}$ are expanded in powers of k ², k being the relative momentum of colliding particles B and C. Then functions g _ij (k) and c _ij (k) are continued analytically to the pole of amplitudes f _ij corresponding to the bound state A of colliding particles. This procedure allows to get the position of the pole as well as the residues of amplitudes f _ij at that pole which are related directly to vertex constants and asymptotic normalization coefficients corresponding to the vertex A ?? B?+?C.     

Distribution of cyclic species in network formation: Microscopic theory of branching process in Ag-R-B f−g model

The distribution of cyclic species is explored for an irreversible A_g-R-B_f-g model on the basis of the concept of the “m tree” which was introduced in a preceding report by the authors. On the assumption of equal reactivity, the explicit solution is derived; i.e., for a sufficiently concentrated solution the concentration of cyclicj-mers can be expressed as \(\left[ {R_j } \right] = \left( {k_{Rj} /k_L } \right)\left[ {\left( {f - g} \right)D_B } \right]^j \omega _j /j\) , wherek _Rj andk _L are the rate constants of cyclicj-mer formation and interconnection, respectively, and $$\omega _j = \sum\limits_{k = 0}^{[j/2]} {\left( {_{2k}^j } \right)} \alpha ^k $$ where α=(g ? 1)(f ? g ? 1)/g(f ? g) and [j/2] is the Gauss' symbol. Forg → 1, ω_j → 1, so that the solution reduces to the A-R-B_f?1 case. At a critical point one observes the strong divergence of the chances ∑ φ_j of cyclization.     

Zero value of the schwarzschild mass for an asymptotically Euclidian system of gravitational waves

A class of asymptotically Euclidian space-times is shown to exist for which the Schwarzschild mass is equal to zero. The coordinate atlases of these space-times satisfy two additional conditions: \(\partial _\kappa ( - gg^{0_k } ) = 0\) and \(\Gamma _{ik}^0 \partial _0 g^{ik} - \Gamma _{ik}^k \partial _0 g^{0_i } = 0\) . In aT-orthogonal metricds ² =g ₀₀ dt ² ?g _αβ dx ^α dx ^β these conditions take a simple form: ?₀(detg _αβ ) = 0 and (?₀ g ^αβ )(?₀ g _αβ ) = 0.     

Theg-factor of the 2+ state of180W and quadrupole moment ratios observed for180W and180Hf by the Mössbauer technique

By Mössbauer absorption experiments the magnetic hyperfine splitting has been observed for the 2+ states of¹⁸⁰W and¹⁸²W in a tungsten iron alloy (3.6 at%W). Since theg-factor of the 2+ state of¹⁸²W is known the measured splitting of the¹⁸²W line could be used for the calibration of the magnetic hyperfine field and the measurement with¹⁸⁰W gave then for the unknowng ₂₊-factor of¹⁸⁰W: $$g_{2 + } (^{180} W) = 0.260 \pm 0.017.$$ By use of a WO₃ absorber the electric quadrupole splittings in the same states were measured. The ratio of the quadrupole moments was derived $$\frac{{Q_{2 + } (^{180} W)}}{{Q_{2 + } (^{182} W)}} = 0.983 \pm 0.022.$$ This ratio is somewhat smaller, but more accurate than the weighted means of previous results and in disagreement with the theoretical prediction. A similar measurement with¹⁷⁸Hf and¹⁸⁰Hf and a HfO₂ absorber gave $$\frac{{Q_{2 + } (^{178} Hf)}}{{Q_{2 + } (^{180} Hf)}} = 1.052 \pm 0.021.$$ This result is larger than the average of previous measurements and agrees with theory. The isomer shifts of the Mössbauer lines of¹⁸⁰W and¹⁸²W were measured for sources in a tantalum metal environment and for absorbers of metallic tungsten. Different signs were observed which indicate that the mean squared charge radius of the 2+ state of¹⁸²W is larger than that of the ground state whereas for¹⁸⁰W the ground state has the larger 〈r ²〉-value.     

Hyperfine structure,g j factors and lifetimes of excited2 P 1/2 states of Rb

The hyperfine structure of the 6² P _1/2 and 7² P _1/2 state of⁸⁵Rb and⁸⁷Rb and of the 6² P _3/2 state of⁸⁷Rb has been investigated with optical double resonance at intermediate magnetic fields. The magnetic interaction constants,g _j factors and lifetimes are: $$\begin{gathered} 6^2 P_{1/2} state: A\left( {^{85} Rb} \right) = 39.11\left( 3 \right) MHz,A\left( {^{87} Rb} \right) = 132.56 \left( 3 \right)MHz, \hfill \\ g_j = 0.6659\left( 3 \right), \tau = 1.14\left( {13} \right) \cdot 10^{ - 7} \sec , \hfill \\ 7^2 P_{1/2} state: A\left( {^{85} Rb} \right) = 17.68\left( 8 \right)MHz,A\left( {^{87} Rb} \right) = 59.92\left( 9 \right)MHz, \hfill \\ g_j = 0.6655\left( 5 \right), \hfill \\ 6^2 P_{3/2} state: g_j = 1.3337\left( {10} \right), \tau = 1.12\left( 8 \right) \cdot 10^{ - 7} \sec for ^{87} Rb. \hfill \\ \end{gathered} $$ From the hfs coupling constants of then ² P multiplets a 11.5% core polarization contribution to the magnetic hfs of then ² P _3/2 states is obtained, which is found to be independent from the main quantum numbern. The expectation values <r ^?3> _j for thenp valence electrons corrected for core polarization are compared with those derived from the² P fine structure separation. Good agreement is achieved for allnp levels with the choice ofZ _i =Z?3=34 for the effective nuclear charge number. The nuclear quadrupole moments of⁸⁵Rb and⁸⁷Rb are rederived on the basis of this more improved treatment for thep-electron-nucleus interaction yielding $$\begin{gathered} Q_N \left( {^{85} Rb} \right) = + 0.274\left( 2 \right) \cdot 10^{ - 24} cm^2 \hfill \\ Q_N \left( {^{85} Rb} \right) = + 0.132\left( 1 \right) \cdot 10^{ - 24} cm^2 \hfill \\ \end{gathered} $$ where the error does not include the remaining theoretical uncertainty of about 10%.     

Magnetic moment of short lived β-emitter 24mAl

The magnetic moment of short lived β-emitter ^24mAl (426 keV, I ^π ?=?1^?+?, T _1/2?=?131 ms) has been measured by means of β-NMR technique, for the first time. From the β-NMR spectrum, the magnetic moment was determined as $\left| {\upmu}\left( ^{\rm 24m}{\rm Al} \right) \right|=\left( {2.99\pm 0.09} \right){\upmu}_{\rm N}$ . Combined with the known magnetic moment of the mirror partner ^24mNa, the expectation value of <?S _z?> is obtained to be (0.08 ± 0.12). These values are reproduced well by the shell model calculation.     

Hölder’s inequality for matrices

We prove that for arbitraryn×n matricesA ₁,A ₂,…,A _m and for positive real numbersp ₁,p ₂,…,p _m withp ₁ ^?1 +p ₂ ^?1 +…+p _m ^/?1 =1, the inequality 1 $$|Tr(A_1 A_2 ...A_m )^2 |< \mathop {II}\limits_{k = 1}^m [Tr(A_k^\dag A_k )^{p_k } ]P_k^{ - 1} $$ holds.