Transient photocurrents in UV-irradiated polytetrafluoroethylene coronoelectrets

It is experimentally found that UV irradiation of 10-m polytetrafluoroethylene films electrified in a negative corona discharge produces a transient current which is unipolar and whose peak value decreases in successive exposures. A model is considered on the basis of spatial impurity-center photoionization and the resultant positive-carrier motion, excluding recapture and recombination, in the strong internal field generated by trapped negative charges. Correlation of the experimental and calculated photocurrent kinetics yield values for the hole mobility (8.9×10^–15 m²·V^–1·sec^–1) and impurity-center concentration (1.5×10¹⁸ m^–3).Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 26–29, June, 1990.     

Nuclear orientation study of the decay of204BiFe

The decay of²⁰⁴Bi nuclei (I =6⁺, T_1/2=11·22 h) oriented in an iron host was investigated on the JINR low-temperature nuclear orientation facility SPIN. The orientation parameterB ₂=1·17 (6) was obtained from the analysis of six prominent E1 gamma-transitions. From the measured normalized intensities of the gamma-rays observed some 70 values of multipole mixing ratios for the gamma-transitions in²⁰⁴Pb nucleus were determined for the first time. The spins 6, 6, 5 and 4 could be uniquely assigned to the²⁰⁴Pb negative parity levels at 3891·5 keV, 3768·4 keV, 3301·5 keV and 2338·2 keV, respectively. The spin-parity assignments of the levels at 4183·8 keV, 4094·2 keV, 3782·0 keV, 2506·9 keV and 2065·1 keV were confirmed as 6^–, 6^–, 5^–, 5^– and 5⁺, respectively. For the level at 3105·1 keV spin-parity 5^– was suggested and spinparity 7^– of the level at 2696·4 keV was called in question. The possible placements of the gammatransitions 3 1351·7 keV and 1353·4 keV in the decay scheme is discussed. The reorientation parameters for the long-living levels at 2264·2 keV (T _1/2=0·45 s) and 1273·9 keV (T _1/2= =265 ns) were determined asG ₂=0·41 (14) andG ₂=0·60 (17), respectively. For the isomeric level at 2185·7 keV (T _1/2=67·2 min) the value ofG ₂=0·88 (49) was proposed.The authors would like to express their thanks to T. I. Kracíková and M. Trhlík for the valuable discussions in the course of the evaluation of the experimental data.     

Electrical properties of p-type ZnGeP2 irradiated by H+ ions

The properties of p-type ZnGeP₂ [p₀=(5–10)·10¹⁰ cm^–3, ₀=(2–5)·10^–7 (·cm)^–1], irradiated with H⁺ ions [E=5 MeV, T_irr=300 K, D=(1·10¹²–1.7·10¹⁶) cm^–2] are studied. An increase in the resistivity (to gr_max - 5·10¹¹ ·cm) and subsequent reduction in for large currents of H⁺ ions ( - 9·10⁸ ·cm for D - 1.7·10¹⁶ cm^–2), is observed in irradiated crystals. The resistivity of irradiated p-type ZnGeP₂ is found to be very sensitive to hydrostatic pressure [(4–5)·10^–5 bar^–1]. The annealing of radiation defects in the temperature interval (20–600) °C is examined.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 91–93, October, 1991.     

Photoinduced Electron Transfer From Carbazole to Halomethanes in a Gas Phase

Intermolecular photoinduced electron transfer (PET) in a gas phase was studied using carbazole vapor fluorescence quenching by halomethanes (CHCl₃, CH₂Br₂, CCl₄, CHBr₃). The fluorescence quenching rate constants k _q changing from 2.3·10⁵ sec^–1·torr^–1 in mixtures with CHCl₃ to 4.6·10⁶ sec^–1·torr^–1 in mixtures with CHBr₃ at a constant temperature of 403 K were estimated. The dependence of the carbazole fluorescence decay rates in the presence of halomethanes on the free energy change G during transfer of the electron from carbazole to halomethanes is considered. It is suggested to take into account the influence of the vibrational energy of the carbazole molecule E _vib and its temperature changes in estimation of the G values. The differences between PET in the gas and liquid phases were analyzed. It is found that for mixtures with CCl₄ and CHBr₃ the negative temperature dependence of k _q is observed, when the decay rates and efficiencies of the intermolecular PET decreased with temperature increase in the range 403–573 K, i.e. these mixtures the electron transfer is not a barrier-restricted process.     

The dependence of the neutron temperature on the geometric parameter for water and loose diphenyl

The dependence of the neutron temperatureT _n on the geometric parameterB ² was measured by the pulse method in water and loose diphenyl. The measurements were made on a moderator poisoned by cadmium sulphate, a substance whose absorption cross-section is non 1/v.The following results were obtained: For waterT _n [eV]=–(0·00391±0·00045)B ² [cm^–2]+(0·02537±0·00035) for loose diphenyl:T _n [eV]=–(0·01014±0·00152)B ² [cm^–2]+(0·02518±0·00054).We are indebted to J. Jirou and J. Jadavan for their assistance in the measurements, the accelerator operation and electronic apparatus maintenance.     

Anomalous behaviour of transient creep in commercially pure aluminium

Transient creep of pure and commercial aluminium was studied under a constant stress of 18·6 MPa at different temperatures ranging from 613 to 698 K. The anomalous values of transient creep parameters, n ranging from 0·003–0·055 (±0·001) and 0·5–1·0 (±0·05) respectively, which were found in this temperature rangs, might bs ascribed to the superplastic behaviour of pure and commercial aluminium. The activation energy of transient creep for pure Al was found to be about (2·4 +0·07) × 10^–22) kJ/atom. characterizing a dislocation glide-cross slipping mechanism.     

Properties of MOS-structures based on anode-oxidized CdSnAs2

The properties of metal (Al, Au)-anodic oxide-CdSnAs₂ monocrystal structures are studied. It is established that MOS-structures using undoped CdSnAs₂ crystals show a high positive fixed charge in the anodic oxide (N_S 5·10¹² cm^–2) and high surface state density on the oxide-CdSnAs₂ boundary surface (N_SS 2·10¹³ cm^–2·eV^–1). In MOS-structures using diffusion-doped (copper) crystals the sign of the fixed charge is negative (N_S 10¹¹ cm^–2, N_SS 2·10¹² cm^–2·eV^–1). The latter structures show a definite photosensitivity and photomemory. The possibility of effective control of the fixed charge value within the oxide by illumination is shown. The surface state distribution over energy, time constant, and capture section is determined.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 90–93, September, 1982.     

The magnitude of the transferred charge in the silent discharge in oxygen

A pulse amplitude analyser was used to measure the distribution functions of the transferred charge in the silent discharge in oxygen under the atmospheric pressure. The charges transferred by one microdischarge were established from these distribution functions. Their magnitude varies from 3×10^–11 C to 1·3×10^–9 C on changing the width of the discharge gap from 0·2 mm to 3·2 mm, respectively.     

Pitfalls in the Use of Common Luminescent Probes for Oxidative and Nitrosative Stress

Lucigenin (LC²⁺, bis-N-methylacridinium) and 2,7-dichlorofluorescin (DCFH₂) are widely used as chemiluminescent or fluorescent probes for cellular oxidative stress, to reflect levels of superoxide (O₂ ^·–) and hydrogen peroxide, respectively. We report mechanistic studies that add to the growing evidence for the unsuitability of either probe except in very well-defined circumstances. The ability for lucigenin to generate superoxide via reduction of LC²⁺ to LC^·+ and redox cycling with oxygen depends on the reduction potential of the LC²⁺/LC^·+ couple. Redox equilibrium between LC^·+ and the redox indicator benzyl viologen is established in microseconds after generation of the radicals by pulse radiolysis and indicated E(LC²⁺/LC^·+) –0.28 V vs. NHE. Reaction of LC^·+ with O₂ to generate O₂ ^·– was also observed directly similarly, occurring in milliseconds, with a rate constant k 3 × 10⁶ M ^–1 s^–1. Quinones act as redox mediators in LC^·+/O₂ redox cycling. Oxidation of DCFH₂ to fluorescent DCF is not achieved by O₂ ^·– or H₂O₂, but NO₂ ^·) reacts rapidly: k 1 × 10⁷ M ^–1 s^–1. Oxidation by H₂O₂ requires a catalyst: cytochrome c (released into the cytosol in apoptosis) is very effective (even 10 nM). Fluorescence reflects catalyst level as much as O₂ ^·–) production.     

Radical concentration measurements in hydrocarbon diffusion flames

Absolute OH· concentrations and relative H-atom and O-atom profiles have been measured in a laminar, co-flowing methane/air diffusion flame burning at atmospheric pressure. Laser absorption and laser-induced fluorescence methods were used to probe the A ² X ²II_itransition in OH·. The maximum OH· concentration is found to be 1.8±0.2 ×10¹⁶ cm^–3 (mole fraction =5.0×10^–3) at a temperature of 2080 K, which is twice the value calculated assuming local total equilibrium but less than half that predicted from partial equilibrium (O₂+H₂ 2OH·). Multiphoton ionization (2+1 process at 243 nm) has been used to detect H atoms, while laser-induced fluorescence at 845 nm excited by two-photon absorption at 226 nm was employed to observe O atoms. In both cases it was found that low photon intensities (2×10⁸W/cm²) and a retroreflected beam, Doppler-free geometry was required in order to avoid the photolytic production of the species of interest. For all of the concentration profile data it is necessary to correct the raw signals for variations in collisional quenching. In the case of the multiphoton ionization measurements the variation in electron detection sensitivity as a function of flame position must be accounted for as well. Establishing absolute H-atom and O-atom concentrations is discussed in terms of partial equilibrium considerations and detailed flame structure calculations.Formerly the National Bureau of Standards     

Nuclear spin lattice relaxation of58CoFe and60CoFe measured by the thermal cycling method

Thermal cycling of thin foil samples is used to measure nuclear spin lattice relaxation of dilute⁵⁸Co and⁶⁰Co in iron at polarizing fields up to 1.3 T. The relaxation rates for the two isotopes differ by a factor of 7.1; the good agreement between the high field values for ² C ₂, (2.93±0.15)·10¹⁵ K·s^–1·T^–2 (⁵⁸Co) and (3.01±0.06)·10¹⁵K·s^–1·T^–2 (⁶⁰Co) verifies the reliability of the experimental method. An enhancement factor model is introduced and shown to give an excellent reproduction of the observed field dependence of the relaxation.     

Parametrization of the radial distribution function and thermodynamic properties of the restricted primitive model of electrolyte solutions

Monte Carlo simulations for the restricted primitive model of 1-1 aqueous electrolyte solutions were performed on a minicomputer. The calculations covered the concentration range from 0·1 to 3 mol/dm³ and the ionic diameter varied from 2·0× ×10^–10 to 4·75×10^–10 m. On the basis of the Monte Carlo results a new analytical radial distribution function and excess internal energy parametrization were proposed for the restricted primitive model.     

Solubility of Na2Co3 in NaCl:CaCl2 crystals

Measurements of electrical conductivity of NaCl 10^–5 molar fr. CaCl2 (1–80)×10^–5 molar fr. Na₂CO₃ crystals have been used to determine the temperature dependence of the solubility of CO₃-ions over the temperature range from 75 to 530 °C. The total solubility of CO₃-ions and that of [CO ₃ ^2– -vacancy] complexes may be expressed by simple relationships andc _ka=3·19× 10^–2 exp (–0·25 eV/kT), resp. The heat of solution of complexes is equal to 0·25 eV and that of free CO ₃ ^2– ions is higher than 1·2 eV. Under conditions of the thermal equilibrium between the solid solution and precipitate, the ratio of Na₂CO₃ and CaCO₃ components in the precipitate has been calculated at various temperatures and CO₃ concentrations.     

ГЕНЕРАТОР ВЫСОКОВОЛ ЬТНЫХ ИМПУЛЬСОВ МАЛО Й ДЛИТЕЛЬНОСТИ С МАЛЫМ ВРЕМЕНЕМ НАРАСТАНИЯ И ЕГО ПРИМЕНЕНИЕ ДЛЯ И ЗМЕРЕНИЯ ПОДВИЖНОСТ ЕЙ ЭЛЕКТРИЧЕСКИХ ЗАРЯД ОВ В ГАЗАХ

The paper describes a generator of square-wave power pulses with a front of 2×10^–8 second and length of 0·6×10^–6 sec for a capacity load of 70 pF, with continuously regulable amplitude from 1 to 9 kV. The current in the pulses >100 A. The delay in the high-power pulse with respect to the triggering pulse does not exceed (0·09–0·15)×10^–6 sec. The generator is intended for operating spark counters of relativistic particles although its range of use may be much greater. The paper points out its use for studying the mobilities of electric charges in gas mixtures of spark counters.     

Production and Application of the Langmuir Aggregates of Eosine with Cetyl Trimethyl Ammonium Bromide

The procedure of microphase adsorption–spectral correction is applied to the interaction of eosine Y (EO) to the micelles of cetyl trimethyl ammonium bromide (CTAB). The Langmuir aggregation of EO on CTAB occurs owing to microelectrostatic attraction. The results have shown that at pH 3.8, monomeric and micellar aggregates have the structure EO₅·CTAB₂ and (EO₅·CTAB₂)₃₉. The adsorption constant of an aggregate is 7.01·10⁵, its molar absorption coefficient is = 8.8·10⁴ liters·mole^–1·cm^–1 at 550 nm. Application of the aggregation of EO on CTAB gives satisfactory results for quantitative determination of cation surfaceactive agents (surfactants).     

Investigations of the excitation energy transport mechanism in donor-acceptor systems

Measurements of fluorescence quantum yield _D/_oD of Na-fluorescein (donor; D) versus concentration of rhodamine B (acceptor; A) in viscous solutions have been carried out. The donor concentration in these solutions was as follows:C _D=2·10^–2 M (system I), 1.5·10^–2 M (II), 10^–2 M (III), 3·10^–3 M (IV), and 5·10^–5 M (V). The experimental results have been compared with current theories of nonradiative electronic energy transfer (NEET). In the case of very strong migration (systems I, II, and III), a significant influence of correlations (between configurations of D and A molecules in the surroundings of successively excited donors) on quantum yield _D/_oD has been determined. Experimental values have been found to be clearly higher in comparison with those predicted theoretically. The influence of possible factors on the decrease in the effectiveness of excitation energy transport to traps-acceptors in systems of very strong migration has been discussed.Dedicated to Professor A. Kawski on the occasion of his 65th birthday.     

Properties of epitaxial layers of p-type germanium-doped gallium arsenide

The electrophysical properties and cathode-luminescence(CL) spectra of p-type layers of GaAsGe with p=1.8·10¹⁷–3.6·10¹⁹ cm^–3 obtained by the method of liquid-phase expitaxy for a Ge content in the solution of 0.4–12 at. % were investigated. Regularities are set up for the change in the Hall constant, the Hall hole mobility, and the CL spectra as a function of the impurity concentration and temperature, which are explained from the viewpoint of an impurity zone mode. On the basis of the data obtained it is assumed that the material properties studied are determined by the impurity centers Ge_As and (Ge_Ga-V_Ga).Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 65–69, January, 1989.     

Simultaneous determination of benomyl and morestan residues in waters by synchronous solid-phase spectrofluorimetry

In this paper a new, sensitive, and simple method for simultaneous determination of pesticides morestan and benomyl at trace levels in waters is reported. Both chemicals, showing native fluorescence in solution at neutral medium, were fixed on C-18 silica gel at pH 1, giving a fluorescent system. The benomyl-morestan-silica gel system, after dry, was packed in a 1-mm silica cell and its synchronous fluorescence spectra were recorded at =80 nm for determination of benomyl and =25 nm for determination of morestan. Measurements of fluorescence were performed at ₁=289 nm and ₂=367 nm for benomyl and morestan analysis, respectively. The applicable concentration ranges were from 0.5 to 15.0 ng·ml^–1 for benomyl and from 0.6 to 15.0 ng·ml^–1 for morestan, with relative standard deviations of 1.2 and 1.5% for benomyl and morestan, respectively, being 0.15 and 0.18 ng·ml^–1 its respective detection limits. The method was applied to the simultaneous determination of residues of both pesticides in water of different provenances.     

An IR-Radiometer with Internal Signal Modulation

An infrared (IR) radiometer electrical circuit on the basis of photoresistors and photodiodes made of silicon doped with zinc (Si) as well as the narrow bandgap semiconductor alloy Pb_0.78Sn_0.22Te is presented. In the circuit suggested a bridge with the photoreceiver connected to the radiometer input and immediately fed by signal generators functions as a radiation modulator. The threshold sensitivity turned out on a recorder is 2·10^–13 W·Hz^–1/2 (for the n⁺–n–n⁺ structures made of Si, =0.8–l.2m, T=300K); 1.4·10^–15W·Hz^–1/2 (for p⁺–n–n⁺ S-diodes on the basis of Si, =0.8–1.2m, T=300K) and 10^–12W·Hz^1/2 (for photodiodes on the basis of Pb_0.78Sn_0.22Te, =8–13m, T=77K).     

Anomalous plasma phenomena of hollow cathode arc discharge

Magnetically confined argon plasma produced by hollow cathode arc discharge has been studied in different experimental conditions, with discharge current from 10–50 A, vessel argon pressure between 10^–3 and 10^–4 torr (1 torr=133·32 Pa) and axial magnetic field up to 0·12 T. The plasma density measured by a cylindrical Langmuir probe is found to be 10¹⁹ to 4 × 10¹⁹ m^–3 and the electron temperatureT _e varies between 2·5 and 4·8 eV. When an external axial magnetic field is applied the plasma temperature decreases with the increase in the magnetic field intensity until it reaches a minimum value at 0·075T and then increases with the same rate. This has been interpreted as high frequency waves excitation due to electron beam-plasma interaction, which explains the electron density jumps with the magnetic field intensity. Enhanced plasma transport across the magnetic field is studied and classified as anomalous diffusion.