Symmetry-breaking and percolation transitions in a surface reaction model with superlattice ordering

A symmetry-breaking order-disorder transition of the Ising type is found in a nonequilibrium surface reaction model for CO oxidation incorporating superlattice ordering of adsorbed oxygen. We relate this transition to the percolation of superlattice domains of oxygen, and discuss the consequences for chemical diffusion of coadsorbed CO. The latter constitutes a new type of problem involving transport in disordered media.     

The High Temperature Ising Model on the Triangular Lattice is a Critical Bernoulli Percolation Model

We define a new percolation model by generalising the FK representation of the Ising model, and show that on the triangular lattice and at high temperatures, the critical point in the new model corresponds to the Ising model. Since the new model can be viewed as Bernoulli percolation on a random graph, our result makes an explicit connection between Ising percolation and critical Bernoulli percolation, and gives a new justification of the conjecture that the high temperature Ising model on the triangular lattice is in the same universality class as Bernoulli percolation.     

Universality of the ratio of the critical amplitudes of the magnetic susceptibility in a two-dimensional ising model with nonmagnetic impurities

The behavior of the magnetic susceptibility of a two-dimensional Ising model with nonmagnetic impurities is investigated numerically. A new method for determining the critical amplitudes and critical temperature is developed. The results of a numerical investigation of the ratio of the critical amplitudes of the magnetic susceptibility are presented. It is shown that the ratio of the critical amplitudes is universal right up to impurity concentrations q ≤ 0.25 (the percolation point of a square lattice is q _c = 0.407254). The behavior of the effective critical exponent γ(q) of the magnetic susceptibility is discussed. Apparently, a transition from Ising-type universal behavior to percolation behavior should occur in a quite narrow concentration range near the percolation point of the lattice.     

Agreement percolation and phase coexistence in some Gibbs systems

We extend some relations between percolation and the dependence of Gibbs states on boundary conditions known for Ising ferromagnets to other systems and investigate their general validity: percolation is defined in terms of the agreement of a configuration with one of the ground states of the system. This extension is studied via examples and counterexamples, including the antiferromagnetic Ising and hard-core models on bipartite lattices, Potts models, and many-layered Ising and continuum Widom-Rowlinson models. In particular our results on the hard square lattice model make rigorous observations made by Hu and Mak on the basis of computer simulations. Moreover, we observe that the (naturally defined) clusters of the Widom-Rowlinson model play (for the WR model itself) the same role that the clusters of the Fortuin-Kasteleyn measure play for the ferromagnetic Potts models. The phase transition and percolation in this system can be mapped into the corresponding liquid-vapor transition of a one-component fluid.     

Scaling Relations for Two-Dimensional Ising Percolation

We consider the percolation problem in the high-temperature Ising model on the two-dimensional square lattice at or near critical external fields. We show that all scaling relations, except for a single hyperscaling relation, hold under the power law assumptions for the one-arm path and the four-arm paths.     

Efficient algorithm for random-bond ising models in 2D

We present an efficient algorithm for calculating the properties of Ising models in two dimensions, directly in the spin basis, without the need for mapping to fermion or dimer models. The algorithm computes the partition function and correlation functions at a single temperature on any planar network of N Ising spins in O(N;{3/2}) time or less. The method can handle continuous or discrete bond disorder and is especially efficient in the case of bond or site dilution, where it executes in O(NlnN) time near the percolation threshold. We demonstrate its feasibility on the ferromagnetic Ising model and the +/-J random-bond Ising model and discuss the regime of applicability in cases of full frustration such as the Ising antiferromagnet on a triangular lattice.     

Island formation and condensation of a chemisorbed overlayer

The condensation of a chemisorbed overlayer from a lattice gas into a particular ordered structure in discussed in terms of the lattice-gas theory of Lee and Yang. The formation of islands of ordered structure is identified with the condensation phenomenon predicted by the theory. The phase diagram (transition temperature versus coverage) based on the theory of a two-dimensional Ising ferromagnet in zero magnetic field is constructed for the condensation of a lattice gas system with net attractive interactions between the particles. It is demonstrated that critical points at coverages other than θ = 0.5 are achieved for overlayer systems with unit meshes larger than (1 × 1). Low-energy electron diffraction results of the thermal disordering (island dissolution) for oxygen chemisorbed on W(110) are compared with the theory, and the effect of substrate surface heterogeneity on the phase diagram is discussed.     

Long-range connections, quantum magnets and dilute contact processes

In this article, we briefly review the critical behaviour of a long-range percolation model in which any two sites are connected with a probability that falls off algebraically with the distance. The results of this percolation transition are used to describe the quantum phase transitions in a dilute transverse Ising model at the percolation threshold p_c of the long-range connected lattice. In the similar spirit, we propose a new model of a contact process defined on the same long-range diluted lattice and explore the transitions at p_c. The long-range nature of the percolation transition allows us to evaluate some critical exponents exactly in both the above models. Moreover, mean field theory is valid for a wide region of parameter space. In either case, the strength of Griffiths McCoy singularities are tunable as the range parameter is varied.     

Clusters and Ising droplets in the antiferromagnetic lattice gas

A definition of clusters of particles and holes with antiferromagnetic order is given for a lattice gas with coupling constant K < 0. In two dimensions it is shown that the Ising antiferromagnetic critical line is also a percolation line if P_b = 1 - exp(-|K|/2). Along this line these clusters called “droplets” diverge with Ising exponents.     

A freezing transition in the lattice-gas model

In the lattice-gas model, condensation of a gas to its liquid phase is identified as the long range ordering transition in the equivalent Ising model. The same model has a second percolation transition at a lower temperature, which is identified here as the freezing transition of the liquid to its solid phase. It predicts that the mass diffusion in a liquid should decay near the freezing point T_F ≈ (T ? T_F)^t?β, where t is the conductivity exponent and β is the percolation probability exponent.     

Magnetic phase transitions in amorphous systems with competing exchange interactions

A method is proposed for analyzing magnetic phase transitions within the Ising model under the conditions of competing direct and indirect exchange interactions. It is demonstrated that the competition of exchange interactions leads to a reentrant phase transition between the ferromagnet and spin glass near the percolation threshold below the Curie temperature.     

Quantum phase transition in an atomic bose gas with a feshbach resonance

We show that in an atomic Bose gas near a Feshbach resonance a quantum phase transition occurs between a phase with only a molecular Bose-Einstein condensate and a phase with both an atomic and a molecular Bose-Einstein condensate. We show that the transition is characterized by an Ising order parameter. We also determine the phase diagram of the gas as a function of magnetic field and temperature: the quantum critical point extends into a line of finite temperature Ising transitions.     

Absence of re-entrant phase transition of the antiferromagnetic Ising model on the simple cubic lattice: Monte Carlo study of the hard-sphere lattice gas

We perform Monte Carlo simulations of the hard-sphere lattice gas on the simple cubic lattice with nearest neighbour exclusion. The critical activity is estimated, z_c = 1.0588 ± 0.0003. Using a relation between the hard-sphere lattice gas and the antiferromagnetic Ising model in an external magnetic field, we conclude that there is no re-entrant phase transition of the latter on the simple cubic lattice.     

A lattice gas coupled to two thermal reservoirs: Monte Carlo and field theoretic studies

We investigate the collective behavior of an Ising lattice gas, driven to non-equilibrium steady states by being coupled to two thermal baths. Monte Carlo methods are applied to a two-dimensional system in which one of the baths is fixed at infinite temperature. Both generic long range correlations in the disordered state and critical properties near the second order transition are measured. Anisotropic scaling, a key feature near criticality, is used to extract and some critical exponents. On the theoretical front, a continuum theory, in the spirit of Landau-Ginzburg, is presented. Being a renormalizable theory, its predictions can be computed by standard methods of -expansions and found to be consistent with simulation data. In particular, the critical behavior of this system belongs to a universality class which is quite different from the uniformly driven Ising model. Received 4 October 2000     

Low-concentration series in general dimension

We discuss recent work on the development and analysis of low-concentration series. For many models, the recent breakthrough in the extremely efficient no- free-end method of series generation facilitates the derivation of 15th-order series for multiple moments in general dimension. The 15th-order series have been obtained for lattice animals, percolation, and the Edwards-Anderson Ising spin glass. In the latter cases multiple moments have been found. From complete graph tables through to 13th order, general dimension 13th-order series have been derived for the resistive susceptibility, the moments of the logarithms of the distribution of currents in resistor networks, and the average transmission coefficient in the quantum percolation problem, 11th-order series have been found for several other systems, including the crossover from animals to percolation, the full resistance distribution, nonlinear resistive susceptibility and current distribution in dilute resistor networks, diffusion on percolation clusters, the dilute Ising model, dilute antiferromagnet in a field, and random field Ising model and self-avoiding walks on percolation clusters. Series for the dilute spin-1/2 quantum Heisenberg ferromagnet are in the process of development. Analysis of these series gives estimates for critical thresholds, amplitude ratios, and critical exponents for all dimensions. Where comparisons are possible, our series results are in good agreement with both-expansion results near the upper critical dimension and with exact results (when available) in low dimensions, and are competitive with other numerical approaches in intermediate realistic dimensions.     

Dynamic percolation transition induced by phase separation: A Monte Carlo analysis

The percolation transition of geometric clusters in the three-dimensional, simple cubic, nearest neighbor Ising lattice gas model is investigated in the temperature and concentration region inside the coexistence curve. We consider quenching experiments, where the system starts from an initially completely random configuration (corresponding to equilibrium at infinite temperature), letting the system evolve at the considered temperature according to the Kawasaki spinexchange dynamics. Analyzing the distributionn _l(t) of clusters of sizel at timet, we find that after a time of the order of about 100 Monte Carlo steps per site a percolation transition occurs at a concentration distinctly lower than the percolation concentration of the initial random state. This dynamic percolation transition is analyzed with finite-size scaling methods. While at zero temperature, where the system settles down at a frozen-in cluster distribution and further phase separation stops, the critical exponents associated with this percolation transition are consistent with the universality class of random percolation, the critical behavior of the transient time-dependent percolation occurring at nonzero temperature possibly belongs to a different, new universality class.     

First order phase transition in an anharmonic ising lattice

Criteria are derived for the existence of a first order phase transition in a compressible anharmonic Ising lattice. The analysis is based on a variational calculation and on the assumption that a compressible harmonic Ising lattice does not show a first order transition. A first order transition can occure only if the lattice and magnetic Grüneisen constants have the same sign and if the pressure is below some critical value. At this pressure the transition changes from first to second order. The results are applied to ammonium cloride exhibiting an order disorder transition of this type.     

3-d Model for strain ordering in steel: I Static effects

We present a spring-defect model in 3-dimensions to describe the connection between elastic distortion and interstitial carbon ordering associated with phase transition from a body centred cubic (BCC) to body centered tetragonal (BCT) structure in BCC metals such as α-iron. The presence or the absence of the carbon is modelled in terms of a pseudo spinŝ=+1or -l.An Ising interaction between carbon atoms is recovered after eliminating the lattice degrees of freedom, which is longranged. The coupling between the spin and lattice degrees of freedom allows for a systematic study of ferroelasticity and the variation of the lattice parameter with carbon concentration. The mean field results for the paraelastic to ferroelastic transition, lattice parameter and static compliance are presented. The significant feature of this calculation is not only a derivation of the defect-defect interaction, but also an explicit calculation of the strain dipole tensor associated with each defect, from a microscopic model.     

Two-dimensional ising models with competing interaction—a Monte Carlo study

Two-dimensional Ising models on a square lattice with competing interactions along one axis or both axes are studied primarily by the Monte Carlo method. Several commensurate-incommensurate transitions are found. Dislocation-like configurations are identified near the sinusoidal — paramagnetic transition in accordance with the idea that the transition might be of Kosterlitz-Thouless, XY-like character.     

Surface and corner magnetizations in the two-dimensional Ising model

We study the anisotropic Ising model on a square lattice with free boundary conditions. A simple explicit result is obtained for the surface magnetization of a system which is inhomogeneous near the surface. The corner magnetization is investigated for a 90° corner in a homogeneous anisotropic system. From the numerical results an analytical formula is found.