New properties of a class of generalized kinetic equations

We give some properties of a new class of hard-sphere kinetic equations of great generality, introduced earlier by Polewczak. The assumptions used to obtain the general class are very weak, and the equations include not only the standard and revised Enskog equations, but also generalizations thereof that can be expected to yield essentially exact transport coefficients. In particular, there is a natural two-particle realization that is obtained from maximizing the information entropy subject to prescribed two-particle and one-particle probability distribution functions;k-particle analogs fork > 2 also naturally follow. We obtain Liapunov functionals for the whole class of equations under consideration and discuss the question of which of these functionals can be expected to play the role ofH-functions. We also obtain several more special results that include new lower bounds on the potential part of theH-function for the revised Enskog equation. The bounds are instrumental in obtaining global existence theorems and also imply that the necessary condition for invertibility of the nonequilibrium extension of local activity as a functional of local density is satisfied.     

H-theorem for the (modified) nonlinear Enskog equation

We construct anH-function suitable for a system of dense hard spheres satisfying the (modified) nonlinear Enskog equation and we show that _t H 0. The equality sign holds only when the system has reached absolute equilibrium, in which caseS=– k_B H becomes the exact equilibrium entropy of the hard-sphere fluid.     

Nonexistence of H Theorem for Some Lattice Boltzmann Models

In this paper, we provide a set of sufficient conditions under which a lattice Boltzmann model does not admit an H theorem. By verifying the conditions, we prove that a number of existing lattice Boltzmann models does not admit an H theorem. These models include D2Q6, D2Q9 and D3Q15 athermal models, and D2Q16 and D3Q40 thermal (energy-conserving) models. The proof does not require the equilibria to be polynomials.     

Entropy Function Approach to the Lattice Boltzmann Method

In this paper, we present the construction of the Lattice Boltzmann method equipped with the H-theorem. Based on entropy functions whose local equilibria are suitable to recover the Navier–Stokes equations in the framework of the Lattice Boltzmann method, we derive a collision integral which enables simple identification of transport coefficients, and which circumvents construction of the equilibrium. We discuss performance of this approach as compared to the standard realizations.     

H-theorem for a linear kinetic theory

A strongH-theorem is proved for the approximate linear kinetic theory of Bawzdziewicz and Cichocki, obtained by truncating a transformed hierarchy of evolution equations. For an ith truncation we define an entropy functional that is strictly increasing in time, unless the ith reduced distribution function depends on position coordinates only. It also follows that the only stationary solution of the linear kinetic theory is the equilibrium solution. In addition, we show that the usual symmetry properties of equilibrium time correlation functions are preserved by the approximate kinetic theory under consideration.On leave of absence from Institute of Physics, Szczecin University, Wielkopolska 15, Szczecin, Poland.     

A nonequilibrium entropy for dynamical systems

It is proposed to define entropy for nonequilibrium ensembles using a method of coarse graining which partitions phase space into sets which typically have zero measure. These are chosen by considering the totality of future possibilities for observation on the system. It is shown that this entropy is necessarily a nondecreasing function of the timet. There is no contradiction with the reversibility of the laws of motion because this method of coarse graining is asymmetric under time reversal. Under suitable conditions (which are stated explicitly) this entropy approaches the equilibrium entropy ast+ and the fine-grained entropy ast–. In particular, the conditions can always be satisfied if the system is aK-system, as in the Sinai billiard models. Some theorems are given which give information about whether it is possible to generate the partition used here for coarse graining from time translates of a finite partition, and at the same time elucidate the connection between our concept of entropy and the entropy invariant of Kolmogorov and Sinai.Research supported in part by NSF grants PHY78-03816 and PHY78-15920.     

Exact solutions of the nonlinear Boltzmann equation

A review is given of research activities since 1976 on the nonlinear Boltzmann equation and related equations of Boltzmann type, in which several rediscoveries have been made and several conjectures have been disproved. Subjects are (i) the BKW solution of the Boltzmann equation for Maxwell molecules, first discovered by Krupp in 1967, and the Krook-Wu conjecture concerning the universal significance of the BKW solution for the large(v, t) behavior of the velocity distribution functionf (v, t); (ii) moment equations and polynomial expansions off (v, t); (iii) model Boltzmann equation for a spatially uniform system of very hard particles, that can be solved in closed form for general initial conditions; (iv) for Maxwell and non-Maxwell-type molecules there exist solutions of the nonlinear Boltzmann equation with algebraic decrease at ; connections with nonuniqueness and violation of conservation laws; (v) conjectured super-H-theorem and the BKW solution; (vi) exactly soluble one-dimensional Boltzmann equation with spatial dependence.Reference due to C. Cercignani.     

H-theorem for an infinite,one-dimensional,hard-point system

We use a well-studied soluble model to define a nonequilibrium entropy. This entropy has all the required properties; in particular, it is not time-reversal invariant, so that its monotonic increase in time also shows up after we perform a velocity inversion experiment.Supported financially by the Belgian Government, Actions de Recherches Concertées, Convention 76/81, II.3.     

Biased lattice gases with correlated equilibrium states

The approach to and structure of the equilibrium state is studied for a 7-bit lattice gas with biased forward and backward transition rates by means of mean field theory and computer simulations. If the rate constants obey the factorizability and the detailed balance conditions, the occupations of different velocity directions are uncorrelated, anH-theorem is valid, and a nonuniversal equilibrium state exists that depends explicitly on the transition rates. In case the above conditions are not satisfied, theH-theorem is no longer valid, and mean field theory also predicts nontrivial velocity correlations in postcollision states. The simulations are mainly concentrated on the time dependence of pre- and postcollision velocity correlations on a single node, and on slowly increasing fluctuations that might indicate metastable behavior.     

Entropy and irreversibility in a dilute gas of hard disks

The partition of the canonical entropy (invariant of motion) into a thermodynamic part 5th and a nonthermodynamic oneS _nonth, respectively increasing and decreasing functions of time for a system approaching equilibrium, was proposed by Prigogine and co-workers. This viewpoint is critically examined in the special case of an initially uncorrelated gas of hard disks. BothSth and the leading term ofS _nonth are evaluated for finite assemblies of 400,1600, and 6400 disks, by the method of molecular dynamics. There is good evidence that, in the limit of an infinite system, the Prigogine scheme is verified.On leave of absence from the University of Brussels, Belgium.     

TheH theorem and irreversible thermodynamics

Following a method first introduced by Prigogine, theH theorem is written as the law of increase of entropy for a slightly inhomogeneous gas. It is shown that the local rate of entropy production for such a gas is simply a homogeneous quadratic form of the generalized forces associated with the various irreversible processes with coefficients possessing all the properties of the phenomenological coefficients of irreversible thermodynamics. The local rate of entropy production is explicitly evaluated for a simple monatomic gas and is compared with the corresponding expression of irreversible thermodynamics.     

Nonlinear evolution equations andH theorems

We prove a structure theorem for evolution equations in the state space of a discrete classical system fulfilling a class ofH theorems. TheseH theorems are proved to give strong implications on the time behavior of the solutions. All the results are demonstrated by examples (Boltzmann-like equations, for example).     

Molecular dynamics of two-dimensional gases with realistic potentials

Molecular dynamics calculations have mainly used hard-core interactions because of computational simplicity and increased speed. Algorithms for realistic intermolecular potentials have been used in studies of solids and liquids. By combining both techniques, an algorithm which can reasonably study dilute gases with realistic potentials has been achieved. The BoltzmannH-function is calculated for a hard-core and Lennard-Jones gas, and the latter is found to decrease more rapidly to equilibrium.Work supported in part by the National Science Foundation under Grant No. NSF-USDP GU-1598 and the U. S. Air Force Office of Scientific Research under Grant No. AF-AFOSR 1257-67.     

Analogous study in low magnetic field between Cu–Ge and Cu–Si ferrites

Two series of mixed copper ferrites, Cu_1+x Ge_x Fe_2−2x O₄ and Cu_1+x Si_x Fe_2−2x O₄, have been analogously investigated for x=0.0, 0.05, 0.1, 0.15, 0.2, 0.25 and 0.3. The two systems were prepared using the standard ceramic techniques. X-ray diffraction analysis indicates that both systems formed in a single phase cubic spinel structure. The lattice parameter has a constant value (0.838 nm±0.001) for the two series. The grain diameter was estimated from the scanning electron microscope micrographs for the two series. Some magnetic properties were measured at room temperature. The magnetization M was measured in the range of magnetizing field up to 5500 Am⁻¹. The relative permeability (μ_r) was calculated from the B–H relation. The B–H loops were measured at constant magnetizing current (I=2.5 A which is equivalent to 900 Am⁻¹). Also, the hystersis area and the magnetic parameters B_r, B_s, m_R (B_r/B_s) and apparent energy loss (E) were estimated from the B–H loops; μ_r, B_r, B_s and E are composition dependent.     

一种双模叠加态光场的两种非线性高阶压缩效应

本文在发展现有理论的基础上提出了双模及多模辐射场的两种非线性高阶压缩(即N次方Y压缩和N次方H压缩)的定义,根据量子力学中的线性叠加原理构造了一美双模叠加志光场|ψ>,对|ψ>的N次方Y压缩及N次方H压缩效应进行了详细研究.结果表明:双模叠加态光场|ψ>是一种典型的非经典光场,它可具有任意阶的N次方Y压缩及N次方H压缩效应;并且,在一定的条件下,这两种非线性高阶压缩效应均可呈现出周期性变化的特性.文献7的单模辐射场振幅N次方压缩的定义,仅仅是本文所提出的N次方Y压缩和N次方H压缩这两种非线性高阶压缩的一般定义在k=1条件下的特例.     

The density functional study of the stabilities,bond characters,static linear polarisabilities,and aromaticities of the ’in-out’ isomerism Hn-60@CnH60（n=70,72,74）

This paper uses the density functional theory to analyse the stabilities,bond characters,static linear polarisabilities,and aromaticities of the ’in-out’ isomerism H n-60 @C n H 60 (n=70,72,74).The binding energies,C-H bond energies,and energy gaps explore that the ’in-out’ isometric perhydrogenation of C n (n=70,72,74) can remarkably improve the stabilities.The static linear polarisabilies of H n-60 @C n H 60 (n=70,72,74) are indeed relative to their shapes,while they show almost nonaromatic character.This study can suggest that the ’in-out’ isometric perhydrogenation of fullerenes could lead to the invention of entirely novel potential hydrogen storage nanomaterials.     

On solutions to the linear Boltzmann equation with general boundary conditions and infinite-range forces

This paper considers the linear space-inhomogeneous Boltzmann equation in a convex, bounded or unbounded bodyD with general boundary conditions. First, mildL ¹-solutions are constructed in the cutoff case using monotone sequences of iterates in an exponential form. Assuming detailed balance relations, mass conservation and uniqueness are proved, together with anH-theorem with formulas for the interior and boundary terms. Local boundedness of higher moments is proved for soft and hard collision potentials, together with global boundedness for hard potentials in the case of a nonheating boundary, including specular reflections. Next, the transport equation with forces of infinite range is considered in an integral form. Existence of weakL ¹-solutions are proved by compactness, using theH-theorem from the cutoff case. Finally, anH-theorem is given also for the infinite-range case.     

On intrinsic randomness of dynamical systems

We discuss the problem of nonunitary equivalence, via positivity-preserving similarity transformations, between the unitary groups associated with deterministic dynamical evolution and semigroups associated with stochastic processes. Dynamical systems admitting such nonunitary equivalence with stochastic Markov processes are said to beintrinsically random. In a previous work, it was found that the so-called Bernoulli systems (discrete time) are intrinsically random in this sense. This result is extended here by showing that a more general class of dynamical systems—the so-calledK systems andK flows—are intrinsically random. The connection of intrinsic randomness with local instability of motion is briefly discussed. We also show that Markov processes associated through nonunitary equivalence tononisomorphic K flows are necessarily non-isomorphic.Dr. Goldstein's research was supported in part by NSF Grant No. PHY78-03816.     

H∞ consensus control of a class of second-order multi-agent systems without relative velocity measurement

This paper studies consensus control problems for a class of second-order multi-agent systems without relative velocity measurement. Some dynamic neighbour-based rules are adopted for the agents in the presence of external disturbances. A sufficient condition is derived to make all agents achieve consensus while satisfying desired H_∞ performance. Finally, numerical simulations are provided to show the effectiveness of our theoretical results.