Break-Through Investigation on Uranium Isotope Separation in the System Uranyl Ion Solution Ti(III)-Cationic Resin

A break-through experiment on separation of uranium isotopes was carried out by use of a cation-exchange resin in Ti(III) form. By analyzing the experimental results the apparent equilibrium constants of the order K = 1·00021–1·00034 were determined.

The maximum value on the experimental curies of the isotopic ratio versus effluent volume was interpreted by considering two antagonistic isotope effects: one relatively large given by an exchange reaction between U(IV) in resin and U(VI) in solution and another smaller given by the reduction reaction of U(VI) with Ti(III). The difference of the equilibrium constants of the these two isotope effects as a function of temperature was used for the determination of the apparent thermodynamic values of the resultant process, determined experimentally: ΔH⁰ = 0.8542 cal mol^?1 and ΔS⁰ = 3.33×10^?3cal°K^?1.     

The New Kinetic Isotope Effect in the Ion Exchange and Liquid-Liquid Extraction Systems

The reaction kinetics of the isotope exchange and ion exchange process was studied on ion exchanger and liquid-liquid extraction systems. At least there were three exchangeable components in these systems (A, B and C); A and B are isòtopes of one element which have different concentrations (A ? B). It has been found that time function of the isotope separation factor has an extreme depending on the equilibrium, kinetic and hydrodynamic parameters.     

Study on the concentration difference heat pump using fusion and freezing processes of acetic acid-acetamide system

The concentration difference heat pump using fusion and freezing processes to generate a cold fluid has been investigated. This heat pump system utilizes the acetic acid-acetamide pair as working material, and consists of a cold fluid generating and a separation process. The operation at the cooling capacity of 3.52 kW (1 ton of refrigeration) has been investigated in this study. At the cold fluid generating process, solid acetic acid at 15°C is fused into an acetamide solution at 15°C, such that the temperature and the concentration of acetamide of the solution decreases. This dilute solution at lower temperature can be used to generate a cold fluid. The lowest attainable temperature of the solution has been investigated experimentally, and also calculated from the energy balance equation. The decreasing rates of the temperature have also been studied. At the separation process, continuous distillation is adopted to concentrate the dilute solution sent from the cold fluid generating process. The data which support the possibility of separation by continuous distillation are presented. The energy demand at the separation process is investigated theoretically.     

Experimental determination of one-and two-neutron separation energies for neutron-rich copper isotopes

A method is proposed to determine the one-neutron S_n or two-neutron S_(2n) separation energy of neutronrich isotopes.Relationships between S_n(S_(2n)) and isotopic cross sections have been deduced from an empirical formula,i.e.,the cross section of an isotope exponentially depends on the average binding energy per nucleon B/A.The proposed relationships have been verified using the neutron-rich copper isotopes measured in the 64 A Me V ~(86)Kr+~9Be reaction.S_n,S_(2n),and B/A for the very neutron-rich ~(77,78,79)Cu isotopes are determined from the proposed correlations.It is also proposed that the correlations between S_n,S_(2n) and isotopic cross sections can be used to find the location of neutron drip line isotopes.     

Letters to the Editor Instrumental Neutron Activation Analysis of Medieval Glasses from the First Bulgarian Capital – Pliska (9th Century)

Ion exchange chromatography of boric acid was carried out using an anion exchange resin in fluoride and chloride forms in order to investigate the temperature dependence of separation factor (S) for boron isotopes. The results are summarized as follows: For the fluoride form resin system, S? 1 = 1348/T² ? 0.0051 (between 5 °C and 35 °C) and for the chloride form resin system, S? 1 = 645/T² ? 0.0053 (between 5 °C and 50 °C) where T is the temperature in units of K.     

C60分子在有序-无序和玻璃态相变间的取向概率与弛豫行为

用极限动力学模型研究了Ｃ₆₀分子在有序-无序相变和玻璃态相变温度区间取向 角为98°和38°的取向概率与温度的关系.计算结果在玻璃态相变点附近的85K,90K和有序- 无序相变点的260K分别与实验值相吻合,取向概率对实验值更精确的拟合及其对温度的二阶 导数预言玻璃态相变点在84K.导出了弛豫规律,其结果表明：双能级的Ｃ₆₀分子从非平衡态到平衡态的弛豫行为与非指数因子β有关,其总的弛豫时间决定于其中一个较 短的弛豫时间,展宽指数形式保持不变.讨论了KWW方程的非 关键词： 60')" href="#">Ｃ₆₀ 取向概率 非平衡态弛豫     

Comparison of the Kinetics of the Exchange Mechanism of the Thallium Ion with 18C6 and with Pentaglyme in Acetonitrile Solutions

Abstract

In acetonitrile solutions, the exchange reaction is bimolecular in the Tl⁺ + 18C6 system, while in the Tl⁺ + pentaglyme system the associative-dissociative and the bimolecular mechanisms coexist at room temperature and the bimolecular exchange reaction dominates at 263° K. For the bimolecular mechanism in the case of Tl⁺ + 18C6 and the associative-dissociative mechanism in the case of Tl⁺ + pentaglyme, the activation energies of the exchange reactions change with temperature. At 298° K, in the Tl⁺ + 18C6 system the activation energy for the bimolecular exchange reaction is ≈ 2 kcal.mol^?1 and exchange rate constant (k₁) is (4.1 ± 0.1) × 10⁷ s^?1mol^?1; in the Tl⁺ + pentaglyme system, the activation energy for the associative-dissociative exchange reaction is ≈ 5 kcal mol^?1 and the decomplexation rate constant (k_?2) is (2.2 ± 0.4) X 10⁵ s^?1. The activation energy for the bimolecular exchange in the Tl⁺ + pentaglyme system was determined to be 3.00 ± 0.05 kcal.mol_?1 and the exchange rate constant (3.0 ± 0.1) X 10⁸ s^?1 mol^?1.     

Investigation of the fusion-fission reaction 12C+208Pb

For the first time the cross section and angular distributions of fission fragments have been measured for the compound nucleus 220 Ra produced in the reaction 12 C+ 208 Pb at three energy values in the range from 0.5 to 8.0 r MeV below the fusion barrier calculated in terms of the Bass model. In the investigated energy range there is a plateau characterized by the relation W (180°)/ W (90°)=1.2 in the angular anisotropy of fission fragments.     

Neutron ambient dose equivalent from 5 MeV/u 10,11B, 12,13C and 16,18O projectiles incident on a thick Al target

The neutron ambient dose equivalent has been measured from ¹⁰B, ¹¹B, ¹²C, ¹³C, ¹⁶O and ¹⁸O projectiles of energy 5 MeV/amu incident on a thick Al target at 0°, 30°, 60° and 90° with respect to the beam direction using a conventional dose equivalent meter. The calculated results obtained using previously reported empirical relations do not reproduce the experimental data. The results obtained from the PACE nuclear reaction code are closer to the experimental data as compared to the various empirical expressions. The ratio of the increase in the dose rates when the projectile is changed from the lighter to the heavier isotopes is fairly reproduced by most of the empirical formulations and the PACE code. A previously reported relation for the slope parameter is used to predict the directional distribution of the neutron dose for the projectiles used in this study. The calculated doses are lower than the experimental results in the forward directions but agree within the uncertainties at the backward directions. A new set of projectile-based parameters have been derived from the present experimental data which can be used in an empirical formulation.     

Annealing behaviour of arsenic implants in silicon

Abstract

The annealing behaviour of 80 keV room temperature arsenic implants in silicon below the amorphization dose has been studied by comparing the physical profile and the electrical profiles following different isochronal anneals.

It is shown that the electrically active fraction, which is about 0.4 after 30 min annealing at 600°C, increases continuously until 100% electrical activation of the arsenic ions is reached at about 900°C.

The activation energy for the annealing process has been found equal to 0.4 eV. A tentative interpretation of the mechanism involved is given.

From the analysis of the physical profiles obtained after isochronal annealing, an effective diffusion coefficient at 900°C equal to 5 × 10^?16 cm² s^?1 has been calculated.     

The adsorption of hydrogen and the reaction of hydrogen with oxygen on Pt (100)

The adsorption of hydrogen on Pt (100) was investigated by utilizing LEED, Auger electron spectroscopy and flash desorption mass spectrometry. No new LEED structures were found during the adsorption of hydrogen. One desorption peak was detected by flash desorption with a desorption maximum at 160 °C. Quantitative evaluation of the flash desorption spectra yields a saturation coverage of 4.6 × 10¹⁴ atoms/cm² at room temperature with an initial sticking probability of 0.17. Second order desorption kinetics was observed and a desorption energy of 15–16 kcal/mole has been deduced. The shapes of the flash desorption spectra are discussed in terms of lateral interactions in the adsorbate and of the existence of two substates at the surface. The reaction between hydrogen and oxygen on Pt (100) has been investigated by monitoring the reaction product H₂O in a mass spectrometer. The temperature dependence of the reaction proved to be complex and different reaction mechanisms might be dominant at different temperatures. Oxygen excess in the gas phase inhibits the reaction by blocking reactive surface sites. At least two adsorption states of H₂O have to be considered on Pt (100). Desorption from the prevailing low energy state occurs below room temperature. Flash desorption spectra of strongly bound H₂O coadsorbed with hydrogen and oxygen have been obtained with desorption maxima at 190 °C and 340 °C.     

A Turbidity Study of the Rate of Dissolution of Zinc-Monoglycerolate in Aqueous Solution

Abstract

The turbidity of suspensions of polymeric zinc monoglycerolate (ZMG) has been used to determine dissolution rates in aqueous solution. The rate was found to be first order with respect to the concentration of undissolved ZMG and of order 1/2 with respect to the hydrogen ion concentration in the pH range 4.1–5.8 and a temperature range of 20°C - 45°C. The temperature dependence at constant pH obeys the Arrhenius equation and the activation energy of the dissolution process was found to be near 35 k J mol^?1.     

Formation and characteristics of graded-index optical waveguides buried in glass

Low-loss optical waveguides have been prepared through thermally induced ion exchange, where sodium ions in glass are replaced by silver ions from an unstirred silver nitrate melt. The index distributions of the inhomogeneous guides produced in the glass are deduced by analysing the measured mode spectra with the WKB-method. The increase in the refractive index caused by the presence of the silver is found to have a nearly Gaussian form with a peak of about 0.082. The index profile is correlated to the two parameters of the preparation process, the diffusion time and the operating temperature. In a typical case (9 hrs and 221°C) the index takes on its maximum value 2.6 μm below the surface of the glass and one obtains an 8-mode guide with five modes buried within the glass and three modes extending to the air-glass interface.A single-mode guide is formed in less than 5 min. The measurements yield an activation energy for the diffusion of Ag⁺ in glass of 8.4·10⁴J/mole and a diffusion coefficient at 221°C of 0.67·10⁻¹² cm²/s, in good agreement with the experimental results reported by other authors. The present observations suggest that a potential gradient is set up in the glass when silver diffuses into it so that the silver ions drift into the glass with a velocity of about 0.3μm/hr.     

Reaction‐Induced Phase Separation in Polyoxyethylene/Polystyrene Blends. I. Ternary Phase Diagram

Abstract

Reaction‐induced, phase separation has been studied in polymer blends. A model crystalline‐amorphous system consisted of semicrystalline polyoxyethylene (POE) dissolved in the monomer styrene, which was used as a reactive solvent to ease processing. When the styrene was polymerized to polystyrene (PS) in the mold, phase separation and phase inversion are induced, and a polymer blend was formed. Polyoxyethylene was selected with a molar mass, M _n  = 8578 g mol^?1 and a polydispersity of 1.19, as determined by using gel permeation chromatography. The polymerization of styrene was initiated by using 1 wt% benzoin methyl ether and 0.2 wt% 2,2′‐azobisisobutyronitrile under ultraviolet light. The polymerization kinetics were determined by monitoring the reduction in the intensity of the C?C stretching vibration band at 1631 cm^?1 in the Raman spectrum of styrene. The onset times for the liquid–solid (L–S) phase separation and crystallization of POE from styrene/PS were observed by using simultaneous small‐angle x‐ray scattering (SAXS) and wide‐angle x‐ray scattering. Onset times for L–S phase separation determined from the SAXS data were combined with the styrene polymerization kinetics to plot the L–S phase separation data onto a ternary phase diagram for the reactive system POE/styrene/PS at 45°C and 50°C.     

Fabrication of porous metal fiber sintered sheet as a flow field for proton exchange membrane fuel cell

To improve the diffusion performance of reactive gas, a porous copper fiber sintered sheet (PCFSS) was fabricated and used as the flow field for proton exchange membrane fuel cell (PEMFC). The pressure and flow velocity distribution of the reaction gas in the PCFSS was firstly compared with the serpentine flow field by using the Fluent simulation software. Our results showed that the superiority of PCFSS in the uniformity of gas diffusion was observed. The total resistance of PEMFC with PCFSS in different porosities was obtained. And the advantages of PCFSS in electronic transmission were found by comparing with the serpentine flow field. Besides, the influences of different operating conditions and different porosities of porous flow fields on the performance of PEMFC were experimentally investigated. With the cell temperature of 70 °C as well as the humidification temperature of 60 °C, a PEMFC with PCFSS of 70% porosity exhibited better performance.     

Study of the structural phase transformation,and optical behavior of the as synthesized ZnO–SnO2–TiO2 nanocomposite

Bulk nanocomposites ZnO–SnO₂–TiO₂ were synthesized by solid-state reaction method. The X-ray diffraction patterns and Raman spectra of bulk nanocomposite as a function of sintering temperature (700 °C–1300 °C) indicate that the structural phases of SnO₂ and TiO₂ depend on the sintering temperature while the ZnO retains its hexagonal wurtzite phase at all sintering temperatures and SnO₂ started to transform into SnO at 900 °C and completely converted into SnO at 1100 °C, whereas the titanium dioxide (TiO₂) exhibits its most stable phase such as rutile at low sintering temperature (≤900°C) and it transforms partially into brookite phase at high sintering temperature (≥ 900 °C). The optical band gap of nanocomposite ZnO–SnO₂–TiO₂ sintered at 700 °C, 900 °C, 1100 °C and 1300 °C for 16 hours is calculated using the transformed diffuse reflectance ultra violet visible near infra red (UV–VisNIR) spectra and has been found to be 3.28, 3.29, 3.31 and 3.32 eV, respectively.     

Calculation of the Thermal Parameters of Boron Silicide by Differential Scanning Calorimetry

The DSC, TG, DTA, and DTG analyses of boron silicides, which are widely applied in radiation material science and nuclear technology, have been performed depending on the thermal treatment rate. The kinetic parameters (energy, enthalpy, oxidation reaction rate, heat capacity, and activation energy) of effects occurring in the thermal treatment of boron silicides of 99.5% purity within a temperature range of 25–900°C at a rate of 5–20°C/min have been established. It has been established that the phase transition typical for silicides with its central peak at a temperature 572 ± 5°C can exist in boron silicides depending on the thermal treatment rate. In TG and DTG spectra, this appears as an oxidation thermal effect at T ≥ 660°C with a change increase in mass of nearly 9%.     

Experimental investigation of the effect of nozzle numbers on Ranque–Hilsch vortex tube performance

The present study investigates the effects of the orifice nozzle number and the inlet pressure experimentally on the cooling performance of the counter flow-type vortex tube. The energy generation has been conducted using a stream-tek generator (model GNMD-KIT) with different numbers of nozzles (2, 3, and 6), an aspect ratio of 1:6, and an inner diameter of 7.5 mm. In the experiments, for each of the orifices, inlet pressures have been adjusted from 200–600 kPa. The energy separation investigated here focuses on the cold temperature difference and coefficient of performance for cooling. The experimental results concluded in this article prove that the greatest effect of nozzle number is for three nozzles, and hence, that nozzle number could affect the energy separation efficiently. A comparison of the present experiments with other published works has been conducted. An analytical study of the characteristics equation has been carried out to evaluate the best correlation of the ratio of cold temperature difference to the inlet temperature as a function of pressure, cold mass fraction, and nozzle number.     

Evaluation of Ph and granite/hot water interaction under geothermal conditions

Abstract

The in-situ laboratory measurement of pH in a granite-hot water reaction system has been undertaken under flowing conditions. The calculation of fluid pH and multi-component chemical equilibria in the granite-hot water reaction system was made, using the calculation program SOLVEQ92. In this study, the chemical equilibrium relationship of granite and hot water interaction was also deduced using the some program. The measurement of in-situ pH in the granite-hot water reaction system was undertaken in the temperature and pressure range of 100–250°C and 20MPa respectively. The in-situ pH value shows good agreement with the pH calculation value with regard to multi-component chemical equilibria. As a result of this work, it is reasonable to suggest that the pH of reservoir fluids in geothermal system can be readily estimated by use of the SOLVEQ92 calculation program, which provides a ‘calculated’ pH value.     

Differential thermal analysis at high pressures—VII: Phase behaviour of solid methanol up to 3kbar

The phase behaviour of solid methanol was investigated from -196°C to the melting temperature and up to 3 kbar, using a low-temperature high-pressure dta apparatus. The melting temperature rises from -98°C at 1 atm to -64°C at 2775 bar. Solid methanol exhibits a transition at atmospheric pressure at approximately -115°C; the transition has a strong tendency to superheat and to occur at -110°C. The transition temperature rises from approximately -115°C at 1 atm to -81°C at 2725 bar. Small impurities of water induce a “second transition” at -117.3°C that must be attributed to the water-methanol eutectic. Volume changes accompanying the phase transition have been calculated using the Clausius Clapeyron equation.