Transport properties of a Van der Waals fluid near the critical point

The behaviour of the transport coefficients of a Van der Waals fluid is studied in the one-phase region along the critical isochore of the liquid-vapour phase transition. When $\text{?=}\text{(T?T}{}_{\mathrm{c}}\text{)}\text{T}{}_{\mathrm{c}}\text{→0}$ the strongest singularity is found in the case of the bulk viscosity (??^?2). The divergence of the heat conductivity is shown to be weaker than $\text{?}{}^{\mathrm{<mtext>?</mtext><mtext>1</mtext><mtext>3</mtext>}}$. The shear viscosity tends to a finite limit. The coefficients of the asymptotic laws are explicitly given. All the results are established in the region where the Ornstein-Zernike theory applies.     

Electric field effect on the critical opalescence in cyclohexane-methanol

Intensity decrease of the Rayleigh scattered light in a critical mixture of cyclohexane-methanol was observed in the temperature range $\text{1 × 10}{}^{\mathrm{?4}}\text{? ? ≡ ∣T - T}{}_{\mathrm{c}}\text{∣}\text{T}{}_{\mathrm{c}}\text{? 4 × 10}{}^{\mathrm{?2}}$ with ac electric field applied.     

A Mössbauer study of amorphous Fe40Ni40B20

Amorphous Fe₄₀Ni₄₀B₂₀ (VITROVAC 0040) alloy has been investigated using ⁵⁷Fe Mössbauer Spectroscopy. The Curie temperature T_c is found to be well defined and is 695 ± 1 K. The quadrupole splitting just above T_c is 0.64 mm sec^?1. The crystallization temperature is 698 ± 2 K, close to but definitely above T_c. The average hyperfine field H_eff(T) of the glassy state shows a temperature dependence of $\text{H}{}_{\mathrm{<mtext>eff</mtext>}}\text{(0)[1 ? B}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{(T/T}{}_{\mathrm{c}}\text{)}{}^{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{? C}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{(T/T}{}_{\mathrm{c}}\text{)}{}^{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{? …]}$ indicative of the existence of spin wave excitations. The values of $\text{B}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ and $\text{C}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ are found to be 0.40 and 0.06, respectively, for T/T_c ? 0.72. At temperatures close to T_c, H_eff(T) varies as (1 ? T/T_c)^β where β is one of the critical exponents and its value is found to be 0.29 ± 0.02.     

Density of states in dirty type II superconductors near Tc

We have determined the behavior of the density of states in the mixed state of superconducting alloys for T → T_c. The local density of states tends towards the BCS expression with the order parameter playing the role of the energy gap. The singularities are smeared out by the spatial average. The effective normal core radius of a vortex diverges like $\text{(1 ?}\text{T}\text{T}{}_{\mathrm{c}}\text{)}{}^{\mathrm{<mtext>?</mtext><mtext>1</mtext><mtext>3</mtext>}}$ for T → T_c unlike the coherence length which diverges like $\text{(1 ?}\text{T}\text{T}{}_{\mathrm{c}}\text{)}{}^{\mathrm{<mtext>?</mtext><mtext>1</mtext><mtext>2</mtext>}}$.     

Functional derivative δTc/δα2 (Ω)F(Ω) for weak coupling superconductors

We present approximate analytic calculation of the functional derivative $\text{δT}{}_{\mathrm{c}}\text{δα}{}^2\text{(Ω)F(Ω)}$, where T_c is the superconducting critical temperature and $\text{α}{}^2\text{(Ω)F(Ω)}$ is the electron-phonon spectral function, within the “square-well model” for the phonon mediated electron-electron interaction and weak coupling limit $\text{ω}{}_{\mathrm{D}}\text{(2πT}{}_{\mathrm{c}}\text{)? 1 (ω}{}_{\mathrm{D}}$ is the Debye energy). It is found that $\text{δT}{}_{\mathrm{c}}\text{δα}{}^2\text{(Ω)F(Ω) = (1 + λ)}{}^{-1}\text{G(Ω)}$ where λ is the familiar electron-phonon coupling parameter and $\text{G(Ω)}$ is a universal function of the reduced frequency $\text{Ω}\text{=}\text{Ω}\text{T}{}_{\mathrm{c}}$. We compare this formula with accurate numerical results for several weak coupling superconductors. The overall agreement is good     

The measurement of the rotational relaxation times of OCS from the nutation signals

The time dependence of microwave absorption was measured for the J = 2-1 and J = 3-2 transitions of OCS under on- and off-resonant conditions utilizing Stark and source modulation, respectively. The two effective pressure parameters obtained under the two conditions, which correspond to $\text{(T}{}_2{}^{\mathrm{?1}}\text{+ T}{}_1{}^{\mathrm{?1}}\text{)}\text{4πP}$ and $\text{(2πT}{}_2\text{P)}{}^{\mathrm{?1}}$, respectively, according to the Bloch equation, are different beyond experimental error; the difference $\text{(T}{}_2{}^{\mathrm{?1}}\text{? T}{}_1{}^{\mathrm{?1}}\text{)}\text{2πP}$ is 0.94 ± 0.38 (2.5σ) MHz/Torr for J = 2?1. This difference was also determined to be 1.19 ± 0.30 MHz/Torr from the dependence of the nutation frequency on the microwave power.     

Properties of anisotropic superconductors containing impurities in SR model

The Josephson current for an anisotropic superconductor, described by Shiba-Rusinov model, containing paramagnetic impurities is calculated by an extension of the theory of Nagi and Upadhyayya. The slope $\text{S}{}^1$ of $\text{J}{}_{\mathrm{s}}\text{(}\text{C}\text{?}\text{, T,}\text{Ω}\text{?}\text{)}$ against temperature T near T_c is also computed and compared with the limiting isotropic case. Thermodynamic critical field $\text{H}{}_{\mathrm{c}}\text{(}\text{C}\text{?}\text{, T,}\text{Ω}\text{?}\text{)}$ for an anisotropic superconductor is also investigated.     

Critical spin relaxation in GdCl3

In the critical region of the insulating, uniaxial ferromagnet GdCl₃ the real part of the uniform susceptibility χ(q = 0, ω; T) has been measured by means of a frequency counting method in the ranges $\text{1.7 MHz ?}\text{ω}\text{2π}\text{? 720 MHz, 0.003 ? (}\text{T}\text{T}{}_{\mathrm{c}}\text{? 1 ≡ ?) ? 0.5}$. Parallel to the easy direction at all temperatures, χ′(ω) has a lorentzian shape, its amplitude being equal to the static susceptibility, χ_T. The half-widths τ^?1 exhibit s critical slowing down: above ?_c = 0.03 they are proportional to χ^?1_T, while at ?_c a change-over to $\text{τ}{}^{\mathrm{?1}}\text{∝ χ}{}^{\mathrm{<mtext>?</mtext><mtext>1</mtext><mtext>2</mtext>}}{}_{\mathrm{T}}$ occurs, the origin of which is uncertain.     

Critical slowing down of fluctuations in squaric acid (H2C4O4) at the phase transition observed by 13C spin-lattice relaxation

Spin lattice relaxation T₁ of naturally abundant ¹³C nuclei in squaric acid was measured close to the antiferroelectric-paraelectric phase transition temperature T_c = 373 K. A rapid increase in $\text{1}\text{T}{}_1$ is observed close to T_c coming from above, which follows the power law $\text{1}\text{T}{}_1\text{～ ε}{}^{\mathrm{?1.4}}$ where $\text{ε =}\text{(T ? T}{}_{\mathrm{c}}\text{)}\text{T}{}_{\mathrm{c}}$. This behaviour is explained on the basis of the two-dimensional character of the fluctuations.     

Two-scale-factor universality near the critical point of fluids

Experimental evidence is presented in support of the validity of the hypothesis of two-scale-factor universality for the correlation function of fluids near the gas-liquid critical point. For Xe, SF₆, and CO₂, the dimensionless quantity $\text{R = ξ}{}_0\text{(}\text{B}{}^2\text{P}{}_{\mathrm{c}}\text{Γk}{}_{\mathrm{B}}\text{T}{}_{\mathrm{c}}\text{)}{}^{\mathrm{<mtext>1</mtext><mtext>3</mtext>}}$ is universal within the experimental accuracy of 10% and agrees with the value predicted by theory.     

Phase transition and phonon-drag conductivity in quasi-unidimensional systems

We investigate the properties of a quasi-unidimensional system which exhibits Peierls instability at T_c(μ), where μ is the Fermi energy as measured from the middle of the conduction band. T_c(μ) decreases as 6μ6 increases. The phonon-drag diagrams contribute to fluctuation conductivity, which is proportional to $\text{(T ? T}{}_{\mathrm{c}}\text{)}{}^{\mathrm{<mtext>?</mtext><mtext>1</mtext><mtext>2</mtext>}}$, if |μ| > 1.056 T_c(0). The Kohn Anomalies do not occur at 2k_F unless μ = 0 or |μ| ? T.     

Coriolis intensity perturbations in the SO2 molecule: Experimental determination of the relative signs of (∂μ∂Qi)

The Coriolis interactions between ν₁ and ν₃, and between ν₂ and ν₃ in SO₂ have been analyzed to obtain the signs of the products $\text{ζ}{}_{3.1}{}^{\mathrm{c}}\text{(}\text{?μ}{}^{\mathrm{a}}\text{?Q}{}_3\text{)(}\text{?μ}{}^{\mathrm{b}}\text{?Q}{}_1\text{)}$ and $\text{ζ}{}_{3.2}{}^{\mathrm{c}}\text{(}\text{?μ}{}^{\mathrm{a}}\text{?Q}{}_3\text{)(}\text{?μ}{}^{\mathrm{b}}\text{?Q}{}_2\text{)}$. It has been found that both of the signs of these products are positive. Then, relative signs of ($\text{?μ}\text{?Q}{}_1$) have been determined using the calculated values of the Coriolis zeta constants for the present definition of the normal coordinates. The obtained sign combination of ($\text{?μ}\text{?Q}{}_{\mathrm{i}}$) is ±(+?+), which agrees with the one predicted by the molecular orbital calculations. Using the sign combination (+?+), the polar tensors of S and O atoms were also calculated.     

Derivation of the dielectric loss formula (a theory of dielectric relaxation in glassy systems)

The derivation is given of the empirical formula tan $\text{σ = A(ω)[}\text{1}\text{B}\text{(T?T}{}_{\mathrm{c}}\text{)]}{}^2\text{sech}{}^2\text{[}\text{1}\text{B}\text{(T?T}{}_{\mathrm{c}}\text{)]}$, where A (ω), B and T_c are constants of the dipolar material at constant applied frequency ω, which has been shown to be in excellent agreement with experimental dielectric loss data on polymers and other amorphous glasses. The derivation is based on the dynamics of a two-level model. The energy splitting, Δ, of the system is derived and determined experimentally for polymers.     

Effects of composition on the upper critical field of V-Ga

Measurements of the temperature dependence of the upper critical field, H_c2(T), for a series of V_100?xGa_x materials are presented for 20.5 ≤ × ≤ 29.6. Fits of the data to conventional theory for a paramagnetically limited, dirty, type II superconductor show: 1) a maximum in T_c and H_c2(0) for x ? 25; 2) a constant ( for x ≤ 25; 3) a slowly increasing value of λ_so with increasing x up to x ～ 25; and 4) good agreement with stoichiometric ordered and thermally disordered V₃Ga. Above $\text{x ? 25}$ broader transitions are observed. For x = 25, T_c = 15.3 K, (, λ_so = 0.3 and H_c2(0) = 23.4 tesla. The effects of inclusion of strong-coupling in the theory are discussed briefly.     

Paramagnetic resonance study of fluctuations near phase transition in triglycine sulphate

The EPR line widths of the high and the low field resonances of Cr³⁺ in triglycine sulphate (TGS) show two distinct anomalous broadenings near T_c. One is associated with a change in the motional frequency of the hindered rotation of the NH₃ groups and the other is related to the fluctuation of the polarization. Just below T_c there is a two fold splitting of the resonances which has a$\text{(}\text{T}{}_{\mathrm{c}}\text{?}\text{T}\text{)}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ temperature dependence indicating the local geometry about the Cr³⁺ ion is determined by mean field theory.     

Non-analyticity of the entropy and Nernst's law in random spin systems

It is shown explicitly for a soluble model that a random spin system can have an entropy which is non-analytic at (H = 0, T = 0), with $\text{(}\text{?S}\text{?H}\text{)}{}_{\mathrm{H=0}}$ and/or $\text{(}\text{?}{}^2\text{S}\text{?H}{}^2\text{)}{}_{\mathrm{H=0}}$non-vanishing in the T → 0 limit, while nevertheless Nernst's law is satisfied.     

Investigation of the central component of SrTiO3 by neutron scattering with eV resolution

We studied the energy width and the width in reciprocal space Δq of the central mode of SrTiO₃ above T_c. At T_c+4° we observed an energy width of about 6×10^?7 eV. If the measured Δq is interpreted by a correlation length $\text{Δq}{}^{\mathrm{?1}}\text{= ξ = ξ}{}_0\text{?}{}^{\mathrm{<mtext>?</mtext><mtext>2</mtext><mtext>3</mtext>}}$ we obtain $\text{ξ}{}_0\text{= 75}\text{A}\text{?}$.     

The ultraviolet absorption spectrum of thioformaldehyde

The spectra of H₂CS and D₂CS were surveyed over the wavelength region from 230 to 180 nm and four distinct absorptions were identified. These are assigned to transitions from the $\text{X}\text{?}{}^1\text{A}{}_1$ ground state to the $\text{B}\text{?}{}^1\text{A}{}_1\text{(π, π}{}^1\text{)}$, $\text{C}\text{?}{}^1\text{B}{}_2\text{(n, 3s)}$, $\text{D}\text{?}{}^1\text{A}{}_1\text{(n, 3p}{}_{\mathrm{y}}\text{)}$, and $\text{E}\text{?}{}^1\text{B}{}_2\text{(n, 3p}{}_{\mathrm{z}}\text{)}$ electronic states. A vibrational and rotational analysis of the second system was undertaken. The results indicate that the molecule is planar in the $\text{C}\text{?}{}^1\text{B}{}_2\text{(n, 3s)}$ state and that while the CH and CS bond lengths remain near their ground-state values, the HCH angle increases substantially.     

Critical small-angle X-ray scattering of the liquid sodium-lithium system

Small-angle X-ray scattering of the liquid sodium-37 w/o lithium system in the range $\text{1.034 × 10}{}^{-4}\text{? (T?T}{}_{\mathrm{<mtext>c</mtext>}}\text{)/T}{}_{\mathrm{<mtext>c</mtext>}}\text{?}\text{1.503 × 10}{}^{-2}$ yields the critical exponents v = 0.655 ± 0.030 and λ = 1.296 ± 0.061 for the temperature dependence of the correlation length η and of the coefficient (?c/?μ)_{T, P} respectively.