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1.
V. V. Sharutin V. S. Senchurin O. K. Sharutina B. B. Kunkurdonova 《Russian Journal of Inorganic Chemistry》2011,56(9):1384-1389
Complexes [Me3EtN]2+[CoI4]2− (I) and [Me3EtN]2+[CoI4]2− (II) were synthesized by reacting trimethylalkylammonium iodide with cobalt(II) iodide in acetone. According to X-ray diffraction
data, complexes I and II consist of tetrahedral tetraalkylammonium cations (for I, N-C is 1.481(5)–1.590(8) CNC is 107.3(3)°–111.6(3)°; for II, N-C is 1.485(8)–1.506(10) ? and CNC is 106.9(7)°–111.7(5)°) and [CoI4]2− anions (for I, Co-I is 2.5951(5)–2.6127(5) ? and ICoI is 104.67(2)°–113.23(2)°; for II, Co-I is 2.5914(8)–2.5943(9) ? and ICoI is 107.05(2)°–114.42(5)°). 相似文献
2.
M. A. Il’in E. V. Kabin V. A. Emel’yanov I. A. Baidina V. A. Vorob’yov 《Journal of Structural Chemistry》2009,50(2):328-334
Methods for the synthesis of trans-diammino complexes [RuNO(NH3)2(NO2)2(OH)] (I) and [RuNO(NH3)2(H2O)(NO3)2](NO3)·H2O (II) are suggested. The compounds were studied by IR spectroscopy and X-ray phase and X-ray structural analyses. Crystal data:
space group P-1; a = 6.2328(2) ?, b = 11.0488(3) ?, c = 11.0981(4) ?, α = 71.942(1)°, β = 83.291(1)°, γ = 86.877(1)° (I); space group P21; a = 6.6290(2) ?, b = 13.4389(5) ?, c = 7.0180(2) ?, β 114.281(1)° (II). Complex II readily lost some part of crystal water on storage in open air.
Original Russian Text Copyright ? 2009 by M. A. Il’in, E. V. Kabin, V. A. Emel’yanov, I. A. Baidina, and V. A. Vorob’yov
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 50, No. 2, pp. 341–348, March–April, 2009. 相似文献
3.
The spectral kinetic characteristics of the triplet states of 1-(4-nitrophenyl)-3-methylpyrazole (1) and 1-ethyl-3-(4-nitrophenyl)-5-chloropyrazole (2) were studied by the laser nanosecond photolysis technique in different solvents. The triplet lifetimes (τT) of molecules 1 and 2 were found to depend strongly on the solvent nature. An increase in τT by approximately two orders of magnitude on going from nonpolar and polar aprotic solvents (τT ≤ 15 ns) to aqueous-acetonitrile solutions (τT = 1100 ns for a volume acetonitrile to water ratio of 1 : 3) was analyzed, taking into account the influence of the medium
on the relative contribution of the n,π*- and π,π*-configurations to the lowest triplet state.
__________
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1115–1119, May, 2005. 相似文献
4.
V. V. Sharutin V. S. Senchurin O. K. Sharutina A. P. Pakusina O. A. Fastovets 《Russian Journal of Inorganic Chemistry》2010,55(9):1415-1420
Triphenylbenzylphosphonium tetrachloroaurate (I) and triethanolammonium tetrachloroaurate hydrate (II) were prepared by reacting tetrachloroauric acid in acetone with triphenylbenzylphosphonium and triethanolammonium, respectively.
Triphenylethylphosphonium hexachlorodicuprate (III) was synthesized from triphenylethylphosphonium chloride and copper chloride in acetone. The crystal structures of complexes
I to III were determined by single-crystal X-ray diffraction. The phosphorus atoms in complex I have a nearly undistorted tetrahedral coordination (CPC, 108.3°–110.6°; P-C, 1.788–1.793 ?). The coordination of nitrogen
atoms in the cations of complex II is a distorted tetrahedron (CNC, 111.7°–112.4°). The square coordination of aurum in I and II is only slightly distorted: the ClAuCl angles are 89.6°–90.3° (I) and 89.5°–90.6° (II) and the Au-Cl distances are 2.256–2.278 ? I) and 2.280–2.285 ? (II). The phosphorus atoms in complex III are tetracoordinated (CPC, 106.34°–111.73°; P-C, 1.790–1.795 ?). The copper atoms in III have a distorted tetrahedral coordination (ClCuCl, 98.48°–144.85°; Cu-Cl, 2.1999–2.3263 ?). The central fragment Cu2Cl2 in the anion of complex III is bent relative to the Cu2 axis (the chlorine atom deviates from the Cu2Cl plane by 0.27 ?). 相似文献
5.
V. V. Sharutin V. S. Senchurin O. K. Sharutina O. A. Fastovets A. P. Pakusina 《Russian Journal of Inorganic Chemistry》2010,55(9):1410-1414
Complexes Ph3(n-Pr)P2+[CoI4]2− (I) and [Ph3(n-Am)P]2+ [CoI4]2− (II) were synthesized by reactions of triphenyl(alkyl)phosphonium iodide with cobalt(II) iodide in acetone. According to the
X-ray diffraction data, complexes I and II consist of tetrahedral triphenyl(alkyl)phosphonium cations (for I, P-C is 1.787(4)–1.804(4) ? and CPC is 106.73(18)°–111.4(18)°; for II P-C is 1.786(6)–1.802(6) ? and CPC is 107.6(3)°–111.7(3)°) and [CoI4]2− anions (Co-I 2.5923(6)–2.6189(6) ?, ICoI 101.86(2)°–113.25(2)° for I; Co-I 2.5899(9)–2.6171(9) 107.01(3)°–110.47(3)° for II). 相似文献
6.
Griesser U. J. Weigand D. Rollinger J. M. Haddow M. Gstrein E. 《Journal of Thermal Analysis and Calorimetry》2004,77(2):511-522
Five crystal polymorphs of the herbicide metazachlor (MTZC) were characterized by means of hot stage microscopy, differential
scanning calorimetry, IR- and Raman spectroscopy as well as X-ray powder diffractometry. Modification (mod.) I, II and III°
can be crystallized from solvents and the melt, respectively, whereas the unstable mod. IV and V crystallize exclusively from
the super-cooled melt. Based on the results of thermal analysis and solvent mediated transformation studies, the thermodynamic
relationships among the polymorphic phases of metazachlor were evaluated and displayed in a semi-schematic energy/temperature-diagram.
At room temperature, mod. III° (T
fus =76°C, Δfus
H
III =26.6 kJ mol-1) is the thermodynamically stable form, followed by mod. II (T
fus =80°C, Δfus
H
II =23.0 kJ mol-1) and mod. I (T
fus =83°C, Δfus
H
II=19.7 kJ mol-1). These forms are enantiotropically related showing thermodynamic transition points at ~55°C (T
trs, III/II), ~60°C (T
trs, III/I) and ~63°C (T
trs, II/I). Thus mod. I is the thermodynamically stable form above 63°C, mod. III° below 55°C and mod. II in a small window between
these temperatures. Mod. IV (T
fus =72-74°C, Δfus
H
II =18.7 kJ mol-1) and mod. V (T
fus =65°C) are monotropically related to each other as well as to all other forms. The metastable mod. I and II show a high kinetic
stability. They crystallize from solvents, and thus these forms can be present in commercial samples. Since metazachlor is
used as an aqueous suspension, the use of the metastable forms is not advisable because of a potential transformation to mod.
III°. This may result in problematic formulations, due to caking and aggregation.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
7.
H-ZSM-5 (Si/Al = 10.6 and 20) efficiently catalyzes the transformation of ethanol into C5-C12 gasoline hydrocarbons in 27–33 mass % yield at 320°C and feed rate 20 mmol C2H5OH/(gcat·h). Only ethylene is produced on the mesoporous zeolite H-ZSM-5/Al-MCM-41 with 100% ethanol conversion. This discrepancy
may be attributed to blockage of the ZSM-5 micropores in the mesoporous zeolite structure. 相似文献
8.
M. M. Monchak A. V. Pavlyuk V. V. Kinzhibalo M. G. Mys’kiv 《Russian Journal of Coordination Chemistry》2009,35(6):405-410
The alkylation of ethylenediamine with allyl bromide in the presence of a fourfold (with respect to ethylenediamine) molar
amount of NaHCO3 in acetone with an ethanol admixture (15: 1) affords LBr2 · 2H2O (I), where L2+ is the N,N,N,N′,N′,N′-hexaallylethylenediaminium cation. Single crystals of complexes L[CuII(Br0.45Cl3.55)] (II), L[Cu4I(Br4.55Cl1.45)] (III), and L[Cu4IBr6] (IV) are prepared by ac electrochemical synthesis from an ethanolic solution of LBr2 · 2H2O, CuCl2 · 2H2O (or CuBr2) at copper wire electrodes. The crystal structures of compounds I–IV are determined by X-ray diffraction analysis. The crystals of complex I are monoclinic: space group P21/n, a = 8.544(3), b = 10.404(3), c = 13.350(4) ?, β = 97.29(3)°, V = 1177.2(6) ?3, Z = 2. The bromine anions in compound I are bonded to the L2+ cations and water molecules through hydrogen contacts (E)H…Br (E = O, C) of 2.57(3)–2.86(3) ?. The crystals of compounds
II–IV are triclinic: space group P
. For II: a = 8.762(4), b = 9.163(4), c = 16.500(6) ?, α = 95.62(4)°, β = 96.39(4)°, γ = 111.46(4)°, V = 1211.4(9) ?3, Z = 2; for III: a = 9.074(4), b = 9.435(4), c = 9.829(5) ?, α = 116.12(4)°, β = 104.14(4)°, γ = 100.22(4)°, V = 692.3(6) ?3, Z = 1; for IV isostructural III: a = 9.084(4), b = 9.404(4), c = 9.869(4) ?, α = 116.31(3)°, β = 104.00(3)°, γ = 100.37(3)°, V = 692.1(5) ?3, Z = 1. Unlike the isolated tetrahedral CuX42− anion in structure II, an original chain anion (Cu4X62−)
n
is observed in the structures of π complexes III and IV.
Original Russian Text ? M.M. Monchak, A.V. Pavlyuk, V.V. Kinzhibalo, M.G. Mys’kiv, 2009, published in Koordinatsionnaya Khimiya,
2009, Vol. 35, No. 6, pp. 414–419. 相似文献
9.
T. G. Kuznetsova K. G. Ione L. V. Malysheva 《Reaction Kinetics and Catalysis Letters》1998,63(1):61-66
Gas phase nitration of benzene on ZSM-5 zeolite has been studied at 140–170°C. Increase in the HNO3/C6H6 ratio of the starting mixture was shown to increase the nitrobenzene yield. Process parameters worsened with time since reagents
and products were strongly adsorbed and left the zeolite surface only at 220–250°C as CO, CO2 and NO. 相似文献
10.
2,5-bis-(4-biphenyl)-yl-1,3,4-oxadiazole (1a), 2,5-bis-(4-(6,8-difluoro)-biphenyl)-yl-1,3,4-oxadiazole (1b) and 2,5-bis-(4-(spiro-fluorenyl)-phenyl)-yl-1,3,4-oxadiazole (1c) were designed, synthesized and characterized. 1a–c were easily obtained from Suzuki reactions between 2,5-bis-(4-bromo-phynyl)-[1,3,4]oxadiazole (2) and aromatic boronic acids (3). They were characterized by 1H-NMR, DSC, TGA, UV-Vis, photoluminescence (PL) spectrometry and CV. The melting temperatures (T
m
) of 1a–c are 237, 208 and 370 °C, respectively, much higher than that of 2-tert-butylphenyl-5-biphenyl-1,3,4-oxadiazole (PBD, T
m
= 136 °C). The oxidation potentials of 1a–c are 1.86, 1.94 and 1.18 V, and their reduction potentials are −2.31, −2.22 and −2.27 V, respectively, indicating that the
introduction of electronegative oxadiazole unit lowers the electron density in molecules and enhances their stabilities. The
LUMO/HOMO energy levels of 1a–c are as low as −2.39/−6.56, −2.48/−6.69 and −2.43/−5.88 eV, respectively. The good thermal stabilities and low orbital levels
of 1a–c make them promising electron-transporting or hole-blocking materials for organic optoelectronic devices. 相似文献
11.
The conversion of dimethyl disulfide in the presence of various supported sulfidized metal-containing catalysts at atmospheric
pressure and T = 150−350°C was studied. Sulfidized transition metals supported onto aluminum oxide were more active than catalysts based
on a carbon support, silicon dioxide, amorphous aluminosilicate, and zeolite ZSM-5. The most active catalyst was 10% Co/Al2O3 prepared with the use of cobalt acetate as an active component precursor and treated with a mixture of hydrogen sulfide with
hydrogen at T = 400°C. From kinetic data, it follows that all of the reaction products were formed simultaneously at a temperature of <200°C,
whereas a consecutive reaction scheme took place at higher temperatures. In the presence of a sulfidized alumina-cobalt catalyst,
the output of dimethyl sulfide was higher than that reached with the use of other well-known catalysts. 相似文献
12.
E. V. Osintseva L. K. Neudachina Yu. G. Yatluk 《Russian Journal of Inorganic Chemistry》2010,55(10):1644-1650
The azo coupling reaction of N-(2-carboxyethyl)anthranilic acid and N,N,N′,N′-tetrabis(2-carboxyethyl)-1,3-phenylenediamine with diazosulfanilic acid yielded the complexones sodium 4-N-(2-carboxyethyl)amino-5-carboxyazobenzene-4′-sulfonate
(I) and 2,4-N,N,N′,N′-tetrabis(2-carboxyethyl)diaminoazobenzene-4′-sulfonic acid (II), respectively. The acidity constants of I and II (20°C, μ = 0.1M KCl) were determined to be as follows: for I, pK
00 = 1.29 ± 0.13, pK
0 = 2.92 ± 0.07, pK
1 = 3.92 ± 0.05, pK
2 = 5.16 ± 0.03; for II, pK
00 = 2.35 ± 0.06, pK
0 = 2.81 ± 0.09, pK
1 = 3.21 ± 0.11, pK
2 = 3.81 ± 0.09, pK
3 = 4.34 ± 0.04, pK
4 = 5.03 ± 0.06, pK
5 = 6.67 ± 0.07. The electronic absorption spectra of I and II were measured, and acid-base equilibrium scheme for I and II in aqueous solutions were suggested. The complexation constants of I and II with copper(II) ions were determined to be logK
CuQI= 5.47 ± 0.06 and logK
CuQII= 5.72 ± 0.13 (20°C, μ = 0.1 M KCl). 相似文献
13.
A. Yu. Tsivadze L. Kh. Minacheva I. S. Ivanova V. E. Baulin E. N. Pyatova V. S. Sergienko 《Russian Journal of Inorganic Chemistry》2008,53(4):545-551
The syntheses of the complex copper salt CuL2 · 2H2O (I) and the erbium nitrate complex Er(NO3)3 · 2HL · 2H2O (II) (HL is 2-[2′-(oxymethyldiphenylphosphinyl)phenyldiazenyl]-4-tert-butylphenol) have been described. Basic vibrational frequencies in the IR spectra of I and II have been interpreted. The crystal structure of I has been determined by X-ray crystallography: the crystals are monoclinic, a = 15.157(3) ?, b = 17.080(2) ?, c = 22.451(9) ?, β = 106.09(3)°, V = 5584(3) ?3, Z = 4, space group C2/c, R = 0.0546 (for 1152 reflections with I > 2σ(I)). The coordination polyhedron of the copper atom (symmetry C
2) can be described as a symmetrically elongated square bipyramid (4+2). The basic square of the Cu polyhedron is formed by
the oxygen atom of the substituted phenol and one of the nitrogen atoms of the azo group of each of the two deprotonated ligands
L− (Cu-N, 1.969(6) ?; Cu-O, 1.899(5) ?). The angles between the opposite O and N atoms are 157.6°, and the other equatorial
angles are in the range 90.6°–95.9°. The axial positions are occupied by the anisole O(2) and O(2A) atoms (Cu-O, 2.737(6)
?, the O(2)Cu(1)O(2A) angle, 132.3°). In the crystal of I, complex molecules and water molecules of crystallization are combined by a system of hydrogen bonds. IR spectra show that,
in complex II, as distinct from compound I, the HL ligand is coordinated to the erbium atom through the phosphoryl oxygen atom.
Original Russian Text ? A.Yu. Tsivadze, L.Kh. Minacheva, I.S. Ivanova, V.E. Baulin, E.N. Pyatova, V.S. Sergienko, 2008, published
in Zhurnal Neorganicheskoi Khimii, 2008, Vol. 53, No. 4, pp. 601–607. 相似文献
14.
M. A. Zanjanch Sh. Sohrabnezhad M. Arvand M. F. Mousavi 《Russian Journal of Electrochemistry》2007,43(7):758-763
The electrochemical properties of thionine dye adsorbed into ZSM-5 and HZSM-5 zeolites (TH/ZSM-5, TH/HZSM-5) are studied in
0.5 M KCl solution. The dye is strongly retained and not easily leached from the zeolites matrix. The samples are incorporated
into the carbon paste electrode (TH/ZSM-5/P, TH/HZSM-5/P) for cyclic voltammetric measurements. The redox reactions of thionine
incorporated into ZSM-5 zeolite contain a quasi-reversible, two-electron one proton in the pH range 1 to 10, but thionine-loaded
HZSM-5 zeolite undergoes a quasi-reversible two-electron two-protons redox reaction under acidic conditions and a one proton
two-electron redox reaction takes place under basic conditions. The separation of the anodic and cathodic potentials (E
p) is high in thionine-loaded zeolites (>100) with respect to the solution of thionine (E
p = 34 for ZSM-5/P and 36 mV for HZSM-5/P), indicating that there are strong interaction between thionine molecules and the
zeolites. The midpoint potentials (E
m) for TH/ZSM-5/P and TH/HZSM-5/P are −0.203 and −0.381 V, respectively. However, the midpoint potentials for the solution
of thionine for the electrode system of ZSM-5/P and HZSM-5/P are −0.335 and −0.407 V, respectively. Thus, thionine dye molecules
incorporated into the zeolites can be reduced more easily with respect to solution of thionine. In various electrolyte solutions,
the midpoint potentials remains constant, but the midpoint potential of the thionine-zeolite electrodes depends on the solution
pH. Influence of the pH of the solution on the midpoint potential of an immobilized dye reveals that thionine molecules are
accessible to protons. This property is ascribed to the formation of mesopores in the structure of our zeolites suffering
from a calcination step.
Published in Russian in Elektrokhimiya, 2007, Vol. 43, No. 7, pp. 794–800.
The text was submitted by the authors in English 相似文献
15.
The delay time τ has been measured for the formation of the ·OH radical in igniting hydrogenoxygen mixtures diluted with argon (79–97%). The experiments have been carried out under incident
shock wave conditions at temperatures of 900–3000 K, pressures of 0.5–2.5 atm, and H2/O2 ratios of 0.2–20. The dependence of τ on the pressure P
s of the stoichiometric part of the combustible mixture (2H2-O2) has been investigated for different mixture compositions. Under the above conditions, τ depends practically linearly on
1/P
s at P
s = 0.02−0.1 atm, irrespective of the mixture composition. This allows the measured τ data to be converted to one quantity,
τP
s. The temperature dependence of τP
s in the P
s range from 0.02 to 0.1 atm is Arrhenius-like. For the hydrogen-rich mixtures (H2/O2 = 2–20), this dependence appears as τP
s= 0.057 + 0.0256exp(7470/T) μs atm; for the lean mixtures (H2/O2 = 0.125–1), τP
s = 0.021 + 0.0069exp(7470/T) μs atm. The length of the shock-heated gas plug in the incident shock wave poses limitations on the ignition delay time
measurements at T < 900 K. 相似文献
16.
A novel polymer-forming diimide–diacid, 5,5′-bis[4-(4-trimellitimido phenoxy)phenyl]-hexahydro-4,7-methanoindan (II), was prepared by the condensation reaction of 5,5′-bis[4-(4-aminophenoxy)phenyl]-hexahydro-4,7-methanoindan with trimellitic
anhydride. A series of novel aromatic poly(amide–imide)s (PAIs) containing polycyclic cardo groups was prepared by the direct
polycondensation of II with various aromatic diamines using phosphorylation techniques. The polymers had inherent viscosities between 0.71 and 0.96 dl/g.
The polymers were soluble in polar solvents such as N-methyl-2-pyrrolidone, N,N-dimethylacetamide (DMAc) and N,N-dimethylformamide, and could be cast from their DMAc solutions into transparent, flexible, and tough films, except for III
a
. These films had yield strengths of 85–114 MPa, tensile strengths of 77–102 MPa, an elongation at break of 8–17%, and initial
moduli of 2.0–2.7 GPa. Wide-angle X-ray diffraction revealed that the polymers are amorphous. The glass-transition temperatures
of the polymers were in the range 242–312 °C. All the PAIs exhibited no appreciable decomposition below 430 °C, and their
10%-weight-loss temperatures were in the range 484–507 °C in nitrogen and 494–515 °C in air.
Received: 26 January 1999 Accepted in revised form: 11 May 1999 相似文献
17.
T. E. Kokina L. A. Glinskaya E. A. Sankova R. F. Klevtsova S. V. Larionov 《Journal of Structural Chemistry》2005,46(6):1031-1038
The interaction of the Co(iso-Bu2PS2)2 chelate with 4-NH2Py afforded a paramagnetic complex [Co(4-NH2Py)(iso-Bu2PS2)2] (μeff = 4.53 BM). Single crystals of [Ni(4-NH2Py)2(iso-Bu2PS2)2] (I) and [Co(4-NH2Py)(iso-Bu2PS2)2] (II) were grown and used for X-ray diffraction investigation (X8 APEX diffractometer, MoK
α radiation). Crystals I are monoclinic with unit cell parameters a = 12.5336(5) Å, b = 9.4356(4) Å, c = 16.4095(6) Å; β = 111.351(1)°; V = 1807.4(1) Å3; Z = 2, ρ = 1.223 g/cm3, space group P21/n. Crystals II are triclinic with unit cell parameters a = 8.7572(4) Å, b = 9.6934(6) Å, c = 18.665(1) Å; α = 79.374(2)°, β = 87.049(2)°, γ = 75.640(2)°; V = 1508.6(1) Å3; Z = 2, ρ = 1.259 g/cm3; space group
. The structures of I and II are formed by isolated mononuclear molecules. The coordination unit is NiN2S4 (octahedron) in I and CoNS4 (tetragonal pyramid) in II. The 4-NH2Py molecule is coordinated through the N atom of the heterocycle. Electronic spectroscopy data for II agree with the symmetry of the NS4 polyhedron found by X-ray diffraction (XRD) analysis. The noncoordinated amine groups link the complex molecules via N-H...S
hydrogen bonds.
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 6, pp.1072–1080, November–December, 2005.
Original Russian Text Copyright ? 2005 by T. E. Kokina, L. A. Glinskaya, E. A. Sankova, R. F. Klevtsova, and S. V. Larionov 相似文献
18.
I. A. Zamilatskov E. V. Savinkina D. V. Albov 《Russian Journal of Coordination Chemistry》2007,33(6):396-399
The complexes of CdI2 with acetamide (AA) and propaneamide (PrA) of the composition [Cd(AA)6][Cd2I6] (I) and [Cd(PrA)6][Cd2I6] (II) were synthesized and studied by X-ray diffraction. Isostructural crystals I and II are triclinic: a = 7.285(3) and 8.066(6), b = 11.266(4) and 11.649(3), c = 11.554(3) and 12.063(2) ?, α = 100.96(2)° and 102.74(2)°, β = 91.59(2)° and 91.73(4)°, γ = 100.76(3)° and 101.05(4)°, V = 912.5 and 1081.9 ?3, respectively; space group
, Z = 1.
Original Russian Text ? I.A. Zamilatskov, E.V. Savinkina, D.V. Al’bov, 2007, published in Koordinatsionnaya Khimiya, 2007,
Vol. 33, No. 6, pp. 407–410. 相似文献
19.
R. F. Klevtsova E. A. Sankova T. E. Kokina L. A. Glinskaya S. V. Larionov 《Journal of Structural Chemistry》2008,49(1):117-124
Mixed-ligand complex compounds [Pb(Phen)(i-Bu2PS2)]2 (I) and [Pb(2,2′-Bipy)(i-Bu2PS2)]2 (II) were synthesized. Their structures were determined from X-ray diffraction data (X8 APEX diffractometer, MoK
α
radiation, 6392
Fhkl
, R = 0.0233 for I and 3937 F
hkl
, R = 0.0252 for II). Crystals I are triclinic: a = 10.2662(3) Å, b = 12.3037(2) Å, c = 14.8444(4) Å; α = 92.054(1)°, β = 103.473(1)°, γ = 105.561(1)°, V = 1746.89(8) Å3, Z = 2, ρcalc = 1.532 g/cm3, space group P
. Crystals II are monoclinic: a = 9.3462(3) Å, b = 26.3310(12) Å, c = 28.5345(13) Å; β = 96.436(1)°, V = 6977.9(5) Å3, Z = 8, ρcalc = 1.489 g/cm3, space group P21/n. The structures are built from mononuclear molecules. In both structures, the intermolecular contacts between the Pb and
S atoms of the neighboring mononuclear molecules form supramolecular assemblies involving two molecules. The environment of
the Pb atoms in the assemblies is a pentagonal bipyramid, N2S4+1. The assemblies are joined into ribbons by π-π interactions of the Phen rings in I and C…C short contacts between the pyridine rings in II.
Original Russian Text Copyright ? 2008 by R. F. Klevtsova, E. A. Sankova, T. E. Kokina, L. A. Glinskaya, and S. V. Larionov
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 49, No. 1, pp. 123–131, January–February, 2008. 相似文献
20.
The transparent TiO2 thin films coated on fused-SiO2 substrates were prepared by the sol–gel method and spin-coating technique. Effects of calcination temperature on crystal
structure, grain size, surface texture, and light transmittance of the films were investigated. After calcining at 600–1,200 °C,
the thicknesses of the TiO2 films were all around 80 nm and the molecular structures of the films were anatase, even at 1,200 °C. The calcined TiO2 films had the ultraviolet light (wavelength 200–400 nm) transmittances of ≤29% and the visible light (wavelength 400–800 nm)
transmittance of ≥72%. By photocatalytically decomposing the methylene blue (MB) in water, the photocatalytic activities of
the TiO2 thin films were measured and represented using the characteristic time constant (τ) for the MB degradation. While the films
prepared at 1,000 and 1,200 °C photodecomposed about 54 mol% of the MB in water (the corresponding τ ≈ 14.8 h) after exposing to 365-nm UV light for 12 h, the films prepared at 600 and 800 °C had smaller τ (≈9.0 h) and photodecomposed
about 74 mol% of the MB in water at the same testing conditions. 相似文献