Valence change of europium in the Eu(Ir1−x Pd x )2Si2 silicides

Eu(Ir_1–x Pd _x )₂Si₂ solid solutions which exist only for 0x0.125 and 0.75x1 crystallize in the tetragonal ThCr₂Si₂-type structure. X-ray diffraction data, magnetic susceptibility and¹⁵¹Eu Mössbauer measurements suggest that these compounds can be characterized as homogeneous mixed valence systems. At room temperature and for 0x0.125, the europium valence decreases asx increases. For 0.75x1, a sharp continuous valence transition from Eu²⁺ to Eu³⁺ occurs near 48 K, 54 K and 78 K forx=0.75, 0.81 and 0.94 respectively. These valence changes are discussed in relation with the Eu–(Ir, Pd) interatomic distance.     

57Fe Mössbauer studies in a new cluster spin glass system RuxFeGa (0.5≦x≦1.5)

⁵⁷Fe Mössbauer and bulk magnetization studies have been carried out in a new magnetic system Ru_xFeGa for 0.5x1.5. The system is seen to freeze into a cluster spin glass phase at 70 K. The freezing temperature and the hyperfine field at Fe at the lowest measured temperature, 190 kOe, is essentially same for all values of x investigated.     

Measurement of the refractive index and optical absorption spectra of epitaxial bismuth substituted yttrium iron garnet films at uv to near-ir wavelengths

Refractive-index and optical-absorption spectra of Bi-substituted yttrium iron garnet films, epitaxially grown by liquid-phase epitaxy, have been measured in the spectral regime 0.26 m1.9 m by thin-film interference for 0.52 m and by ellipsometry for0.52 m. The Y_3–x–y Bi _x Pb _y Fe_5–z Pt _z O₁₂ films contain bismuth in the range Ox 1.42, lead in the range 0.01 y0.08 and platinum in the range 0.005<=z0.03. There is satisfactory coincidence between the results from ellipsometry and thin-film interference in the overlapping wavelength region. The materials investigated are the same as reported earlier from this laboratory in ter mof their magnetic and magnetooptic properties.     

57Fe Mössbauer investigations in the series Fe4−2xRuxSix(1.0≦x≦1.7)

⁵⁷Fe Mössbauer and magnetization studies on a new series Fe_4–2xRu_xSi_x (1.0x1.7) are reported. The system is seen to transform from a collinear ferromagnet for x1.2 to a cluster spin glass for x>=1.54 In the intermediate region the magnetic behaviour of the system, as probed by the Mössbauer effect, is dominated by the presence of clusters and their dynamics. The alloys have large ordering temperatures ( 750 K) throughout the series except for x>1.54 where they drop sharply. The moment values, in contrast, fall sharply from 4.8_B at x=1 to 0.5_B at x=1.6C. The average value of the HF at⁵⁷Fe measured at 15 K does not change significantly throughout the series.     

Magnetic properties of Nd3+ in Nd−Ba−Cu−O-compounds

Neutron diffraction, neutron spectroscopy and magnetization measurements have been employed to study the structural, electronic, and magnetic behavior of eleven compounds with the general formula Nd_1+y Ca _v Ba_2–y–v Cu₃O _x (0y0.5; 0v0.25; 6x7). The structure turned out to react to oxygen reduction similar as other 123-compounds, yielding discontinuities close to the metal-insulator-transition and the well-known relations of bond lengths as a function ofT _c. The crystalline electric field (CEF) interaction, splitting the 10-fold degenerate ground-state J-multiplet of the Nd³⁺-ions into five doublet states, was investigated by neutron spectroscopy. The derived CEF parameters have been used to determine changes in the electronic surroundings of the Nd³⁺ ions. In addition, with the help of the CEF parameters the thermodynamic magnetic properties of these compounds were calculated which turn out to be in good agreement with the experimental data.     

On the magnetic susceptibility of Pd1−x Ag x in the range 0.5≦x≦1

The weak variation of the magnetic bulk susceptibility of Pd_1–x Ag _x with temperature T and silver mole fractionx within 0.5x1 has been investigated in the range 5KT400K. Experimental evidence can be given for an intersection point of the susceptibility isotherms (T=const,x) atx=0.55. The observed dependence of on T andx is interpreted by means of a semiphenomenological alloy susceptibility function (T,x).     

Influence of Ce spin fluctuations on the Gd ESR in Y1−xCexAl2

The Gd ESR and magnetic susceptibility of Y_1–xCe_xAl₂ (0.01x1) were measured in the temperature range 1.5–25 K (ESR) and 2.6–290 K (), respectively. The Gd ESR spectrum is substantially altered in the presence of Ce ions. The Gd resonance linewidth shows a non-linear temperature dependence which is more pronounced for higher Ce concentrations. A model is suggested to explain the linewidth behaviour and to estimate the spin fluctuation time of Ce ions in this system.     

Oxygen content of superconducting Ba2YCu3O6.5+x

Single-phase non-stoichiometric Ba₂YCu₃O_6.5+x with –0.248x0.300 can be obtained by annealing prereacted samples at 0.01–1 bar oxygen partial pressure. Samples withx=–0.248 are semiconducting, samples at 0.239x0.300 are metallic withT _c increasing from 92.2 to 94.0 K for annealing in 0.02–1 bar O₂.     

An unambiguous procedure for discovering relaxation influence on Mössbauer spectra

A mathematical procedure which gives an opportunity to distinguish between relaxation and distribution mechanisms of the Mössbauer line broadening is proposed. It is based on the method of Mössbauer line sharpening developed recently [1] and allows one to answer unambiguously the question whether or not relaxation manifests itself in Mössbauer measurements by examining the wings of the spectrum. The procedure is applied to the spectra of high spin ferric metmyoglobin and (Fe_0.65Ni_0.35)_1–x Mn _x alloys. Analysis of the metmyoglobin spectra manifests the presence of the relaxation influence in the temperature range 10 KT100 K. Analysis of the alloy spectra shows that for the temperatures 4 KT300 K and Mn concentrations 0x0.245 no relaxation is observed and the line broadening is mainly caused by the distributions of magnetic hyperfine fields. A possible explanation of this result is given.     

The electrical resistivity of the reentrant spin glass alloys (Fe0.65Ni0.35)1−x Mn x in the temperature range 4 to 280 K

The specific electrical resistivityp(T) was measured for the reentrant spin glass system (Fe_0.65Ni_0.35)_1–x Mn _x (0x0.102) in the temperature range 4 KT280 K. We used our own phenomenological ansatz to explain the results obtained in order to provide the fitted parameters with physical meaning. The cause of the observed minimum in the measured curves can be given by a model of local magnetism.     

Mössbauer investigation of In and Sc substituted barium hexaferrite

A detail Mössbauer analysis has been performed on polycrystalline samples of hexagonal ferrites with composition BaFe_12-x In _x O₁₉ (0x4) and BaFe_12-x ScxO₁₉ (0x3). The dependence on composition of the distribution of metallic cations among the five sublattices of the structure has been determined: these data confirm the strong preference of Sc and In ions for the sites belonging to the R block.As a consequence iron ions located in the main spin up sublattice (12k) with different number of neighbouring Fe³⁺ ions display different temperature dependences of the magnetization. The occurrence of non-collinear spin configurations, even for very low degrees of substitution of iron, has also been evidenced.     

Intrinsic carrier concentration in Hg1−xCdxTe

The effective mass of heavy holes has been determined on the basis of simultaneous analysis of the Hall coefficient and conductivity data obtained in the temperature region 100–300 K on well characterized p-type Hg_1–x Cd_xTe (x0·2) samples. Its value is 0·7m₀. The calculation of intrinsic carrier concentration for 0·19 x0·3 and 50 Kg T 300 K has been carried out using the above value of the effective mass of holes, Hansen's expression for the band gap and momentum matrix element from magneto-optical measurements.     

Proton spin-lattice relaxation times in ytterbium hydrides

The measurements of the proton (NMR) spinlattice relaxation times have been made in a series of ytterbium hydrides, YbH _x . Results are reported forx=1.80, 1.95, 2.00 and 2.62 and temperatures 4.2T297K. In the orthorhombic phase (1.80x2.00), the spin-lattice relaxation times are dominated by the hyperfine interaction of protons with conduction electrons and the spin diffusion mechanism. In the cubic phase (x=2.62), the relaxation times are five orders of magnitude shorter than in the orthorhombic one. This is interpreted in terms of the proton coupling with the Yb³⁺ ion spin fluctuations.     

β-Relaxation and low-temperature specific heat in (KBr)1−x(KCN)x

The specific heat in (KBr)_1–x(KCN)_x has been measured for concentrations 0.00x0.93 and for temperatures 2 KT50 K. In addition, the dipolar relaxation phenomena were studied using dielectric spectroscopy. The relaxation behaviour was parametrized assuming a Gaussian distribution of energy barriers and the mean activation energies, the distribution widths, and the attempt frequencies have been determined as a function of the CN^– concentration. With these parameters the linear and the excess specific heat contributions were calculated and compared to the calorimetric results.     

Properties of LiZn x V2−x O4 and LiMg x V2−x O4 mixed oxides

The phase composition of the mixed oxides, series LiMe _x V_2–x O₄, where Me=Zn, Mg, was studied using X-ray analysis. The minor phases present in the investigated samples together with the basic spinel phase were determined as Li₃VO₄ and Zn₂V₂O₇ or Mg₂V₂O₇ respectively. Their presence is caused by the tendency of tetravalent vanadium ions to the disproportionation. For the compositionsx=0·375 were determined the quantitative phase compositions. The lattice constant of the spinel phase is linearly changing according to Vegard's rule, for the zinc series in the range 0x0·375 and for the magnesium series in the range 0xs0·25. Further substitution in magnesium series caused tetragonal deformation of the cubic spinel lattice.The author is indebted to Dr. A.Bergstein for helpful discussions and to Mrs. E.Hrubá for technical assistance.     

The magnetic anisotropy of manganate ferrites

The anisotropy constants K₁ for systems Mn_xFe_3–xO₄, with 1x 1·8, are calculated on the basis of the one-ion model and it is shown that the anomalous temperature dependence of the constant K₁ can be explained by the presence of Mn³⁺ ions in octahedral positions. The influence of the spin order on the magnetic anisotropy and the uniaxial anisotropy in systems Mn_xFe_3–xO₄ are discussed.     

Implementation of comparative probability by normal states. Infinite dimensional case

Let be an infinite dimensional Hilbert space and () the set of all (orthogonal) projections on . A comparative probability on () is a linear preorder on () such thatOP1,1O and such that ifP┴R,Q┴R, thenPQP+RQ+R for allP, Q, R in (). We give a sufficient and necessary condition for to be implemented in a canonical way by a normal state onB(), the bounded linear operators on .     

Strong coupling in the quantum field theory with nonlocal nonpolynomial interaction

In the relativistic quantum field theory the representation for theS-matrix elements is obtained for any coupling constantsg in the case of a one component scalar field (x) with nonlocal nonpolynomial interaction _I ()=gU() when the causal function is bounded in the Euclidean region 0D _c (x _E ² D _c (0)< and the function |U(u)|1 for realu. It is proved that the two point Green function is bounded in the physical region of momenta variablep ².     

Spin-glass behavior of (La,Gd)B6 alloys

The low-frequency ac magnetic susceptibility of (La_1–x Gd _x )B₆ alloys (0.0035x0.0812) was measured between 0.04 and 10 K in very low and moderate applied magnetic fields up to 8 kOe. In addition, the low-field static susceptibility was measured between 4.2 and 200 K. At low temperatures the alloys exhibit the basic features of the spin glass state, that is sharp maxima and time dependent effects in the low-field ac susceptibility. The temperature and field dependence of the susceptibility follows a law of corresponding states forx0.01, which is characteristic for Ruderman-Kittel-Kasuya-Yosida (RKKY) interactions. Effects from interactions between the Gd ions observed above the freezing temperature are consistent with a recent theory based on a virial expansion of the magnetic free energy for the RKKY model and yield |J|=0.04 eV for the magnitude of thes–f exchange integral. The same value is obtained from the initial susceptibility atT0 when compared with a molecular-field result. Above 1 K the initial susceptibility follows a single-impurity Curie law with the free-ion value of the magnetic moment of the Gd solute.     

Effect of thallium on magnetic susceptibility of arsenic sulphides

Magnetic susceptibility was studied of samples of Tl_2xAs₂S_3+x and Tl_2xAs₂S₄ series where 0x1 differing in abundance of bonds in structural units. Absolute value of specific magnetic susceptibility decreases with increasing thallium content. Separation of susceptibility in dia- and paramagnetic parts made it possible to refer to the correlation of absorption edge position and paramagnetic susceptibility component.