通过四波参量过程,在钠蒸汽中产生相干可调谐的330nm和333nm辐射

在钠蒸汽中,调谐输入激光波长,使之与钠原子3s—4d双光子跃迁共振,通过四波参量过程产生紫外可调谐的相干辐射。本文报告所产生的330nm333nm相干辐射强度,随钠蒸汽密度、输入基波功率和波长的变化。在平面波近似和紧聚焦条件下,对产生的紫外相干辐射进行了比较。在紧聚焦条件下。产生330nm和333nm的总转换效率为3％。     

Na原子中3S—4D双光子共振增强紫外相干辐射的观测和研究

用Na原子3S—4D双光子共振增强的受激超Raman散射、四波混频和光泵受激发射过程,获得230—340nm范围内两组紫外相干辐射,分析了这一系列紫外相干辐射的产生机制和谐线特性。     

锂蒸气中双光子泵浦的六波、四波混频和受激辐射

本文报道锂蒸气中由双光子泵浦所产生的位于紫外、可见和红外区的相干和受激辐射。包括:由一特殊六波混频过程产生的在1.03μm附近的可调谐相干辐射,由锂分子双光子离解或原子串级跃迁产生的波长为812.6nm的受激辐射,以及由四波混频产生的位于323.3nm和670.8nm的相干辐射。 关键词：     

深紫外非线性光学晶体及全固态深紫外相干光源研究进展

全固态深紫外相干光源在前沿科学、高技术等领域均有重要应用。产生全固态深紫外相干光源的一种有效而可行的技术途径是将商业化的可见、近红外全固态激光作为基频光源,通过非线性光学晶体的多级变频技术产生深紫外激光。本文系统地介绍了深紫外非线性光学晶体及全固态深紫外相干光源的研究进展。主要以KBBF晶体为代表,详细介绍了发现KBBF晶体的过程,晶体生长技术,棱镜耦合器件技术,KBBF晶体的主要光学性质以及产生深紫外相干光源的能力,同时证实了KBBF晶体是目前能使用直接倍频方法实现深紫外激光输出的非线性光学晶体。此外,文中还详细介绍了基于KBBF晶体及棱镜耦合技术的深紫外相干光源的应用情况,尤其是在超高分辨率光电子能谱仪方面的应用及取得的重要成果。最后,展望了深紫外非线性光学晶体及全固态深紫外激光技术的发展方向。     

YVO_4∶Tm~(3+)的真空紫外发光性能(英文)

通过高温固相反应合成YVO4∶xTm(x=0.001,0.003,0.005,0.007,0.01,0.03,0.05)蓝色系列粉末状发光材料。经X射线衍射分析产物为单相,属四方锆英石结构,其结果与JCPDS标准卡(72-0861)相符。检测了材料的真空紫外激发光谱和发射光谱。YVO4∶xTm的真空紫外激发光谱在120~350 nm范围内为连续的带状峰,在155 nm和333 nm附近有明显的峰值。在155 nm激发下,YVO4∶xTm的发射光谱由两部分组成,其中主发射峰在474 nm附近呈一尖锐的线状,来自Tm3+的1G4→3H6跃迁;在650 nm左右有一弱发射峰,来自Tm3+的1G4→3H4跃迁。另外,还有一较弱的带状发射,中心位于540 nm左右,来自样品的VO3-4离子的宽带发射。随着Tm3+摩尔分数x由0.001增加到0.005,Tm3+发射光谱强度逐渐增加到最大值。之后随着x继续增加,发射光谱强度逐渐下降,呈现明显的浓度猝灭现象。通过对YVO4∶xTm的光谱分析及其发光机理进行推导,认为YVO4∶Tm3+在紫外及真空紫外激发下,是一种具有较高发光效率以及色纯度较好的蓝色发光材料。     

真空紫外和极紫外相干光源的研究及进展

本文简明扼要地介绍和评论了真空紫外和极紫外波段相干光源研究的现状和发展前景 ,重点包括 :真空紫外和极紫外波段相干光源的产生机制 ,理论描述 ,实验方法 ,以及一些典型的实验结果。最后对该领域的发展前景做了简要的评述。     

非线性光学产生XUV相干辐射的新进展

北京大学非线性光学方法产生XUV相干辐射机制研究课题组继去年取得83～200nm范围一系列可调谐相干辐射的成果以后,今年又在Kr,Xe等稀有气体中把产小可调谐的相干辐射波长推进到72nm,至此,该课题组已能在72nm以上的XUV/VUV范围任何波长产生可调谐的相干辐射输出,达到了国际上同类工作的先进水平,为今后开展XUV相干辐射的应用研究奠定了基础。     

近紫外非相干宽带腔增强吸收光谱应用于Cl原子启动的光化学反应过程中OClO及CH2O的探 (cited: 3)

OClO是Cl原子活性的一个重要的指示剂,对OClO的检测有利于更好的理解Cl原子的化学反应过程及其对沿海及工业污染地区空气质量的影响. 本工作建立了一套基于氙灯的近紫外(335～375 nm)非相干宽带腔增强吸收光谱系统,并将其应用于烟雾箱中OClO的定量测量研究,同时测量了反应过程中重要的中间产物CH₂O及大气中重要的痕量气体NO₂. 结果表明,非相干宽带腔增强吸收光谱可应用于实验室大气卤素化学方面的研究.     

K_2Te(Cs)日盲紫外光电阴极研究

研究了K2Te(Cs)日盲紫外阴极的制作工艺并制作了K2Te(Cs)日盲紫外阴极.测量了K2Te(Cs)日盲紫外阴极样品的光谱响应、光谱反射率和250nm波长激发条件下的荧光谱,测量结果表明:与Cs2Te日盲紫外阴极相比,在现有工艺条件下,K2Te(Cs)日盲紫外阴极的灵敏度高于Cs2Te日盲紫外阴极,光谱响应的峰值波长更短,位于250nm,而长波截止波长位于336nm;633nm的光谱灵敏度为10-4 mA/W数量级,较Cs2Te日盲紫外阴极低一个数量级.光谱反射率测量结果表明:K2Te(Cs)日盲紫外阴极的光谱反射率在200~437nm的波长范围内,均高于Cs2Te日盲紫外阴极,而在437~600nm的波长范围内,反射率却与Cs2Te日盲紫外阴极基本相同;折射率及消光系数也低于Cs2Te日盲紫外阴极.荧光谱测试结果表明:在同样条件下,250~350nm波长范围内,由于K2Te(Cs)紫外阴极的荧光强于Cs2Te紫外阴极,因此跃迁电子数量更多,阴极灵敏度更高,比较适用于日盲紫外探测成像器件的制造.     

紫外像增强器辐射灵敏度测量系统

紫外像增强器是紫外探测系统的核心器件，是一种电真空成像器件，可将微弱的紫外光图像转换并增强为肉眼可见、亮度可见的光图像，其研制与应用是微光夜视技术的重要发展方向。辐射灵敏度是评价紫外像增强器的重要参数，直接决定了紫外探测系统的性能。介绍了紫外像增强器辐射灵敏度的测量原理，采用紫外辐射光源、光栅单色仪系统、测试暗箱、微电流计、计算机及测量软件组建了辐射灵敏度测量系统。对3只紫外像增强器在260 nm、280 nm及320 nm波长下的辐射灵敏度进行了测量，并分析了其测量不确定度。该测量系统的建立，将辐射灵敏度测量系统的光谱范围拓展至200 nm～400 nm，弥补了现有系统的不足，具有广泛的应用前景。     

Refractive-index gratings written by near-ultraviolet radiation

This is the first report, to our knowledge, of refractive-index grating side writing in 10 mol.% GeO(2)-doped fiber by the near-UV light of a cw Ar(+) laser (333-364 nm). An induced-index magnitude as large as 1.9 x 10(-4) at 1.7x10(5) W/cm(2) UV power density has been achieved. The observed gratings have exhibited the same temperature stability as gratings written by a KrF excimer laser (248 nm).     

Coherent two-dimensional ultraviolet spectroscopy in fully noncollinear geometry

We introduce fully noncollinear coherent two-dimensional (2D) spectroscopy in the UV domain with an all-reflective and miniaturized setup design. Phase stability is achieved via pairwise beam manipulation, and the concept can be transferred to all wavelength regimes. Here we present results from an implementation that has been optimized for wavelengths between 250 and 375 nm. Interferometric measurements prove phase stability over several hours. We obtained 2D spectra of the nonpolar UV chromophore p-terphenyl in ethanol, excited with 50 fs pulses at 287 nm.     

Tunable deep-ultraviolet source generated by scattering off adiabatically prepared Raman coherence in hydrogen gas

We demonstrate a tunable deep-ultraviolet coherent source generated by the beating of a tunable UV laser and strongly driven vibrational Raman coherence in hydrogen. The total energy conversion efficiency reaches a maximum of 50% at the phase side of the Raman coherence. The generated spectrum of Raman sidebands tunes with the input and extends from 435 to 146 nm for an input at 282 nm.     

Direct shaping of tunable UV ultra-short pulses

Time shaping of ultra-short UV pulses has been performed using a specially designed acousto-optic programmable dispersive filter in KDP material. A time shaping window up to 5 ps has been obtained in the 260–410 nm range. A temporal/spectral characterization of shaped pulses on this broad UV spectral range is presented. The efficiency at shorter wavelength is limited by two-photon absorption. However several µJ is obtained at the output of the device allowing chemistry coherent control experiment.     

Efficient fourth harmonic UV generation of passively Q-switched Nd:GdVO4/Cr:YAG lasers

A coherent UV passively Q-switched diode pumped Nd:GdVO₄ laser source is proposed. During pumping of the β-BBO crystal a stable light with power 0.6 W with wavelength 532 nm and pulse duration 9 ns at frequency repetition 16 kHz was applied. The output UV light has a power about 79 mW at wavelength 266 nm during diode-pumping with 8 W incident light.     

UV and IR coherent radiation generated simultaneously by two-photon and hybrid excitations in sodium vapor

UV coherent radiation at 330.2 nm and IR stimulated radiations at 2.34μm,2.21μm and 1.64μm were generated via processes of unequal-frequency two-photon(3S-6S)resonantly enhanced excitation and equal frequency hybrid resonant excitation with particularexcited wavelength in Na_2-Na system.The competition of the two processes is obviously.     

Photodegradation of melanin by an interferometric technique

Photodegradation of melanin thin films is investigated for a UVA wavelength of 355 nm and a UVC wavelength of 244 nm. The technique involves interferometric exposure of melanin with two coherent beams from a low-power UV laser. The periodic photodegradation-grating pattern is monitored by diffraction of a second low-power He-Ne laser. Dependence of the photodegradation rate on UV intensity as well as the effect of ambient humidity is investigated and explained with a simple model. The technique has promise for investigating photo-induced effects in other biomolecular substrates as well.     

芴类荧光染料掺杂DNA-CTMA薄膜的放大自发辐射特性

钯催化Suzuki反应合成得到一种9,9-二乙基-2,7-二-(4-吡啶)芴（DPFP）荧光染料,研究了该染料的吸收和荧光光学特性,以及DPFP掺杂DNA-CTMA薄膜的荧光光谱特性和放大自发辐射特性。实验结果表明:DPFP的吸收峰位于333 nm,DPFP的荧光光谱在370 nm和386 nm出现荧光峰,在408 nm出现肩峰,存在从激发态S1能级到基态S0能级的S10-S00,S10-S01和S10-S02三种振动带的电子跃迁;同时,在Nd:YAG纳秒激光器355 nm输出光的泵浦下,DPFP掺杂DNA-CTMA薄膜在波长390 nm和406 nm处实现了放大自发辐射,其阈值能量密度分别为3.24和3.40 mJ/cm2;此外,通过调节DPFP掺杂DNA-CTMA的质量比可以实现特定波长的放大自发辐射。