A Functionalized Ag2S Molecular Architecture: Facile Assembly of the Atomically Precise Ferrocene‐Decorated Nanocluster [Ag74S19(dppp)6(fc(C{O}OCH2CH2S)2)18] |
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| Authors: | Yiyi Liu Bahareh Khalili?Najafabadi Mahmood Azizpoor?Fard Prof?Dr John F Corrigan |
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| Affiliation: | 1. Department of Chemistry, The University of Western Ontario, London, Ontario, N6A 5B7 (Canada);2. Centre for Advanced Materials and Biomaterials Research, The University of Western Ontario, London, Ontario, N6A 5B7 (Canada) |
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| Abstract: | A ferrocene‐based dithiol 1,1′‐fc(C{O}OCH2CH2SH)2] has been prepared and treated with a AgI salt to form the stable dithiolate compound fc(C{O}OCH2CH2SAg)2]n (fc=Fe(η5‐C5H4)2]). This is used as a reagent for the preparation of the nanocluster Ag74S19(dppp)6(fc(C{O}OCH2CH2S)2)18] which was obtained in good yield (dppp=1,3‐bis(diphenylphosphino)propane). |
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| Keywords: | cluster compounds iron metallocenes silver structure elucidation |
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