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Controlled Light‐Mediated Preparation of Gold Nanoparticles by a Norrish Type I Reaction of Photoactive Polymers |
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| Authors: | Florian Mäsing Dr Artur Mardyukov Carsten Doerenkamp Prof Dr Hellmut Eckert Ursula Malkus Harald Nüsse Prof Dr Jürgen Klingauf Prof Dr Armido Studer |
| Affiliation: | 1. Westf?lische Wilhelms‐Universit?t, Organisch‐Chemisches Institut, Corrensstrasse 40, 48149 Münster (Germany);2. Westf?lische Wilhelms‐Universit?t, Physikalisch‐Chemisches Institut, Corrensstrasse 28/30, 48149 Münster (Germany);3. Institute of Medical Physics and Biophysics, Robert‐Koch‐Strasse 31, 48149 Münster (Germany) |
| Abstract: | Gold nanoparticles (AuNPs) are subjects of broad interest in scientific community due to their promising physicochemical properties. Herein we report the facile and controlled light‐mediated preparation of gold nanoparticles through a Norrish type I reaction of photoactive polymers. These carefully designed polymers act as reagents for the photochemical reduction of gold ions, as well as stabilizers for the in situ generated AuNPs. Manipulating the length and composition of the photoactive polymers allows for control of AuNP size. Nanoparticle diameter can be controlled from 1.5 nm to 9.6 nm. |
| Keywords: | controlled radical polymerization gold metal nanoparticles photochemistry radicals |
