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Self‐Assembly of a Giant Tetrahedral 3 d–4 f Single‐Molecule Magnet within a Polyoxometalate System |
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| Authors: | Dr Masooma Ibrahim Dr Valeriu Mereacre Dr Nicolas Leblanc Prof Wolfgang Wernsdorfer Dr Christopher E Anson Prof Annie K Powell |
| Affiliation: | 1. Institut für Nanotechnologie, Karlsruher Institut für Technologie, 76344 Eggenstein‐Leopoldshafen (Germany);2. Permanent address: University of Balochistan, 87300, Quetta (Pakistan);3. Institut für Anorganische Chemie, Karlsruher Institut für Technologie, Engesserstrasse 15, 76131 Karlsruhe (Germany);4. Institut Néel CNRS/UJF UPR2940, 25 Rue des Martyrs BP 166, 38042 Grenoble cedex 9 (France) |
| Abstract: | A giant tetrahedral heterometallic polyoxometalate (POM) Dy30Co8Ge12W108O408(OH)42(OH2)30]56?, which shows single‐molecule magnet (SMM) behavior, is described. This hybrid contains the largest number of 4f ions of any polyoxometalate (POM) reported to date and is the first to incorporate two different 3d–4f and 4f coordination cluster assemblies within same POM framework. |
| Keywords: | dysprosium inorganic synthesis polyoxometalates self‐assembly single‐molecule magnets |
