A Kinetic Self‐Sorting Approach to Heterocircuit [3]Rotaxanes |
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Authors: | Dr Edward A Neal Dr Stephen M Goldup |
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Affiliation: | 1. School of Biological and Chemical Sciences, Queen Mary University of London, UK;2. School of Chemistry, University of Southampton, Southampton, UK |
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Abstract: | In this proof‐of‐concept study, an active‐template coupling is used to demonstrate a novel kinetic self‐sorting process. This process iteratively increases the yield of the target heterocircuit 3]rotaxane product at the expense of other threaded species. |
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Keywords: | active templates cycloaddition CuAAC rotaxanes self-sorting |
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