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A Kinetic Self‐Sorting Approach to Heterocircuit [3]Rotaxanes
Authors:Dr Edward A Neal  Dr Stephen M Goldup
Affiliation:1. School of Biological and Chemical Sciences, Queen Mary University of London, UK;2. School of Chemistry, University of Southampton, Southampton, UK
Abstract:In this proof‐of‐concept study, an active‐template coupling is used to demonstrate a novel kinetic self‐sorting process. This process iteratively increases the yield of the target heterocircuit 3]rotaxane product at the expense of other threaded species.
Keywords:active templates  cycloaddition  CuAAC  rotaxanes  self-sorting
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