|
|||||
|
|
Designed Assembly of Heterometallic Cluster Organic Frameworks Based on Anderson‐Type Polyoxometalate Clusters |
|
| Authors: | Dr Xin‐Xiong Li Yang‐Xin Wang Prof?Dr Rui‐Hu Wang Cai‐Yan Cui Dr Chong‐Bin Tian Prof?Dr Guo‐Yu Yang |
| Affiliation: | 1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, China;2. MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing, China |
| Abstract: | A new approach to prepare heterometallic cluster organic frameworks has been developed. The method was employed to link Anderson‐type polyoxometalate (POM) clusters and transition‐metal clusters by using a designed rigid tris(alkoxo) ligand containing a pyridyl group to form a three‐fold interpenetrated anionic diamondoid structure and a 2D anionic layer, respectively. This technique facilitates the integration of the unique inherent properties of Anderson‐type POM clusters and cuprous iodide clusters into one cluster organic framework. |
| Keywords: | cluster organic frameworks copper heterometallic structures luminescence polyoxometalates |
