Novel propargyl‐substituted azo‐coupled phenolic resins |
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| Authors: | Denis Kalugin Denis Luchinkin Sergey Nechausov Artem Malakho Alexey Rogozin Nikita Garadja |
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| Affiliation: | 1. Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russia;2. Institute of New Carbon Materials and Technologies, Moscow, Russia;3. Aleksin Chemical Plant, Aleksin, Tula Region, Russia |
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| Abstract: | Novel propargyl that contains phenolic resins via azo‐coupling reaction was synthesized. Peculiarities of curing process were investigated by differential scanning calorimetry analysis. Polymerization of resins with azo groups was estimated to be affected by radicals obtained at resin decomposition causing 10°C peak shift to lower temperatures in comparison with resin containing only propargyl group. At the same time, polymerization of triple propargyl bond was shown to not proceed at radical initiation until Cleisen rearrangement and chromene formation. Thermogravimetric analysis revealed increase of thermal stability by 170–190°C and char yield by up to 20% for modified resins in comparison with original novolac resin. Heat deflection temperature estimated by dynamic mechanical analysis was also shown to be increased by at least 110°C for modified resins in comparison with novolac resin. All the synthesized resins are soluble in acetone and used for preparation of unidirectional glass fiber‐based composites. Flexural strength and modulus for modified resins‐based composites were shown to increase by at least 25% and 10% correspondingly in comparison with novolac‐based composite. Copyright © 2015 John Wiley & Sons, Ltd. |
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| Keywords: | polymer‐matrix composites thermosets cure behavior mechanical properties azo coupling |
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