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New Calix[4]arene‐Cored Peripherally Functionalized Dendrimers: Synthesis and Conformational Characteristics
Authors:Georgios Paraskevopoulos  Dimitrios Alivertis  Vassiliki Theodorou  Konstantinos Skobridis
Affiliation:1. Department of Chemistry, University of Ioannina, GR‐45110 Ioannina, (phone: +30‐265‐1008598;2. fax: +30‐265‐1008682);3. Department of Biological Applications and Technology, University of Ioannina, GR‐45110 Ioannina
Abstract:New calixarene‐based dendrimers, containing calix4]arene as the core and different generations of Fréchet‐type poly(benzyl ether) dendrons as building blocks, which possess either Br‐atoms or COOtBu groups at their surface were synthesized and presented herein for the first time. The new calix4]arene‐cored dendritic macromolecules were fully characterized and found to prefer strictly the cone conformation.
Keywords:Calixarenes  Cone conformation  Dendrimers  Host  guest compounds  Supramolecular chemistry
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