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Switching the Stiffness of Polyelectrolyte Assembly by Light to Control Behavior of Supported Cells
Authors:Sviatlana A Ulasevich  Nadzeya Brezhneva  Yulia Zhukova  Helmuth Möhwald  Peter Fratzl  Felix H Schacher  Dmitry V Sviridov  Daria V Andreeva  Ekaterina V Skorb
Affiliation:1. Max Planck Institute of Colloids and Interfaces, Potsdam, Germany;2. Friedrich‐Schiller‐Universit?t Jena, Institut für Organische Chemie und Makromolekulare Chemie, Jena, Germany;3. Chemistry Department, Belarusian State University, Minsk, Belarus;4. Physical Chemistry II, Bayreuth University, Bayreuth, Germany
Abstract:Polyelectrolyte block copolymer micelles assembled thin film is switched in response to local photocatalytic reactions on titanium dioxide, resulting in a layer of variable height, stiffness in response to visible light irradiation. Preosteoblasts migrate toward stiffer side of the substrates.
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Keywords:actuation  layer‐by‐layer assembly  polyelectrolytes  stimuli‐responsive materials  TiO2
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