Metal Trimethylsilylthiolates for the Synthesis of Trinuclear MnPd2 Complexes |
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| Authors: | Kyle N W Rozic Mahmood Azizpoor Fard Bahareh Khalili Najafabadi John F Corrigan |
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| Affiliation: | 1. Department of Chemistry, The University of Western Ontario, London, Ontario, Canada;2. Centre for Advanced Materials and Biomaterials Research, The University of Western Ontario, London, Ontario, Canada |
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| Abstract: | The manganese(II)‐palladium(II)‐sulfide complex MnCl2(μ3‐S)2Pd2(dppp)2] ( 2 ) was prepared from the reaction of PdCl2(dppp)] with Li(N,N'‐tmeda)]2Mn(SSiMe3)4] ( 2 ) in a 2:1 ratio under mild conditions. The new trimethylsilylthiolate complex Pd(dppp)(SSiMe3)2] ( 3 ) was synthesized from the reaction of Pd(dppp)(OAc)2] with two equivalents of LiSSiMe3]; this was then used in a reaction with Mn(CH3CN)2(OTf)2] to form the manganese(II)‐palladium(II)‐sulfide cluster Mn(OTf)(thf)2(μ3‐S)2Pd2(dppp)2]OTf ( 4 ). |
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| Keywords: | Manganese Palladium Trimethylsilylthiolate complex |
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