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A New Simple Chromo‐fluorogenic Probe for NO2 Detection in Air
Authors:L Alberto Juárez  Prof Ana M Costero  Dr Félix Sancenón  Prof Ramón Martínez‐Máñez  Prof Margarita Parra  Dr Pablo Gaviña
Affiliation:1. Centro de Reconocimiento Molecular y Desarrollo Tecnológico (IDM), Unidad Mixta Universidad Politécnica de Valencia, Universidad de Valencia (Spain);2. Departamento de Química orgánica, Universidad de Valencia, Doctor Moliner 50, 46100, Burjassot, Valencia (Spain);3. Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera s/n, 46022‐Valencia (Spain);4. CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER‐BBN)
Abstract:A new chromo‐fluorogenic probe, consisting of a biphenyl derivative containing both a silylbenzyl ether and a N,N‐dimethylamino group, for NO2 detection in the gas phase has been developed. A clear colour change from colourless to yellow together with an emission quenching was observed when the probe reacted with NO2. A limit of detection to the naked eye of about 0.1 ppm was determined and the system was successfully applied to the detection of NO2 in realistic atmospheric conditions.
Keywords:chromogenic detection  gas phase reactions  NO2  sensors
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