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A New Approach to Prepare Efficient Blue AIE Emitters for Undoped OLEDs
Authors:Jing Huang  Runli Tang  Tian Zhang  Prof Qianqian Li  Prof Gui Yu  Shuyi Xie  Prof Yunqi Liu  Dr Shanghui Ye  Prof Jingui Qin  Prof Zhen Li
Affiliation:1. Department of Chemistry, Hubei Key Laboratory on Organic and Polymeric Opto‐Electronic Materials, Wuhan University, Wuhan 430072 (P.R. China), Fax: (+86)?27‐68756757;2. Organic Solids Laboratories, Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080 (P.R. China);3. Key Laboratory for Organic Electronics and Information Displays (KLOEID), Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, Nanjing 210046 (P.R. China)
Abstract:Two aggregation‐induced emission active luminogens (TPE–pTPA and TPE–mTPA) were successfully synthesized. For comparison, another six similar compounds were prepared. Because of the introduced hole‐dominated triphenylamine (TPA), fluorene groups with high luminous efficiency, and unconjugated linkages, the π conjugation length of the obtained luminogens is effectively restricted to ensure their blue emission. The undoped organic light‐emitting diodes based on TPE–pTPA and TPE–mTPA exhibited blue or deep‐blue emissions, low turn‐on voltages (3 V), and high electroluminescence efficiencies with Lmax, ηC,max, and ηP,max values of up to 26 697 cd m?2, 3.37 cd A?1, and 2.40 Lm W?1.
Keywords:aggregation‐induced emission  blue emitters  luminescence  organic light‐emitting diodes  tetraphenylethene
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