Quinonediimine‐Induced Oxidative Coupling of Organomagnesium Reagents |
| |
| Authors: | Dr Toru Amaya Riyo Suzuki Prof?Dr Toshikazu Hirao |
| |
| Affiliation: | Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada‐oka, Suita, Osaka 565‐0871(Japan), Fax: (+81)?6‐6879‐7415 |
| |
| Abstract: | N,N′‐Diphenyl‐p‐benzoquinonediimine, a redox‐active unit of polyaniline, efficiently induced the oxidative homocoupling of various aryl‐ and vinylmagnesium reagents in suppressing the side reactions, such as 1,2‐ or 1,4‐addition reaction. |
| |
| Keywords: | C C coupling electron transfer Grignard reaction oxidation redox chemistry |
|
|
