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Spectroscopic Characteristics of Hyperbranched Conjugated Polymers Studied by One- and Two-Photon Excitations
Authors:Zhi Yang  Na Li  An-dong Xia  Qing-guo He  Hong-zhen Lin  Feng-lian Bai
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Abstract:Spectroscopic properties of new hyperbranched conjugated polymers functionalized in periphery with N,N-dimethylaniline and tert-butyl-benzene as terminal groups are investigated by one- and two-photon excitations. The absorption, °uorescence excitation and emission spectra are examined in chloroform and N,N-dimethylformamide. The two-photon excitation measurements show that the new hyperbranched conjugated polymer possesses large two-photon excitation cross section which makes it a very attractive candidate for the potential application as nonlinear optical materials. As an example, the two-photon induced three-dimensional data storage is also demonstrated.
Keywords:Hyperbranched conjugated polymer  Two-photon excitation cross section  Two-photon induced optical data storage  
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