| 迭代Suzuki偶联反应合成全氟环丁基芳基醚齐聚物的研究 |
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| 引用本文： | 张森,李永军,童亮,陆国林,黄晓宇.迭代Suzuki偶联反应合成全氟环丁基芳基醚齐聚物的研究[J].化学学报,2009,67(5):425-434. |
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| 作者姓名： | 张森 李永军 童亮 陆国林 黄晓宇 |
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| 作者单位： | 中国科学院上海有机化学研究所有机氟化学重点实验室,上海,200032 |
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| 基金项目： | 国家高技术研究发展计划(863计划)，国家自然科学基金 |
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| 摘 要： | 对迭代Suzuki偶联反应合成全氟环丁基芳基醚齐聚物的方法进行了研究, 并合成了全氟环丁基芳基醚齐聚物. 首先从对溴苯酚出发, 合成了含有一个全氟环丁基芳基醚结构单元的中间体3. 芳基硼酸与中间体3进行Suzuki偶联反应, 得到了含有一个全氟环丁基芳基醚结构单元的硼酸. 重复与中间体3进行Suzuki偶联反应, 从而合成了全氟环丁基芳基醚二聚体和三聚体. 最后通过热环化二聚反应合成了全氟环丁基芳基醚三聚体、五聚体和七聚体.
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| 关 键 词： | 全氟环丁基芳基醚 齐聚物 Suzuki偶联反应 |
| 收稿时间： | 2008-9-28 |
| 修稿时间： | 2008-11-11 |
Synthesis of Perfluorocyclobutyl Aryl Ether-based Oligomers via Iterative Suzuki Coupling |
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| Zhang,Sen,Li,Yongjun,Tong,Liang,Lu,Guolin,Huang,Xiaoyu.Synthesis of Perfluorocyclobutyl Aryl Ether-based Oligomers via Iterative Suzuki Coupling[J].Acta Chimica Sinica,2009,67(5):425-434. |
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| Authors: | Zhang Sen Li Yongjun Tong Liang Lu Guolin Huang Xiaoyu |
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| Affiliation: | Key Laboratory of Organofluorine Chemistry;Shanghai Institute of Organic Chemistry;Chinese Academy of Sciences;Shanghai 200032 |
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| Abstract: | Perfluorocyclobutyl aryl ether-based oligomers were synthesized via iterative Suzuki coupling reaction. Firstly, intermediate 3 containing one perfluorocyclobutyl aryl ether unit was prepared using 4-bromophenol as starting material followed by Suzuki coupling reaction with aryl-based boronic acid to provide a boronic acid consisting of one perfluorocyclobutyl aryl ether unit. Thus, perfluorocyclobutyl aryl ether-based dimer and trimer were synthesized by repeated Suzuki coupling reactions with intermediate... |
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| Keywords: | perfluorocyclobutyl aryl ether oligomer Suzuki coupling reaction |
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